CN106070213A - A kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1 methyl cyclopropene - Google Patents

A kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1 methyl cyclopropene Download PDF

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Publication number
CN106070213A
CN106070213A CN201610454783.XA CN201610454783A CN106070213A CN 106070213 A CN106070213 A CN 106070213A CN 201610454783 A CN201610454783 A CN 201610454783A CN 106070213 A CN106070213 A CN 106070213A
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Prior art keywords
diethyl aminoethyl
methyl cyclopropene
aminoethyl hexanoate
composition pesticide
methyl
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CN201610454783.XA
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Inventor
王礼文
张志伟
朱刚
陈佛祥
吴泽伟
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Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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Priority to CN201610454783.XA priority Critical patent/CN106070213A/en
Publication of CN106070213A publication Critical patent/CN106070213A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/12Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N27/00Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N3/00Preservation of plants or parts thereof, e.g. inhibiting evaporation, improvement of the appearance of leaves or protection against physical influences such as UV radiation using chemical compositions; Grafting wax
    • A01N3/02Keeping cut flowers fresh chemically

Abstract

The invention discloses a kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1 methyl cyclopropene, including usual auxiliaries, diethyl aminoethyl hexanoate and 1 methyl cyclopropene, the mass fraction of diethyl aminoethyl hexanoate and 1 methyl cyclopropene is than for 30:1~1:10;Oil-suspending agent that this compositions can be configured to agriculturally to allow, wettable powder, water dispersible granules, soluble liquid;Diethyl aminoethyl hexanoate and compounding with 1 methyl cyclopropene after crop yield had obvious synergistic function, it is adaptable to the volume increase of crop such as Oryza sativa L., Semen Tritici aestivi, Semen Maydis, potatoes and other crops, the fresh keeping time of notable prolongation cut-flower, there is preservation.

Description

A kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1-methyl cyclopropene
Technical field
The composition pesticide that the present invention relates to, is with diethyl aminoethyl hexanoate and 1-methyl cyclopropene as active component, it is adaptable to Semen Tritici aestivi, Semen Maydis, Oryza sativa L., the volume increase of potatoes and other crops, have crop yield effect;The notable fresh keeping time extending cut-flower, has fresh-keeping Effect.
Background technology
Diethyl aminoethyl hexanoate (diethyl aminoethyl hexanoate), also known as DA-6, it can improve plant peroxidases With the activity of nitrate reductase, improve chlorophyllous content and accelerate photosynthetic speed, promote division and the elongation of plant cell, promote The growth of root system, regulates the balance of internal nutrient.
Diethyl aminoethyl hexanoate can improve chlorophyll in plant body, protein, the content of nucleic acid and photosynthetic rate, improves peroxidase And the activity of nitrate reductase, promote the carbon of plant, nitrogen metabolism, strengthen the plant absorption to liquid manure and the accumulation of dry, adjust Joint internal water balance, strengthens crop, fruit tree disease-resistant, drought resisting, cold tolerance;Delay plant senesecence, promote early ripening of the crops, increasing Produce, improve the quality of crop;Thus reach volume increase, increase matter.
1-methyl cyclopropene (1-Methylcyclopropene), is abbreviated as 1-MCP, is that a kind of very effective ethylene produces The raw inhibitor with ethylene action, can be produced by Activities of Some Plants self as the plant hormone ethylene promoting ripening and senscence, Can there is again a certain amount in storage environment even air, ethylene combines with the associated receptor within thin fertilizer, could activate A series of biochemical reactions relevant with maturation, accelerate old and feeble and dead.L-MCP can also tie with ethylene receptor well Close, but this combination will not cause maturation biochemical reaction, therefore, plant endogenous ethylene produce or exogenous ethylene effect it Before, use 1-MCP, it will be tried to be the first and be combined with ethylene receptor, thus stops the combination of ethylene and its receptor, extends well The process of fruit and vegerable ripening and senscence, extends freshness date.Can delaying ripening, aging well, keep the hardness of product, crisp well Degree, keeps color, local flavor, fragrance and nutritional labeling, can effectively keep the disease resistance of plant, and alleviate that microorganism causes rots With alleviate physiological disease, and can reduce moisture evaporation, prevent wilt.Under room temperature state, 1-methyl cyclopropene is gas, 1-methyl Cyclopropylene can exist with the powder type of alpha-cyclodextrin molecule or beta-schardinger dextrin-molecule Rubber Capsule, it is also possible to other cyclodextrin The powder type of molecule Rubber Capsule exists.
