CN103725150A - Novel fireproof paint - Google Patents
Novel fireproof paint Download PDFInfo
- Publication number
- CN103725150A CN103725150A CN201310719311.9A CN201310719311A CN103725150A CN 103725150 A CN103725150 A CN 103725150A CN 201310719311 A CN201310719311 A CN 201310719311A CN 103725150 A CN103725150 A CN 103725150A
- Authority
- CN
- China
- Prior art keywords
- parts
- resin
- carbon black
- weight
- unsaturated polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title abstract description 4
- 238000000576 coating method Methods 0.000 claims abstract description 33
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000011248 coating agent Substances 0.000 claims abstract description 32
- 239000006229 carbon black Substances 0.000 claims abstract description 28
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 20
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 17
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 claims abstract description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000001257 hydrogen Substances 0.000 claims abstract description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 13
- 239000001301 oxygen Substances 0.000 claims abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000019241 carbon black Nutrition 0.000 claims description 25
- 229910052796 boron Inorganic materials 0.000 claims description 19
- 230000009970 fire resistant effect Effects 0.000 claims description 15
- -1 boron modified phenolic resin Chemical class 0.000 claims description 11
- 239000005011 phenolic resin Substances 0.000 claims description 8
- 229920001568 phenolic resin Polymers 0.000 claims description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 abstract 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Abstract
The invention discloses novel fireproof paint comprising the following raw materials in parts by weight: 25-40 parts of boron-modified phenolic resin, 10-15 parts of M-unsaturated polyester resin, 12-20 parts of formaldehyde resin, 6-10 parts of ortho-xylene, 10-14 parts of ethylbenzene, 3-7 parts of dilauryl thiodipropionate, 2-4 parts of carbon black, and 2-6 parts of diaminodiphenyl-methane, wherein the content of oxygen in the carbon black is 0.75-3.5%, and the content of hydrogen in the carbon black is 0.5-0.7%. The novel fireproof paint disclosed by the invention is excellent in fireproof performance, good in coating performance, relatively low in cost and long in service life.
Description
Technical field
The present invention relates to technical field of coatings, relate in particular to a kind of Novel fire-resistant coating.
Background technology
High-temperature resistant coating refers in a specified time, in certain temperature section, can stand the coating of hot environment oxidation corrosion, thereby protection coated article can at high temperature normally be worked, for flammable substrates surface, can reduce the combustibility that is coated with material surface, the rapid spread of retardance fire, or for non-combustible substrate surface, in order to improve a kind of speciality coating that is coated with material fire endurance, frie retardant coating is coated in substrate surface, except thering is fire retardation, also have antirust, waterproof, anticorrosion, wear-resisting and resistance toheat, its coating has tenacity, tint permanence, adhesion, easily dryness and certain gloss, can be widely used in iron and steel manufacture, metallurgical, petroleum industry, Natural gas extraction, the industrial circles such as aerospace, though produced multiple refractory paint at present, still can not meet demand, how to prepare a kind of fire performance excellence, spreading property is good, can meet the coating of fire performance under special conditions and become the current technical issues that need to address.
Summary of the invention
The present invention proposes a kind of Novel fire-resistant coating, its fire performance excellence, cost is lower, long service life.
A kind of Novel fire-resistant coating that the present invention proposes, its raw material comprises by weight: boron modified phenolic resin 25-40 part, metaphenylene unsaturated polyester resin 10-15 part, diphenyletherformalde-hyde resin 12-20 part, o-Xylol 6-10 part, ethylbenzene 10-14 part, Tyox B 3-7 part, carbon black 2-4 part, diaminodiphenyl-methane 2-6 part, wherein the oxygen level of carbon black is 0.75-3.5%, and hydrogen content is 0.5-0.7%.
