CN106049101B - A kind of marine alga non-woven fabrics normal temperature quickly contaminates and the method for enhancing ultraviolet resistance - Google Patents
A kind of marine alga non-woven fabrics normal temperature quickly contaminates and the method for enhancing ultraviolet resistance Download PDFInfo
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- CN106049101B CN106049101B CN201610416909.4A CN201610416909A CN106049101B CN 106049101 B CN106049101 B CN 106049101B CN 201610416909 A CN201610416909 A CN 201610416909A CN 106049101 B CN106049101 B CN 106049101B
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- woven fabrics
- marine alga
- copper phthalocyanine
- phthalocyanine pigments
- dyeing
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- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 16
- 230000006750 UV protection Effects 0.000 title claims abstract description 14
- 230000002708 enhancing effect Effects 0.000 title claims abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 45
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 238000010016 exhaust dyeing Methods 0.000 claims abstract description 9
- 238000004043 dyeing Methods 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 15
- VVOPUZNLRVJDJQ-UHFFFAOYSA-N phthalocyanine copper Chemical compound [Cu].C12=CC=CC=C2C(N=C2NC(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2N1 VVOPUZNLRVJDJQ-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- WWSNLNXXISONLQ-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC)Cl(C)(C)C Chemical compound C(CCCCCCCCCCCCCCC)Cl(C)(C)C WWSNLNXXISONLQ-UHFFFAOYSA-N 0.000 claims 1
- 238000002604 ultrasonography Methods 0.000 claims 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 abstract description 3
- 238000007639 printing Methods 0.000 abstract description 3
- 239000004753 textile Substances 0.000 abstract description 2
- 239000003093 cationic surfactant Substances 0.000 abstract 1
- 238000002834 transmittance Methods 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 29
- 235000010443 alginic acid Nutrition 0.000 description 18
- 229920000615 alginic acid Polymers 0.000 description 18
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 16
- 229940072056 alginate Drugs 0.000 description 16
- 239000000975 dye Substances 0.000 description 14
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- 230000005540 biological transmission Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 235000019270 ammonium chloride Nutrition 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000000982 direct dye Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 239000000783 alginic acid Substances 0.000 description 2
- 229960001126 alginic acid Drugs 0.000 description 2
- 150000004781 alginic acids Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 206010003549 asthenia Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- HJORILXJGREZJU-UHFFFAOYSA-L disodium 7-[(5-chloro-2,6-difluoropyrimidin-4-yl)amino]-4-hydroxy-3-[(4-methoxy-2-sulfonatophenyl)diazenyl]naphthalene-2-sulfonate Chemical compound ClC=1C(=NC(=NC1F)F)NC1=CC=C2C(=C(C(=CC2=C1)S(=O)(=O)[O-])N=NC1=C(C=C(C=C1)OC)S(=O)(=O)[O-])O.[Na+].[Na+] HJORILXJGREZJU-UHFFFAOYSA-L 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
- D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The method of ultraviolet resistance is quickly contaminated and strengthened the present invention relates to a kind of marine alga non-woven fabrics, in particular with copper phthalocyanine pigments to the quick dip-dye of marine alga non-woven fabrics and the method for enhancing ultraviolet resistance, belongs to technical field of textile printing.The present invention prepares the tiny copper phthalocyanine pigments of the stable dispersion in water using cationic surfactant hexadecyltrimethylammonium chloride, realize to the quick exhaust dyeing of marine alga non-woven fabrics normal temperature, it can substantially reduce uv transmittance simultaneously, the ultraviolet protection coefficient UPF of non-woven fabrics is significantly improved, so that the ultraviolet resistance of marine alga non-woven fabrics is remarkably reinforced.
Description
Technical field
The method of ultraviolet resistance, particularly profit are quickly contaminated and strengthened the present invention relates to a kind of marine alga non-woven fabrics normal temperature
The method of ultraviolet resistance is quickly contaminated marine alga non-woven fabrics and strengthened with copper phthalocyanine pigments, belongs to textile printing and dyeing technology neck
Domain.
Background technology
Alginate fibre is using the alginic acid isolated in seaweed plants as fiber made of raw material, and its product has good
It is biocompatibility, high-hygroscopicity, high skin-friendly, radiation proof, antiultraviolet, antistatic, inherent flame retardant, antibacterial and deodouring, degradable
The specific functions such as absorption, and resource is very abundant.The production process of alginate fibre is a typical wet spinning process, first
First, sodium alginate is dissolved in water to form sticky spinning solution, and the aqueous solution of calcium chloride etc. is squeezed into after deaeration, filtering.
