CN106049175A - Method for preparing woodgrained paper - Google Patents
Method for preparing woodgrained paper Download PDFInfo
- Publication number
- CN106049175A CN106049175A CN201610385702.5A CN201610385702A CN106049175A CN 106049175 A CN106049175 A CN 106049175A CN 201610385702 A CN201610385702 A CN 201610385702A CN 106049175 A CN106049175 A CN 106049175A
- Authority
- CN
- China
- Prior art keywords
- paper
- modified
- preparation
- resin
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/32—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31F—MECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31F1/00—Mechanical deformation without removing material, e.g. in combination with laminating
- B31F1/07—Embossing, i.e. producing impressions formed by locally deep-drawing, e.g. using rolls provided with complementary profiles
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
- D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
Abstract
The invention discloses a method for preparing woodgrained paper. The method includes the following steps of a, printing, wherein primary-color kraft paper is printed through water-based ink; b, gum dipping, wherein the printed primary-color kraft paper is subjected to gum dipping with modified melamine resin or modified phenolic resin, the modified melamine resin is modified through a plasticizer, and the modified phenolic resin is modified through melamine; c, drying, wherein the primary-color kraft paper subjected to gum dipping is dried; d, hot pressing molding. According to the method, the primary-color kraft paper is adopted, health hazards and environment pollution in the bleaching process of existing products are avoided, the woodgrained paper prepared with the method has the advantages of being heatproof, resistant to flame, free of warping and crazing and easy to clean, color and varieties are various, patterns are rich and attractive, and the color is fresh and bright.
Description
Technical field
The present invention relates to finishing paper technical field, be specifically related to the preparation method of a kind of woodgrained paper.
Background technology
Along with the fast development of the industries such as laminated flooring, dipping paper, face artificial board, furniture and fixtures, finishing paper is used
Amount is continuously increased, and quality improves constantly, and designs and varieties become increasingly abundant.But existing finishing paper is mostly through bleaching and to dye
Journey.Some finishing paper uses oxidative bleaches, such as liquid chlorine, hypochlorite etc., completes discoloration, thus obtains high whiteness
Slurry.Some finishing paper is when preparing paper stock, adds the pigment of different color, dyes.Bleaching and dyeing course are used
Chemicals health is had a certain impact, waste water is dealt with improperly and be will also result in environmental pollution.
Melamine-impregnated resin is respectively put into maceration tank and the second glue spreader by existing melamine impregnated paper
In storage glue groove, body paper is introduced maceration tank carries out impregnation for the first time, be dried for the first time, followed by second time impregnation, the
After secondary dipping, carry out second time and be dried, then cooling and shearing test package warehouse-in.This production process through twice impregnation, two
Secondary dry run, production process is complicated, and the performance of dipping paper also needs to be improved further.
Summary of the invention
In order to solve the problem that above-mentioned prior art exists, it is an object of the invention to provide the preparation side of a kind of woodgrained paper
Method, uses unbleached kraft paper, it is to avoid the health hazard of existing product bleaching process and environmental pollution, the woodgrained paper prepared
Have heat insulation, fire-retardant, not warpage, do not ftracture, the good characteristic such as easy to clean, and designs and varieties are many, pattern enrich attractive in appearance, color and luster is fresh
Gorgeous beautiful.
The present invention is to be achieved through the following technical solutions:
The preparation method of a kind of woodgrained paper, it is characterised in that comprise the steps:
A, printing: unbleached kraft paper is used water color ink printing;
B, impregnation: the unbleached kraft paper modified cyanurotriamide resin after printing or phenol-formaldehyde resin modified are carried out impregnation, wherein,
Described modified cyanurotriamide resin is that plasticizer modification prepares, and described phenol-formaldehyde resin modified is cyanurotriamide modified preparing;
C, be dried: by after impregnation unbleached kraft paper dry;
D, hot-forming.
In step a of the present invention, described unbleached kraft paper uses pure wood pulp production, does not bleaches, and fiber is wrapped in one uniformly
Rising, free from admixture, thus ensure good outward appearance, its grammes per square metre is 40 ~ 80 grams/m, for ensureing preferable printing effect, described
The smoothness of unbleached kraft paper is 115-125.
In step b of the present invention, for increasing the pliability of resin, described modified cyanurotriamide resin is by plasticizer modification system
, described plasticizer is Polyethylene Glycol or diethylene glycol.
For ensureing good impregnation resin content, the solid content of modified cyanurotriamide resin of the present invention is 56-60%;Described change
Property phenolic resin solid content is 52-55%.
