CN106047040A - Water-resistant architectural paint with excellent film-forming properties - Google Patents
Water-resistant architectural paint with excellent film-forming properties Download PDFInfo
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- CN106047040A CN106047040A CN201610496047.0A CN201610496047A CN106047040A CN 106047040 A CN106047040 A CN 106047040A CN 201610496047 A CN201610496047 A CN 201610496047A CN 106047040 A CN106047040 A CN 106047040A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C09D161/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a water-resistant architectural paint with excellent film-forming properties. The architectural paint is prepared from the following raw materials in parts by weight: 5-18 parts of organosilicon-modified phenolic resin, 14-22 parts of bisphenol A unsaturated polyester, 8-15 parts of diphenyletherformalde-hyde resin, 1-2 parts of diamidodiphenylmethane, 3-6 parts of nano diatomite, 2-5 parts of mica powder, 2-10 parts of modified wheat protein, 1-5 parts of fibrous talc powder, 5-15 parts of ethyl acetate, 10-20 parts of triethanolamine and 5-15 parts of epoxypropane. The architectural paint has the advantages of favorable mechanical properties, excellent film-forming properties and favorable water resistance.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of waterproof and that there is excellent filming performance building coating.
Background technology
It is broadly divided into water-repellent paint at architectural used coating, there is waterproof, seepage control function.In actual applications, acid
The impact of rain is increasing, the external coating of architectural needs while there is excellent water resistance, mechanical property and film property
Require the highest.Being exposed to the outermost coating of building at present, the degree that is damaged under the effect of acid rain is relatively big, makes coating to building
The protective capability building body reduces.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of waterproof and has building of excellent filming performance
Building coating, mechanical property is good, and filming performance is excellent, good waterproof performance.
Propose a kind of waterproof of the present invention and there is the building coating of excellent filming performance, its raw material includes by weight:
Effect of Organosilicon-modified Phenol-formaldehyde Resin 5-18 part, bisphenol A-type unsaturated polyester (UP) 14-22 part, diphenyletherformalde-hyde resin 8-15 part, diaminourea
Diphenyl methane 1-2 part, nano diatomite 3-6 part, mica powder 2-5 part, modified wheat albumen 2-10 part, fibrous talc 1-
5 parts, ethyl acetate 5-15 part, triethanolamine 10-20 part, expoxy propane 5-15 part.
Preferably, Effect of Organosilicon-modified Phenol-formaldehyde Resin, bisphenol A-type unsaturated polyester (UP), diphenyletherformalde-hyde resin, modified wheat egg
White weight ratio is 10-13:16-20:10-13:4-8.
Preferably, modified wheat albumen, triethanolamine, ethyl acetate, the weight ratio of expoxy propane are 4-8:12-18:8-
12:8-12.
Preferably, modified wheat albumen, diaminodiphenyl-methane, fibrous talc, nano diatomite, mica powder
Weight ratio is 4-8:1.2-1.8:2-4:4-5:3-4.
Preferably, its raw material includes by weight: Effect of Organosilicon-modified Phenol-formaldehyde Resin 10-13 part, bisphenol A-type unsaturated polyester (UP)
16-20 part, diphenyletherformalde-hyde resin 10-13 part, diaminodiphenyl-methane 1.2-1.8 part, nano diatomite 4-5 part, Muscovitum
Powder 3-4 part, modified wheat albumen 4-8 part, fibrous talc 2-4 part, ethyl acetate 8-12 part, triethanolamine 12-18 part, ring
Ethylene Oxide 8-12 part.
Preferably, modified wheat albumen uses following technique to prepare: by molten to wheat protein, soybean protein isolate, Semen Maydis alcohol
Albumen, deionized water mix homogeneously, microwave treatment, add absolute ethyl alcohol and stirring, add neutral protease, glutamine transaminage
Stirring, regulation system pH value to neutral, stirs, enzyme denaturing, adds Polyethylene Glycol, glycerol, glucose mixing and stirring, regulates body
Be pH value to 8.5-9.5, heating in water bath, de-soak, obtain modified wheat albumen.
Preferably, modified wheat albumen uses following technique to prepare: by molten to wheat protein, soybean protein isolate, Semen Maydis alcohol
Albumen, deionized water mix homogeneously, microwave treatment, addition absolute ethyl alcohol and stirring 60-100min, addition neutral protease,
0.002-0.006 part glutamine transaminage stirring 10-20min, regulation system pH value is to neutral, and 80-90 DEG C is stirred 8-
15min, enzyme denaturing, add Polyethylene Glycol, glycerol, glucose mixing and stirring, regulation system pH value to 8.5-9.5, at 75-85
DEG C heating in water bath 2-10min, de-soak, obtain modified wheat albumen.