The present invention can be with excipient for the most normal with 1-methyl cyclopropene compositions by certain technological means diethyl aminoethyl hexanoate Dosage form.
Summary of the invention
It is desirable to provide the synergetic pesticide composition that a kind of effective ingredient is diethyl aminoethyl hexanoate and 1-methyl cyclopropene, for making The fresh-keeping offer one of thing volume increase and cut-flower effectively manages instrument.
The present invention is achieved through the following technical solutions:
A kind of synergistic composition compounding with 1-methyl cyclopropene containing diethyl aminoethyl hexanoate, diethyl aminoethyl hexanoate and the matter of 1-methyl cyclopropene Amount portion rate is 30:1~1:10, and diethyl aminoethyl hexanoate calculates with molecular compound, and 1-methyl cyclopropene is with alpha-cyclodextrin molecule or β-ring The powder type of dextrin molecule Rubber Capsule exists.
Described composition pesticide effective ingredient total content is 0.1%~30%.
Described composition pesticide adds auxiliary agent and excipient is made by certain technological means and dispersibled oil-suspending agent, water The dosage form that dispersible granule, wettable powder, soluble concentrate etc. are agriculturally conventional.
Described oil-suspending agent dosage form weight percent consists of: diethyl aminoethyl hexanoate 0.1~20%, 1-methyl cyclopropene 0.1~ 10%, dispersant 0.1~14%, wetting agent 0.1~13%, thickening agent 0.1~3%, antifreezing agent 0.1~5%, liquid-carrier is mended Foot is to 100%.Concrete production stage is: effective ingredient and other auxiliary agent are mixed, sand milling in high speed shear dispersion, sand mill After, oil system medium is formed high dispersive, stable suspension system, prepares the oil-suspending agent of corresponding weight percentage, 1-first Cyclopropene exists with the powder type of alpha-cyclodextrin molecule or beta-schardinger dextrin-molecule Rubber Capsule.
Described dosage form of water dispersible granule weight percent consists of: diethyl aminoethyl hexanoate 0.1~20%, 1-methyl cyclopropene 0.1 ~10%, dispersant 0.1~10%, wetting agent 0.1~12%, disintegrating agent 0.2~10%, solid carrier complements to 100%.Tool Body production stage is: by effective ingredient and other auxiliary agent mix homogeneously, pulverizes with micro jet, through mediating, then adds Fluidized bed granulating and drying machine carries out pelletize, dry, screening, prepares the water dispersible granules of corresponding weight percentage, 1-first Cyclopropene exists with the powder type of alpha-cyclodextrin molecule or beta-schardinger dextrin-molecule Rubber Capsule.
Described wettable powder formulation weight percent consists of: diethyl aminoethyl hexanoate 0.1~20%, 1-methyl cyclopropene 0.1 ~10%, dispersant 0.1~14%, wetting agent 0.1~12%, solid carrier complements to 100%.Concrete production stage is: tool Body production stage is: effective ingredient and other auxiliary agent are mixed, and again through comminution by gas stream, mix homogeneously after mechanical activation comminution, prepares phase Answering the wettable powder of weight percentage, 1-methyl cyclopropene is with alpha-cyclodextrin molecule or the powder of beta-schardinger dextrin-molecule Rubber Capsule End form exists.
Described soluble liquid weight percent consists of: diethyl aminoethyl hexanoate 0.1%~20%, 1-methyl cyclopropene 0.1~ 10%, solvent 1~40%, dispersant 0.1~14%, emulsifying agent 0.1~12%, liquid-carrier complements to 100%.Concrete production Step is: effective ingredient and solvent are mixed, and mixes with other auxiliary agent after fully dissolving, and liquid-carrier complements to 100%, mixing Uniformly, preparing the soluble liquid of corresponding weight percentage, 1-methyl cyclopropene divides with alpha-cyclodextrin molecule or beta-schardinger dextrin- The powder type of attached bag capsule exists.
Described defoamer can be one or more in silicone compound, epoxy soybean oil, methanol, silicone oil etc..
