CN106046595A - Low-moisture-absorption safety data transmission cable material and preparation method thereof - Google Patents
Low-moisture-absorption safety data transmission cable material and preparation method thereof Download PDFInfo
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- CN106046595A CN106046595A CN201610420478.9A CN201610420478A CN106046595A CN 106046595 A CN106046595 A CN 106046595A CN 201610420478 A CN201610420478 A CN 201610420478A CN 106046595 A CN106046595 A CN 106046595A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
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Abstract
The invention discloses a low-moisture-absorption safety data transmission cable material, characterized by comprising the following components according to parts by weight: 90 parts of XS-3 type PVC (polyvinyl chloride) resin, 30 parts of polytetrafluoroethylene, 95 parts of XS-2 type polyvinyl chloride, 15 parts of polycarbonate, 2 parts of barium stearate, 12 parts of dioctyl epoxytetrahydrophthalate, 10 parts of tributyl phosphate, 3 parts of glyceryl monostearate, 8 parts of hydrated zinc borate, 5 parts of zinc oxide, 20 parts of antimony trioxide, 5 parts of nano boron nitride, 8 parts of coal gangue, 12 parts of liquid coumarone resin, 2 parts of pentaerythritol stearate, and 1.5 parts of antioxidant 1010. The low-moisture-absorption safety data transmission cable material is suitable particularly for cables for marine or underwater operations and has good water resistance and acid and alkali resistance.
Description
Technical field
The invention belongs to cable material technical field, a kind of low moisture absorption safety data transmission strands and preparation side thereof
Method.
Background technology
Data wire (data cable), its effect connects mobile device and computer, reaches data transmission or logical
Letter purpose.Popular say, it is simply that connect computer and mobile device and be used for transmitting the path instrument of the files such as video, the tinkle of bells, picture.
Now, the development maked rapid progress along with electron trade, data wire has had become as part indispensable in our life.Cable
Sheath is cable indispensable intermediate structure part, plays a part to protect cable, it is ensured that the energising safety of cable, allows copper
Silk and the medium such as water, air completely cut off, it is to avoid leaky occur.Modern times are the data message epoch, the dependence day to data wire
Deep increasingly, therefore, good data wire plays vital effect to improving work efficiency.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of cable cable material good waterproof performance, lower low water,
Leakage resistance is strong, is particularly suitable for boats and ships or underwater performance cable, resistance to water, the safe number of the low moisture absorption that resistance to acids and bases is good
According to transmission strands and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of low moisture absorption safety data transmission strands, it is characterised in that include following parts by weight of component: XS-3 type PVC resin
70-90, politef 20-30, XS-2 type polrvinyl chloride 75-95, Merlon 10-15, barium stearate 1-2, epoxy
Tetrahydro-2-ethylhexyl phthalate 8-12, tributyl phosphate 5-10, glyceryl monostearate 2-3, hydration zinc borate 4-8,
Zinc oxide 3-5, antimony oxide 10-20, nm-class boron nitride 3-5, gangue 4-8, liquid coumarone indene resin 8-12, season penta
Tetrol stearate 1-2, antioxidant 1010 0.5-1.5, epoxy soybean oil 12-18, di-n-octyl sebacate 8-12, optimization
Filler 10-14；
The preparation method of described optimization filler is as follows: take the raw material of following weight portion: titanium dioxide 7-9, alumina powder 5.5-7,
Stalactitum powder 6-8, cashew shell oil 0.5-0.8, SA 1-2, n-methyl pyrrolidone 46-50, tributyl citrate
6-10, ethylenediamine 10-14, styroflex 4-6, propenyl 2-3, trihydroxy ethylamine oleate soap 1-2；By titanium dioxide, oxygen
Change aluminium powder, Stalactitum powder, cashew shell oil mixed grinding, place into n-methyl pyrrolidone, tributyl citrate, ethylenediamine,
70-80 DEG C of heating in water bath 1-2h, take out dry, being crushed to granularity is 0.1-0.2mm, be subsequently adding styroflex, third
Enol, trihydroxy ethylamine oleate soap, at 4000-5000rpm speed lapping 10-15min, dry and pulverize, cross 300-400 mesh sieve
Obtain.
