CN107419351A - A kind of preparation technology of acrylic fiber - Google Patents
A kind of preparation technology of acrylic fiber Download PDFInfo
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- CN107419351A CN107419351A CN201710622686.1A CN201710622686A CN107419351A CN 107419351 A CN107419351 A CN 107419351A CN 201710622686 A CN201710622686 A CN 201710622686A CN 107419351 A CN107419351 A CN 107419351A
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- acrylic fiber
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/40—Modacrylic fibres, i.e. containing 35 to 85% acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D1/00—Treatment of filament-forming or like material
- D01D1/02—Preparation of spinning solutions
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
Abstract
The invention provides a kind of preparation technology of acrylic fiber, the preparation technology comprises the following steps:(1)Spinning moulding;(2)As-spun fibre is shaped into secondary coagulating bath, then carry out cold drawing-off, washing and hot gas spring, total draft multiplying power is less than or equal to 12, and speed is 30 60m/min;Tank temperature is 80 90 DEG C during washing, and washing flow is 3000L/h;(3)Heat drying densification, 60 80 DEG C of wet-bulb temperature, 120 150 DEG C of dry-bulb temperature are carried out to the fiber;(4)Thermal finalization is carried out to the fiber, heat setting temperature is 102 120 DEG C;(5)It is 1.4 1.8 in stretch rate by the tow after sizing by steam chest:Tow is stretched under conditions of 1, the acrylic fiber is made.Invention enhances the flexibility of fiber and thermoelasticity, improves the shrinkage of fiber, obtains 4 grades of acrylic fiber anti-pilling property grade >.
Description
Technical field
The present invention relates to clothes material technology field, and in particular to a kind of preparation technology of acrylic fiber.
Background technology
Acrylic fiber(Polyacrylonitrile fibre)Have the title of artificial wool, have it is soft, bulk, easy dye, it is bright in colour, resistance to
Light, antibacterial, the advantages that damaging by worms is not afraid of it.Elasticity is good, and rebound degree can still keep 65% during elongation 20%, fluffy curling and it is soft, it is warming
Property is higher than wool by 15%, and intensity is higher than wool 1-2.5 times.Sun-proof function admirable, open-air exposure 1 year, intensity only declines 20%.It is fine
190-230 DEG C of softening temperature, the acidproof, antioxidant of energy and common organic solvents are tieed up, but alkali resistance is poor.According to different purposes
It is required that pure can spin or with natural fibre blended, its textile is widely used in fields such as clothes, decorations.
In addition, high-shrinkage fibre has potential highly shrinkable by oneself with it a variety of knit can be made with conventional fibre blending
Thing, have the characteristics that soft, fabric is abundant, plentiful, warmth retention property is good, can also produce unusual luster effect.Therefore, it is high to receive
The market demand of contracting acrylic fibers product is increasingly good.
The phenomenon of fuzz balls can all occur in use in most of synthetic fibers.Although acrylic fibers have U.S. of artificial wool
Reputation, because acrylic fiber macromolecular is in irregular helical conformation, without real crystalline texture, the strength of fiber is than natural
Fiber and regenerated fiber are much higher, and the synthesis speed of its product surface fiber spherolite is more than exfoliation rates, thus frictional force without
In the case that method eliminates fiber spherolite, the fiber spherolite president's phase formed retains on the surface of the fabric, is knitted so as to have a strong impact on
The outward appearance and snugness of fit of thing.At present, the method for reducing acrylic fibers balling-up mainly has:(1) in fiber or fabric face coating one
Layer modification agent, to reduce fabric face pilling.This method subject matter is that finishing agent once fails in fiber surface,
The anti-pilling property of fiber just declines;(2) change in spinning production process by acrylic fiber and reduce pilling, lead to
The fuzz balls performance for crossing control acrylic fiber spinning production process technology condition to change and reduce fiber, but it is ineffective, and
And the dyeability of fiber is poor, it is impossible to meets the requirement of production high-grade fabric, anti-pilling property grade only reaches 3-4 levels.