Described antifreezing agent can be one or more in glycerol, propylene glycol, diethylene glycol, carbamide etc..
Described wetting agent can be sodium lauryl sulphate, dodecylbenzene sodium sulfonate, sodium butylnaphthalenesulfonate, alkyl sulphur One or more in acid sodium, tea seed cake powder, spaonin powder, Fructus Sapindi Mukouossi powder etc..
Described dispersant can be alkylphenol polyoxyethylene formaldehyde condensation products, naphthalenesulfonate formaldehyde condensation compound, to first Epoxide fatty acyl anilinesulfonic acid, lignosulfonates, polycarboxylate, alkylphenol polyoxyethylene sulfate, alkyl benzene sulphonate Calcium salt, fatty acid ester sulfate, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, polyglycol distearate, sorbose One or more in alcohol oleate, nekal, wood powder, Fagopyrum esculentum Moench powder etc..
Described disintegrating agent can be carboxymethyl starch sodium, low-substituted hydroxypropyl cellulose, cross-linking sodium carboxymethyl cellulose, Polyvinylpolypyrrolidone, chitosan, sodium alginate sodium bicarbonate, magnesium chloride, aluminum chloride, sodium chloride, carbamide, ammonium sulfate, bentonite etc. In one or more.
Described thickening agent can be polyvinyl acetate, xanthan gum, gelatin, Radix Acaciae senegalis, aluminium-magnesium silicate, phenolic aldehyde tree One or more in fat, hydroxymethyl cellulose, sodium alginate etc..
Described solid carrier can be precipitated calcium carbonate, potter's clay, Kaolin, kieselguhr, bentonite, white carbon, clay, One or more in attapulgite, Pulvis Talci, quartz sand, wood powder, walnut parting, lignin etc..
Described liquid-carrier can be exquisite soybean oil, Semen Maydis oil, Oleum Brassicae campestris, Oleum Terebinthinae, methyl oleate, Oleum Cocois, One or more in Petiolus Trachycarpi oil, safflower oil, Oleum Sesami, Oleum Ricini, Oleum Verniciae fordii, olive oil etc., and the ester of above vegetable oil, especially It it is methyl ester.
Described solvent is methanol, ethanol, ethylene glycol, n-butyl alcohol, dimethyl acetylamide, acetone, dimethyl sulfoxide, pyrrole One or more in pyridine, trimethylbenzene, durene etc..
Described deionized water is industrialization deionized water.
Described binding agent can be sucrose, polyvinyl alcohol, Polyethylene Glycol, sodium carboxymethyl cellulose, carboxymethyl cellulose One in calcium, carboxy-propyl cellulose, dextrin, amylodextrin, polyvinylpyrrolidone, viscosity Kaolin, paraffin, Colophonium etc. or Several.
Detailed description of the invention
In order to be more fully understood that the essence of the present invention, below in conjunction with embodiment, present disclosure is described further, But can not be considered as limitation of the present invention, the following stated is only used for explaining the present invention, for without departing from present invention spirit and principle The amendment made, replace or improve, belong to the scope of protection of present invention.
Embodiment one: 10% diethyl aminoethyl hexanoate 1-methyl cyclopropene soluble liquid.
Weigh diethyl aminoethyl hexanoate 98 grams, 1-methyl cyclopropene 12 grams, fatty alcohol-polyoxyethylene ether 5.1 grams, n-butyl alcohol 5.2 grams, two Methyl sulfoxide 250 grams, dimethyl acetylamide 150 grams, ethylene glycol complements to 1000 grams, by diethyl aminoethyl hexanoate in above-mentioned formula and 1-methyl Cyclopropylene is put in proportion in dimethyl acetylamide, dimethyl sulfoxide, glycerol, ethylene glycol mixture and is dissolved, and adds after dissolving Aliphatic alcohol polyethenoxy, last spent glycol complements to 100%, after testing, and diethyl aminoethyl hexanoate content 9.0%, 1-methyl cyclopropene powder End form content 1.0%, the diethyl aminoethyl hexanoate 1-methyl cyclopropene soluble liquid of total content 10%.1-methyl cyclopropene is with α-ring The powder type of dextrin molecule or beta-schardinger dextrin-molecule Rubber Capsule exists.
Embodiment two: 30% diethyl aminoethyl hexanoate 1-methyl cyclopropene oil-suspending agent.
