CN106077558A - A kind of method and system of aluminium alloy semi-solid extrusion casint - Google Patents

A kind of method and system of aluminium alloy semi-solid extrusion casint Download PDF

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CN106077558A
CN106077558A CN201610446993.4A CN201610446993A CN106077558A CN 106077558 A CN106077558 A CN 106077558A CN 201610446993 A CN201610446993 A CN 201610446993A CN 106077558 A CN106077558 A CN 106077558A
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aluminium alloy
solid
alloy semi
semi
heat insulating
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CN106077558B (en
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侯华
田晋忠
鲁若鹏
程书建
赵宇宏
王冰
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North University of China
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North University of China
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D17/00Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
    • B22D17/007Semi-solid pressure die casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D17/00Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
    • B22D17/20Accessories: Details
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D17/00Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
    • B22D17/20Accessories: Details
    • B22D17/2015Means for forcing the molten metal into the die

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Of Metal (AREA)
  • Continuous Casting (AREA)

Abstract

The present invention relates to the method and system of a kind of aluminium alloy semi-solid extrusion casint, belong to nonferrous materials preparation and the technical field of application.The method is coated with aluminium foil after comprising the steps: aluminium alloy block first cuts into aluminium alloy small blocks respectively, then by the aluminium alloy small blocks preheating of cladding;By preheated described aluminium alloy small blocks melting, obtain liquid aluminium alloy;Liquid aluminium alloy is injected in attemperator is incubated by having the cast gate of bending channel or inverted-cone shape passage, obtains aluminium alloy semi-solid slurry;Aluminium alloy semi-solid slurry is poured into heat insulating ability extrusion die, carries out extruded process;Last continuation after described extruded process completes presses, and ejects foundry goods, air cooling afterwards, finally gives aluminium alloy semi-solid squeeze casting.This preparation method technique is advanced, and operation is tight, and data are the fullest and the most accurate, and after preparing aluminium alloy semi-solid squeeze casting heat treatment, hardness is up to 82.9HB, and tensile strength is up to 279Mpa.

Description

A kind of method and system of aluminium alloy semi-solid extrusion casint
Technical field
The present invention relates to the method and system of a kind of aluminium alloy semi-solid extrusion casint, belong to nonferrous materials preparation and answer Technical field.
Background technology
Aluminium alloy is non-ferrous alloy, has preferable intensity, toughness, electric conductivity, heat conductivity, is commonly used for structural material, Aero-Space, electronics industry, automobile manufacturing field are widely used;But aluminium alloy tensile strength is low, hardness is low, corrosion resistant Erosion property is poor so that it is application industrially is restricted.
The relatively broad aluminium alloy forming method of current application is compression casting.But, easily there is oxidation, gas in die casting The defects such as hole, cause the mechanical properties decrease of foundry goods.Semi-solid squeeze casting method, is a kind of method of near-net-shape, has The advantages such as processing temperature is low, heat-treatable strengthened, cost-effective.At present, aluminium alloy semi-solid extrusion casting method is also in grinding Studying carefully the stage, its Technology need to improve.Present stage semi-solid forming development bottleneck is mainly: 1) prepare semi solid slurry work Skill poor stability, preparation cost is higher;2) semi solid slurry transfer difficulty is bigger, it is impossible to make semi solid slurry transfer to smoothly Mould is processed molding.
Summary of the invention
For the deficiencies in the prior art, a kind of method that it is an object of the invention to provide aluminium alloy semi-solid extrusion casint And system.The method is with aluminium alloy as raw material, through preparing at vacuum melting furnace melting, slurry, extruded, closes improving aluminum The mechanical property of gold copper-base alloy.The present invention proposes preparation method of semisolid state slurry thereof and the system of a kind of simplicity, the most also realizes half solid State slurry automatic casting, quantitative pouring, solve slurry transport difficulties during semi-solid forming, reduce semisolid simultaneously Slurry preparation cost.
For achieving the above object, the present invention is by the following technical solutions:
A kind of method of aluminium alloy semi-solid extrusion casint, comprises the steps:
Step one, aluminium alloy pretreatment: be coated with aluminium foil respectively after first aluminium alloy block is cut into aluminium alloy small blocks, Then by the aluminium alloy small blocks preheating of cladding;
Step 2, melting: by preheated described aluminium alloy small blocks melting, obtain liquid aluminium alloy;
Step 3, the preparation of aluminium alloy semi-solid slurry: liquid aluminium alloy step 2 obtained is logical by having bending The cast gate (i.e. having bending channel or the mould of inverted-cone shape passage) of road or inverted-cone shape passage is injected in attemperator Row insulation, obtains aluminium alloy semi-solid slurry;
Step 4, extruded process: described aluminium alloy semi-solid slurry step 3 obtained is poured into heat insulating ability and squeezes Compression mould, carries out extruded process;
Step 5, the demoulding cools down: continues pressure after described extruded process completes, ejects foundry goods afterwards, air cooling, Obtain aluminium alloy semi-solid squeeze casting eventually.