Preferably, modified wheat albumen uses following technique to prepare: by weight by 20-40 part wheat protein, 10-20 part
Soybean protein isolate, 5-15 part zein, 100-200 part deionized water mix homogeneously, microwave treatment, add 20-40
Part absolute ethyl alcohol and stirring 60-100min, addition 0.004-0.008 part neutral protease, 0.002-0.006 part glutamine turn ammonia
Enzyme stirring 10-20min, regulation system pH value to neutrality, 80-90 DEG C of stirring 8-15min, enzyme denaturing, addition 2-6 part Polyethylene Glycol,
1-2 part glycerol, 3-5 part glucose mixing and stirring, regulation system pH value to 8.5-9.5, at 75-85 DEG C of heating in water bath 2-
10min, de-soak, obtain modified wheat albumen.
In the present invention, Effect of Organosilicon-modified Phenol-formaldehyde Resin, bisphenol A-type unsaturated polyester (UP) and diphenyletherformalde-hyde resin coordinate to be made
With, can mutually make up respective deficiency, not only filming performance is fabulous, and heat resistance is the most excellent, further with the modification added
Wheat protein effect, filming performance further enhances, and waterproof, flexility is excellent;In modified wheat albumen, Semen Tritici aestivi egg
In vain, soybean protein isolate, zein synergism, can effectively make up respective deficiency, Mechanical Properties of Products is good, film property
Can be excellent, good waterproof performance, soybean protein isolate, wheat protein powder, zein appropriateness enzymolysis under certain condition, can show
Writing and improve mutual dispersibility, cross-link with glutamine transaminage further, emulsifiability is excellent, and toughness is fabulous, and adds
Polyethylene Glycol, glycerol can effectively reduce adjacent inter-chain action with glucose, increase space, and goods toughness further enhances, and soft
Good toughness, water resistance is good, and technique is simple, free from environmental pollution;And modified wheat albumen and triethanolamine, ethyl acetate, epoxy
Propane effect, the compatibility is good, and emulsifying effectiveness is notable, can significantly improve the compatibility between each raw material;Modified wheat albumen and diaminourea
Diphenyl methane is worked in coordination with and fibrous talc, nano diatomite, mica powder effect, not only can form smooth film, and knot
The most extremely strong, excellent with the binding ability of ground, service life is long.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
Propose a kind of waterproof of the present invention and there is the building coating of excellent filming performance, its raw material includes by weight:
Effect of Organosilicon-modified Phenol-formaldehyde Resin 5 parts, bisphenol A-type unsaturated polyester (UP) 22 parts, diphenyletherformalde-hyde resin 8 parts, diamino-diphenyl first
2 parts of alkane, nano diatomite 3 parts, mica powder 5 parts, 2 parts of modified wheat albumen, fibrous talc 5 parts, ethyl acetate 5 parts, three
Ethanolamine 20 parts, expoxy propane 5 parts.
Embodiment 2
Propose a kind of waterproof of the present invention and there is the building coating of excellent filming performance, its raw material includes by weight:
Effect of Organosilicon-modified Phenol-formaldehyde Resin 18 parts, bisphenol A-type unsaturated polyester (UP) 14 parts, diphenyletherformalde-hyde resin 15 parts, diamino-diphenyl
1 part of methane, nano diatomite 6 parts, mica powder 2 parts, modified wheat protein 10 part, fibrous talc 1 part, ethyl acetate 15
Part, triethanolamine 10 parts, expoxy propane 15 parts.
Modified wheat albumen uses following technique to prepare: by wheat protein, soybean protein isolate, zein, go
Ionized water mix homogeneously, microwave treatment, add absolute ethyl alcohol and stirring, add neutral protease, glutamine transaminage stirring, adjust
Joint system pH, to neutral, stirs, enzyme denaturing, adds Polyethylene Glycol, glycerol, glucose mixing and stirring, regulation system pH value
To 8.5-9.5, heating in water bath, de-soak, obtain modified wheat albumen.
Embodiment 3
Propose a kind of waterproof of the present invention and there is the building coating of excellent filming performance, its raw material includes by weight:
Effect of Organosilicon-modified Phenol-formaldehyde Resin 10 parts, bisphenol A-type unsaturated polyester (UP) 20 parts, diphenyletherformalde-hyde resin 10 parts, diamino-diphenyl
1.8 parts of methane, nano diatomite 4 parts, mica powder 4 parts, 4 parts of modified wheat albumen, fibrous talc 4 parts, ethyl acetate 8
Part, triethanolamine 18 parts, expoxy propane 8 parts.
