CN106065317A - Fast setting non-volatile LEDbulb lamp adhesive glue and preparation method thereof - Google Patents
Fast setting non-volatile LEDbulb lamp adhesive glue and preparation method thereof Download PDFInfo
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- CN106065317A CN106065317A CN201610549162.XA CN201610549162A CN106065317A CN 106065317 A CN106065317 A CN 106065317A CN 201610549162 A CN201610549162 A CN 201610549162A CN 106065317 A CN106065317 A CN 106065317A
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- volatile
- ledbulb lamp
- adhesive glue
- fast setting
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of fast setting non-volatile LEDbulb lamp adhesive glue and preparation method thereof, it includes following component: ethenyl blocking polydimethylsiloxane, Vinyl MQ silicon resin, linear methyl hydrogen silicone oil, viscosifier, inhibitor, thixotropic agent and platinum catalyst.The formula of the fast setting non-volatile LEDbulb lamp adhesive glue that the present invention provides is reasonable, platinum catalyst catalytic reaction is utilized to form, even if also can fast reaction in airtight environment, and produce without little molecule after reacting, and then meet the mass of current LEDbulb lamp adhesive glue, the condition of high performance production, LEDbulb lamp product quality is effectively ensured, without hazing, corroding the phenomenons such as shell, increase the service life, and can translucent or white effect, with meet different product use demand；The preparation method that the present invention provides can quickly make fast setting non-volatile LEDbulb lamp adhesive glue, and processing step is succinct, it is easy to accomplish, productivity ratio is high.
Description
Technical field
The present invention relates to LEDbulb lamp adhesive glue technical field, be specifically related to a kind of fast setting non-volatile LED ball bubble
Lamp adhesive glue and preparation method thereof.
Background technology
Country 12 planning in energy-conserving and environment-protective, green health proposal under, LED obtains as forth generation lighting source
Development at a high speed.LEDbulb lamp also obtains development at full speed as a member indispensable in LED industry, and demand is increasingly
Greatly.
But the normal temperature cure condensed type silicone rubber that LEDbulb lamp adhesive glue is all on the market at present.This kind of glue due to
Produce reaction, solidification by the dampness in absorption air, but after closeing the lid after bulb lamp gluing, form an environment sealed,
With regard to difficult contact wetting to causing glue curing very slow, deep cure difficulty, after often wanting 24 hours more even 48 hours
Can be only achieved inherent strength, greatly have impact on production efficiency；And can produce in colloid after reacting due to the silicone rubber of condensed type
Raw little molecule such as methanol, ethanol, acetic acid etc., this micromolecular, during use in the future, progressively separates out under hot environment, from
And make lampshade send out mist or corrode the effect that lampshade generation is bad.Therefore a kind of fast setting bonding use of non-volatile LEDbulb lamp of research
Glue and preparation method thereof is needed for generation.
Summary of the invention
For above-mentioned deficiency, an object of the present invention is, it is provided that a kind of formula is reasonable, even if in airtight environment
Also can fast reaction, and the fast setting non-volatile LEDbulb lamp adhesive glue that produces without little molecule after reacting.
The two of the purpose of the present invention are, for above-mentioned deficiency, it is provided that a kind of can quick Fabrication go out above-mentioned fast setting without
The preparation method of volatilization LEDbulb lamp adhesive glue.
For achieving the above object, technical scheme provided by the present invention is: a kind of non-volatile LEDbulb lamp of fast setting is glued
Connect with glue, include following component according to parts by weight:
Ethenyl blocking polydimethylsiloxane 20～50 parts,
Vinyl MQ silicon resin 30～60 parts,
Linear methyl hydrogen silicone oil 2～15 parts,
Viscosifier 1～5 parts,
Inhibitor 0.1～2.0 parts,
Thixotropic agent 5～60 parts,
Platinum catalyst 0.1～2.0 parts.
As a modification of the present invention, described viscosifier are the 6040 of DOW CORNING, step the A-186 of figure, the A-of figure advanced in years
187, one or more in KH-570 and 1, the 3-diallyl monoglycidyl ether of figure are stepped.
As a modification of the present invention, described inhibitor is ethynylcyclohexanol, 1-methyl butynol, vinyl acetate
Ester, dipropyl maleate one or more.
As a modification of the present invention, described thixotropic agent is hydrophobic type aerosil or polyether modified silicon oil.
As a modification of the present invention, described thixotropic agent is active nano-calcium carbonate.
