CN105885301A - Fatigue-resistant data transmission line and method for preparing same - Google Patents

Fatigue-resistant data transmission line and method for preparing same Download PDF

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Publication number
CN105885301A
CN105885301A CN201610473316.1A CN201610473316A CN105885301A CN 105885301 A CN105885301 A CN 105885301A CN 201610473316 A CN201610473316 A CN 201610473316A CN 105885301 A CN105885301 A CN 105885301A
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China
Prior art keywords
powder
parts
fatigue
data transmission
transmission line
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Pending
Application number
CN201610473316.1A
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Chinese (zh)
Inventor
杨先云
董涛
査莉花
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Anhui Woyaoliuliu Information Technology Co Ltd
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Anhui Woyaoliuliu Information Technology Co Ltd
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Priority to CN201610473316.1A priority Critical patent/CN105885301A/en
Publication of CN105885301A publication Critical patent/CN105885301A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

Abstract

The invention discloses a fatigue-resistant data transmission line. The fatigue-resistant data transmission line is characterized by comprising, by weight, 66-70 parts of SG-3PVC (polyvinyl chloride), 68-70 parts of polyvinyl chloride resin, 12-14 parts of butyl methacrylate, 5-6 parts of ammonium polyphosphate, 0.02-0.04 part of tert-butyl hydroperoxide, 4-6 parts of quartz sand, 6-9 parts of talc powder, 3-4 parts of estersil, 3-5 parts of nanometer graphite powder, 12-15 parts of acrylic cyclic amyl ester, 1.5-3 parts of PE (polyethylene) wax and octadecadienoic acid. The fatigue-resistant data transmission line has the advantages that a method for preparing the fatigue-resistant data transmission line is simple, the fatigue-resistant data transmission line is in a reasonable composition raw material formula and is high in tensile strength and fatigue resistance, and the performance of the fatigue-resistant data transmission line can be greatly improved.