Because the ion in solidification liquid exchanges with sodium ion in spinning solution, the sodium alginate not soluble in water is set to be precipitated in the form of strand
After obtain as-spun fibre, then stretched, washing, dry, obtain alginate fibre after the processing such as winding.Alginate fibre thickness is equal
Even, longitudinal surface has groove, and lateral cross section is in irregular zigzag.Alginate fibre as a kind of novel biomass regenerated fiber
It is widely used in the fields such as medicine, weaving, printing and dyeing, food, papermaking, wastewater treatment, there is huge development potentiality.At present, permitted
More alginate fibre products are presented in the form of non-woven fabrics, and it is a kind of fabric that need not be spinned cotton and woven cloth and be formed, and is only needed
Marine alga chopped fiber or long filament are oriented or random alignment, fibre net structure is formed, then using mechanical, hot sticky or chemical etc.
Method is reinforced and formed.
Alginate fiber fabric can carry out exhaust dyeing with activity, direct dyes etc., but dyeing temperature is higher, dyeing time
Long, the damage to fiber is also larger.Liu Jie etc. once with dye alginate fibre on Drimarene K-type reactive dye and drew optimization work
Skill condition：Dye dosage 1% (omf), CaC12Dosage 1.0 g/L, 70 DEG C of fixation 40 min, pH 7, on this condition marine alga
The strength loss of fiber is still above 30%.The A of patent of invention CN 103981744 disclose one kind using direct dyes to alginic acid
Calcium fiber salt-free dyeing method, this method need to carry out aluminum sulfate pretreatment to alginate fibre first, then with direct dyes in 70-
30-60min is contaminated at a temperature of 90 DEG C.
Pigment is also a kind of coloring material, but its property has notable difference with dyestuff.Patent of invention CN 103556301A
A kind of method of nano dye to alginate fibre original liquid coloring is disclosed, takes a certain amount of ultra-thin water nano pigment to be added to sea
In algae fiber spinning dope, the alginate fibre of coloring is prepared by wet spinning process.The invention is prepared used in nano dye
Dispersant is the polymeric dispersant containing carboxyl that number-average molecular weight is 2000-8000, and wetting agent used is anionic surface
One kind in activating agent and nonionic surfactant.In addition to original liquid coloring, alginate fiber fabric is contaminated using pigment
The method of dyeing then has no report.
The content of the invention
The present invention is utilized by appropriate cation-modified water-insoluble copper phthalocyanine pigments at normal temperatures to marine alga non-woven fabrics
Quick exhaust dyeing is carried out, dyeing course can be completed within a short period of time, staining efficiency is high, and because copper phthalocyanine pigments exist
Being deposited on marine alga non-woven fabrics fully, can significantly improve the ultraviolet resistance of marine alga non-woven fabrics.
The present invention includes following technique：
（1）Copper phthalocyanine pigments dispersion liquid is prepared, the cetyl front three for accounting for that pigment mass percentage is 15% is added in water
Ammonium chloride is simultaneously sufficiently stirred dissolving, then adds copper phthalocyanine pigments, its quality accounts for the 20% of water quality, is placed in after being sufficiently stirred
60min is handled in ultrasonic disintegrator；
（2）Prepare copper phthalocyanine pigments dyeing liquor and exhaust dyeing is carried out to marine alga non-woven fabrics, added in water above-mentioned scattered
Liquid, phthalocyanine copper mass is accounted for the 0.2-3% of marine alga non-woven fabrics quality to be dyed, marine alga non-woven fabrics is put into, adjustment dye bath ratio is
10:1, in 30 DEG C of upper dye 5-10min；Finally, marine alga non-woven fabrics after dyeing is dehydrated and dried at 60 DEG C.
Copper phthalocyanine pigments hydrophobicity is very strong, not soluble in water, it is necessary to can be just scattered in the aqueous solution simultaneously by surfactant
Form stable suspension.Surfactant used in the present invention is the hexadecyltrimethylammonium chloride of cationic, in aqueous phase
Its band certain amount positive charge can be made with quick adsorption to surface of pigments, acted on by electronic double layer repulsion and accelerate granules of pigments to crush
It is suspending stabilized with promotion.Further, since the substantial amounts of negative electrical charge of alginate fibre band, the copper phthalocyanine pigments particle of positively charged can be normal
Under temperature quickly through boundary layer it is upper dye arrive fiber, realize quick exhaust dyeing, can at utmost reduce fiber be swelled and it is right
The damage of fiber.The mass percent that the dosage of hexadecyltrimethylammonium chloride accounts for pigment have when being 15% it is optimal scattered and
Dyeability.The quality for adding pigment is the 20% of water quality, causes pigment valid density in dispersion liquid low less than the value, and high
It can then cause the significant changes such as system viscosity in this value and make less efficient dispersal.By well-mixed dispersion liquid in the super of routine
60min is handled under sound pulverizer, can be substantially reduced the particle diameter of pigment, pigment is also beneficial to and quickly above contaminates onto alginate fibre.
