CN106057657A - Multiple imaging method - Google Patents

Multiple imaging method Download PDF

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Publication number
CN106057657A
CN106057657A CN201610585518.5A CN201610585518A CN106057657A CN 106057657 A CN106057657 A CN 106057657A CN 201610585518 A CN201610585518 A CN 201610585518A CN 106057657 A CN106057657 A CN 106057657A
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CN
China
Prior art keywords
polysilicon
fin structure
layer
silicon
side wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610585518.5A
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Chinese (zh)
Inventor
鲍宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Huali Microelectronics Corp
Original Assignee
Shanghai Huali Microelectronics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Huali Microelectronics Corp filed Critical Shanghai Huali Microelectronics Corp
Priority to CN201610585518.5A priority Critical patent/CN106057657A/en
Publication of CN106057657A publication Critical patent/CN106057657A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/033Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
    • H01L21/0334Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
    • H01L21/0337Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment

Abstract

The present invention provides a multiple imaging method. The method comprises: the first step: forming a hard mask layer and a polysilicon layer on a substrate in order; performing imaging of the polysilicon layer to form a polysilicon fin structure; performing surface processing of the top surface and the surface of a first side wall of the polysilicon fin structure while without the surface processing of the surface of the second side wall of the olysilicon fin structure; forming side wall material layers, and forming side wall material layers with different thicknesses on two side walls of the polysilicon; etching the side wall material layers so as to form the first side wall portion with the first thickness on the first side wall of the polysilicon fin structure, forming the second side wall portion with the second thickness different from the first thickness on the second side wall of the polysilicon fin structure; and removing the polysilicon fin structure.