As a modification of the present invention, it also includes 0.5～5 part of titanium dioxide.
A kind of preparation method of fast setting non-volatile LEDbulb lamp adhesive glue, it comprises the following steps:
(1) component of following parts by weight is prepared: ethenyl blocking polydimethylsiloxane 20～50 parts, Vinyl MQ silicon resin
30～60 parts, linear methyl hydrogen silicone oil 2～15 parts, viscosifier 1～5 parts, inhibitor 0.1～2.0 parts, thixotropic agent 5～60 parts, platinum
Au catalyst 0.1～2.0 parts；
(2) prepare base glue: by 50～100% formula ratio ethenyl blocking polydimethylsiloxane and Vinyl MQ silicon resin add
Entering in kneader, then add in kneader by thixotropic agent, room temperature is warming up to 110～130 DEG C, then after mediating 40～80 minutes
After mediating 1～2 hour under vacuum, stop evacuation and add the ethenyl blocking polydimethylsiloxanes of remaining formula ratio
Alkane and Vinyl MQ silicon resin, to be mixed uniformly after be cooled to room temperature, prepared base glue；
(3) linear methyl hydrogen silicone oil, viscosifier, inhibitor are added base glue, and stir, be subsequently adding platinum catalyst and enter
Row stirs, and prepares fast setting non-volatile LEDbulb lamp adhesive glue after evacuation.
The invention have the benefit that the formula of the fast setting non-volatile LEDbulb lamp adhesive glue that the present invention provides
Rationally, utilize platinum catalyst catalytic reaction to form, though in airtight environment also can fast reaction, and react after without little
Molecule produces, and then meets the mass of current LEDbulb lamp adhesive glue, the condition of high performance production, and LED is effectively ensured
Bulb lamp product quality, without hazing, corroding the phenomenons such as shell, increases the service life；And can be by changing the class of thixotropic agent
Type can obtain translucent or white effect, and to meet different product use demand, motility is high, applied widely；Vinyl
Polymer based on end-blocking polydimethylsiloxane, linear body improves pliability and the hot strength of sizing material；Vinyl MQ silicon tree
Fat is supporting material, can increase the mechanical property of material and improve adhesive force；Thixotropic agent is supporting material, can increase the power of material
Learning performance, viscosifier can improve adhesive force；Linear methyl hydrogen silicone oil is cross-linking agent, can produce the solid glue of three-dimensional netted crosslinking,
Good stability；Platinum catalyst is the carrying out of catalytic reaction, and inhibitor is regulation curing rate, it is achieved quick-setting purpose.
The preparation method that the present invention provides can quickly make fast setting non-volatile LEDbulb lamp adhesive glue goods, and processing step
Succinctly, it is easy to accomplish, productivity ratio is high.
Below in conjunction with embodiment, the present invention is further described.
Detailed description of the invention
Embodiment 1, a kind of fast setting non-volatile LEDbulb lamp adhesive glue that the present embodiment provides, according to weight portion
Count and include following component: ethenyl blocking polydimethylsiloxane 30 parts, Vinyl MQ silicon resin 40 parts, linear methyl hydrogen silicone oil
15 parts, viscosifier 1 part, inhibitor 2 parts, thixotropic agent 5 parts, platinum catalyst 2 parts.Use ethenyl blocking polydimethylsiloxane
Based on polymer, linear body improves the pliability of sizing material and hot strength；Vinyl MQ silicon resin is supporting material, can increase
Add the mechanical property of material and improve adhesive force；Linear methyl hydrogen silicone oil is cross-linking agent, can produce the solid glue of three-dimensional netted crosslinking
Shape, good stability；Platinum catalyst is the carrying out of catalytic reaction.
It is also preferred that the left described viscosifier are preferably the 6040 of DOW CORNING, step the A-186 of figure, the A-187 of figure advanced in years, the KH-of figure advanced in years
One or more in 570 and 1,3-diallyl monoglycidyl ether.Viscosifier can improve adhesive force.Described inhibitor is preferred
For ethynylcyclohexanol, 1-methyl butynol, vinyl acetate, dipropyl maleate one or more.Inhibitor can regulate
Curing rate, it is achieved quick-setting purpose.
