CN106070294B - 一种含噻虫胺和唑蚜威的农药组合物 - Google Patents
一种含噻虫胺和唑蚜威的农药组合物 Download PDFInfo
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- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
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- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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Abstract
本发明公开了一种含有噻虫胺和唑蚜威的增效杀虫组合物，噻虫胺和唑蚜威的质量份数比为1:30‑20：1。本发明的增效杀虫组合物适用于防治果树蚜虫。本发明两种有效成分复配具有明显的增效作用，提高了防治效果；降低了农药使用量，其推广应用有较大的经济效益和社会效益。
Description
技术领域
本发明属于农药领域，具体涉及一种噻虫胺与唑蚜威复配的组合物，用于防治作物上的蚜虫、稻飞虱、粉虱。
背景技术
唑蚜威是一种高选择性内吸杀虫剂，对胆碱酯酶有快速抑制作用，通过蚜虫内脏壁的吸附作用和接触作用，它对多种作物种群上的各种蚜虫均有效，可用于多种作物上防除水稻飞虱、叶蝉、蓟马等，对有益昆虫和蜜蜂安全。
噻虫胺是新烟碱类中的一种杀虫剂，是高效安全、高选择性的新型杀虫剂，起作用与烟碱乙酰胆碱受体类似，具有触杀、胃毒和内吸作用，主要用于水稻、蔬菜、果树及其他作物上防治蚜虫、叶蝉、蓟马、飞虱等半翅目、鞘翅目，具有高效、光谱、用量少、毒性低、药效持效期长、对作物安全等有点，有卓越的内吸和渗透作用，是替代高毒有机磷农药的新品种。
单一活性成分的杀虫剂品种在农业田间害虫防治上往往存在不同程度的缺陷，如用药剂量大害虫容易产生抗药性，杀虫范围窄，施用次数多，加重环境污染等。对于防治农业上产生抗性的害虫，途径之一是推出新的与现有品种无交互抗性的新成分，但是，新农药化合物开发成本高、周期长；其它途径如轮作、农药品种轮换等，在实际生产中，也很难真正起到明显的效果。
发明内容
为解决上述问题，本发明提供了一种杀虫谱广、成本低、具有增效作用的复配杀虫组合物。
为达到上述目的，本发明采用如下技术方案：一种含有噻虫胺与唑蚜威的杀虫组合物，其中，噻虫胺与唑蚜威的重量比为1:30-20:1，所述噻虫胺与唑蚜威的总重量占组合物的重量百分比为1-60%。
进一步的，所述组合物还包括农药制剂辅助成分，所述农药制剂辅助成分包括分散剂、润湿剂、乳化剂、防冻剂、消泡剂、增稠剂、稳定剂、崩解剂、成膜剂、着色剂、填料和溶剂。
进一步的，所述组合物可以制成适于农业生产的各种剂型，包括可湿性粉剂、颗粒剂、水分散粒剂、悬浮剂、悬乳剂、水乳剂、微乳剂、微囊悬浮剂。
含噻虫胺和唑蚜威的农药组合物在防治作物蚜虫、稻飞虱、粉虱上的应用。
本发明的有益效果为：
1、本发明由不同作用机理的农药活性成分复配使用，且两者复配后可以起到协同增效作用，在一定范围内有利于减少各单剂的使用量，有助于降低农药成本。
2、本发明的农药组合物对作物安全，防效好，持效期长。
具体实施方式
为了使本发明的目的、技术方案以及优点更加清楚明白，下面结合实施例对本发明进行详细说明。
一、制剂实施例
实施例1:50%噻虫胺·唑蚜威可湿性粉剂（噻虫胺：唑蚜威=1:9）
噻虫胺 5%
唑蚜威 45%
十二烷基硫酸钠 6%
白炭黑 8%
高岭土 余量
实施例2:30%噻虫胺·唑蚜威水分散粒剂（噻虫胺：唑蚜威=1：2）
噻虫胺 10%
唑蚜威 20%
十二烷基苯磺酸钠 5%
烷基萘磺酸盐甲醛缩合物 4%
硅藻土 余量
实施例3： 45%噻虫胺·唑蚜威悬浮剂（噻虫胺：唑蚜威=2:7）
噻虫胺 10%
唑蚜威 35%
萘磺酸盐 4%
壬基酚聚氧乙烯醚 3%
乙二醇 3%
硅酸镁铝 0.3%
去离子水 余量
实施例4: 40%噻虫胺·唑蚜威微乳剂 （噻虫胺：唑蚜威=7：1）
噻虫胺 35%
唑蚜威 5%
乙酸乙酯 15%
农乳600# 6%
乙二醇 5%
硅油 1%