In specific embodiment, the weight part of boron modified phenolic resin can be 25, 26.4, 27, 28.4, 30, 32, 33, 35, 37, 38, 40, the weight part of metaphenylene unsaturated polyester resin can be 10, 10.7, 11, 12, 12.5, 13, 14, 14.4, 15, the weight part of diphenyletherformalde-hyde resin can be 12, 13, 15, 15.8, 16, 17, 17.5, 18, 19, 19.3, 20, the weight part of o-Xylol can be 6, 6.8, 7, 8, 8.5, 9, 9.3, 9.6, 10, the weight part of ethylbenzene can be 10, 10.7, 11, 12, 12.5, 13, 13.3, 13.6, 13.8, 14, the weight part of Tyox B can be 3, 3.7, 4, 4.4, 5, 5.3, 5.8, 6, 6.7, 7, the weight part of carbon black can be 2, 2.2, 2.5, 2.8, 3, 3.2, 3.5, 3.6, 3.8, 3.9, 4, the weight part of diaminodiphenyl-methane can be 2, 2.3, 2.8, 3, 3.7, 4, 4.3, 4.5, 5, 5.8, 6.
Preferably, boron modified phenolic resin, metaphenylene unsaturated polyester resin and diphenyletherformalde-hyde resin three's total weight parts is no less than 50 parts, and the weight ratio of boron modified phenolic resin, metaphenylene unsaturated polyester resin and diphenyletherformalde-hyde resin can be (7-8): (2-3): 3.
Preferably, the weight ratio of o-Xylol and ethylbenzene is 0.5-0.85.
Preferably, its raw material comprises by weight: boron modified phenolic resin 30-35 part, metaphenylene unsaturated polyester resin 13-15 part, diphenyletherformalde-hyde resin 16-18 part, o-Xylol 8-9 part, ethylbenzene 13-14 part, Tyox B 5-6 part, carbon black 3.5-4 part, diaminodiphenyl-methane 4-5 part, wherein the oxygen level of carbon black is 2.7%, and hydrogen content is 0.65%.
Preferably, its raw material comprises by weight: 32 parts of boron modified phenolic resins, 14 parts of metaphenylene unsaturated polyester resins, 17 parts of diphenyletherformalde-hyde resins, 8 parts of o-Xylols, 13.6 parts, ethylbenzene, 5.8 parts of Tyox Bs, 3.8 parts of carbon blacks, 4.3 parts of diaminodiphenyl-methanes, wherein the oxygen level of carbon black is 2.7%, and hydrogen content is 0.65%.
In the present invention, use boron modified phenolic resin, metaphenylene unsaturated polyester resin and diphenyletherformalde-hyde resin are as the base material of novel refractory, ratio by rational proportion three in raw material, and control three's shared gross weight in raw material, make the heat decomposition temperature of coating apparently higher than common coating, can greatly strengthen the fire performance of coating, Tyox B high temperature process is difficult for decomposing, it is with even dimethylbenzene and toluene mix use, the dilution of coating and steadily volatilize effective, can form more level and smooth film, in the present invention, the fire performance excellence of described high-strength wearable coating, spreading property is good, cost is lower, work-ing life is longer.
Embodiment
Embodiment 1
In the present embodiment, a kind of Novel fire-resistant coating, its raw material comprises by weight: 25 parts of boron modified phenolic resins, 14.4 parts of metaphenylene unsaturated polyester resins, 13 parts of diphenyletherformalde-hyde resins, 6.8 parts of o-Xylols, 13.8 parts, ethylbenzene, 3.7 parts of Tyox Bs, 4 parts of carbon blacks, 2 parts of diaminodiphenyl-methanes, wherein the oxygen level of carbon black is 1.2%, hydrogen content is 0.58%.
Embodiment 2
In the present embodiment, a kind of Novel fire-resistant coating, its raw material comprises by weight: 26.4 parts of boron modified phenolic resins, 14 parts of metaphenylene unsaturated polyester resins, 15.8 parts of diphenyletherformalde-hyde resins, 8.5 parts of o-Xylols, 13.3 parts, ethylbenzene, 4.4 parts of Tyox Bs, 3.8 parts of carbon blacks, 2.8 parts of diaminodiphenyl-methanes, wherein the oxygen level of carbon black is 0.75%, hydrogen content is 0.63%.
Embodiment 3
In the present embodiment, a kind of Novel fire-resistant coating, its raw material comprises by weight: 28.4 parts of boron modified phenolic resins, 12.5 parts of metaphenylene unsaturated polyester resins, 17.5 parts of diphenyletherformalde-hyde resins, 9 parts of o-Xylols, 13 parts, ethylbenzene, 5.3 parts of Tyox Bs, 3.5 parts of carbon blacks, diaminodiphenyl-methane 2-6 part, wherein the oxygen level of carbon black is 2.4%, hydrogen content is 0.7%.