The preparation method of described low moisture absorption safety data transmission strands, it is characterised in that comprise the following steps:
(1) by barium stearate, epoxy tetrahydro-2-ethylhexyl phthalate, tributyl phosphate, glyceryl monostearate, hydration boric acid
The mixing of zinc, zinc oxide, antimony oxide, nm-class boron nitride, gangue carries out 70-80 DEG C of heating in water bath 2-3h and obtains slurry, higher
Speed ground slurry particle diameter, to below 10 μm, is spray dried to powder, standby；
(2) by liquid coumarone indene resin, pentaerythritol stearate, antioxidant 1010, epoxy soybean oil, di-n-octyl sebacate,
Optimize filler and be heated to 100 DEG C-120 DEG C, stirring reaction 30-40 minute, then carry out high speed shear dispersion 10-15min, standby
With；
(3) step (1), (2) gained raw material mix and blend are put into high-speed kneading machine and be heated to 50-60 DEG C, carry out mediating 4-
6min, takes out and adds other surplus stocks and send in mill together and plasticate, and roller temperature control is at 145-165 DEG C, and plasticate 15-
25min, rear extrusion granulating.
The cable material good waterproof performance of the present invention, leakage resistance is strong, is particularly suitable for boats and ships or underwater performance cable,
Resistance to water, resistance to acids and bases is good.
Detailed description of the invention
A kind of low moisture absorption safety data transmission strands, it is characterised in that include following parts by weight of component: XS-3 type PVC
Resin 90, politef 30, XS-2 type polrvinyl chloride 95, Merlon 15, barium stearate 2, epoxy tetrahydrophthalic acid
Dioctyl ester 12, tributyl phosphate 10, glyceryl monostearate 3, hydration zinc borate 8, zinc oxide 5, antimony oxide 20, nanometer nitrogen
Change boron 5, gangue 8, liquid coumarone indene resin 12, pentaerythritol stearate 2, antioxidant 1010 1.5, epoxy soybean oil
18, di-n-octyl sebacate 12, optimization filler 14；
The preparation method of described optimization filler is as follows: take the raw material of following weight portion: titanium dioxide 9, alumina powder 7, Stalactitum powder
8, cashew shell oil 0.8, SA 2, n-methyl pyrrolidone 50, tributyl citrate 10, ethylenediamine 14, styroflex
6, propenyl 3, trihydroxy ethylamine oleate soap 2；By titanium dioxide, alumina powder, Stalactitum powder, cashew shell oil mixed grinding, place into
N-methyl pyrrolidone, tributyl citrate, ethylenediamine, at 70-80 DEG C of heating in water bath 1-2h, take out and dry, be crushed to grain
Degree is 0.1-0.2mm, is subsequently adding styroflex, propenyl, trihydroxy ethylamine oleate soap, at 4000-5000rpm at a high speed
Grind 10-15min, dry and pulverize, cross 400 mesh sieves and get final product.
The preparation method of described low moisture absorption safety data transmission strands, it is characterised in that comprise the following steps:
(1) by barium stearate, epoxy tetrahydro-2-ethylhexyl phthalate, tributyl phosphate, glyceryl monostearate, hydration boric acid
The mixing of zinc, zinc oxide, antimony oxide, nm-class boron nitride, gangue carries out 70-80 DEG C of heating in water bath 2-3h and obtains slurry, higher
Speed ground slurry particle diameter, to below 10 μm, is spray dried to powder, standby；
(2) by liquid coumarone indene resin, pentaerythritol stearate, antioxidant 1010, epoxy soybean oil, di-n-octyl sebacate,
Optimize filler and be heated to 100 DEG C-120 DEG C, stirring reaction 30-40 minute, then carry out high speed shear dispersion 10-15min, standby
With；
(3) step (1), (2) gained raw material mix and blend are put into high-speed kneading machine and be heated to 50-60 DEG C, carry out mediating 4-
6min, takes out and adds other surplus stocks and send in mill together and plasticate, and roller temperature control is at 145-165 DEG C, and plasticate 15-
25min, rear extrusion granulating.
Experimental data: the final cable material of the present embodiment is used for the protective cover material of data line, addition is 10-
15%, the test data of protective cover material are as follows: hot strength: 20.5 MPa；Elongation at break: 400%；Oil resistivity:
100 DEG C × 70h of 20# machine oil, elongation at break conservation rate 62.2%, tensile strength retention 79.9%；Resistance to ozone: 26
DEG C, 24h, ozone concentration 0.026%, without cracking；Ageing-resistant: 120 DEG C, 120h, tensile strength retention 64.4%, fracture
Percent retention of elongation 72.2%.