The impregnation resin content of woodgrained paper is one of factor directly affecting the performance of decorative panel and cost, when impregnation resin content is less than
200%, the fire resistance of decorative panel is poor, when impregnation resin content is higher than 240%, can cause the waste of dipping solution, therefore, of the present invention
The impregnation resin content of unbleached kraft paper is 200%-240%.
The temperature of baking oven can affect the procuring degree of woodgrained paper, it is preferred that the temperature of drying of the present invention is 125-165
DEG C, the speed of service is 30-35 m/min.Drying area be divided into four control temperature sections, be respectively as follows: low temperature, middle temperature, middle high temperature,
High temperature.The temperature of low temperature exists: 125-130 DEG C, dries some water and low molecular weight volatile thing, it is to avoid woodgrained paper premature cure.Middle temperature,
Middle high temperature, high temperature temperature about at 135-165 DEG C, at this dry at a temperature of, whole drying course ensure resin dried
Journey carries out certain polycondensation reaction, and ensures have a certain proportion of pre-curing resin and uncured resin, thus in hot pressing
Time have good mobility, produce superior in quality decorative panel.
In step d of the present invention, described hot-forming temperature is 135-140 DEG C, and pressure is 12-14kgf, and the time is 5-7
Minute.
Procuring degree and fugitive constituent reflect the quality of resin condensation degree of dissolved in woodgrained paper, determine end product quality and outward appearance
Quality, under above drying process, the procuring degree of woodgrained paper of the present invention is 15%-20%, and fugitive constituent is 7.4%-7.9%.
The present invention compared with prior art, has the following technical effect that
(1) present invention uses unbleached kraft paper to carry out printing decorative pattern as base stock, it is to avoid the healthy danger that bleaching process is brought
Evil
And environmental pollution;Owing to belonging to primary colors, decrease the printing of printing link background color, reduce printing process;Use aqueous
Ink printing, environmental protection;
(2) production process of the present invention is simple, by controlling the technique bars such as impregnation resin content, the temperature of drying, procuring degree, fugitive constituent
Part, the woodgrained paper prepared is mainly used in the armour layer of the wood-based plate such as fibre board, particieboard, the various decoration materials being fabricated to
Material, have heat insulation, fire-retardant, not warpage, do not ftracture, the good characteristic such as easy to clean, and designs and varieties are many, pattern enriches attractive in appearance, color
Pool is bright-coloured beautiful.
Detailed description of the invention
Further illustrating the present invention below by detailed description of the invention, following example are the present invention preferably embodiment,
But embodiments of the present invention are not limited by following embodiment.
Embodiment 1
The preparation method of a kind of woodgrained paper, comprises the steps:
A, printing: be that 40 grams/m of unbleached kraft paper use water color ink printings by grammes per square metre;
B, impregnation: the unbleached kraft paper modified cyanurotriamide resin after printing is carried out impregnation, wherein, described modified melamine
Polyimide resin is to be prepared by Polyethylene Glycol PEG modification;The solid content of described modified cyanurotriamide resin is 56%;Impregnation resin content is 200%;
C, be dried: by after impregnation unbleached kraft paper through drying, then rolling finished product, wherein, the temperature of described drying is
125-165 DEG C, drying area is divided into four to control temperature section, is respectively as follows: low temperature, middle temperature, middle high temperature, high temperature, runs speed
Degree is 60 ms/min;The procuring degree of described woodgrained paper is 15%, and fugitive constituent is 7.7%;
D, hot-forming, described hot-forming temperature is 135 DEG C, and pressure is 14kgf, and the time is 5 minutes.
This product outward appearance becomes Okoume pattern wood grain, smooth clearly.
Embodiment 2
The preparation method of a kind of woodgrained paper, comprises the steps:
A, printing: be that 60 grams/m of unbleached kraft paper use water color ink printings by grammes per square metre;
B, impregnation: the unbleached kraft paper modified cyanurotriamide resin after printing is carried out impregnation, wherein said modified melamine
Polyimide resin is to be prepared by Polyethylene Glycol PEG modification;The solid content of described modified cyanurotriamide resin is 58%;Impregnation resin content is 220%;
C, be dried: by after impregnation unbleached kraft paper through drying, then rolling finished product, wherein, the temperature of described drying is
125-165 DEG C, drying area is divided into four to control temperature section, is respectively as follows: low temperature, middle temperature, middle high temperature, high temperature, and the speed of service is
50 ms/min;The procuring degree of described woodgrained paper is 18%, and fugitive constituent is 7.6%;
D, hot-forming, described hot-forming temperature is 138 DEG C, and pressure is 13kgf, and the time is 6 minutes.
This product outward appearance becomes Okoume pattern wood grain, smooth clearly.