Description

Multiple patterning methods
Technical field
The present invention relates to field of semiconductor manufacture, it is more particularly related to a kind of multiple patterning methods.
Background technology
Side wall transfer (Spacer transfer) is a kind of method of Dual graphing (double patterning), uses To overcome the limit of photoetching.By the width of the side wall that control is formed, obtain homogeneous hard mask.
United States Patent (USP) US7187042B2 proposes to be processed by the surface of fin structure side, can be formed in fin structure both sides The gate dielectric layer of different-thickness.This dissymmetrical structure is used for rear grid (back gate) structure.
But, the processing procedure of prior art is relatively complicated, can't obtain difference by a Dual graphing The hard mask of side wall of width.
Wish to improve the hard mask of side wall that a kind of technical scheme obtains different in width by Dual graphing.
Summary of the invention
The technical problem to be solved is for there is drawbacks described above in prior art, it is provided that one can be multiple Graphic method, the hard mask of side wall obtaining different in width by Dual graphing.
In order to realize above-mentioned technical purpose, according to the present invention, it is provided that a kind of multiple patterning methods, including:
First step: sequentially form hard mask layer and polysilicon layer on substrate;
Second step: be patterned polysilicon layer to form polysilicon fin structure;
Third step: top surface and the first side wall surface to polysilicon fin structure carry out surface process, to polysilicon Second sidewall surfaces of fin structure does not carry out surface process;
4th step: form spacer material layer, form the spacer material layer of different-thickness on two sidewalls of polysilicon;
5th step: the offside walling bed of material performs etching, thus on the first side wall of polysilicon fin structure, form first First sidewall section of thickness, and on the second sidewall of polysilicon fin structure, form second thickness different from the first thickness The second sidewall section;
6th step: remove polysilicon fin structure.
Preferably, described surface processes is that nitrogen gas plasma surface processes.
Preferably, the process of described surface is the ion implanting of silicon or argon.
Preferably, the material of hard mask layer is silicon nitride, and the material of spacer material layer is silicon oxide.
Preferably, the material of hard mask layer is silicon oxide, and the material of spacer material layer is silicon nitride.
In order to realize above-mentioned technical purpose, according to the present invention, additionally provide a kind of multiple patterning methods, including:
First step: sequentially form hard mask layer and polysilicon layer on substrate;
Second step: be patterned polysilicon layer to form polysilicon fin structure;
Third step: top surface and the first side wall surface to polysilicon fin structure carry out first surface process, to many Second sidewall surfaces of crystal silicon fin structure carries out second surface process.
4th step: form spacer material layer;Owing to the process of nitrogen gas plasma surface can make the spacer material of formation Layer is thinning, and the spacer material layer that the introducing of silicon or argon can make formation is thickening, thus can on the two of polysilicon sidewall shape Become the spacer material layer of different-thickness;
5th step: the offside walling bed of material performs etching, thus on the first side wall of polysilicon fin structure, form first First sidewall section of thickness, and on the second sidewall of polysilicon fin structure, form second thickness different from the first thickness The second sidewall section;
6th step: remove polysilicon fin structure.
Preferably, described first surface processes is that nitrogen gas plasma surface processes.
Preferably, the process of described second surface is the ion implanting of silicon or argon.
Preferably, the material of hard mask layer is silicon nitride, and the material of spacer material layer is silicon oxide.
Preferably, the material of hard mask layer is silicon oxide, and the material of spacer material layer is silicon nitride.
Accompanying drawing explanation
In conjunction with accompanying drawing, and by with reference to detailed description below, it will more easily the present invention is had more complete understanding And its adjoint advantage and feature is more easily understood, wherein:
Fig. 1 schematically shows the first step of multiple patterning methods according to the preferred embodiment of the invention.
Fig. 2 schematically shows the second step of multiple patterning methods according to the preferred embodiment of the invention.
Fig. 3 schematically shows the third step of multiple patterning methods according to the preferred embodiment of the invention.
Fig. 4 schematically shows the 4th step of multiple patterning methods according to the preferred embodiment of the invention.
Fig. 5 schematically shows the 5th step of multiple patterning methods according to the preferred embodiment of the invention.
Fig. 6 schematically shows the 6th step of multiple patterning methods according to the preferred embodiment of the invention.
It should be noted that accompanying drawing is used for illustrating the present invention, and the unrestricted present invention.Note, represent that the accompanying drawing of structure can Can be not necessarily drawn to scale.Further, in accompanying drawing, same or like element indicates same or like label.
Detailed description of the invention