The content of the invention
The purpose of the present invention is to be directed to problem of the prior art, there is provided a kind of high convergency and the acrylic fiber of anti pilling and its
Preparation technology.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of preparation technology of acrylic fiber, the preparation technology comprise the following steps:
(1)Spinning moulding;
A. required raw material is got out:Weigh acrylonitrile 89-94 parts, vinyl chloride 5-10 parts, vinyl acetate 5-6 parts and metering system sulphur
Sour sodium 0.3-0.5 parts are standby;
B. acrylonitrile, vinyl chloride, vinyl acetate and methylpropene sodium sulfonate are mixed, and the concentration after being mixed is adjusted to 30-
40wt%, in 58-62 DEG C, pH is that aqueous suspension polymerization reaction is carried out continuously under 2.5-3.5 environment;Reacted polymer is through chela
Reaction terminating is closed, deviates from unreacted monomer with stripper, then removes salinity, moisture through water washed filter, after granulating and forming
The powdery polymer that drying obtains and dimethyl acetamide mixed dissolution, filter and spinning solution are made;
C. the spinning solution is heated to 82-90 DEG C by heated device, and the stoste after heating is squeezed from the rectangular opening of spinneret
Go out, extrusion pressure 0.7-0.9MPa, as-spun fibre is formed through double diffusion in coagulating bath;
(2)As-spun fibre is shaped into secondary coagulating bath, then carry out cold drawing-off, washing and hot gas spring, total draft multiplying power is small
In equal to 12, speed 30-60m/min;Tank temperature is 80-90 DEG C during washing, and washing flow is 3000L/h;
(3)Heat drying densification, 60-80 DEG C of wet-bulb temperature, 120-150 DEG C of dry-bulb temperature are carried out to the fiber;
(4)Thermal finalization is carried out to the fiber, heat setting temperature is 102-120 DEG C;
(5)It is 1.4-1.8 in stretch rate by the tow after sizing by steam chest:Tow is stretched under conditions of 1,
The acrylic fiber is made.
Further, the step(1)In, required raw material includes 92 parts of acrylonitrile, 8 parts of vinyl chloride, 5 parts of vinyl acetate and
0.4 part of methylpropene sodium sulfonate.
Further, the step(2), it is necessary to which filament surface after drawing coats smooth agent after completion.
Further, the smooth agent is the compound of nonionic surfactant and cationic surfactant, described
Nonionic surfactant, cationic surfactant, the mol ratio of smooth agent are 2:4:1.
Further, the addition of the smooth agent accounts for the 0.3-0.7% of tow gross mass.
Further, the thermal finalization handles 45-50min under 300-400kPa.
Further, the step(1)The rectangular opening length-width ratio of middle spinneret is 2-13:1, the hole count of spinneret is
10000-40000。
Further, the step(1)The middle temperature into stoste during coagulating bath is 80-90 DEG C, coagulation bath temperature 30-
45℃。
The present invention compared with prior art, has following beneficial effect:
The present invention mixes acrylonitrile, vinyl chloride, vinyl acetate and methylpropene sodium sulfonate according to specific proportioning, poly- through suspending
The steps such as conjunction obtain co-polymer, drop low-fiber glass transition temperature, remaining routinely spinning technique spinning, enhance fiber
Flexibility and thermoelasticity, the shrinkage of fiber is improved, make acrylic fiber be easier to paint, while obtain acrylic fiber anti-pilling property
4 grades of grade >, its hook are by force 0.6 ± 0.2CN/dtex.