During dyeing, when amount of pigment is relatively low, only needs 5min to be contaminated on 30 DEG C and finish, when amount of pigment is higher, proper extension
Dyeing time can complete dyeing to 10min at 30 DEG C, realize and the normal temperature of marine alga non-woven fabrics is quickly contaminated.Due to contaminating temperature
It is low, the time is short, alginate fibre degree of swelling is smaller, tiny cationization copper phthalocyanine pigments can preferably deposit to marine alga without
Spin in the space between measuring fiber, the transmissivity of ultraviolet light can be substantially reduced, improve the ultraviolet protection index of fabric, enhancing
The anti-uv-ray of fabric.On the contrary, if long dyeing time, the violent swelling of alginate fibre will hinder face at relatively high temperatures
Material is poor in interfibrous deposition filling, treatment effect.In addition, certain fastness is produced in nonwoven surface if necessary to pigment,
It can then use conventional binder to handle it, improve pigment and the bond strength of marine alga nonwoven surface.
Embodiment
The present invention is further illustrated below by embodiment.
Embodiment 1
（1）Copper phthalocyanine pigments dispersion liquid is prepared, the cetyl front three for accounting for that pigment mass percentage is 15% is added in water
Ammonium chloride is simultaneously sufficiently stirred dissolving, then adds copper phthalocyanine pigments, its quality accounts for the 20% of water quality, is placed in after being sufficiently stirred
60min is handled in ultrasonic disintegrator；
（2）Prepare copper phthalocyanine pigments dyeing liquor and exhaust dyeing is carried out to marine alga non-woven fabrics, added in water above-mentioned scattered
Liquid, phthalocyanine copper mass is accounted for the 0.2% of marine alga non-woven fabrics quality to be dyed, marine alga non-woven fabrics is put into, adjustment dye bath ratio is
10:1, in 30 DEG C of upper dye 5min；Marine alga non-woven fabrics after dyeing is dehydrated and dried at 60 DEG C.
After measured, be unstained marine alga non-woven fabrics ultraviolet transmission rate T (UVA), T (UVB) be 23.37%, 17.04%, it is ultraviolet
Protecting factor UPF be 5.53, through above-mentioned 0.2% copper phthalocyanine pigments quickly contaminate after marine alga non-woven fabrics ultraviolet transmission rate T (UVA),
T (UVB) is reduced to 2.24%, 1.39%, and ultraviolet protection coefficient UPF increases to 74.28.
Embodiment 2
（1）Copper phthalocyanine pigments dispersion liquid is prepared, the cetyl front three for accounting for that pigment mass percentage is 15% is added in water
Ammonium chloride is simultaneously sufficiently stirred dissolving, then adds copper phthalocyanine pigments, its quality accounts for the 20% of water quality, is placed in after being sufficiently stirred
60min is handled in ultrasonic disintegrator；
（2）Prepare copper phthalocyanine pigments dyeing liquor and exhaust dyeing is carried out to marine alga non-woven fabrics, added in water above-mentioned scattered
Liquid, phthalocyanine copper mass is accounted for the 1% of marine alga non-woven fabrics quality to be dyed, marine alga non-woven fabrics is put into, adjustment dye bath ratio is 10:
1, in 30 DEG C of upper dye 8min；Marine alga non-woven fabrics after dyeing is dehydrated and dried at 60 DEG C.
After measured, be unstained marine alga non-woven fabrics ultraviolet transmission rate T (UVA), T (UVB) be 23.37%, 17.04%, it is ultraviolet
Protecting factor UPF is 5.53, the ultraviolet transmission rate T (UVA) of the marine alga non-woven fabrics after above-mentioned 1% copper phthalocyanine pigments rapid dyeing,
T (UVB) is reduced to 0.48%, 0.35%, and ultraviolet protection coefficient UPF increases to 310.95.