The know-why of the present invention is: 1) using bending channel or inverted-cone shape passage, be preferably as the criterion serpentine channel legal system Standby metal semi-solid slurry, technique is simple, and preparation cost is relatively low, utilize quasi-serpentine channel from stirring action, smash dendrite;With Time quasi-serpentine channel cast gate temperature relatively low, aluminium alloy obtains bigger degree of supercooling, a large amount of forming cores, crystal grain thinning, finally gives half Solid size;2) using electromagnetic pump cast, semi solid slurry, under the effect of Lorentz force, is poured into extrusion die profile;More Preferably, controlled by programmable logic controller (PLC) (PLC), it is achieved automatic casting and quantitative pouring.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, in step one, described pre- The temperature of heat be 180-220 DEG C (such as 182 DEG C, 185 DEG C, 188 DEG C, 195 DEG C, 200 DEG C, 205 DEG C, 210 DEG C, 215 DEG C, 218 DEG C), more preferably 195 DEG C-205 DEG C, the time of described preheating be 10-25min (such as 11min, 13min, 15min, 18min, 21min, 23min, 24min), the time of the most described preheating is 15min.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, in step one, described Aluminium alloy small blocks size (i.e. length × width × height)≤50mm × 50mm × 50mm.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, in step 2, described molten Refining is carried out in medium frequency induction melting furnace, and complete during Frequency Induction Heating, evacuation, argon bottom blowing.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, the melting bag of step 2 Include the first sub-step and the second sub-step successively carried out, in described first sub-step, be evacuated to described Medium frequency induction melting Pressure≤10Pa in stove;Heating-up temperature be 580-620 DEG C (such as 582 DEG C, 585 DEG C, 590 DEG C, 595 DEG C, 600 DEG C, 605 DEG C, 610 DEG C, 615 DEG C, 618 DEG C), more preferably 595-605 DEG C;Heat time heating time be 30-45min (such as 31min, 33min, 35min, 38min, 41min, 43min, 44min), more preferably 40min;In described second sub-step, carry out argon bottom blowing, argon Gas speed is 800-1200C3/ min (such as 810C3/min、830C3/min、850C3/min、900C3/min、950C3/min、 1000C3/min、1150C3/min、1170C3/min、1190C3/min、1200C3/ min), argon speed is preferably 1000C3/ Min, in making medium frequency induction melting furnace, pressure is maintained at 0.045Mpa, now continues to be heated to 680-750 DEG C and carries out melting (such as 685 DEG C, 690 DEG C, 695 DEG C, 700 DEG C, 710 DEG C, 720 DEG C, 730 DEG C, 735 DEG C, 740 DEG C, 745 DEG C), more preferably heat Be warming up to 715-725 DEG C and carry out melting, and constant temperature insulation 15-30min (such as 16min, 18min, 20min, 24min, 26min, 28min, 29min), more preferably constant temperature insulation is 20min.Preferably reason: the first sub-step more preferably heating-up temperature 595-605 DEG C Being because, the liquidus temperature of aluminium alloy is 617 DEG C, opens argon bottom-blowing device, i.e. do not result in after being heated to 595-605 DEG C Argon is wasted, and after aluminum alloy melting, can play again the purpose of uniform al alloy component, remove impurity and degasification;Second sub-step Smelting temperature is more preferably because at 715-725 DEG C, pours into a mould, both can guarantee that passage will not block, and again might be used in this temperature range To obtain tissue topography's preferable semisolid ZL 101 alloy blank, temperature retention time 20min, this is to obtain through many experiments Optimal parameter, it is possible to the field trash of the larger particles of Dispersed precipitate in clear melt.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, in step 3, described Bending channel is as the criterion serpentine channel or spiroid canal passage.It is highly preferred that described bending channel is provided with 3-5 bend.Accurate snakelike Channel runners has from stirring action, can smash dendrite;The most quasi-serpentine channel cast gate temperature is relatively low, and aluminium alloy obtains bigger Degree of supercooling, a large amount of forming cores, crystal grain thinning, thus obtain semi solid slurry.Being subsequently injected in holding furnace insulation can be further Make semi solid slurry microstructure homogenization.Further, flow velocity during the described attemperator of described liquid aluminium alloy injection is 0.2- 1kg/s, preferably 0.5kg/s.Quasi-serpentine channel has chilling action, along with bend quantity increases, and the semi-solid blank of preparation Quality also can increase therewith, but with the increase of bend quantity, bridging solidification chitin ratio increases considerably, and easily blocking is logical Road, reduces formation efficiency.Through repeatedly attempting in the present invention, bending channel is provided with 3-5 bend, it is ensured that blank quality Meanwhile, will not blocking channel.When poring rate is higher, blank outer surface can be coarse, and forms pit, when poring rate is relatively low, Blank surface is smooth, and consistency increases, but relatively low poring rate be unfavorable for that alloy melt is full of quasi-serpentine channel.Through too much Secondary experiment, is set to 0.5kg/s by optimal poring rate, both can guarantee that alloy melt is full of whole quasi-serpentine channel, can obtain again Smooth surface, blank that consistency is high.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, in step 3, described guarantor The temperature of temperature be 550-620 DEG C (such as 552 DEG C, 555 DEG C, 560 DEG C, 570 DEG C, 580 DEG C, 590 DEG C, 600 DEG C, 615 DEG C, 618 DEG C), the time of insulation is 15-20min (such as 16min, 17min, 18min, 19min).