Weigh diethyl aminoethyl hexanoate 153 grams, 1-methyl cyclopropene 151 grams, 48 grams of lignosulfonates sodium, fatty alcohol-polyoxyethylene ether 52 grams, methyl oleate 249 grams, organobentonite 83 grams, dodecyl sodium sulfonate calcium salt 60 grams, Oleum Terebinthinae complements to 1000 grams, will Above-mentioned formula is pulverized the most in advance, adds in sand mill and grinds, and after high shear mixing, allotment prepares diethyl aminoethyl hexanoate 1-methyl cyclopropene oil-suspending agent, after testing, diethyl aminoethyl hexanoate effective content 15.1%, 1-methyl cyclopropene powder type effective content 15.0%, total effective content 30.1%, 1-methyl cyclopropene is with alpha-cyclodextrin molecule or the powder of beta-schardinger dextrin-molecule Rubber Capsule Form exists.
Embodiment three: 30% diethyl aminoethyl hexanoate 1-methyl cyclopropene water dispersible granules.
Weigh diethyl aminoethyl hexanoate 255 grams, 1-methyl cyclopropene 56 grams, sodium lignin sulfonate 48 grams, chitosan 61 grams, glucose 55 Gram, wood powder 39 grams, Kaolin complements to 1000.By above-mentioned formula dry pulverization process in proportion, pelletize, be dried, screening preparation system i.e. Obtain diethyl aminoethyl hexanoate 1-methyl cyclopropene water dispersible granules, after testing, diethyl aminoethyl hexanoate effective content 25.1%, 1-methyl cyclopropene powder Form effective content 5.1%, total effective content 30.2%, 1-methyl cyclopropene is with alpha-cyclodextrin molecule or beta-schardinger dextrin-molecule bag The powder type of capsule exists.
Embodiment four: 30% diethyl aminoethyl hexanoate 1-methyl cyclopropene wettable powder.
Weigh diethyl aminoethyl hexanoate 204 grams, 1-methyl cyclopropene 107 grams, lignosulfonates calcium 53 grams, sodium lauryl sulphate 47 Gram, Fagopyrum esculentum Moench powder 53 grams, white carbon 57 grams, Kaolin complements to 1000 grams.Mixing will be entered after the coarse pulverization in proportion of above-mentioned formula Mix homogeneously in device, then after comminution by gas stream, i.e. prepare diethyl aminoethyl hexanoate 1-methyl cyclopropene wettable powder, after testing, diethyl aminoethyl hexanoate Effective content 20.1%, 1-methyl cyclopropene powder type effective content 10.1%, total effective content 30.2%, 1-methyl ring third Alkene exists with the powder type of alpha-cyclodextrin molecule or beta-schardinger dextrin-molecule Rubber Capsule.
Embodiment five: the fresh-keeping test of Carnation Flower.
Cut-flower is cut after treatment and is dipped in clear water at stem, is placed in humidity 60%, 12 hours dark rooms of illumination in 12 hours Temperature preserves in greenhouse, processes the calculating time as the fresh keeping time time between petal 20% wilting with Fresh Cutting flower, and unit is My god.
Table 1, the different disposal fresh keeping time to fresh Carnation Flower
As can be seen from Table 1, diethyl aminoethyl hexanoate and 1-methyl cyclopropene process fresh Carnation Flower and all can prolong storage period, and amine Fresh ester and 1-methyl cyclopropene are used in mixed way the fresh Carnation Flower of process, fresh keeping time all can relative to single dose extend 50% with On, process relative to clear water and all can extend more than 100%, the notable fresh keeping time extending fresh Carnation Flower, it can be seen that amine It is fresh-keeping significant that fresh ester and 1-methyl cyclopropene are applied in combination Carnation Flower, and 1-methyl cyclopropene is stuck with paste with α-ring The powder type of essence molecule or beta-schardinger dextrin-molecule Rubber Capsule exists.
Embodiment six: the fresh-keeping test of cutting flower.
Cut-flower is cut after treatment and is dipped in clear water at stem, is placed in humidity 60%, 12 hours dark rooms of illumination in 12 hours Temperature preserves in greenhouse, processes the calculating time to the time that petal 20% is wilted as fresh keeping time with Fresh Cutting flower, and unit is sky.