Modified wheat albumen uses following technique to prepare: by weight by 40 parts of wheat protein, 10 parts of soybean protein isolates,
15 parts of zein, 100 parts of deionized water mix homogeneously, microwave treatment, add 40 parts of absolute ethyl alcohol and stirring 60min, add
Entering 0.008 part of neutral protease, 0.002 part of glutamine transaminage stirring 20min, regulation system pH value is to neutral, and 80 DEG C are stirred
Mix 15min, enzyme denaturing, add 2 parts of Polyethylene Glycol, 2 parts of glycerol, 3 parts of glucose mixing and stirring, regulation system pH value to 8.5-
9.5, in 85 DEG C of heating in water bath 2min, de-soak, obtain modified wheat albumen.
Embodiment 4
Propose a kind of waterproof of the present invention and there is the building coating of excellent filming performance, its raw material includes by weight:
Effect of Organosilicon-modified Phenol-formaldehyde Resin 13 parts, bisphenol A-type unsaturated polyester (UP) 16 parts, diphenyletherformalde-hyde resin 13 parts, diamino-diphenyl
1.2 parts of methane, nano diatomite 5 parts, mica powder 3 parts, 8 parts of modified wheat albumen, fibrous talc 2 parts, ethyl acetate 12
Part, triethanolamine 12 parts, expoxy propane 12 parts.
Modified wheat albumen uses following technique to prepare: by weight by 20 parts of wheat protein, 20 parts of soybean protein isolates,
5 parts of zein, 200 parts of deionized water mix homogeneously, microwave treatment, add 20 parts of absolute ethyl alcohol and stirring 100min, add
Entering 0.004 part of neutral protease, 0.006 part of glutamine transaminage stirring 10min, regulation system pH value is to neutral, and 90 DEG C are stirred
Mix 8min, enzyme denaturing, add 6 parts of Polyethylene Glycol, 1 part of glycerol, 5 parts of glucose mixing and stirring, regulation system pH value to 8.5-
9.5, in 75 DEG C of heating in water bath 10min, de-soak, obtain modified wheat albumen.
Embodiment 5
Propose a kind of waterproof of the present invention and there is the building coating of excellent filming performance, its raw material includes by weight:
Effect of Organosilicon-modified Phenol-formaldehyde Resin 12 parts, bisphenol A-type unsaturated polyester (UP) 18 parts, diphenyletherformalde-hyde resin 11 parts, diamino-diphenyl
1.5 parts of methane, nano diatomite 4.5 parts, mica powder 3.5 parts, 6 parts of modified wheat albumen, fibrous talc 3 parts, acetic acid second
Ester 10 parts, triethanolamine 15 parts, expoxy propane 10 parts.
Modified wheat albumen uses following technique to prepare: by weight by 30 parts of wheat protein, 15 parts of soybean protein isolates,
10 parts of zein, 150 parts of deionized water mix homogeneously, microwave treatment, add 30 parts of absolute ethyl alcohol and stirring 80min, add
Entering 0.006 part of neutral protease, 0.004 part of glutamine transaminage stirring 15min, regulation system pH value is to neutral, and 85 DEG C are stirred
Mixing 12min, enzyme denaturing, add 4 parts of Polyethylene Glycol, 1.5 parts of glycerol, 4 parts of glucose mixing and stirring, regulation system pH value is extremely
8.5-9.5, in 80 DEG C of heating in water bath 6min, de-soak, obtains modified wheat albumen.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (8)
1. one kind waterproof and there is the building coating of excellent filming performance, it is characterised in that its raw material includes by weight: organic
Si modification phenolic resin 5-18 part, bisphenol A-type unsaturated polyester (UP) 14-22 part, diphenyletherformalde-hyde resin 8-15 part, diaminourea hexichol
Methylmethane 1-2 part, nano diatomite 3-6 part, mica powder 2-5 part, modified wheat albumen 2-10 part, fibrous talc 1-5 part,
Ethyl acetate 5-15 part, triethanolamine 10-20 part, expoxy propane 5-15 part.
The most according to claim 1 waterproof and there is the building coating of excellent filming performance, it is characterised in that organosilicon changes
Property phenolic resin, bisphenol A-type unsaturated polyester (UP), diphenyletherformalde-hyde resin, the weight ratio of modified wheat albumen are 10-13:16-
20:10-13:4-8.
The most according to claim 1 and 2 waterproof and there is the building coating of excellent filming performance, it is characterised in that modified
Wheat protein, triethanolamine, ethyl acetate, the weight ratio of expoxy propane are 4-8:12-18:8-12:8-12.
4. according to waterproof described in any one of claim 1-3 and the building coating with excellent filming performance, it is characterised in that
Modified wheat albumen, diaminodiphenyl-methane, fibrous talc, nano diatomite, the weight ratio of mica powder are 4-8:
1.2-1.8:2-4:4-5:3-4.