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, in step 4, described crowded Molded nip pressure be 80-120MPa (such as 82MPa, 85MPa, 88MPa, 92MPa, 95MPa, 100MPa, 105MPa, 110MPa, 115MPa, 118MPa), the dwell time is 15-30s (such as 16s, 18s, 20s, 24s, 26s, 28s), and heat insulating ability squeezes The temperature of compression mould is 180-220 DEG C, it is highly preferred that nip pressure is 100Mpa, the dwell time is 20s, heat insulating ability extrusion die The temperature of tool is 200 DEG C.Within the specific limits, nip pressure is the biggest, and grain refinement effect is the most obvious.And in the present invention, when squeezing After pressure pressure is more than 100Mpa, refining effect slows down, and macro-mechanical property tends towards stability.Mold temperature is 180-220 DEG C, preferably Being 200 DEG C, be because mold temperature too low, setting rate can be too fast, even if increasing pressure also it be cannot be carried out feeding, from And produce casting flaw;Mold temperature is too high, and the heat of aluminium alloy melt can be made to be not easy to scatter and disappear, and causes crystal grain length thick, shadow Ring final performance;After test of many times, preferably 200 DEG C.In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as one Preferred implementation, in step 4, described extrusion die material is hot die steel, cavity dimension be 120mm × 30mm × 50mm, mold cavity surface roughness is Ra0.08-0.16 μm.The cavity dimension of indication refers to after punch lid is to die recessed herein Void size in mould.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, in step 4, described Before aluminium alloy semi-solid slurry is poured into extrusion die, also include the mold cavity surface pretreatment of extrusion die: equal with coating agent The mold cavity surface of the described extrusion die of even coating, coat thickness is 0.3-0.5mm;The compound method of described coating agent include as Lower step: weigh a certain amount of zinc oxide and waterglass, adds a certain amount of deionized water, is uniformly mixing to obtain milky and suspends Shape liquid, i.e. coating agent;It is highly preferred that the mass ratio of described zinc oxide, waterglass and deionized water is 4-6:1:40-60;Institute The revolution stating stirring is 40-60r/min (such as 42r/min, 45r/min, 48r/min, 52r/min, 56r/min, 58r/ Min), mixing time is 60-90min (such as 65min, 68min, 72min, 76min, 80min, 85min, 88min), further Ground, the revolution of described stirring is 50r/min, and mixing time is 80min.Coating agent is mainly used for protecting mould, makes the demoulding hold Easily;Coating agent has insulation effect simultaneously, prevents semi-solid aluminium alloy blank rate of cooling too fast, improves crystallized ability.Coat Thickness is preferably 0.3-0.5mm.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, described in step 5 Extruded process continues pressure 15-20s (such as 16s, 18s) after completing.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, as a kind of preferred implementation, also wrap after step 5 Including heat treatment step, concrete grammar is as follows: first carry out solution treatment, solid solubility temperature 535 ± 5 DEG C, solution time 5h;Then adopt Quench with the warm water of 75-85 DEG C;Carry out Ageing Treatment afterwards: aging temp is 200 ± 5 DEG C, aging time 4h, last air cooling To room temperature.
In the method for above-mentioned aluminium alloy semi-solid extrusion casint, present invention is mainly used for the casting that semi-solid temperature district is bigger Making aluminium alloy, such as semi-solid temperature district is more than 40 DEG C, and such aluminium alloy has ZAlSi7Mg、ZAlSi9Mg, 6061, A357 Deng.As a kind of preferred implementation, described aluminium alloy is ZAlSi7Mg (alloy designations ZL101).
One prepares aluminium alloy semi-solid slurry cast gate, and described mould has bending channel or inverted-cone shape passage.
In above-mentioned cast gate, as a kind of preferred implementation, described bending channel is provided with 3-5 bend.
A kind of system of aluminium alloy semi-solid extrusion casint, including:
Aluminium alloy semi-solid slurry preparation facilities, including: above-mentioned cast gate and attemperator;Wherein:
Described cast gate is arranged at the porch of described attemperator and internal with described attemperator connects, and is used for receiving molten Refine the liquid aluminium alloy obtained and tentatively prepare described aluminium alloy semi-solid slurry;Described attemperator is for receiving by described Described aluminium alloy semi-solid slurry that cast gate tentatively prepares also is incubated, and starches forming the aluminium alloy semi-solid of even tissue Material;
Extrusion forming device, including heat insulating ability extrusion die, for by the described aluminium alloy half from described attemperator Solid size is extruded.
In said system, as a kind of preferred implementation, described system also includes: aluminium alloy semi-solid slurry conveying dress Put, for described aluminium alloy semi-solid slurry is delivered in described heat insulating ability extrusion die;Wherein said aluminium alloy semi-solid Slurry conveying device includes: heat insulating ability conveying pipeline, and import is connected with the outlet of described attemperator, exports and is squeezed into described in stretching into In type device and align with described heat insulating ability extrusion die;And electromagnetic pump, it is arranged at described heat insulating ability conveying pipeline import and outlet Between;It is highly preferred that described electromagnetic pump is controlled by programmable logic controller (PLC) (PLC), to realize automatically and quantitative pouring.
In said system, as a kind of preferred implementation, described aluminium alloy semi-solid slurry preparation facilities also includes: set Cylinder, is used for fixing described cast gate in described attemperator porch;With the lowering or hoisting gear of the described sleeve of support, it is used for moving institute State cast gate;It is highly preferred that described aluminium alloy semi-solid slurry preparation facilities also to include that dolly, described lowering or hoisting gear are fixed on described On dolly, described attemperator is positioned on described dolly.Lowering or hoisting gear and attemperator are positioned on dolly, it is possible to simply have Imitate realizes semi-solid squeeze casting.