Table 2, the different disposal fresh keeping time to scarlet cutting flower
As can be seen from Table 2, diethyl aminoethyl hexanoate and 1-methyl cyclopropene process scarlet cutting flower and all can prolong storage period, and amine Fresh ester and 1-methyl cyclopropene are used in mixed way the scarlet cutting flower of process, fresh keeping time all can relative to single dose extend 50% with On, process relative to clear water and all can extend more than 100%, the notable fresh keeping time extending scarlet cutting flower, it can be seen that amine It is fresh-keeping significant that fresh ester and 1-methyl cyclopropene are applied in combination red rose cut-flower, and 1-methyl cyclopropene is stuck with paste with α-ring The powder type of essence molecule or beta-schardinger dextrin-molecule Rubber Capsule exists.
Embodiment seven: the fresh-keeping test of lily cut flowers.
Cut-flower is cut after treatment and is dipped in clear water at stem, is placed in humidity 60%, 12 hours dark rooms of illumination in 12 hours Temperature preserves in greenhouse, processes the calculating time to the time that petal 20% is wilted as fresh keeping time with Fresh Cutting flower, and unit is sky.
Table 3, the different disposal fresh keeping time to fresh white lily cut flowers
As can be seen from Table 3, diethyl aminoethyl hexanoate and 1-methyl cyclopropene process fresh white lily cut flowers and all can prolong storage period, and amine Fresh ester and 1-methyl cyclopropene are used in mixed way the fresh white lily cut flowers of process, fresh keeping time all can relative to single dose extend 50% with On, process relative to clear water and all can extend more than 100%, the notable fresh keeping time extending fresh white lily cut flowers, it can be seen that amine Fresh ester and 1-methyl cyclopropene are applied in combination the fresh-keeping significant of dialogue lily cut flowers, and 1-methyl cyclopropene is stuck with paste with α-ring The powder type of essence molecule or beta-schardinger dextrin-molecule Rubber Capsule exists.
Embodiment eight: the production-increasing function of crop is tested by diethyl aminoethyl hexanoate with 1-methyl cyclopropene.
After results after each process fringe threshing, randomly select 2 500 and weigh, if 2 500 weight differentials are little, then Data are added and try to achieve mass of 1000 kernel (moisture < 13%), are repeated 4 times, and calculate the mass of 1000 kernel increment rate often processed.
Evaluating herbicide associated form (NY/T 1155.7-2006) according to Gowing method, its formula is as follows:
E0X Y XY/100
In formula, X is diethyl aminoethyl hexanoate with certain dosage mass of 1000 kernel increment rate/yield increment rate to target time alone;Y is 1-methyl Cyclopropylene is with certain dosage mass of 1000 kernel increment rate/yield increment rate to target time alone;E0For diethyl aminoethyl hexanoate, 1-methyl cyclopropene two Theoretical value to target mass of 1000 kernel increment rate/yield increment rate during kind of pharmacy mix;E is diethyl aminoethyl hexanoate, 1-methyl cyclopropene two kinds Measured value to target mass of 1000 kernel increment rate/yield increment rate during pharmacy mix.
1-methyl cyclopropene exists with the powder type of alpha-cyclodextrin molecule or beta-schardinger dextrin-molecule Rubber Capsule.
Evaluation criterion: as E E0During > 10%, it is expressed as potentiation;As 10%≤E E0When≤10%, show as phase Add effect;As E E0During < 10%, show as antagonism.
(1) diethyl aminoethyl hexanoate and the 1-methyl cyclopropene production-increasing function to Semen Tritici aestivi.
Table 4, diethyl aminoethyl hexanoate and 1-methyl cyclopropene and mixture combination thereof
Thousand grain weight of wheat is increased measurement result
By table 4 it is known that the compounding production-increasing function to Semen Tritici aestivi of diethyl aminoethyl hexanoate and 1-methyl cyclopropene is obvious, all 15% with On, and synergism is obvious, E-E0More than 10%, showing as synergistic function, 1-methyl cyclopropene is with alpha-cyclodextrin molecule Or the powder type of beta-schardinger dextrin-molecule Rubber Capsule exists.
(2) diethyl aminoethyl hexanoate and the 1-methyl cyclopropene production-increasing function to Oryza sativa L.
