CN106070235A - A kind of composite bactericide containing Enestroburin - Google Patents

A kind of composite bactericide containing Enestroburin Download PDF

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Publication number
CN106070235A
CN106070235A CN201610483390.1A CN201610483390A CN106070235A CN 106070235 A CN106070235 A CN 106070235A CN 201610483390 A CN201610483390 A CN 201610483390A CN 106070235 A CN106070235 A CN 106070235A
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CN
China
Prior art keywords
composite bactericide
enestroburin
gross mass
accounts
tebuconazole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610483390.1A
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Chinese (zh)
Inventor
陆学云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LIANGMANCANG AGROCHEMISTRY CO Ltd
Original Assignee
LIANGMANCANG AGROCHEMISTRY CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LIANGMANCANG AGROCHEMISTRY CO Ltd filed Critical LIANGMANCANG AGROCHEMISTRY CO Ltd
Priority to CN201610483390.1A priority Critical patent/CN106070235A/en
Publication of CN106070235A publication Critical patent/CN106070235A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids

Abstract

A kind of composite bactericide containing Enestroburin, belongs to technical field of compounded pesticide, is specifically related to prevent and treat the technology of preparing of resistance disease composite bactericide.The effective ingredient of composite bactericide is Tebuconazole and Enestroburin, the present invention can produce good potentiation after compounding to Enestroburin and Tebuconazole, relatively Enestroburin, Tebuconazole single dose significantly improve bactericidal effect, thus reduce using dosage, save cost, delay generation and the development of single dose resistance.Mixture effect on environment is little, safer.It can prevent and treat multiple diseases, and has obvious potentiation, and expands fungicidal spectrum, decreases pesticide usage amount, reduces pesticide residual quantity on crop, alleviates environmental pollution;To person poultry safety, Environmental compatibility is good, be not likely to produce Drug resistance.