In said system, as a kind of preferred implementation, described attemperator includes: be positioned at the Heat preservation of internal layer Silk;It is positioned at the outer layer heat-preservation cotton outside described Heat preservation silk.
In said system, as a kind of preferred implementation, described extrusion forming device includes that extruder, heat insulating ability extrude Mould, push pedal, push rod;Described extruder includes being arranged at the master cylinder on top, the auxiliary oil cylinder being arranged at bottom and base;Described Heat insulating ability extrusion die includes punch and the die being oppositely arranged, and described punch is squeezed with described by the first screw and the first fixed plate Press connect, described punch be internally provided with heating rod;Described die is by the second screw and the second fixed plate and described extruding Machine connect, described die be internally provided with heater strip;Described push pedal is arranged at the top of described auxiliary oil cylinder, described push pedal upper Surface connects push rod, for being ejected by the foundry goods of squeeze cast form.
In said system, as a kind of preferred implementation, described heat insulating ability conveying pipeline is the most successively by conveying pipeline Heater strip, conveying pipeline heat-preservation cotton, housing are constituted.
In said system, as a kind of preferred implementation, described heat insulating ability conveying pipeline is by connected head-to-tail first level The second horizontal part and described that portion's first rise part vertical with described first horizontal part is vertical with described first rise part The second rise part that two horizontal parts are vertical is constituted, the head end of wherein said first horizontal part and the outlet at bottom of described attemperator Being connected, run horizontally for some distance and arrive the tail end of described first horizontal part later, the tail end at described first horizontal part is bent up Qu Yanshen certain distance arrived the tail end of described first rise part later, horizontal-extending after the tail end of described first rise part bends Certain distance forms described second horizontal part, and is bent to form downwards described second at the tail end of described second horizontal part and erects Portion, the tail end at described second rise part is the opening pouring into a mould described aluminium alloy semi-solid slurry in described die;More preferably Ground, described electromagnetic pump is arranged in the first rise part of described heat insulating ability conveying pipeline.
The pattern of aluminium alloy semi-solid squeeze casting prepared by the method provided by the present invention, color and luster, metallographic structure, Mechanical property carries out detecting, analyzes, characterizes: carry out metallographic structure analysis with Metallographic Analysis instrument;With the omnipotent examination of microcomputer controlled electronic The machine of testing carries out tensile strength analysis;Tensile fracture analysis is carried out with scanning electron microscope;Hardness analysis is carried out with Brinell hardness tester.With this The aluminium alloy semi-solid squeeze casting prepared of method that invention provides is block, hardness up to 82.9HB, tensile strength up to 279Mpa。
Compared with prior art, the invention has the beneficial effects as follows:
(1) the present invention is directed to the situation that aluminum alloy die casting intensity is low, the most heat-treatable strengthened, be former material with aluminium alloy Material, through preparing at vacuum melting furnace melting, semi solid slurry, extruded, makes semi-solid state extrusion foundry goods, this preparation method work Skill is advanced, and operation is tight, and data are the fullest and the most accurate, the aluminium alloy semi-solid squeeze casting after heat treatment hardness of preparation up to 82.9HB, tensile strength, up to 279Mpa, is very good aluminium alloy semi-solid forming method.
(2) present invention uses the preferred quasi-serpentine channel method of bending channel to prepare metal semi-solid slurry, and technique is simple, preparation Cost is relatively low, utilize quasi-serpentine channel from stirring action, smash dendrite;The most quasi-serpentine channel cast gate temperature is relatively low, alloy Liquid obtains bigger degree of supercooling, a large amount of forming cores, crystal grain thinning, thus obtains preliminary semi solid slurry;Reduce half solid simultaneously State slurry preparation cost.
(3) present invention uses electromagnetic pump to pour into a mould, and semi solid slurry, under the effect of Lorentz force, is poured into extrusion die type Chamber, by PLC control, it is achieved automatic casting and quantitative pouring, solves slurry transport difficulties during semi-solid forming.
Accompanying drawing explanation
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing In having technology to describe, the required accompanying drawing used is briefly described, it should be apparent that, the accompanying drawing in describing below is this Some bright embodiments, for those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to Other accompanying drawing is obtained according to these accompanying drawings.
Fig. 1 is the system schematic of aluminium alloy semi-solid extrusion casint;
Fig. 2 is the aluminium alloy semi-solid squeeze casting metallographic microstructure figure of embodiment 1 preparation;
Fig. 3 is the aluminium alloy semi-solid squeeze casting stretching fracture shape appearance figure of embodiment 1 preparation;
Fig. 4 is aluminium alloy liquid squeeze casting metallographic microstructure figure prepared by conventional method.
Detailed description of the invention
Hereinafter will combine accompanying drawing by embodiment present disclosure is described in further detail, the protection of the present invention Scope is including but not limited to following embodiment.
Unreceipted specific experiment step or condition person in embodiment, according to the normal experiment described by the document in this area The operation of step or condition can be carried out.The various reagent and the raw material that use in embodiment are commercially available prod.