In order to make present disclosure more clear and understandable, below in conjunction with specific embodiments and the drawings in the present invention Appearance is described in detail.
<first embodiment>
Fig. 1 to Fig. 6 schematically shows each step of multiple patterning methods according to the preferred embodiment of the invention.
Specifically, as shown in Figures 1 to 6, multiple patterning methods includes according to the preferred embodiment of the invention:
First step: sequentially form hard mask layer 200 and polysilicon layer 300 on the substrate 100;
Second step: be patterned to form polysilicon fin structure 400 to polysilicon layer 300;
Third step: top surface and the first side wall surface to polysilicon fin structure 400 carry out surface process;To polycrystalline Second sidewall surfaces of silicon fin structure 400 does not carry out surface process.
Such as, described surface processes is that nitrogen gas plasma surface processes.Or, such as, described surface process be silicon or The ion implanting of argon.
4th step: form spacer material layer 500;Owing to the process of nitrogen gas plasma surface can make the side wall material of formation The bed of material is thinning, and the spacer material layer that the introducing of silicon or argon can make formation is thickening, so can be on the two of polysilicon sidewall Form the spacer material layer of different-thickness;
Preferably, the material of hard mask layer 200 is silicon nitride, and the material of spacer material layer 500 is silicon oxide.Or, Preferably, the material of hard mask layer 200 is silicon oxide, and the material of spacer material layer 500 is silicon nitride.
5th step: the offside walling bed of material 500 performs etching, thus shape on the first side wall of polysilicon fin structure 400 Become the first sidewall section 600 of the first thickness, and formed with the first thickness not on the second sidewall of polysilicon fin structure 400 Second sidewall section 700 of the second same thickness;
6th step: remove polysilicon fin structure 400.
The present invention, with polysilicon as core, carries out surface process, thus changes the deposition of thick of spacer material layer in its side Degree, obtains the side wall of different in width by Dual graphing.
<the second embodiment>
Impurity can be introduced, it is also possible to introduce the impurity of not same-action in the both sides of polysilicon to increase not with polysilicon side Symmetry.Thus presently describe the impurity introducing not same-action in the both sides of polysilicon to increase being embodied as of unsymmetry Example.
Multiple patterning methods according to second preferred embodiment of the invention includes:
First step: sequentially form hard mask layer 200 and polysilicon layer 300 on the substrate 100;
Second step: be patterned to form polysilicon fin structure 400 to polysilicon layer 300;
Third step: top surface and the first side wall surface to polysilicon fin structure 400 carry out first surface process, right Second sidewall surfaces of polysilicon fin structure 400 carries out second surface process.
Such as, described first surface processes is that nitrogen gas plasma surface processes.Such as, described second surface processes is silicon Or the ion implanting of argon.
4th step: form spacer material layer 500;Owing to the process of nitrogen gas plasma surface can make the side wall material of formation The bed of material is thinning, and the spacer material layer that the introducing of silicon or argon can make formation is thickening, so can be on the two of polysilicon sidewall Form the spacer material layer of different-thickness;
Preferably, the material of hard mask layer 200 is silicon nitride, and the material of spacer material layer 500 is silicon oxide.Or, Preferably, the material of hard mask layer 200 is silicon oxide, and the material of spacer material layer 500 is silicon nitride.
5th step: the offside walling bed of material 500 performs etching, thus shape on the first side wall of polysilicon fin structure 400 Become the first sidewall section 600 of the first thickness, and formed with the first thickness not on the second sidewall of polysilicon fin structure 400 Second sidewall section 700 of the second same thickness;
6th step: remove polysilicon fin structure 400.
The present invention, with polysilicon as core, introduces the impurity of not same-action to increase unsymmetry in the both sides of polysilicon, Thus change the deposit thickness of spacer material layer, the side wall of different in width is obtained by Dual graphing.
Furthermore, it is necessary to explanation, unless stated otherwise or point out, otherwise the term in description " first ", " the Two ", " the 3rd " etc. describe be used only for distinguishing in description each assembly, element, step etc. rather than for representing each Logical relation between assembly, element, step or ordering relation etc..
Although it is understood that the present invention discloses as above with preferred embodiment, but above-described embodiment being not used to Limit the present invention.For any those of ordinary skill in the art, without departing under technical solution of the present invention ambit, Technical solution of the present invention is made many possible variations and modification by the technology contents that all may utilize the disclosure above, or is revised as Equivalent embodiments with change.Therefore, every content without departing from technical solution of the present invention, according to the technical spirit pair of the present invention Any simple modification made for any of the above embodiments, equivalent variations and modification, all still fall within the scope of technical solution of the present invention protection In.