In the present embodiment, described thixotropic agent is hydrophobic type aerosil or polyether modified silicon oil, can prepare in semi-transparent
The fast setting non-volatile LEDbulb lamp adhesive glue of obvious results fruit, to meet different product use demand.Thixotropic agent is reinforcing material
Material, mechanical property and the viscosifier that can increase material improve adhesive force；In other embodiments, described thixotropic agent can be that activity is received
Rice calcium carbonate, then adds 0.5～5 part of titanium dioxide, i.e. can obtain the fast setting non-volatile LED ball bubble of white effect
Lamp adhesive glue, motility is high, applied widely.
A kind of preparation method of fast setting non-volatile LEDbulb lamp adhesive glue, it comprises the following steps:
(1) component of following parts by weight is prepared: ethenyl blocking polydimethylsiloxane 30 parts, Vinyl MQ silicon resin 40
Part, linear methyl hydrogen silicone oil 15 parts, viscosifier 1 part, inhibitor 2 parts, thixotropic agent 5 parts, platinum catalyst 2 parts；
(2) prepare base glue: by 50～100% formula ratio ethenyl blocking polydimethylsiloxane and Vinyl MQ silicon resin add
Entering in kneader, then add in kneader by thixotropic agent, room temperature is warming up to 110～130 DEG C, then after mediating 40～80 minutes
After mediating 1～2 hour under vacuum, stop evacuation and add the ethenyl blocking polydimethylsiloxanes of remaining formula ratio
Alkane and Vinyl MQ silicon resin, to be mixed uniformly after be cooled to room temperature, prepared base glue；
(3) linear methyl hydrogen silicone oil, viscosifier, inhibitor are added base glue, and stir, be subsequently adding platinum catalyst and enter
Row stirs, and prepares fast setting non-volatile LEDbulb lamp adhesive glue after evacuation.
Embodiment 2, a kind of fast setting non-volatile LEDbulb lamp adhesive glue of the present embodiment offer and preparation side thereof
Method, it is substantially the same manner as Example 1, and distinctive points is that its composition weight number is than difference: ethenyl blocking poly dimethyl silicon
50 parts of oxygen alkane, Vinyl MQ silicon resin 50 parts, linear methyl hydrogen silicone oil 10 parts, viscosifier 3 parts, inhibitor 1 part, thixotropic agent 30
Part, platinum catalyst 0.9 part, wherein said thixotropic agent is hydrophobic type aerosil.
Embodiment 3, a kind of fast setting non-volatile LEDbulb lamp adhesive glue of the present embodiment offer and preparation side thereof
Method, it is substantially the same manner as Example 1, and distinctive points is that its composition weight number is than difference: ethenyl blocking poly dimethyl silicon
20 parts of oxygen alkane, Vinyl MQ silicon resin 30 parts, linear methyl hydrogen silicone oil 2 parts, viscosifier 5 parts, inhibitor 0.1 part, thixotropic agent 20
Part, platinum catalyst 0.1 part, wherein said thixotropic agent is hydrophobic type aerosil.
Embodiment 4, a kind of fast setting non-volatile LEDbulb lamp adhesive glue of the present embodiment offer and preparation side thereof
Method, it is substantially the same manner as Example 1, and distinctive points is that its composition weight number is than difference: ethenyl blocking poly dimethyl silicon
20 parts of oxygen alkane, Vinyl MQ silicon resin 30 parts, linear methyl hydrogen silicone oil 2 parts, viscosifier 5 parts, inhibitor 0.1 part, thixotropic agent 20
Part, platinum catalyst 0.1 part, 0.5 part of titanium dioxide, wherein said thixotropic agent is active nano-calcium carbonate.
Embodiment 5, a kind of fast setting non-volatile LEDbulb lamp adhesive glue of the present embodiment offer and preparation side thereof
Method, it is substantially the same manner as Example 1, and distinctive points is that its composition weight number is than difference: ethenyl blocking poly dimethyl silicon
25 parts of oxygen alkane, Vinyl MQ silicon resin 55 parts, linear methyl hydrogen silicone oil 13 parts, viscosifier 4 parts, inhibitor 1.5 parts, thixotropic agent 60
Part, platinum catalyst 1.2 parts, 3 parts of titanium dioxides, wherein said thixotropic agent is active nano-calcium carbonate.
Embodiment 6, a kind of fast setting non-volatile LEDbulb lamp adhesive glue of the present embodiment offer and preparation side thereof
Method, it is substantially the same manner as Example 1, and distinctive points is that its composition weight number is than difference: ethenyl blocking poly dimethyl silicon
38 parts of oxygen alkane, Vinyl MQ silicon resin 45 parts, linear methyl hydrogen silicone oil 14 parts, viscosifier 3.5 parts, inhibitor 0.8 part, thixotropic agent
30 parts, platinum catalyst 1.8 parts, 5 parts of titanium dioxides, wherein said thixotropic agent is active nano-calcium carbonate.