Embodiment 1
The aluminium alloy semi-solid extrusion casting method using the present invention to provide prepares aluminium alloy semi-solid squeeze casting.This reality The chemical substance material executing example use is: aluminium alloy, zinc oxide, waterglass, aluminium foil, acetone, deionized water, argon;It prepares Consumption is following (with gram, milliliter, centimetre3For measurement unit):
Concrete preparation method is as follows:
(1) extrusion die is prepared
Extrusion die is rectangle, and material is rustless steel, mold cavity a size of 120mm × 30mm × 50mm, die cavity table Surface roughness is Ra0.08-0.16 μm.
(2) preparation coating agent and coating extrusion die
Weigh zinc oxide 50g ± 1g, waterglass 10g ± 1g, measure deionized water 500mL ± 5mL, add in mixing hollander Row stirring, agitation revolution 50r/min, mixing time 80min;Milky suspension liquid, i.e. coating agent is become after stirring.With coating Agent uniformly coats the mold cavity surface of above-mentioned extrusion die, and coat thickness is 0.3-0.5mm.
(3) aluminium alloy pretreatment
1. aluminium alloy block machinery (such as by modes such as line cuttings) is cut into small blocks, small blocks size≤50mm ×50mm×50mm;
2. (can reduce and the contacting of air by aluminium foil cladding by the aluminium alloy small blocks after aluminium foil cladding cutting, reduce The probability that aluminium alloy is oxidized);
3. preheating: preheat in the aluminium alloy small blocks of cladding is placed in heating furnace, preheat temperature 200 DEG C ± 5 DEG C, during preheating Between 15min.
(4) aluminium alloy semi-solid slurry is prepared
The melting of aluminium alloy is carried out in medium frequency induction melting furnace, in Frequency Induction Heating, evacuation, argon bottom blowing During complete.Specifically comprise the following steps that
1. open medium frequency induction melting furnace, inside cleaning graphite melting kettle, and clean with acetone, make crucible internal clean Only;
2. the Al alloy block of cladding aluminium foil is placed in crucible bottom;
3. medium frequency induction melting furnace is closed, and airtight;Be then turned on vacuum pump, extract furnace air, make pressure in stove≤ 10Pa;Being then turned on medium frequency induction melting furnace heater, begin to warm up, heating-up temperature 600 DEG C ± 5 DEG C, heat time heating time is 40min;
4. bottom graphite crucible, it is passed through argon bottom blowpipe, in crucible, inputs argon, argon bottom blowing speed 1000C3/ Min, in making stove, pressure is maintained at 0.045MPa, and by pipe valve regulation and control of giving vent to anger;Continuing to add hot smelting, smelting temperature is 720 DEG C ± 5 DEG C, it is incubated 20min at this thermostatic.
Cast: close argon bottom blowpipe, removes crucible inner melt surface slag, then starts semi-solid slurry preparation dress Put, graphite crucible mouth alignment is had the quasi-serpentine channel cast gate of four bends, molten aluminium alloy is poured into attemperator In, melt temperature during cast is 700 DEG C;Wherein, the channel diameter of quasi-serpentine channel cast gate is 25mm, and four bends water open height For 380mm, poring rate 0.5kg/s.
Insulation: be incubated in holding furnace by the aluminium alloy semi-solid slurry preliminarily formed of quasi-serpentine channel cast gate, is protected Temperature temperature is 580 DEG C, and temperature retention time is 15-20min.
(5) extruded
Dolly moves to specifying position, connects aluminium alloy semi-solid slurry conveyer device and passes through aluminium alloy semi-solid slurry Conveyer device by the semi solid slurry quantitative pouring after insulation to the concave die cavity in extrusion forming device, afterwards dolly together with Aluminium alloy semi-solid slurry conveyer device is return, and starts extruder and extrudes, and nip pressure is 100MPa, dwell time 20s; To heat to mould while starting extruder, make mold temperature maintain 200 DEG C.Heating mould is to make mould at one Working at a temperature of higher, before being mainly after extruder is opened, during several castings production, effect is relatively big, when producing continuously, mainly It is used for regulating mold temperature, makes mould be in a relatively stable temperature range, it is ensured that the stability of technique.
(6) demoulding, cooling: continue pressure 15s, so that foundry goods under high pressure solidifies, crystal grain thinning after extruded, afterwards Eject foundry goods, be cooled to 25 DEG C in atmosphere, finally give aluminium alloy semi-solid squeeze casting.
(7) Technology for Heating Processing: aluminium alloy semi-solid squeeze casting prepared by step (7) is carried out solution treatment, solid solution temperature Spend 535 ± 5 DEG C, solution time 5h, then use the warm water quenching of about 80 DEG C;Carry out artificial aging process subsequently: timeliness temperature Degree is 200 ± 5 DEG C, aging time 4h, last air cooling.
(8) detect, analyze, characterize
The thermally treated pattern of aluminium alloy semi-solid squeeze casting, color and luster, metallographic structure, mechanical property are examined Survey, analyze, characterize: carry out metallographic structure analysis with Metallographic Analysis instrument;Tension is carried out strong with microcomputer controlled electronic universal tester Degree is analyzed;Tensile fracture analysis is carried out with scanning electron microscope;Hardness analysis is carried out with Brinell hardness tester.Concrete outcome is shown in Table 1.