Embodiment 4
In the present embodiment, a kind of Novel fire-resistant coating, its raw material comprises by weight: 35 parts of boron modified phenolic resins, 10.7 parts of metaphenylene unsaturated polyester resins, 19.3 parts of diphenyletherformalde-hyde resins, 9.3 parts of o-Xylols, 12.5 parts, ethylbenzene, 5.8 parts of Tyox Bs, 2.8 parts of carbon blacks, diaminodiphenyl-methane 2-6 part, wherein the oxygen level of carbon black is 1.09%, hydrogen content is 0.55%.
Embodiment 5
In the present embodiment, a kind of Novel fire-resistant coating, its raw material comprises by weight: 38 parts of boron modified phenolic resins, 10 parts of metaphenylene unsaturated polyester resins, 20 parts of diphenyletherformalde-hyde resins, 9.6 parts of o-Xylols, 10.7 parts, ethylbenzene, 6.7 parts of Tyox Bs, 2.2 parts of carbon blacks, diaminodiphenyl-methane 2-6 part, wherein the oxygen level of carbon black is 3.5%, hydrogen content is 0.5%.
Embodiment 6
In the present embodiment, a kind of Novel fire-resistant coating, its raw material comprises by weight: 32 parts of boron modified phenolic resins, 14 parts of metaphenylene unsaturated polyester resins, 17 parts of diphenyletherformalde-hyde resins, 8 parts of o-Xylols, 13.6 parts, ethylbenzene, 5.8 parts of Tyox Bs, 3.8 parts of carbon blacks, 4.3 parts of diaminodiphenyl-methanes, wherein the oxygen level of carbon black is 2.7%, hydrogen content is 0.65%.
In embodiment 1-6, use boron modified phenolic resin, metaphenylene unsaturated polyester resin and diphenyletherformalde-hyde resin are as the base material of novel refractory, ratio by rational proportion three in raw material, and control three's shared gross weight in raw material, make the heat decomposition temperature of coating apparently higher than common coating, can greatly strengthen the fire performance of coating, Tyox B high temperature process is difficult for decomposing, it is with even dimethylbenzene and toluene mix use, the dilution of coating and steadily volatilize effective, can form more level and smooth film, in the present invention, the fire performance excellence of described high-strength wearable coating, spreading property is good, cost is lower, work-ing life is longer.
The above; it is only preferably embodiment of the present invention; but protection scope of the present invention is not limited to this; any be familiar with those skilled in the art the present invention disclose technical scope in; according to technical scheme of the present invention and inventive concept thereof, be equal to replacement or changed, within all should being encompassed in protection scope of the present invention.
Claims (5)
1. a Novel fire-resistant coating, it is characterized in that, its raw material comprises by weight: boron modified phenolic resin 25-40 part, metaphenylene unsaturated polyester resin 10-15 part, diphenyletherformalde-hyde resin 12-20 part, o-Xylol 6-10 part, ethylbenzene 10-14 part, Tyox B 3-7 part, carbon black 2-4 part, diaminodiphenyl-methane 2-6 part, wherein the oxygen level of carbon black is 0.75-3.5%, hydrogen content is 0.5-0.7%.
2. Novel fire-resistant coating according to claim 1, it is characterized in that, boron modified phenolic resin, metaphenylene unsaturated polyester resin and diphenyletherformalde-hyde resin three's total weight parts is no less than 50 parts, and the weight ratio of boron modified phenolic resin, metaphenylene unsaturated polyester resin and diphenyletherformalde-hyde resin can be (7-8): (2-3): 3.
3. Novel fire-resistant coating according to claim 1, is characterized in that, the weight ratio of o-Xylol and ethylbenzene is 0.5-0.85.
4. Novel fire-resistant coating according to claim 1, it is characterized in that, its raw material comprises by weight: boron modified phenolic resin 30-35 part, metaphenylene unsaturated polyester resin 13-15 part, diphenyletherformalde-hyde resin 16-18 part, o-Xylol 8-9 part, ethylbenzene 13-14 part, Tyox B 5-6 part, carbon black 3.5-4 part, diaminodiphenyl-methane 4-5 part, the oxygen level of carbon black is 2.7%, hydrogen content is 0.65%.