Description

Endurance data line material and preparation method thereof
Technical field
The invention belongs to cable material technical field, specifically a kind of endurance data line material and preparation method thereof.
Background technology
Data wire (data cable), its effect connects mobile device and computer, reaches data transmission or logical Letter purpose.Popular say, it is simply that connect computer and mobile device and be used for transmitting the path instrument of the files such as video, the tinkle of bells, picture. Now, the development maked rapid progress along with electron trade, data wire has had become as part indispensable in our life.Cable Sheath is cable indispensable intermediate structure part, plays a part to protect cable, it is ensured that the energising safety of cable, allows copper Silk and the medium such as water, air completely cut off, it is to avoid leaky occur.Modern times are the data message epoch, the dependence day to data wire Deep increasingly, therefore, good data wire plays vital effect to improving operating efficiency.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of preparation method is simple, and constitutive material is joined Fang Heli, performance is greatly improved endurance data line material of hot strength, endurance life and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of endurance data line material, it is characterised in that include following parts by weight of component: SG-3PVC 66-70, polychlorostyrene second Olefine resin 68-70, butyl methacrylate 12-14, APP 5-6, TBHP 0.02-0.04, quartz Sand 4-6, talcum powder 6-9, estersil 3-4, Nano graphite powder 3-5, acrylic acid ring pentyl ester 12-15, PE wax 1.5-3,18 carbon Dienoic acid 1-1.2, benzoyl peroxide 0.02-0.03, trimellitic acid decyl octyl group ester 9.5-11.5, molybdenum trioxide 1-2, Optimize filler 10-13；
The preparation method of described optimization filler is as follows: take the raw material of following weight portion: titanium dioxide 7-9, alumina powder 5.5-7, Stalactite powder 6-8, cashew nut shell oil 0.5-0.8, SA 1-2, n-methyl pyrrolidone 46-50, ATBC 6-10, ethylenediamine 10-14, styroflex 4-6, propenyl 2-3, trihydroxy ethylamine oleate soap 1-2；By titanium dioxide, oxygen Change aluminium powder, stalactite powder, cashew nut shell oil mixed grinding, place into n-methyl pyrrolidone, ATBC, ethylenediamine, 70-80 DEG C of heating water bath 1-2h, take out dry, being crushed to granularity is 0.1-0.2mm, be subsequently adding styroflex, third Enol, trihydroxy ethylamine oleate soap, at 4000-5000rpm speed lapping 10-15min, dry and pulverize, cross 300-400 mesh sieve Obtain.
The preparation method of described endurance data line material, it is characterised in that comprise the following steps:
(1) by butyl methacrylate, APP, TBHP, quartz sand, talcum powder, estersil, nano-graphite The mixing of powder, acrylic acid ring pentyl ester carries out 70-80 DEG C of heating water bath 2-3h and obtains slurry, then speed lapping slurry particle diameter is to 10 μm Hereinafter, it is spray dried to powder, standby；
(2) filler and PE wax, octadecadienoic acid, benzoyl peroxide, trimellitic acid decyl octyl group ester, molybdenum trioxide will be optimized It is heated to 100 DEG C-120 DEG C, stirring reaction 30-40 minute, then carry out high speed shear dispersion 10-15min, standby；
(3) step (1), (2) gained raw material mix and blend are put into high-speed kneading machine and be heated to 50-60 DEG C, carry out mediating 4- 6min, takes out and adds other surplus stocks and send in mill together and plasticate, and roller temperature control is at 145-165 DEG C, and plasticate 15- 25min, rear extrusion granulating.
Advantages of the present invention: preparation method of the present invention is simple, rationally, performance is greatly improved constitutive material formula, and stretching is strong Degree, endurance life, aging after stretching strength retentivity and fracture stretch out the performance of conservation rate.
Detailed description of the invention
A kind of endurance data line material, it is characterised in that include following parts by weight of component: SG-3PVC 70, polychlorostyrene Vinyl 70, butyl methacrylate 14, APP 6, TBHP 0.04, quartz sand 6, talcum powder 9, estersil 4, Nano graphite powder 5, acrylic acid ring pentyl ester 15, PE wax 3, octadecadienoic acid 1.2, benzoyl peroxide 0.03, trimellitic acid decyl octyl group ester 11.5, molybdenum trioxide 2, optimization filler 13；
The preparation method of described optimization filler is as follows: take the raw material of following weight portion: titanium dioxide 9, alumina powder 7, stalactite Powder 8, cashew nut shell oil 0.8, SA 2, n-methyl pyrrolidone 50, ATBC 10, ethylenediamine 14, polyphenyl Vinyl fiber 6, propenyl 3, trihydroxy ethylamine oleate soap 2；By titanium dioxide, alumina powder, stalactite powder, cashew nut shell oil mixing Grind, place into n-methyl pyrrolidone, ATBC, ethylenediamine, at 70-80 DEG C of heating water bath 1-2h, take out and dry Dry, being crushed to granularity is 0.1-0.2mm, is subsequently adding styroflex, propenyl, trihydroxy ethylamine oleate soap, at 4000- 5000rpm speed lapping 10-15min, dries and pulverizes, and crosses 300-400 mesh sieve and get final product.
The preparation method of described endurance data line material, it is characterised in that comprise the following steps:
(1) by butyl methacrylate, APP, TBHP, quartz sand, talcum powder, estersil, nano-graphite The mixing of powder, acrylic acid ring pentyl ester carries out 70-80 DEG C of heating water bath 2-3h and obtains slurry, then speed lapping slurry particle diameter is to 10 μm Hereinafter, it is spray dried to powder, standby；
(2) filler and PE wax, octadecadienoic acid, benzoyl peroxide, trimellitic acid decyl octyl group ester, molybdenum trioxide will be optimized It is heated to 100 DEG C-120 DEG C, stirring reaction 30-40 minute, then carry out high speed shear dispersion 10-15min, standby；
(3) step (1), (2) gained raw material mix and blend are put into high-speed kneading machine and be heated to 50-60 DEG C, carry out mediating 4- 6min, takes out and adds other surplus stocks and send in mill together and plasticate, and roller temperature control is at 145-165 DEG C, and plasticate 15- 25min, rear extrusion granulating.
Experimental data: the final cable material of the present embodiment is used for the protective cover material of data line, addition is 10- 15%, the test data of protective cover material are as follows: hot strength: 20.5 MPa；Elongation at break: 400%；Oil resistivity: 100 DEG C × 70h of 20# machine oil, elongation at break conservation rate 62.2%, tensile strength retention 79.9%；Resistance to ozone: 26 DEG C, 24h, ozone concentration 0.026%, without cracking；Ageing-resistant: 120 DEG C, 120h, tensile strength retention 64.4%, fracture Percent retention of elongation 72.2%.