Claims (10)

1. a multiple patterning methods, it is characterised in that including:
First step: sequentially form hard mask layer and polysilicon layer on substrate;
Second step: be patterned polysilicon layer to form polysilicon fin structure;
Third step: top surface and the first side wall surface to polysilicon fin structure carry out surface process, ties polycrystalline silicon fin Second sidewall surfaces of structure does not carry out surface process;
4th step: form spacer material layer, form the spacer material layer of different-thickness on two sidewalls of polysilicon;
5th step: the offside walling bed of material performs etching, thus on the first side wall of polysilicon fin structure, form the first thickness The first sidewall section, and on the second sidewall of polysilicon fin structure, form the of second thickness different from the first thickness Two sidewall section;
6th step: remove polysilicon fin structure.
Multiple patterning methods the most according to claim 1, it is characterised in that it is nitrogen gas plasma that described surface processes Surface processes.
Multiple patterning methods the most according to claim 1, it is characterised in that the process of described surface is the ion of silicon or argon Inject.
Multiple patterning methods the most according to claim 1 and 2, it is characterised in that the material of hard mask layer is nitridation Silicon, the material of spacer material layer is silicon oxide.
Multiple patterning methods the most according to claim 1 and 2, it is characterised in that the material of hard mask layer is oxidation Silicon, the material of spacer material layer is silicon nitride.
6. a multiple patterning methods, it is characterised in that including:
First step: sequentially form hard mask layer and polysilicon layer on substrate;
Second step: be patterned polysilicon layer to form polysilicon fin structure;
Third step: top surface and the first side wall surface to polysilicon fin structure carry out first surface process, to polysilicon Second sidewall surfaces of fin structure carries out second surface process.
4th step: form spacer material layer;The spacer material layer of formation can be made to become owing to nitrogen gas plasma surface processes Thin, and the spacer material layer that the introducing of silicon or argon can make formation is thickening, so can be formed not on the two of polysilicon sidewall The spacer material layer of stack pile;
5th step: the offside walling bed of material performs etching, thus on the first side wall of polysilicon fin structure, form the first thickness The first sidewall section, and on the second sidewall of polysilicon fin structure, form the of second thickness different from the first thickness Two sidewall section;
6th step: remove polysilicon fin structure.
Multiple patterning methods the most according to claim 6, it is characterised in that described first surface processes be nitrogen etc. from Daughter surface processes.
8. according to the multiple patterning methods described in claim 6 or 7, it is characterised in that described second surface process be silicon or The ion implanting of argon.
9. according to the multiple patterning methods described in claim 6 or 7, it is characterised in that the material of hard mask layer is nitridation Silicon, the material of spacer material layer is silicon oxide.
10. according to the multiple patterning methods described in claim 6 or 7, it is characterised in that the material of hard mask layer is oxidation Silicon, the material of spacer material layer is silicon nitride.
CN201610585518.5A 2016-07-22 2016-07-22 Multiple imaging method Pending CN106057657A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109216165A (en) * 2017-07-06 2019-01-15 中芯国际集成电路制造(天津)有限公司 The manufacturing method of multiple graphics and semiconductor devices
CN109309005A (en) * 2017-07-27 2019-02-05 中芯国际集成电路制造(上海)有限公司 Semiconductor structure and forming method thereof
CN112563200A (en) * 2019-09-26 2021-03-26 中芯国际集成电路制造(上海)有限公司 Semiconductor device and method of forming the same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1691294A (en) * 2004-04-28 2005-11-02 国际商业机器公司 Backgated finfet having diferent oxide thicknesses
CN102420574A (en) * 2011-11-22 2012-04-18 上海华力微电子有限公司 Method for improving frequency characteristic of common-source operational amplifier
US20120235247A1 (en) * 2011-03-17 2012-09-20 International Business Machines Corporation Fin field effect transistor with variable channel thickness for threshold voltage tuning
CN103578930A (en) * 2012-07-20 2014-02-12 中芯国际集成电路制造(上海)有限公司 Forming method for multiple graphical mask layer and semiconductor structure

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1691294A (en) * 2004-04-28 2005-11-02 国际商业机器公司 Backgated finfet having diferent oxide thicknesses
US20120235247A1 (en) * 2011-03-17 2012-09-20 International Business Machines Corporation Fin field effect transistor with variable channel thickness for threshold voltage tuning
CN102420574A (en) * 2011-11-22 2012-04-18 上海华力微电子有限公司 Method for improving frequency characteristic of common-source operational amplifier
CN103578930A (en) * 2012-07-20 2014-02-12 中芯国际集成电路制造(上海)有限公司 Forming method for multiple graphical mask layer and semiconductor structure

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109216165A (en) * 2017-07-06 2019-01-15 中芯国际集成电路制造(天津)有限公司 The manufacturing method of multiple graphics and semiconductor devices
CN109216165B (en) * 2017-07-06 2020-11-03 中芯国际集成电路制造(天津)有限公司 Method for manufacturing multiple patterns and semiconductor device
CN109309005A (en) * 2017-07-27 2019-02-05 中芯国际集成电路制造(上海)有限公司 Semiconductor structure and forming method thereof
CN109309005B (en) * 2017-07-27 2022-03-22 中芯国际集成电路制造(上海)有限公司 Semiconductor structure and forming method thereof
CN112563200A (en) * 2019-09-26 2021-03-26 中芯国际集成电路制造(上海)有限公司 Semiconductor device and method of forming the same
CN112563200B (en) * 2019-09-26 2023-12-22 中芯国际集成电路制造(上海)有限公司 Semiconductor device and method of forming the same

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Application publication date: 20161026