5. Novel fire-resistant coating according to claim 4, it is characterized in that, its raw material comprises by weight: 32 parts of boron modified phenolic resins, 14 parts of metaphenylene unsaturated polyester resins, 17 parts of diphenyletherformalde-hyde resins, 8 parts of o-Xylols, 13.6 parts, ethylbenzene, 5.8 parts of Tyox Bs, 3.8 parts of carbon blacks, 4.3 parts of diaminodiphenyl-methanes, the oxygen level of carbon black is 2.7%, hydrogen content is 0.65%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310719311.9A CN103725150B (en) | 2013-12-23 | 2013-12-23 | A kind of refractory paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310719311.9A CN103725150B (en) | 2013-12-23 | 2013-12-23 | A kind of refractory paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103725150A true CN103725150A (en) | 2014-04-16 |
| CN103725150B CN103725150B (en) | 2015-09-30 |
Family
ID=50449458
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310719311.9A Active CN103725150B (en) | 2013-12-23 | 2013-12-23 | A kind of refractory paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103725150B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009853A (en) * | 2016-06-29 | 2016-10-12 | 芜湖县双宝建材有限公司 | Waterproof architectural coating with excellent mechanical property |
| CN106047040A (en) * | 2016-06-29 | 2016-10-26 | 芜湖县双宝建材有限公司 | Water-resistant architectural paint with excellent film-forming properties |
| CN107177270A (en) * | 2017-05-22 | 2017-09-19 | 如皋市下原科技创业服务有限公司 | A kind of Novel fireproof paint |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3969291A (en) * | 1974-03-06 | 1976-07-13 | Sumitomo Chemical Company, Limited | Intumescent fire-retardant coating compositions containing amide-polyphosphates |
| WO2003066749A1 (en) * | 2002-02-09 | 2003-08-14 | W. & J. Leigh & Co., | Radiation curable intumescent coatings |
| CN1552784A (en) * | 2003-12-18 | 2004-12-08 | 中国化工建设总公司常州涂料化工研究 | High temperature resistant paint for glass fibre reinforced plastic grille |
| CN102702962A (en) * | 2012-06-14 | 2012-10-03 | 天长市银狐漆业有限公司 | Expansion type fire-retardant coating |
-
2013
- 2013-12-23 CN CN201310719311.9A patent/CN103725150B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3969291A (en) * | 1974-03-06 | 1976-07-13 | Sumitomo Chemical Company, Limited | Intumescent fire-retardant coating compositions containing amide-polyphosphates |
| WO2003066749A1 (en) * | 2002-02-09 | 2003-08-14 | W. & J. Leigh & Co., | Radiation curable intumescent coatings |
| CN1552784A (en) * | 2003-12-18 | 2004-12-08 | 中国化工建设总公司常州涂料化工研究 | High temperature resistant paint for glass fibre reinforced plastic grille |
| CN102702962A (en) * | 2012-06-14 | 2012-10-03 | 天长市银狐漆业有限公司 | Expansion type fire-retardant coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009853A (en) * | 2016-06-29 | 2016-10-12 | 芜湖县双宝建材有限公司 | Waterproof architectural coating with excellent mechanical property |
| CN106047040A (en) * | 2016-06-29 | 2016-10-26 | 芜湖县双宝建材有限公司 | Water-resistant architectural paint with excellent film-forming properties |
| CN107177270A (en) * | 2017-05-22 | 2017-09-19 | 如皋市下原科技创业服务有限公司 | A kind of Novel fireproof paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103725150B (en) | 2015-09-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Mei Changlin Inventor after: Zhang Guosheng Inventor after: Zhu Hengheng Inventor before: Mei Changlin Inventor before: Zhang Guosheng Inventor before: Zhu Hengheng |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A fire-resistant coating Effective date of registration: 20230330 Granted publication date: 20150930 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI JINDUN PAINT Co.,Ltd. Registration number: Y2023980036889 |
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| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20150930 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI JINDUN PAINT Co.,Ltd. Registration number: Y2023980036889 |