5. according to waterproof described in any one of claim 1-4 and the building coating with excellent filming performance, it is characterised in that
Its raw material includes by weight: Effect of Organosilicon-modified Phenol-formaldehyde Resin 10-13 part, bisphenol A-type unsaturated polyester (UP) 16-20 part, diphenyl ether
Formaldehyde resin 10-13 part, diaminodiphenyl-methane 1.2-1.8 part, nano diatomite 4-5 part, mica powder 3-4 part, modified little
Aleuronat 4-8 part, fibrous talc 2-4 part, ethyl acetate 8-12 part, triethanolamine 12-18 part, expoxy propane 8-12 part.
6. according to waterproof described in any one of claim 1-5 and the building coating with excellent filming performance, it is characterised in that
Modified wheat albumen uses following technique to prepare: wheat protein, soybean protein isolate, zein, deionized water are mixed
Close uniformly, microwave treatment, add absolute ethyl alcohol and stirring, add neutral protease, glutamine transaminage stirring, regulation system pH
Value, to neutral, stirs, enzyme denaturing, adds Polyethylene Glycol, glycerol, glucose mixing and stirring, regulation system pH value to 8.5-
9.5, heating in water bath, de-soak, obtain modified wheat albumen.
7. according to waterproof described in any one of claim 1-6 and the building coating with excellent filming performance, it is characterised in that
Modified wheat albumen uses following technique to prepare: wheat protein, soybean protein isolate, zein, deionized water are mixed
Close uniformly, microwave treatment, add absolute ethyl alcohol and stirring 60-100min, add neutral protease, 0.002-0.006 part glutamy
Amine transaminase stirs 10-20min, regulation system pH value to neutrality, 80-90 DEG C of stirring 8-15min, enzyme denaturing, addition Polyethylene Glycol,
Glycerol, glucose mixing and stirring, regulation system pH value to 8.5-9.5, at 75-85 DEG C of heating in water bath 2-10min, de-soak,
Obtain modified wheat albumen.
8. according to waterproof described in any one of claim 1-7 and the building coating with excellent filming performance, it is characterised in that
Modified wheat albumen uses following technique to prepare: by weight by 20-40 part wheat protein, 10-20 part soybean protein isolate, 5-
15 parts of zein, 100-200 part deionized water mix homogeneously, microwave treatment, add 20-40 part absolute ethyl alcohol and stirring
60-100min, adds 0.004-0.008 part neutral protease, 0.002-0.006 part glutamine transaminage stirring 10-
20min, regulation system pH value to neutral, 80-90 DEG C of stirring 8-15min, enzyme denaturing, add 2-6 part Polyethylene Glycol, 1-2 part glycerol,
3-5 part glucose mixing and stirring, regulation system pH value to 8.5-9.5, at 75-85 DEG C of heating in water bath 2-10min, de-soak,
Obtain modified wheat albumen.
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CN201610496047.0A CN106047040A (en) | 2016-06-29 | 2016-06-29 | Water-resistant architectural paint with excellent film-forming properties |
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CN106674709A (en) * | 2016-12-09 | 2017-05-17 | 晋源电气集团股份有限公司 | Cable with good toughness and excellent thermal stability |
CN106700282A (en) * | 2016-12-09 | 2017-05-24 | 晋源电气集团股份有限公司 | Anti-aging cable with excellent toughness |
CN107057499A (en) * | 2017-05-31 | 2017-08-18 | 合肥绿洁环保科技有限公司 | A kind of environmental-friendly aqueous coating |
CN107337944A (en) * | 2017-08-01 | 2017-11-10 | 惠安县科联农业科技有限公司 | A kind of building coating with Air purification and preparation method thereof |
CN109401530A (en) * | 2018-09-12 | 2019-03-01 | 安徽康瑞高科新材料技术工程有限公司 | A kind of epoxy finish and preparation method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106674709A (en) * | 2016-12-09 | 2017-05-17 | 晋源电气集团股份有限公司 | Cable with good toughness and excellent thermal stability |
CN106700282A (en) * | 2016-12-09 | 2017-05-24 | 晋源电气集团股份有限公司 | Anti-aging cable with excellent toughness |
CN107057499A (en) * | 2017-05-31 | 2017-08-18 | 合肥绿洁环保科技有限公司 | A kind of environmental-friendly aqueous coating |
CN107337944A (en) * | 2017-08-01 | 2017-11-10 | 惠安县科联农业科技有限公司 | A kind of building coating with Air purification and preparation method thereof |
CN109401530A (en) * | 2018-09-12 | 2019-03-01 | 安徽康瑞高科新材料技术工程有限公司 | A kind of epoxy finish and preparation method thereof |
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Application publication date: 20161026 |