Description

A kind of composite bactericide containing Enestroburin
Technical field
The invention belongs to technical field of compounded pesticide, be specifically related to prevent and treat the technology of preparing of resistance disease composite bactericide.
Background technology
Different cultivars composition is compounded, is to prevent and treat the method that resistance disease is the most common.Heterogeneity compounds, root According to practical application effect, judge certain compounding be potentiation, add and or antagonism.In most cases, the answering of pesticide Joining effect is all additive effect, really have potentiation compounding seldom, especially potentiation clearly, co-toxicity coefficient very High is compounding the most less.
Summary of the invention
Present invention aim at proposing a kind of compound sterilizing containing Enestroburin with notable synergistic and lasting effect Agent.
The effective ingredient of composite bactericide of the present invention is Tebuconazole and Enestroburin.
Described Tebuconazole and Enestroburin account for the 1~80% of composite bactericide gross mass.
Described Tebuconazole accounts for the 1~80% of composite bactericide gross mass, and described Enestroburin accounts for composite bactericide gross mass 1~80%.
Discovery is studied: good potentiation can be produced after compounding to Enestroburin and Tebuconazole through inventor, and Wheat scab relevant report is prevented and treated the openest about Enestroburin and Tebuconazole built agent.
The present invention is had the beneficial effects that by compounding its, shows good potentiation, relatively in certain ratio range Enestroburin, Tebuconazole single dose significantly improve bactericidal effect, thus reduce using dosage, have saved cost, have delayed list The generation of agent resistance and development.Mixture effect on environment is little, safer.
The beneficial effects of the present invention is: it can prevent and treat multiple diseases, and has obvious potentiation, and expand and kill Bacterium is composed, and decreases pesticide usage amount, reduces pesticide residual quantity on crop, alleviate environmental pollution;To person poultry safety, ring The border compatibility is good, be not likely to produce Drug resistance.
Instant invention overcomes Enestroburin, resistance that Tebuconazole single dose life-time service may bring occurs, degradation under drug effect Problem, it is an advantage of the current invention that:
1, after Enestroburin and Tebuconazole compound, there is notable synergistic and lasting effect;
2, the present invention expands fungicidal spectrum, and wheat powdery mildew, rust, head blight class etc. are all had greater activity;
3, use the present invention, reached to reduce the dosage of pesticide, reduced pesticide residual quantity on crop, alleviate environmental pollution Purpose;
4, the present invention is good to person poultry safety, Environmental compatibility, disease is not likely to produce Drug resistance.
5, a spray is prevented more: a dispenser can prevent and treat wheat scab, powdery mildew, rust simultaneously.Reduce the life of peasant Produce cost, save labor time.
Further, composite bactericide of the present invention can be wettable powder, except being Tebuconazole containing effective ingredient Beyond Enestroburin, also include accounting for respectively composite bactericide gross mass 2~clean Xian's agent of the dispersant of 5%, 2~5%, 1.5~ The wetting agent pulling open the lignosulfonates of powder, 2~8%, 0.5~3% of 5%, remaining is filler.The manufacture of this wettable powder Method is simple, comminution by gas stream energy consumption is low, wear and tear and stick little, narrow particle distribution, conforming product rate high, enterprise is processed into The advantages such as this is low.
More preferably: in wettable powder, described Enestroburin accounts for composite bactericide gross mass 10%, Tebuconazole accounts for multiple Join antibacterial gross mass 30%, dispersant accounts for composite bactericide gross mass 3%, calcium lignosulfonate accounts for composite bactericide gross mass 3%, pull open that powder accounts for composite bactericide gross mass 1.5%, sodium lauryl sulphate accounts for composite bactericide gross mass 2%.Through Nanjing agriculture The inhibition of fusarium graminearum mycelial growth is shown by university's test Enestroburin Tebuconazole: when Enestroburin and penta azoles The proportioning of alcohol is when 1: 3, and potentiation becomes apparent from highlighting, and its virulence maximum EC5013.2937ug/ml, potentiation is the most Substantially.
Composite bactericide of the present invention is alternatively aqueous suspension agent, except being Tebuconazole and Enestroburin containing effective ingredient In addition, also include accounting for composite bactericide gross mass 1~the emulsifying of the Enestroburin of the Tebuconazole of 80%, 1~80%, 3~6% respectively The defoamer of the thickening agent of the antifreezing agent of the dispersant of agent, 1~5%, 1~5%, 0.1~5%, 0~0.3%, remaining is water.This water Suspending agent particle diameter is little, and suspensibility is high, when making residual spray, will not block shower nozzle, can't see obvious medicine mark on dispenser surface, give People is with clean feel;During dispenser, zest is little, and safety is good, and strong etc. to the adhesive force on dispenser surface, more can give full play to drug effect, It is the green pesticide form more advanced than wettable powder.
More preferably: in aqueous suspension agent, described Enestroburin accounts for composite bactericide gross mass 7%, Tebuconazole accounts for compounding killing Microbial inoculum gross mass 21%, emulsifying agent account for composite bactericide gross mass 5%, dispersant accounts for composite bactericide gross mass 1.5%, thickening agent Account for composite bactericide gross mass 4 %, antifreezing agent accounts for composite bactericide gross mass 1.5%, defoamer accounts for composite bactericide gross mass 0.2%.Through Agricultural University Of Nanjing, the inhibition of fusarium graminearum mycelial growth is shown by test Enestroburin Tebuconazole: When the proportioning of Enestroburin and Tebuconazole is 1: 3, potentiation becomes apparent from highlighting, and its virulence is maximum EC5013.2937ug/ml, potentiation is the most obvious.
Detailed description of the invention
One, method prepared by 40% alkene oxime Tebuconazole wettable powder:
Weigh the Enestroburin 10kg of percentage amount, Tebuconazole 30kg, dispersant 3kg, calcium lignosulfonate 3 kg respectively, pull open powder 1.5 kg, SDS 2kg, and the filler of surplus, to reach gross mass as 100kg.
First by Enestroburin, Tebuconazole, dispersant, calcium lignosulfonate, pull open powder, SDS, filler addition Slightly mix in blender, then pulverize through jet mill, mix through secondary, prepare 40% alkene oxime Tebuconazole wettable powder Agent.
Two, method prepared by 28% alkene oxime Tebuconazole aqueous suspension agent:
Weigh respectively the Enestroburin 7kg of percentage amount, Tebuconazole 21kg, emulsifying agent 5kg, dispersant 1.5kg, thickening agent 4 kg, Antifreezing agent 1.5 kg, defoamer 0.2kg, and the water of surplus, to reach gross mass as 100kg.
First the water of Enestroburin, Tebuconazole, emulsifying agent, dispersant and 70% total amount is joined in sand milling still and grind Grind.The addition of thickening agent, antifreezing agent, defoamer and excess water is modulated after terminating by barreling, obtains 28% alkene oxime Tebuconazole water Suspending agent.
Three, field is used:
1, application process, dosage:
Should use at wheat scab their early stage, every mu of use 40% alkene oxime Tebuconazole wettable powder 40~50 grams, 28% alkene Oxime Tebuconazole aqueous suspension agent 50~60 grams.It is watered 50Kg even spraying.
2, rear effect is used
Show through certain county's plant protection unit field control effectiveness test result: mu 40% alkene oxime Tebuconazole wettable powder 40~50 grams, 28% Alkene oxime Tebuconazole aqueous suspension agent 50~60 grams.Preventing and treating wheat scab, its preventive effect is 84.65%~87.28%.Prevention effect is equal It is better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects, wheat powdery mildew is also had very well simultaneously Preventive effect.