Embodiment 7, a kind of fast setting non-volatile LEDbulb lamp adhesive glue of the present embodiment offer and preparation side thereof
Method, it is substantially the same manner as Example 1, and distinctive points is that its composition weight number is than difference: ethenyl blocking poly dimethyl silicon
40 parts of oxygen alkane, Vinyl MQ silicon resin 60 parts, linear methyl hydrogen silicone oil 5 parts, viscosifier 1.8 parts, inhibitor 1.2 parts, thixotropic agent
45 parts, platinum catalyst 1.5 parts, 4 parts of titanium dioxides, wherein said thixotropic agent is active nano-calcium carbonate.
Above-described embodiment is only the preferable embodiment of the present invention, and the present invention can not enumerate out whole embodiment party
Formula, the technical scheme of one of all employing above-described embodiments, or the equivalent variations done according to above-described embodiment, all protect in the present invention
In the range of protecting.
The formula of the fast setting non-volatile LEDbulb lamp adhesive glue that the present invention provides is reasonable, utilizes platinum catalyst
Catalytic reaction forms, though in airtight environment also can fast reaction, and produce without little molecule after reacting, and then meet mesh
The condition that the mass of front LEDbulb lamp adhesive glue, high performance produce, is effectively ensured LEDbulb lamp product quality, without rising
The phenomenons such as mist, corrosion shell, increase the service life, beneficially the synthesized competitiveness of enterprise.
The announcement of book and teaching according to the above description, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula changes and revises.Therefore, the invention is not limited in detailed description of the invention disclosed and described above, to the present invention's
Some modifications and changes should also be as falling in the scope of the claims of the present invention.Although additionally, this specification using
Some specific terms, but these terms are merely for convenience of description, the present invention does not constitute any restriction.Such as the present invention
Described in above-described embodiment, use same or similarity method and component and other compositions of obtaining and preparation method thereof all exists
In scope.
Claims (7)
1. a fast setting non-volatile LEDbulb lamp adhesive glue, it is characterised in that include following group according to parts by weight
Point:
Ethenyl blocking polydimethylsiloxane 20～50 parts,
Vinyl MQ silicon resin 30～60 parts,
Linear methyl hydrogen silicone oil 2～15 parts,
Viscosifier 1～5 parts,
Inhibitor 0.1～2.0 parts,
Thixotropic agent 5～60 parts,
Platinum catalyst 0.1～2.0 parts.
Fast setting the most according to claim 1 non-volatile LEDbulb lamp adhesive glue, it is characterised in that: described thickening
Agent is the 6040 of DOW CORNING, steps the A-186 of figure, the A-187 of figure advanced in years, KH-570 and 1, the 3-diallyl list (+)-2,3-Epoxy-1-propanol of figure advanced in years
One or more in ether.
Fast setting the most according to claim 1 non-volatile LEDbulb lamp adhesive glue, it is characterised in that: described suppression
Agent be ethynylcyclohexanol, 1-methyl butynol, vinyl acetate, dipropyl maleate one or more.
Fast setting the most according to claim 1 non-volatile LEDbulb lamp adhesive glue, it is characterised in that: described thixotroping
Agent is hydrophobic type aerosil or polyether modified silicon oil.
Fast setting the most according to claim 1 non-volatile LEDbulb lamp adhesive glue, it is characterised in that: described thixotroping
Agent is active nano-calcium carbonate.
Fast setting the most according to claim 5 non-volatile LEDbulb lamp adhesive glue, it is characterised in that: it also includes
0.5～5 part of titanium dioxide.