Embodiment 3
（1）Copper phthalocyanine pigments dispersion liquid is prepared, the cetyl front three for accounting for that pigment mass percentage is 15% is added in water
Ammonium chloride is simultaneously sufficiently stirred dissolving, then adds copper phthalocyanine pigments, its quality accounts for the 20% of water quality, is placed in after being sufficiently stirred
60min is handled in ultrasonic disintegrator；
（2）Prepare copper phthalocyanine pigments dyeing liquor and exhaust dyeing is carried out to marine alga non-woven fabrics, added in water above-mentioned scattered
Liquid, phthalocyanine copper mass is accounted for the 3% of marine alga non-woven fabrics quality to be dyed, marine alga non-woven fabrics is put into, adjustment dye bath ratio is 10:
1, in 30 DEG C of upper dye 10min；Marine alga non-woven fabrics after dyeing is dehydrated and dried at 60 DEG C.
After measured, be unstained marine alga non-woven fabrics ultraviolet transmission rate T (UVA), T (UVB) be 23.37%, 17.04%, it is ultraviolet
Protecting factor UPF is 5.53, the ultraviolet transmission rate T (UVA) of the marine alga non-woven fabrics after above-mentioned 3% copper phthalocyanine pigments rapid dyeing,
T (UVB) is reduced to 0.08%, 0.06%, and ultraviolet protection coefficient UPF increases to 500.
Claims (1)
1. a kind of marine alga non-woven fabrics quickly contaminates and the method for enhancing ultraviolet resistance, it is characterised in that uses following technique：
（1）Copper phthalocyanine pigments dispersion liquid is prepared, the cetyl trimethyl chlorine for accounting for that pigment mass percentage is 15% is added in water
Change ammonium and be sufficiently stirred dissolving, then add copper phthalocyanine pigments, its quality accounts for the 20% of water quality, and ultrasound is placed in after being sufficiently stirred
60min is handled in pulverizer；
（2）Prepare copper phthalocyanine pigments dyeing liquor and exhaust dyeing is carried out to marine alga non-woven fabrics, above-mentioned dispersion liquid is added in water, is made
Phthalocyanine copper mass accounts for the 0.2-3% of marine alga non-woven fabrics quality to be dyed, and marine alga non-woven fabrics is put into, and adjustment dye bath ratio is 10:1,
In 30 DEG C of upper dye 5-10min；Finally, marine alga non-woven fabrics after dyeing is dehydrated and dried at 60 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610416909.4A CN106049101B (en) | 2016-06-12 | 2016-06-12 | A kind of marine alga non-woven fabrics normal temperature quickly contaminates and the method for enhancing ultraviolet resistance |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610416909.4A CN106049101B (en) | 2016-06-12 | 2016-06-12 | A kind of marine alga non-woven fabrics normal temperature quickly contaminates and the method for enhancing ultraviolet resistance |
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| CN106049101A CN106049101A (en) | 2016-10-26 |
| CN106049101B true CN106049101B (en) | 2018-04-06 |
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| CN108914573A (en) * | 2018-06-19 | 2018-11-30 | 青岛大学 | A method of improving alginic acid non-woven fabrics antibiotic property |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| BE588503A (en) * | 1959-03-13 | 1900-01-01 | ||
| JPH0643562B2 (en) * | 1982-05-06 | 1994-06-08 | 三菱化成株式会社 | Reactive dyes for cellulose fibers |
| JPH07507112A (en) * | 1992-06-04 | 1995-08-03 | チバ‐ガイギー アクチエンゲゼルシャフト | Method for fixing dyes containing at least one polymerizable double bond by UV light |
| CN1153542A (en) * | 1994-05-03 | 1997-07-02 | 巴斯福股份公司 | Use of hydrophilically modified polyisocyanates in field of textiles |
| TW290606B (en) * | 1995-03-17 | 1996-11-11 | Ciba Geigy Ag | |
| KR101533669B1 (en) * | 2009-12-01 | 2015-07-03 | 토요잉크Sc홀딩스주식회사 | Blue-colored composition for color filter, color filter and color display |
| JP2014503647A (en) * | 2010-12-22 | 2014-02-13 | ソルヴェイ（ソシエテ アノニム） | Process for the preparation of products based on copper phthalocyanine (CuPc) particles |
| CN103556301B (en) * | 2013-10-18 | 2016-06-22 | 江南大学 | A kind of nano dye is to the painted method of alginate fibre |
| CN104372690A (en) * | 2014-11-25 | 2015-02-25 | 青岛大学 | Cationic polymer emulsion for dip dyeing of coating |
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2016
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