Embodiment 3
The preparation method of a kind of woodgrained paper, comprises the steps:
A, printing: be that 80 grams/m of unbleached kraft paper use water color ink printings by grammes per square metre;
B, impregnation: the unbleached kraft paper modified cyanurotriamide resin after printing is carried out impregnation, wherein, described modified melamine
Polyimide resin is that diethylene glycol DEG modification prepares;The solid content of described modified cyanurotriamide resin is 60%;Impregnation resin content is 240%;
C, be dried: by after impregnation unbleached kraft paper through drying, then rolling finished product, wherein, the temperature of described drying is
125-165 DEG C, drying area is divided into four to control temperature section, is respectively as follows: low temperature, middle temperature, middle high temperature, high temperature, and the speed of service is
35 ms/min;The procuring degree of described woodgrained paper is 20%, and fugitive constituent is 7.9%;
D, hot-forming, described hot-forming temperature is 140 DEG C, and pressure is 12kgf, and the time is 7 minutes.
This product outward appearance becomes Okoume pattern wood grain, smooth clearly.
Embodiment 4
The preparation method of a kind of woodgrained paper, comprises the steps:
A, printing: be that 40 grams/m of unbleached kraft paper use water color ink printings by grammes per square metre;
B, impregnation: the unbleached kraft paper phenol-formaldehyde resin modified after printing is carried out impregnation, and wherein, described phenol-formaldehyde resin modified is
Prepared by cyanurotriamide modified;The solid content of described phenol-formaldehyde resin modified is 54%;Impregnation resin content is 210%;
C, be dried: by after impregnation unbleached kraft paper through drying, then rolling finished product, wherein, the temperature of described drying is
125-165 DEG C, drying area is divided into four to control temperature section, is respectively as follows: low temperature, middle temperature, middle high temperature, high temperature, and the speed of service is
65 ms/min;The procuring degree of described woodgrained paper is 16%, and fugitive constituent is 7.6%;
D, hot-forming, described hot-forming temperature is 135 DEG C, and pressure is 14kgf, and the time is 5 minutes.
This product outward appearance becomes Okoume pattern wood grain, smooth clearly.
Claims (8)
1. the preparation method of a woodgrained paper, it is characterised in that comprise the steps:
A, printing: unbleached kraft paper is used water color ink printing;
B, impregnation: the unbleached kraft paper modified cyanurotriamide resin after printing or phenol-formaldehyde resin modified are carried out impregnation, wherein,
Described modified cyanurotriamide resin is that plasticizer modification prepares, and described phenol-formaldehyde resin modified is cyanurotriamide modified preparing;
C, be dried: by after impregnation unbleached kraft paper dry;
D, hot-forming.
The preparation method of a kind of woodgrained paper the most according to claim 1, it is characterised in that: in step a, described unbleached kraft
Paper is to use pure wood pulp production, does not bleaches, and its grammes per square metre is 40 ~ 80 grams/m, and smoothness is 115-125.
The preparation method of a kind of woodgrained paper the most according to claim 1, it is characterised in that: in step b, described plasticizer is
Polyethylene Glycol or diethylene glycol.
The preparation method of a kind of woodgrained paper the most according to claim 1, it is characterised in that: in step b, described modified trimerization
The solid content of melamine resin is 56-60%, and the solid content of described phenol-formaldehyde resin modified is 52-55%.
The preparation method of a kind of woodgrained paper the most according to claim 1, it is characterised in that: in step b, described unbleached kraft
The impregnation resin content of paper is 200-240%.
The preparation method of a kind of woodgrained paper the most according to claim 1, it is characterised in that: in step c, the temperature of described drying
Degree is for 125-165 DEG C, and drying area is divided into four to control temperature section, is respectively as follows: low temperature, middle temperature, middle high temperature, high temperature, runs speed
Degree is for 30-35 m/min.
The preparation method of a kind of woodgrained paper the most according to claim 1, it is characterised in that: in step d, described hot-forming
Temperature be 135-140 DEG C, pressure is 12-14kgf, and the time is 5-7 minute.
The preparation method of a kind of woodgrained paper the most according to claim 1, it is characterised in that: the procuring degree of described woodgrained paper
For 15%-20%, fugitive constituent is 7.4%-7.9%.