7. the preparation method of a fast setting non-volatile LEDbulb lamp adhesive glue, it is characterised in that: it includes following step
Rapid:
(1) component of following parts by weight is prepared: ethenyl blocking polydimethylsiloxane 20～50 parts, Vinyl MQ silicon resin
30～60 parts, linear methyl hydrogen silicone oil 2～15 parts, viscosifier 1～5 parts, inhibitor 0.1～2.0 parts, thixotropic agent 5～60 parts, platinum
Au catalyst 0.1～2.0 parts；
(2) prepare base glue: by 50～100% formula ratio ethenyl blocking polydimethylsiloxane and Vinyl MQ silicon resin add
Entering in kneader, then add in kneader by thixotropic agent, room temperature is warming up to 110～130 DEG C, then after mediating 40～80 minutes
After mediating 1～2 hour under vacuum, stop evacuation and add the ethenyl blocking polydimethylsiloxanes of remaining formula ratio
Alkane and Vinyl MQ silicon resin, to be mixed uniformly after be cooled to room temperature, prepared base glue；
(3) linear methyl hydrogen silicone oil, viscosifier, inhibitor are added base glue, and stir, be subsequently adding platinum catalyst and enter
Row stirs, and prepares fast setting non-volatile LEDbulb lamp adhesive glue after evacuation.
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| CN201610549162.XA CN106065317A (en) | 2016-07-13 | 2016-07-13 | Fast setting non-volatile LEDbulb lamp adhesive glue and preparation method thereof |
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| CN201610549162.XA CN106065317A (en) | 2016-07-13 | 2016-07-13 | Fast setting non-volatile LEDbulb lamp adhesive glue and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502279A (en) * | 2017-08-11 | 2017-12-22 | 汕头市骏码凯撒有限公司 | A kind of high temperature resistant thixotropy LED packaging plastics and preparation method thereof |
| CN108893092A (en) * | 2018-07-19 | 2018-11-27 | 深圳市希顺有机硅科技有限公司 | Low-temperature fast-curing additional organosilicon is bonded silicon rubber in one kind |
| CN109337640A (en) * | 2018-08-28 | 2019-02-15 | 佛山市南海区长彤新材料科技有限公司 | A kind of MQ resin modified organic silicon packaging glue and preparation method thereof |
| CN111718486A (en) * | 2020-06-22 | 2020-09-29 | 湖北回天新材料股份有限公司 | Thixotropic agent and two-component silicone sealant containing same |
| CN113337127A (en) * | 2021-06-26 | 2021-09-03 | 深圳市华源宏新材料有限公司 | Silicon resin virgin rubber and manufacturing method thereof |
| CN114686161A (en) * | 2022-06-02 | 2022-07-01 | 南宝光电材料(昆山)有限公司 | Organic silicon die bond adhesive and preparation method and application thereof |
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| CN104893600A (en) * | 2015-05-14 | 2015-09-09 | 天津德高化成新材料股份有限公司 | Viscous fluorescent glue film for fast package of light emitting diode and preparation method and application thereof |
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| CN104789186A (en) * | 2015-04-28 | 2015-07-22 | 杭州福斯特光伏材料股份有限公司 | Single-component LED (light-emitting diode) filament thixotrope without oil discharge and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502279A (en) * | 2017-08-11 | 2017-12-22 | 汕头市骏码凯撒有限公司 | A kind of high temperature resistant thixotropy LED packaging plastics and preparation method thereof |
| CN108893092A (en) * | 2018-07-19 | 2018-11-27 | 深圳市希顺有机硅科技有限公司 | Low-temperature fast-curing additional organosilicon is bonded silicon rubber in one kind |
| CN109337640A (en) * | 2018-08-28 | 2019-02-15 | 佛山市南海区长彤新材料科技有限公司 | A kind of MQ resin modified organic silicon packaging glue and preparation method thereof |
| CN111718486A (en) * | 2020-06-22 | 2020-09-29 | 湖北回天新材料股份有限公司 | Thixotropic agent and two-component silicone sealant containing same |
| CN113337127A (en) * | 2021-06-26 | 2021-09-03 | 深圳市华源宏新材料有限公司 | Silicon resin virgin rubber and manufacturing method thereof |
| CN114686161A (en) * | 2022-06-02 | 2022-07-01 | 南宝光电材料(昆山)有限公司 | Organic silicon die bond adhesive and preparation method and application thereof |
| CN114686161B (en) * | 2022-06-02 | 2022-09-23 | 南宝光电材料(昆山)有限公司 | Organic silicon die bond adhesive and preparation method and application thereof |
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Address after: Southern Industrial Village Dalingshan Town in Guangdong province 523000 Dongguan Zhenhua Road stone furniture building 1 floor B District 2 Applicant after: Guangdong Tianxin Mstar Technology Ltd Address before: Southern Industrial Village Dalingshan Town in Guangdong province 523000 Dongguan Zhenhua Road stone furniture building 1 floor B District 2 Applicant before: Dongguan Tianxin Material Co., Ltd. |
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Application publication date: 20161102 |
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