Concentration, temperature of the invention by adjusting stoste, concentration, temperature, the internal circulating load of solidification liquid, Reasonable adjustment washing temperature
Degree, drafting multiple, and drying, the temperature of sizing, pressure, and the technological parameter such as draw ratio of high convergency are controlled, make the present invention
The shrinkage of acrylic fiber is high, soft, and rigidity is strong, and resilience, bulkiness, spreadability, hydrophobicity, spinnability are good.This hair
It is bright to have rationally designed spinneret, make the technological process of production smooth, the simulation quality of acrylic fiber is high, makes obtained acrylic fiber
Soft handle, can increase the flexibility and feel of fiber, and and can ensures the shrinkage and resilience of fiber.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of preparation technology of acrylic fiber, it is characterised in that the preparation technology comprises the following steps:
(1)Spinning moulding;
A. required raw material is got out:Weigh 89 parts of acrylonitrile, 5 parts of vinyl chloride, 5 parts of vinyl acetate and methylpropene sodium sulfonate 0.3
Part, it is standby;
B. acrylonitrile, vinyl chloride, vinyl acetate and methylpropene sodium sulfonate are mixed, and the concentration after being mixed is adjusted to
30wt%, in 58 DEG C, pH is that aqueous suspension polymerization reaction is carried out continuously under 2.5 environment;Reacted polymer is through chelatropic reaction
Terminate, deviate from unreacted monomer with stripper, then remove salinity, moisture through water washed filter, through drying after granulating and forming
Obtained powdery polymer and dimethyl acetamide mixed dissolution, filter and spinning solution are made;
C. the spinning solution is heated to 82 DEG C by heated device, and the stoste after heating is extruded from the rectangular opening of spinneret,
Extrusion pressure is 0.7MPa, and as-spun fibre is formed through double diffusion in coagulating bath;
(2)As-spun fibre is shaped into secondary coagulating bath, then carry out cold drawing-off, washing and hot gas spring, total draft multiplying power is small
In equal to 12, speed 30m/min;Tank temperature is 80 DEG C during washing, and washing flow is 3000L/h;
(3)Heat drying densification, 60 DEG C of wet-bulb temperature, 120 DEG C of dry-bulb temperature are carried out to the fiber;
(4)Thermal finalization is carried out to the fiber, heat setting temperature is 102 DEG C;
(5)It is 1.4 in stretch rate by the tow after sizing by steam chest:Tow is stretched under conditions of 1, is made
The acrylic fiber.
The step(2), it is necessary to which filament surface after drawing coats smooth agent after completion.
The smooth agent is the compound of nonionic surfactant and cationic surfactant, the non-ionic surface
Activating agent, cationic surfactant, the mol ratio of smooth agent are 2:4:1.
The addition of the smooth agent accounts for the 0.3% of tow gross mass.
The thermal finalization handles 45-50min under 300kPa.
The step(1)The rectangular opening length-width ratio of middle spinneret is 2:1, the hole count of spinneret is 10000.
The step(1)The middle temperature into stoste during coagulating bath is 80 DEG C, and coagulation bath temperature is 30 DEG C.
Embodiment 2
A kind of preparation technology of acrylic fiber, it is characterised in that the preparation technology comprises the following steps:
(1)Spinning moulding;
A. required raw material is got out:Weigh 94 parts of acrylonitrile, 10 parts of vinyl chloride, 6 parts of vinyl acetate and methylpropene sodium sulfonate 0.5
Part, it is standby;
B. acrylonitrile, vinyl chloride, vinyl acetate and methylpropene sodium sulfonate are mixed, and the concentration after being mixed is adjusted to
40wt%, in 62 DEG C, pH is that aqueous suspension polymerization reaction is carried out continuously under 3.5 environment;Reacted polymer is through chelatropic reaction
Terminate, deviate from unreacted monomer with stripper, then remove salinity, moisture through water washed filter, through drying after granulating and forming
Obtained powdery polymer and dimethyl acetamide mixed dissolution, filter and spinning solution are made;
C. the spinning solution is heated to 90 DEG C by heated device, and the stoste after heating is extruded from the rectangular opening of spinneret,
Extrusion pressure is 0.9MPa, and as-spun fibre is formed through double diffusion in coagulating bath;
(2)As-spun fibre is shaped into secondary coagulating bath, then carry out cold drawing-off, washing and hot gas spring, total draft multiplying power is small
In equal to 12, speed 60m/min;Tank temperature is 90 DEG C during washing, and washing flow is 3000L/h;
(3)Heat drying densification, 80 DEG C of wet-bulb temperature, 150 DEG C of dry-bulb temperature are carried out to the fiber;
(4)Thermal finalization is carried out to the fiber, heat setting temperature is 120 DEG C;
(5)It is 1.8 in stretch rate by the tow after sizing by steam chest:Tow is stretched under conditions of 1, is made
The acrylic fiber.
The step(2), it is necessary to which filament surface after drawing coats smooth agent after completion.
The smooth agent is the compound of nonionic surfactant and cationic surfactant, the non-ionic surface
Activating agent, cationic surfactant, the mol ratio of smooth agent are 2:4:1.
The addition of the smooth agent accounts for the 0.7% of tow gross mass.
The thermal finalization handles 50min under 400kPa.
The step(1)The rectangular opening length-width ratio of middle spinneret is 13:1, the hole count of spinneret is 40000.
The step(1)The middle temperature into stoste during coagulating bath is 90 DEG C, and coagulation bath temperature is 45 DEG C.