Claims (2)
1. one kind low moisture absorption safety data transmission strands, it is characterised in that include following parts by weight of component: XS-3 type PVC
Resin 70-90, politef 20-30, XS-2 type polrvinyl chloride 75-95, Merlon 10-15, barium stearate 1-
2, epoxy tetrahydro-2-ethylhexyl phthalate 8-12, tributyl phosphate 5-10, glyceryl monostearate 2-3, hydration zinc borate
4-8, zinc oxide 3-5, antimony oxide 10-20, nm-class boron nitride 3-5, gangue 4-8, liquid coumarone indene resin 8-12,
Pentaerythritol stearate 1-2, antioxidant 1010 0.5-1.5, epoxy soybean oil 12-18, di-n-octyl sebacate 8-12,
Optimize filler 10-14；
The preparation method of described optimization filler is as follows: take the raw material of following weight portion: titanium dioxide 7-9, alumina powder 5.5-7,
Stalactitum powder 6-8, cashew shell oil 0.5-0.8, SA 1-2, n-methyl pyrrolidone 46-50, tributyl citrate
6-10, ethylenediamine 10-14, styroflex 4-6, propenyl 2-3, trihydroxy ethylamine oleate soap 1-2；By titanium dioxide, oxygen
Change aluminium powder, Stalactitum powder, cashew shell oil mixed grinding, place into n-methyl pyrrolidone, tributyl citrate, ethylenediamine,
70-80 DEG C of heating in water bath 1-2h, take out dry, being crushed to granularity is 0.1-0.2mm, be subsequently adding styroflex, third
Enol, trihydroxy ethylamine oleate soap, at 4000-5000rpm speed lapping 10-15min, dry and pulverize, cross 300-400 mesh sieve
Obtain.
The preparation method of low moisture absorption safety data transmission strands the most as claimed in claim 1, it is characterised in that include following step
Rapid:
By barium stearate, epoxy tetrahydro-2-ethylhexyl phthalate, tributyl phosphate, glyceryl monostearate, hydration zinc borate,
The mixing of zinc oxide, antimony oxide, nm-class boron nitride, gangue carries out 70-80 DEG C of heating in water bath 2-3h and obtains slurry, then high speed
Ground slurry particle diameter, to below 10 μm, is spray dried to powder, standby；
By liquid coumarone indene resin, pentaerythritol stearate, antioxidant 1010, epoxy soybean oil, di-n-octyl sebacate, excellent
Change filler and be heated to 100 DEG C-120 DEG C, stirring reaction 30-40 minute, then carry out high speed shear dispersion 10-15min, standby
With；
(3) step (1), (2) gained raw material mix and blend are put into high-speed kneading machine and be heated to 50-60 DEG C, carry out mediating 4-
6min, takes out and adds other surplus stocks and send in mill together and plasticate, and roller temperature control is at 145-165 DEG C, and plasticate 15-
25min, rear extrusion granulating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610420478.9A CN106046595A (en) | 2016-06-14 | 2016-06-14 | Low-moisture-absorption safety data transmission cable material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610420478.9A CN106046595A (en) | 2016-06-14 | 2016-06-14 | Low-moisture-absorption safety data transmission cable material and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106046595A true CN106046595A (en) | 2016-10-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610420478.9A Pending CN106046595A (en) | 2016-06-14 | 2016-06-14 | Low-moisture-absorption safety data transmission cable material and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109306A (en) * | 2014-06-23 | 2014-10-22 | 安徽荣玖光纤通信科技有限公司 | Optical fiber cable-used insulated cable material and preparation method thereof |
| CN104292646A (en) * | 2014-10-30 | 2015-01-21 | 安徽电信器材贸易工业有限责任公司 | High temperature resisting material for communication optical cable sheath and preparation method of high temperature resisting material |
| CN105037994A (en) * | 2015-06-23 | 2015-11-11 | 中山市鸿程科研技术服务有限公司 | Corrosion-resistant flame-retardant cable material and preparation method thereof |
-
2016
- 2016-06-14 CN CN201610420478.9A patent/CN106046595A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109306A (en) * | 2014-06-23 | 2014-10-22 | 安徽荣玖光纤通信科技有限公司 | Optical fiber cable-used insulated cable material and preparation method thereof |
| CN104292646A (en) * | 2014-10-30 | 2015-01-21 | 安徽电信器材贸易工业有限责任公司 | High temperature resisting material for communication optical cable sheath and preparation method of high temperature resisting material |
| CN105037994A (en) * | 2015-06-23 | 2015-11-11 | 中山市鸿程科研技术服务有限公司 | Corrosion-resistant flame-retardant cable material and preparation method thereof |
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Application publication date: 20161026 |
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