Claims (7)

1. the composite bactericide containing Enestroburin, it is characterised in that the effective ingredient of described composite bactericide is Tebuconazole And Enestroburin.
Contain the composite bactericide of Enestroburin the most according to claim 1, it is characterised in that described Tebuconazole and alkene oxime bacterium Ester accounts for the 1~80% of composite bactericide gross mass.
Contain the composite bactericide of Enestroburin the most according to claim 2, it is characterised in that described Tebuconazole accounts for compounding killing The 1~80% of microbial inoculum gross mass, described Enestroburin accounts for the 1~80% of composite bactericide gross mass.
Contain the composite bactericide of Enestroburin the most according to claim 3, it is characterised in that described composite bactericide is can WP, also includes accounting for respectively the drawing of clean Xian's agent, 1.5~5% of composite bactericide gross mass 2~the dispersant of 5%, 2~5% Opening the wetting agent of the lignosulfonates of powder, 2~8%, 0.5~3%, remaining is filler.
Contain the composite bactericide of Enestroburin the most according to claim 4, it is characterised in that described Enestroburin accounts for compounding Antibacterial gross mass 10%, Tebuconazole account for composite bactericide gross mass 30%, dispersant accounts for composite bactericide gross mass 3%, lignin Sulfoacid calcium accounts for composite bactericide gross mass 3%, pulls open that powder accounts for composite bactericide gross mass 1.5%, sodium lauryl sulphate accounts for compounding Antibacterial gross mass 2%.
Contain the composite bactericide of Enestroburin the most according to claim 3, it is characterised in that described composite bactericide is water Suspending agent, also includes accounting for composite bactericide gross mass 1~the breast of the Enestroburin of the Tebuconazole of 80%, 1~80%, 3~6% respectively The defoamer of the thickening agent of the antifreezing agent of the dispersant of agent, 1~5%, 1~5%, 0.1~5%, 0~0.3%, remaining is water.
Contain the composite bactericide of Enestroburin the most according to claim 6, it is characterised in that described Enestroburin accounts for compounding Antibacterial gross mass 7%, Tebuconazole account for composite bactericide gross mass 21%, emulsifying agent accounts for composite bactericide gross mass 5%, dispersant Account for composite bactericide gross mass 1.5%, thickening agent accounts for composite bactericide gross mass 4 %, antifreezing agent accounts for composite bactericide gross mass 1.5%, defoamer accounts for composite bactericide gross mass 0.2%.
CN201610483390.1A 2016-06-28 2016-06-28 A kind of composite bactericide containing Enestroburin Pending CN106070235A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610483390.1A CN106070235A (en) 2016-06-28 2016-06-28 A kind of composite bactericide containing Enestroburin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610483390.1A CN106070235A (en) 2016-06-28 2016-06-28 A kind of composite bactericide containing Enestroburin

Publications (1)

Publication Number Publication Date
CN106070235A true CN106070235A (en) 2016-11-09

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007017231A1 (en) * 2005-08-05 2007-02-15 Basf Aktiengesellschaft Use of arylanilides for seed treatment
CN1918989A (en) * 2005-08-26 2007-02-28 沈阳化工研究院 Bactericide composition
CN101087525A (en) * 2004-12-23 2007-12-12 巴斯福股份公司 Fungicidal mixtures containing enestroburin and at least one active substance from the group of azoles

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101087525A (en) * 2004-12-23 2007-12-12 巴斯福股份公司 Fungicidal mixtures containing enestroburin and at least one active substance from the group of azoles
WO2007017231A1 (en) * 2005-08-05 2007-02-15 Basf Aktiengesellschaft Use of arylanilides for seed treatment
CN1918989A (en) * 2005-08-26 2007-02-28 沈阳化工研究院 Bactericide composition

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Application publication date: 20161109