Table 5, diethyl aminoethyl hexanoate and 1-methyl cyclopropene and mixture combination thereof
Oryza sativa L. mass of 1000 kernel is increased measurement result
By table 5 it is known that the compounding production-increasing function to Oryza sativa L. of diethyl aminoethyl hexanoate and 1-methyl cyclopropene is obvious, all 16% with On, and synergism is obvious, E-E0More than 10%, show as Synergistic, 1-methyl cyclopropene with alpha-cyclodextrin molecule or β- The powder type of cyclodextrin molecular Rubber Capsule exists.
(3) diethyl aminoethyl hexanoate and the 1-methyl cyclopropene production-increasing function to Semen Maydis.
Table 6, diethyl aminoethyl hexanoate and 1-methyl cyclopropene and mixture combination thereof
Semen Maydis 100-grain weight is increased measurement result
By table 6 it is known that the compounding production-increasing function to Semen Maydis of diethyl aminoethyl hexanoate and 1-methyl cyclopropene is obvious, all 13% with On, and synergism is obvious, E-E0More than 10%, showing as synergistic function, 1-methyl cyclopropene is with alpha-cyclodextrin molecule Or the powder type of beta-schardinger dextrin-molecule Rubber Capsule exists.
(4) diethyl aminoethyl hexanoate and the 1-methyl cyclopropene production-increasing function to Rhizoma Solani tuber osi.
Table 7, diethyl aminoethyl hexanoate and 1-methyl cyclopropene and mixture combination thereof
Rhizoma Solani tuber osi per mu yield is increased measurement result
By table 7 it is known that diethyl aminoethyl hexanoate production-increasing function to Rhizoma Solani tuber osi compounding with 1-methyl cyclopropene is obvious, all 20% Above, and synergism is substantially, E-E0More than 10%, showing as synergistic function, 1-methyl cyclopropene divides with alpha-cyclodextrin The powder type of son or beta-schardinger dextrin-molecule Rubber Capsule exists.

Claims (8)

1. one kind contain diethyl aminoethyl hexanoate and the composition pesticide of 1-methyl cyclopropene, it is characterised in that: effective ingredient be diethyl aminoethyl hexanoate and 1-methyl cyclopropene, the mass fraction of diethyl aminoethyl hexanoate and 1-methyl cyclopropene is than for 30:1~1:10.
It is the most according to claim 1 a kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1-methyl cyclopropene, it is characterised in that: Described composition pesticide effective ingredient total content is 0.1%~30%.
It is the most according to claim 1 a kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1-methyl cyclopropene, it is characterised in that: The mass fraction of diethyl aminoethyl hexanoate and 1-methyl cyclopropene is than for 5:1~1:5.
It is the most according to claim 1 a kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1-methyl cyclopropene, it is characterised in that: The mass fraction of diethyl aminoethyl hexanoate and 1-methyl cyclopropene is than for 1:1.
It is the most according to claim 1 a kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1-methyl cyclopropene, it is characterised in that: The mass fraction of diethyl aminoethyl hexanoate and 1-methyl cyclopropene is than for 1:5.
It is the most according to claim 1 a kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1-methyl cyclopropene, it is characterised in that: Described composition pesticide is made and is dispersibled what oil-suspending agent, water dispersible granules, wettable powder or soluble concentrate were agriculturally commonly used Dosage form.
7. a kind of composition pesticide containing diethyl aminoethyl hexanoate and 1-methyl cyclopropene described in claim 1 for Semen Tritici aestivi, Semen Maydis, Oryza sativa L., the purposes of volume increase of potato crop.
8. a kind of composition pesticide containing diethyl aminoethyl hexanoate and 1-methyl cyclopropene described in claim 1 is for cutflower preservation Purposes.
CN201610454783.XA 2016-06-21 2016-06-21 A kind of containing diethyl aminoethyl hexanoate with the composition pesticide of 1 methyl cyclopropene Pending CN106070213A (en)

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CN107135832A (en) * 2017-06-09 2017-09-08 华中农业大学 1 methyl cyclopropene reduce citrus survive the winter shedding and extension picking time in application
WO2022237008A1 (en) * 2021-05-13 2022-11-17 中国热带农业科学院环境与植物保护研究所 Pesticide composition for preventing and treating banana thrips

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Application publication date: 20161109