去离子水 余量
二、生物活性测定和药效试验例
本发明实施例采用室内毒力测定和田间试验相结合的方法。先通过室内毒力测定（按照孙云沛法），明确两种药剂按一定比例复配后的共毒系数CTC,CTC﹤80为拮抗作用，80≤CTC≤120为相加作用，CTC﹥120为增效作用，在此基础上，再进行田间试验。
选择室内饲养的2代3龄柑橘蚜虫幼虫，饥饿4-8h，选取50头幼虫。先用有机溶剂溶解原药，再稀释为5个系列浓度梯度。采用NY/T 1154.1-2006推荐的点滴法进行测定，将微量点滴器用溶剂清先，调节点滴器至备用状态。用毛笔选取整齐一致的试虫置于9cm培养皿中，接着用微量点滴器将药剂逐头点滴于试虫的虫体腹部，每头点滴药液0.1ul,以点滴0.1ul含有相应丙酮的处理为对照。将点滴后的试虫分别转移至培养室中正常培养。每处理5次重复,每重复试虫20头。
处理后24h调查试虫死亡情况(判断供试虫死亡标准是以针轻刺无自主反应)，记录总虫数和死虫数。
根据调查数据，计算各处理的校正死亡率，并计算共毒系数，试验结果如表1所示。
通过表1的数据可以看出：噻虫胺：唑蚜威在1:30-20:1时共毒系数均高于120，表现出较好的协同增效作用，证明噻虫胺与吡蚜酮在一定的复配比例下对蚜虫有增效作用。
为了更好的验证本发明的实际应用效果，下面采用本发明的实施例的制剂，做柑橘蚜虫防治效果田间药效试验，将实施例1、2、4共三种药剂分别兑水均匀系时候进行喷雾处理，设置药剂对照和空白清水对照，各处理见随机区组排列，每种处理三次重复。分别在药后3天、7天调查害虫数量，计算死亡率和防治效果，试验结果如表2所示。
供试药剂为：（1）实施例1所述的制剂；（2）实施例2所述的制剂；（3）实施例4所述的制剂；（4）24%唑蚜威乳油；（5）50%噻虫胺水分散粒剂；
由表2可以看出，噻虫胺与唑蚜威复配对柑橘蚜虫具有很好的防治效果，与单剂相比，在用量减少的情况下， 防效反而表现的更优异，并具有较好的速效性和持效性，在本试验用药范围内，对柑橘安全。
综上所述，噻虫胺与唑蚜威复配后在实际应用中比单一活性成分的单剂表现出更优异的杀虫活性，降低了用药量，减少了用工成本，提高了效率，对作物安全，环境污染小。所以，本发明的研发与推广具有十分重要的意义。
Claims (4)
1.一种农药复配组合物，其特征在于，活性成分包含噻虫胺与唑蚜威，其中，噻虫胺和唑蚜威的重量比为1:10-5:1。
2.根据权利要求1所述的农药复配组合物，其特征在于，所述噻虫胺与唑蚜威质量总和在农药组合物中的重量百分比为1-60%。
3.根据权利要求1或2所述的农药复配组合物，其特征在于，它的剂型为可湿性粉剂、颗粒剂、水分散粒剂、悬浮剂、悬乳剂、水乳剂、微乳剂、微囊悬浮剂中的一种。
4.根据权利要求1-3中任一项权利要求所述的农药复配组合物在防治蚜虫上的应用。
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| CN101610677A (zh) * | 2007-02-05 | 2009-12-23 | 巴斯夫欧洲公司 | 农药混合物 |
| CN101796960A (zh) * | 2010-04-16 | 2010-08-11 | 陕西美邦农药有限公司 | 一种含噻虫胺的杀虫组合物 |
| CN102172242A (zh) * | 2008-11-13 | 2011-09-07 | 陕西韦尔奇作物保护有限公司 | 一种含烯啶虫胺的杀虫组合物 |
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| CN101610677A (zh) * | 2007-02-05 | 2009-12-23 | 巴斯夫欧洲公司 | 农药混合物 |
| CN102172242A (zh) * | 2008-11-13 | 2011-09-07 | 陕西韦尔奇作物保护有限公司 | 一种含烯啶虫胺的杀虫组合物 |
| CN101796960A (zh) * | 2010-04-16 | 2010-08-11 | 陕西美邦农药有限公司 | 一种含噻虫胺的杀虫组合物 |
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