The average Brinell hardness of foundry goods prepared by table 1 the present embodiment and average tensile strength
After testing, aluminium alloy semi-solid squeeze casting prepared by the present embodiment is block, and after heat treatment hardness reaches 82.9HB, tensile strength reaches 279Mpa.Fig. 2 is aluminium alloy semi-solid squeeze casting metallographic microstructure prepared by the present embodiment Figure;From this figure, it can be seen that alloy molten solution is through the cooling of quasi-serpentine channel and stirring action, primary α-Al becomes the most spherical, The primary α-Al of dendritic crystalline disappears substantially;Additionally, the strip of eutectic Si is broken up after extruding and is disperseed in the base.From Eutectic Silicon in Al-Si Cast Alloys knowable to high power figure (i.e. Fig. 2) is interrupted by elongated needle-like and becomes tiny, and it is more uniform to be distributed ratio;This and conventional cast The tissue differences of part is obvious, and (Fig. 4 is aluminium alloy TUBE BY LIQUID EXTRUSION casting prepared by conventional method as shown in Figure 4 in conventional cast sturcture Part metallographic microstructure figure, the preparation process condition of this foundry goods is: pouring temperature is 720 DEG C, and squeeze pressure is 100Mpa, pressurize Time is 20s;After heat treatment, the tensile strength of this foundry goods reaches 241.5Mpa, and hardness is up to 52.3HB).Fig. 3 is the present embodiment The aluminium alloy semi-solid squeeze casting stretching fracture shape appearance figure of preparation, is scanned through Electronic Speculum and finds, aluminium alloy semi-solid extruding casting Part consistency increases, and presents obvious ductile rupture feature.
Embodiment 2
The present embodiment provides the system of a kind of aluminium alloy semi-solid extrusion casint, as it is shown in figure 1, on this system can be applicable to Stating in the method for aluminium alloy semi-solid extrusion casint, be used for preparing aluminium alloy semi-solid squeeze casting, this system includes:
Aluminium alloy semi-solid slurry preparation facilities, including cast gate 13 and attemperator 17;Wherein: cast gate 13 is arranged at insulation The porch of device 17 and internal with attemperator 17 connect, is used for receiving aluminium alloy that melting obtains and tentatively prepares aluminium alloy Semi solid slurry;Attemperator 17 is for the aluminium alloy semi-solid slurry tentatively prepared received by cast gate 13 and protects Temperature, to form the aluminium alloy semi-solid slurry of even tissue;
Extrusion forming device, including heat insulating ability extrusion die (2,21), for the aluminium alloy half of self-heat conserving device 17 in the future Solid size is extruded.
Preferably, said system also includes: aluminium alloy semi-solid slurry conveyer device, for by aluminium alloy semi-solid slurry It is delivered in heat insulating ability extrusion die 21;Wherein aluminium alloy semi-solid slurry conveyer device includes: heat insulating ability conveying pipeline 7, import Outlet with attemperator 17 is connected, and in described extrusion forming device is stretched in outlet and aligns with heat insulating ability extrusion die 21;With Electromagnetic pump 19, is arranged between heat insulating ability conveying pipeline 7 import and outlet;It is highly preferred that electromagnetic pump 19 is by FPGA control Device processed (PLC) controls, to realize automatically and quantitative pouring.
Preferably, aluminium alloy semi-solid slurry preparation facilities also includes: sleeve 14, is used for fixing cast gate 13 in attemperator The porch of 17;Lowering or hoisting gear 15 with stop sleeve 14, in order to mobile cast gate 13;It is highly preferred that aluminium alloy semi-solid slurry Material preparation facilities also includes that dolly 16, lowering or hoisting gear 15 are fixed on dolly 16, and attemperator 17 is positioned on dolly 16.
Preferably, attemperator 17 includes: be positioned at the Heat preservation silk 11 of internal layer;Outside being positioned at outside Heat preservation silk 11 Layer heat-preservation cotton 12.
Preferably, extrusion forming device includes extruder 1, heat insulating ability extrusion die (2,21), push pedal 26, push rod 27;Squeeze Press 1 includes being arranged at the master cylinder 6 on top, the auxiliary oil cylinder 25 being arranged at bottom and base 24;Heat insulating ability extrusion die (2, 21) including punch 2 and the die 21 being oppositely arranged, punch 2 is by the first screw 4 and first fixed plate 5 board with extruder 1 Backboard connect, punch 2 be internally provided with heating rod 3;Die 21 is by the second screw 22 and the second fixed plate 23 and extruder 1 Base 24 connects, die 21 be internally provided with heater strip 20;Push pedal 26 is arranged on auxiliary oil cylinder 25, the upper surface of push pedal 26 Connect and have push rod 27, for the foundry goods of squeeze cast form is ejected.It is provided with in the bottom of die 21 and supplies push rod 27 to pass Hole, when needed, foundry goods is ejected in die 21 by push rod 27 through this hole.Owing to setting respectively in die 21 and punch 2 It is equipped with heater strip 20 and the heating rod 3 of heating, so heat insulating ability extruding can be realized when extruding.
Preferably, heat insulating ability conveying pipeline 7 is the most successively by conveying pipeline heater strip 10, conveying pipeline heat-preservation cotton 9, housing 8 Constitute.