Embodiment 3
A kind of preparation technology of acrylic fiber, it is characterised in that the preparation technology comprises the following steps:
(1)Spinning moulding;
A. required raw material is got out:Weigh 92 parts of acrylonitrile, 8 parts of vinyl chloride, 5 parts of vinyl acetate and methylpropene sodium sulfonate 0.4
Part, it is standby;
B. acrylonitrile, vinyl chloride, vinyl acetate and methylpropene sodium sulfonate are mixed, and the concentration after being mixed is adjusted to
35wt%, in 60 DEG C, pH is that aqueous suspension polymerization reaction is carried out continuously under 3 environment;Reacted polymer is whole through chelatropic reaction
Only, deviate from unreacted monomer with stripper, then remove salinity, moisture through water washed filter, through drying after granulating and forming
The powdery polymer arrived and dimethyl acetamide mixed dissolution, filter and spinning solution are made;
C. the spinning solution is heated to 86 DEG C by heated device, and the stoste after heating is extruded from the rectangular opening of spinneret,
Extrusion pressure is 0.8MPa, and as-spun fibre is formed through double diffusion in coagulating bath;
(2)As-spun fibre is shaped into secondary coagulating bath, then carry out cold drawing-off, washing and hot gas spring, total draft multiplying power is small
In equal to 12, speed 45m/min;Tank temperature is 85 DEG C during washing, and washing flow is 3000L/h;
(3)Heat drying densification, 70 DEG C of wet-bulb temperature, 136 DEG C of dry-bulb temperature are carried out to the fiber;
(4)Thermal finalization is carried out to the fiber, heat setting temperature is 111 DEG C;
(5)It is 1.6 in stretch rate by the tow after sizing by steam chest:Tow is stretched under conditions of 1, is made
The acrylic fiber.
The step(2), it is necessary to which filament surface after drawing coats smooth agent after completion.
The smooth agent is the compound of nonionic surfactant and cationic surfactant, the non-ionic surface
Activating agent, cationic surfactant, the mol ratio of smooth agent are 2:4:1.
The addition of the smooth agent accounts for the 0.5% of tow gross mass.
The thermal finalization handles 48min under 350kPa.
The step(1)The rectangular opening length-width ratio of middle spinneret is 7:1, the hole count of spinneret is 30000.
The step(1)The middle temperature into stoste during coagulating bath is 85 DEG C, and coagulation bath temperature is 38 DEG C.
The present invention mixes acrylonitrile, vinyl chloride, vinyl acetate and methylpropene sodium sulfonate according to specific proportioning, through outstanding
The steps such as floating polymerization obtain co-polymer, drop low-fiber glass transition temperature, remaining routinely spinning technique spinning, enhance fibre
The flexibility and thermoelasticity of dimension, the shrinkage of fiber is improved, makes acrylic fiber be easier to paint, while obtain acrylic fiber anti pilling
4 grades of performance rate >, its hook are by force 0.6 ± 0.2CN/dtex.
Concentration, temperature of the invention by adjusting stoste, concentration, temperature, the internal circulating load of solidification liquid, Reasonable adjustment washing temperature
Degree, drafting multiple, and drying, the temperature of sizing, pressure, and the technological parameter such as draw ratio of high convergency are controlled, make the present invention
The shrinkage of acrylic fiber is high, soft, and rigidity is strong, and resilience, bulkiness, spreadability, hydrophobicity, spinnability are good.This hair
It is bright to have rationally designed spinneret, make the technological process of production smooth, the simulation quality of acrylic fiber is high, makes obtained acrylic fiber
Soft handle, can increase the flexibility and feel of fiber, and and can ensures the shrinkage and resilience of fiber.