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106835848A (en) * | 2017-03-22 | 2017-06-13 | 山东东宇鸿翔装饰材料有限公司 | 45 grams of preparation methods of facing paper |
CN109235118A (en) * | 2018-09-20 | 2019-01-18 | 方建波 | A kind of preparation method of fire-resistant waterproof glass fiber reinforcement decorative panel |
CN109649065A (en) * | 2018-12-26 | 2019-04-19 | 罗力诚 | A kind of formaldehydeless wood grain paster of high-performance and production technology |
CN109706783A (en) * | 2018-12-26 | 2019-05-03 | 罗力诚 | A kind of formaldehydeless woodgrained paper dipping glue of high-performance and preparation method |
CN109720078A (en) * | 2018-12-28 | 2019-05-07 | 武汉积墨包装印刷有限公司 | A kind of woodgrained paper and its press-paste technique method |
CN109736131A (en) * | 2018-12-11 | 2019-05-10 | 鄢国宾 | It is a kind of for packing the white light paper simulated grain wrapping paper of flowers and trees |
CN111962334A (en) * | 2020-08-28 | 2020-11-20 | 广东福美新材料科技有限公司 | Wear-resistant wood-grain paper and preparation method thereof |
CN112301800A (en) * | 2020-10-30 | 2021-02-02 | 杭州天元诚达装饰材料有限公司 | Electrostatically adsorbable wood grain paper and preparation method thereof |
CN113389347A (en) * | 2021-07-14 | 2021-09-14 | 德尔未来科技控股集团股份有限公司 | High-simulation digital printing decorative paper laminate wood floor and preparation method thereof |
CN113524936A (en) * | 2021-07-14 | 2021-10-22 | 德尔未来科技控股集团股份有限公司 | Preparation method, product and application of high-simulation digital printing impregnated bond paper |
CN113602033A (en) * | 2021-08-20 | 2021-11-05 | 崔荣争 | Preparation method of wear-resistant wood veneer decorative plate |
CN115094672A (en) * | 2022-06-24 | 2022-09-23 | 杭州博思特装饰材料有限公司 | Manufacturing process of wood grain paper |
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CN105383115A (en) * | 2015-10-14 | 2016-03-09 | 太尔胶粘剂(广东)有限公司 | Novel ageing-resistant and combustion-resistant wood-based panel with immersion film paper veneer and preparation method thereof |
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JP2000170361A (en) * | 1998-12-08 | 2000-06-20 | Lg Chem Ltd | Melamine sheet-laminated decorative floor covering material and its manufacture |
CN102650154A (en) * | 2011-02-24 | 2012-08-29 | 徐六峰 | Composite floor board and manufacture method thereof |
CN103171211A (en) * | 2013-03-12 | 2013-06-26 | 河南永威安防股份有限公司 | Granulation-free ecological plate high-pressure decorative surface material and manufacturing method thereof |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106835848A (en) * | 2017-03-22 | 2017-06-13 | 山东东宇鸿翔装饰材料有限公司 | 45 grams of preparation methods of facing paper |
CN109235118A (en) * | 2018-09-20 | 2019-01-18 | 方建波 | A kind of preparation method of fire-resistant waterproof glass fiber reinforcement decorative panel |
CN109736131A (en) * | 2018-12-11 | 2019-05-10 | 鄢国宾 | It is a kind of for packing the white light paper simulated grain wrapping paper of flowers and trees |
CN109706783B (en) * | 2018-12-26 | 2021-09-14 | 罗力诚 | High-performance formaldehyde-free wood-grain paper impregnating glue and preparation method thereof |
CN109649065A (en) * | 2018-12-26 | 2019-04-19 | 罗力诚 | A kind of formaldehydeless wood grain paster of high-performance and production technology |
CN109706783A (en) * | 2018-12-26 | 2019-05-03 | 罗力诚 | A kind of formaldehydeless woodgrained paper dipping glue of high-performance and preparation method |
CN109720078A (en) * | 2018-12-28 | 2019-05-07 | 武汉积墨包装印刷有限公司 | A kind of woodgrained paper and its press-paste technique method |
CN111962334A (en) * | 2020-08-28 | 2020-11-20 | 广东福美新材料科技有限公司 | Wear-resistant wood-grain paper and preparation method thereof |
CN112301800A (en) * | 2020-10-30 | 2021-02-02 | 杭州天元诚达装饰材料有限公司 | Electrostatically adsorbable wood grain paper and preparation method thereof |
CN113389347A (en) * | 2021-07-14 | 2021-09-14 | 德尔未来科技控股集团股份有限公司 | High-simulation digital printing decorative paper laminate wood floor and preparation method thereof |
CN113524936A (en) * | 2021-07-14 | 2021-10-22 | 德尔未来科技控股集团股份有限公司 | Preparation method, product and application of high-simulation digital printing impregnated bond paper |
CN113602033A (en) * | 2021-08-20 | 2021-11-05 | 崔荣争 | Preparation method of wear-resistant wood veneer decorative plate |
CN115094672A (en) * | 2022-06-24 | 2022-09-23 | 杭州博思特装饰材料有限公司 | Manufacturing process of wood grain paper |
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