Preferably, heat insulating ability conveying pipeline 7 is by first erect vertical with the first horizontal part of connected head-to-tail first horizontal part The second rise part that vertical portion second horizontal part vertical with the first rise part is vertical with the second horizontal part is constituted;Wherein the first water The head end in flat portion is connected with the outlet at bottom of attemperator 17, runs horizontally for some distance later to the tail end of the first horizontal part, Tail end at the first horizontal part be bent upwards extension certain distance later to the tail end of the first rise part, at the tail of the first rise part Run horizontally for some distance after end bending formation the second horizontal part, and be bent to form downwards second at the tail end of the second horizontal part and erect Vertical portion, the tail end at the second rise part is the opening of cast aluminum alloy semi-solid slurry in die 21;It is highly preferred that electromagnetic pump 19 are arranged in the first rise part of heat insulating ability conveying pipeline 7.
Preferably, cast gate 13 is bending channel mould, the most quasi-serpentine channel cast gate or spiroid canal channel runners;For standard For serpentine channel mould, 3-5 bend is generally set;Such as, channel diameter is 25mm, and three bend mold heights are 310mm, four bend mold heights are 380mm, five bend mold heights are 450mm.Cast gate 13 can also is that have inverted-cone shape The cast gate of passage, but quasi-serpentine channel best results.
As shown in the system schematic of Fig. 1 aluminium alloy semi-solid extrusion casint, erecting device, position, each portion is wanted correct, is pressed Sequence operates.Specific works process is as follows: after pretreated aluminium alloy smelting completes, and closes argon bottom blowpipe, removes in crucible Molten surface slag, then starts running gate system, and dolly moves to specifying position, and graphite crucible mouth is directed at serpentine channel cast gate 13, by the liquid aluminium alloy obtained by, in quasi-serpentine channel cast gate 13 quantitative pouring to attemperator 17, being poured, dolly Return.The semi solid slurry obtained by the cast of quasi-serpentine channel cast gate 13 is incubated in attemperator 17, is incubated a period of time Rear formation aluminium alloy semi-solid slurry 18;Aluminium alloy semi-solid slurry 18 enters recessed by electromagnetic pump 19 and heat insulating ability conveying pipeline 7 Mould 21, starts extruder and carries out extruded;Continuing pressure after extruded, push rod 27 ejects foundry goods, is cooled in atmosphere 25 DEG C, finally give aluminium alloy semi-solid squeeze casting.

Claims (10)

1. the method for an aluminium alloy semi-solid extrusion casint, it is characterised in that comprise the steps:
Step one, aluminium alloy pretreatment: be coated with, then with aluminium foil respectively after first aluminium alloy block is cut into aluminium alloy small blocks By the aluminium alloy small blocks preheating of cladding;
Step 2, melting: by preheated described aluminium alloy small blocks melting, obtain liquid aluminium alloy;
Step 3, the preparation of aluminium alloy semi-solid slurry: the liquid aluminium alloy that step 2 is obtained by have bending channel or The cast gate of inverted-cone shape passage is injected in attemperator and is incubated, and obtains aluminium alloy semi-solid slurry;
Step 4, extruded process: described aluminium alloy semi-solid slurry step 3 obtained is poured into heat insulating ability extrusion die Tool, carries out extruded process;
Step 5, the demoulding cools down: continues pressure after described extruded process completes, ejects foundry goods afterwards, air cooling, final To aluminium alloy semi-solid squeeze casting.
The method of aluminium alloy semi-solid extrusion casint the most according to claim 1, it is characterised in that
In step one, the temperature of described preheating is 180-220 DEG C, and the time of described preheating is 10-25min;Preferably, described pre- The temperature of heat is 195 DEG C-205 DEG C, and the time of described preheating is 15min;Described aluminium alloy small blocks size≤50mm × 50mm ×50mm;
In step 2, described melting is carried out in medium frequency induction melting furnace, and at Frequency Induction Heating, evacuation, argon Complete during bottom blowing;
Preferably, the melting of step 2 includes the first sub-step and the second sub-step successively carried out, in described first sub-step, It is evacuated to pressure≤10Pa in described medium frequency induction melting furnace;Heating-up temperature is 580-620 DEG C, and heat time heating time is 30- 45min, more preferably heating-up temperature are 595-605 DEG C, and heat time heating time is 40min;In described second sub-step, carry out at the bottom of argon Blowing, argon speed is 800-1200C3/ min, argon speed is preferably 1000C3/ min, in making medium frequency induction melting furnace, pressure is protected Hold at 0.045Mpa, now continue to be heated to 680-750 DEG C and carry out melting, be more preferably heated to 715-725 DEG C and enter Row melting, and constant temperature insulation 15-30min, more preferably constant temperature is incubated as 20min.
The method of aluminium alloy semi-solid extrusion casint the most according to claim 1, it is characterised in that
In step 3, described bending channel is as the criterion serpentine channel or spiroid canal passage;Preferably, described bending channel is provided with 3- 5 bends;Further, flow velocity during the described liquid aluminium alloy described attemperator of injection is 0.2-1kg/s, is preferably 0.5kg/s;
In step 3, the temperature of described insulation is 550-620 DEG C, and the time of insulation is 15-20min.