The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although with reference to the foregoing embodiments
The present invention is described in detail, for those skilled in the art, it still can be to foregoing embodiments institute
The technical scheme of record is modified, or carries out equivalent substitution to which part technical characteristic.It is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (8)
1. a kind of preparation technology of acrylic fiber, it is characterised in that the preparation technology comprises the following steps:
(1)Spinning moulding;
A. required raw material is got out:Weigh acrylonitrile 89-94 parts, vinyl chloride 5-10 parts, vinyl acetate 5-6 parts and metering system sulphur
Sour sodium 0.3-0.5 parts are standby;
B. acrylonitrile, vinyl chloride, vinyl acetate and methylpropene sodium sulfonate are mixed, and the concentration after being mixed is adjusted to 30-
40wt%, in 58-62 DEG C, pH is that aqueous suspension polymerization reaction is carried out continuously under 2.5-3.5 environment;Reacted polymer is through chela
Reaction terminating is closed, deviates from unreacted monomer with stripper, then removes salinity, moisture through water washed filter, after granulating and forming
The powdery polymer that drying obtains and dimethyl acetamide mixed dissolution, filter and spinning solution are made;
C. the spinning solution is heated to 82-90 DEG C by heated device, and the stoste after heating is squeezed from the rectangular opening of spinneret
Go out, extrusion pressure 0.7-0.9MPa, as-spun fibre is formed through double diffusion in coagulating bath;
(2)As-spun fibre is shaped into secondary coagulating bath, then carry out cold drawing-off, washing and hot gas spring, total draft multiplying power is small
In equal to 12, speed 30-60m/min;Tank temperature is 80-90 DEG C during washing, and washing flow is 3000L/h;
(3)Heat drying densification, 60-80 DEG C of wet-bulb temperature, 120-150 DEG C of dry-bulb temperature are carried out to the fiber;
(4)Thermal finalization is carried out to the fiber, heat setting temperature is 102-120 DEG C;
(5)It is 1.4-1.8 in stretch rate by the tow after sizing by steam chest:Tow is stretched under conditions of 1,
The acrylic fiber is made.
A kind of 2. preparation technology of acrylic fiber according to claim 1, it is characterised in that the step(1)In, it is required
Raw material includes 0.4 part of 92 parts of acrylonitrile, 8 parts of vinyl chloride, 5 parts of vinyl acetate and methylpropene sodium sulfonate.
A kind of 3. preparation technology of acrylic fiber according to claim 1, it is characterised in that the step(2)Complete it
Afterwards, it is necessary to which filament surface after drawing coats smooth agent.
4. the preparation technology of a kind of acrylic fiber according to claim 3, it is characterised in that the smooth agent is nonionic
The compound of surfactant and cationic surfactant, the nonionic surfactant, cationic surfactant, put down
The mol ratio of lubrication prescription is 2:4:1.
A kind of 5. preparation technology of acrylic fiber according to claim 3, it is characterised in that the addition of the smooth agent
Account for the 0.3-0.7% of tow gross mass.
6. the preparation technology of a kind of acrylic fiber according to claim 1, it is characterised in that the thermal finalization is in 300-
45-50min is handled under 400kPa.
A kind of 7. preparation technology of acrylic fiber according to claim 1, it is characterised in that the step(1)Middle spinneret
The rectangular opening length-width ratio of plate is 2-13:1, the hole count of spinneret is 10000-40000.
A kind of 8. preparation technology of acrylic fiber according to claim 1, it is characterised in that the step(1)Middle entrance
The temperature of stoste is 80-90 DEG C during coagulating bath, and coagulation bath temperature is 30-45 DEG C.
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CN108385185A (en) * | 2018-02-24 | 2018-08-10 | 中科纺织研究院(青岛)有限公司 | A kind of stone needle health care acrylic fiber |
CN111826764A (en) * | 2020-07-28 | 2020-10-27 | 吴忠德悦纺织科技有限公司 | Preparation method of modified multi-component composite yarn |
CN115182064A (en) * | 2021-04-01 | 2022-10-14 | 中国石油天然气股份有限公司 | Plant antibacterial acrylic fiber and production method thereof |
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CN108385185A (en) * | 2018-02-24 | 2018-08-10 | 中科纺织研究院(青岛)有限公司 | A kind of stone needle health care acrylic fiber |
CN108385185B (en) * | 2018-02-24 | 2021-02-09 | 中科纺织研究院(青岛)有限公司 | Stone needle health acrylic fiber |
CN111826764A (en) * | 2020-07-28 | 2020-10-27 | 吴忠德悦纺织科技有限公司 | Preparation method of modified multi-component composite yarn |
CN115182064A (en) * | 2021-04-01 | 2022-10-14 | 中国石油天然气股份有限公司 | Plant antibacterial acrylic fiber and production method thereof |
CN115182064B (en) * | 2021-04-01 | 2023-12-22 | 中国石油天然气股份有限公司 | Plant antibacterial acrylic fiber and production method thereof |
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