The method of aluminium alloy semi-solid extrusion casint the most according to claim 1, it is characterised in that in step 4, described Extruded nip pressure is 80-120MPa, and the dwell time is 15-30s, and the temperature of heat insulating ability extrusion die is 180-220 ℃;Preferably, nip pressure is 100Mpa, and the dwell time is 20s, and the temperature of heat insulating ability extrusion die is 200 DEG C;
Preferably, in step 4, before described aluminium alloy semi-solid slurry is poured into extrusion die, also include extrusion die Mold cavity surface pretreatment: uniformly coat the mold cavity surface of described extrusion die with coating agent, coat thickness is 0.3-0.5mm; The compound method of described coating agent comprises the steps: to weigh a certain amount of zinc oxide and waterglass, add a certain amount of go from Sub-water, is uniformly mixing to obtain milky suspension liquid, i.e. coating agent;It is highly preferred that described zinc oxide, waterglass and deionization The mass ratio of water is 4-6:1:40-60;The revolution of described stirring is 40-60r/min, and mixing time is 60-90min, further Ground, the revolution of described stirring is 50r/min, and mixing time is 80min.
The method of aluminium alloy semi-solid extrusion casint the most according to claim 1, it is characterised in that described in step 5 Extruded process continues pressure 15-20s after completing;
Preferably, also including heat treatment step after step 5, concrete grammar is as follows: first carry out solution treatment, solid solubility temperature 535 ± 5 DEG C, solution time 5h;Then the warm water quenching of 75-85 DEG C is used;Carry out Ageing Treatment afterwards: aging temp is 200 ± 5 DEG C, aging time 4h, last air cooling is to room temperature.
6. prepare aluminium alloy semi-solid slurry cast gate for one kind, it is characterised in that described cast gate has bending channel or is inverted cone Shape passage;Preferably, described bending channel is provided with 3-5 bend.
7. the system of an aluminium alloy semi-solid extrusion casint, it is characterised in that including:
Aluminium alloy semi-solid slurry preparation facilities, including: the cast gate described in claim 6 and attemperator;Wherein:
Described cast gate is arranged at the porch of described attemperator and connects with described attemperator inside, is used for receiving melting and obtains To liquid aluminium alloy and tentatively prepare described aluminium alloy semi-solid slurry;Described attemperator is for receiving by described cast gate The described aluminium alloy semi-solid slurry tentatively prepared and be incubated, to form the aluminium alloy semi-solid slurry of even tissue;
Extrusion forming device, including heat insulating ability extrusion die, for by the described aluminium alloy semi-solid from described attemperator Slurry is extruded.
System the most according to claim 7, it is characterised in that described system also includes: aluminium alloy semi-solid slurry carries Device, for being delivered to described aluminium alloy semi-solid slurry in described heat insulating ability extrusion die;Wherein said aluminium alloy half is solid State slurry conveying device includes: heat insulating ability conveying pipeline, and import is connected with the outlet of described attemperator, and described extruding is stretched in outlet In shaped device and align with described heat insulating ability extrusion die;And electromagnetic pump, it is arranged at described heat insulating ability conveying pipeline import and goes out Between Kou;
Preferably, described electromagnetic pump passes through PLC controls, to realize automatically and quantitative pouring;
It is highly preferred that described heat insulating ability conveying pipeline is the most successively by conveying pipeline heater strip, conveying pipeline heat-preservation cotton, housing structure Become;
Further, described heat insulating ability conveying pipeline by connected head-to-tail first horizontal part vertical with described first horizontal part The second rise part structure that the second horizontal part that one rise part is vertical with described first rise part is vertical with described second horizontal part Becoming, the head end of wherein said first horizontal part is connected with the outlet at bottom of described attemperator, runs horizontally for some distance later To the tail end of described first horizontal part, the tail end at described first horizontal part is bent upwards extension certain distance and arrived described the later The tail end of one rise part, run horizontally for some distance after the tail end of described first rise part bends described second level of formation Portion, and it is bent to form downwards described second rise part, at the tail end of described second rise part at the tail end of described second horizontal part For pouring into a mould the opening of described aluminium alloy semi-solid slurry in described die;
Further, in described electromagnetic pump is arranged on the first rise part of described heat insulating ability conveying pipeline.
System the most according to claim 7, it is characterised in that described extrusion forming device includes that extruder, heat insulating ability squeeze Compression mould, push pedal, push rod;Described extruder includes being arranged at the master cylinder on top, the auxiliary oil cylinder being arranged at bottom and base;Institute State punch and die that heat insulating ability extrusion die includes being oppositely arranged, described punch by the first screw and the first fixed plate with described Extruder connect, described punch be internally provided with heating rod;Described die is squeezed with described by the second screw and the second fixed plate Press connect, described die be internally provided with heater strip;Described push pedal is arranged at the top of described auxiliary oil cylinder, described push pedal Upper surface connects push rod, for being ejected by the foundry goods of squeeze cast form.
System the most according to claim 7, it is characterised in that
Described attemperator includes: be positioned at the Heat preservation silk of internal layer;It is positioned at the outer layer heat-preservation cotton outside described Heat preservation silk;
Preferably, described aluminium alloy semi-solid slurry preparation facilities also includes: sleeve, is used for fixing described cast gate in described insulation At device portal;With the lowering or hoisting gear of the described sleeve of support, it is used for moving described cast gate;It is highly preferred that described aluminium alloy half is solid State slurry preparation device also includes that dolly, described lowering or hoisting gear are fixed on described dolly, and described attemperator is positioned over described On dolly.
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