Claims (2)

1. an endurance data line material, it is characterised in that include following parts by weight of component: SG-3PVC 66-70, polychlorostyrene Vinyl 68-70, butyl methacrylate 12-14, APP 5-6, TBHP 0.02-0.04, stone Sand 4-6, talcum powder 6-9, estersil 3-4, Nano graphite powder 3-5, acrylic acid ring pentyl ester 12-15, PE wax 1.5-3,18 Carbon dienoic acid 1-1.2, benzoyl peroxide 0.02-0.03, trimellitic acid decyl octyl group ester 9.5-11.5, molybdenum trioxide 1- 2, filler 10-13 is optimized；
The preparation method of described optimization filler is as follows: take the raw material of following weight portion: titanium dioxide 7-9, alumina powder 5.5-7, Stalactite powder 6-8, cashew nut shell oil 0.5-0.8, SA 1-2, n-methyl pyrrolidone 46-50, ATBC 6-10, ethylenediamine 10-14, styroflex 4-6, propenyl 2-3, trihydroxy ethylamine oleate soap 1-2；By titanium dioxide, oxygen Change aluminium powder, stalactite powder, cashew nut shell oil mixed grinding, place into n-methyl pyrrolidone, ATBC, ethylenediamine, 70-80 DEG C of heating water bath 1-2h, take out dry, being crushed to granularity is 0.1-0.2mm, be subsequently adding styroflex, third Enol, trihydroxy ethylamine oleate soap, at 4000-5000rpm speed lapping 10-15min, dry and pulverize, cross 300-400 mesh sieve Obtain.
2. the preparation method of endurance data line material as claimed in claim 1, it is characterised in that comprise the following steps:
By butyl methacrylate, APP, TBHP, quartz sand, talcum powder, estersil, Nano graphite powder, third The mixing of olefin(e) acid ring pentyl ester carries out 70-80 DEG C of heating water bath 2-3h and obtains slurry, then speed lapping slurry particle diameter is to below 10 μm, It is spray dried to powder, standby；
Optimization filler is added with PE wax, octadecadienoic acid, benzoyl peroxide, trimellitic acid decyl octyl group ester, molybdenum trioxide Heat is to 100 DEG C-120 DEG C, and stirring is reacted 30-40 minute, then carries out high speed shear dispersion 10-15min, standby；
(3) step (1), (2) gained raw material mix and blend are put into high-speed kneading machine and be heated to 50-60 DEG C, carry out mediating 4- 6min, takes out and adds other surplus stocks and send in mill together and plasticate, and roller temperature control is at 145-165 DEG C, and plasticate 15- 25min, rear extrusion granulating.
CN201610473316.1A 2016-06-26 2016-06-26 Fatigue-resistant data transmission line and method for preparing same Pending CN105885301A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106221077A (en) * 2016-08-31 2016-12-14 高亚莉 The anti-PVC material and preparation method thereof that fractures of environment-friendly type
CN106380736A (en) * 2016-08-31 2017-02-08 高亚莉 Environmentally-friendly anti-wear flexible PVC material and preparation method thereof
CN106398040A (en) * 2016-08-31 2017-02-15 高亚莉 Environment-friendly cold-resistant flame-retardant PVC material and preparation method thereof
CN108299995A (en) * 2017-08-17 2018-07-20 安徽卓越电力设备有限公司 A kind of cable special coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102336987A (en) * 2011-07-18 2012-02-01 苏州华盈塑化有限公司 High humidity tolerance, high electric performance and environment-friendly polyvinyl chloride insulation material for electric wires and cables
CN104761848A (en) * 2015-03-27 2015-07-08 和县电力电线电缆有限责任公司 Higher-performance flexible polyvinyl chloride (PVC) cable material and preparation method thereof
CN105131576A (en) * 2015-09-21 2015-12-09 安徽徽宁电器仪表集团有限公司 Halogen-free flame retardant environment-friendly flexible cable sheathing compound for portable power source and preparation method of sheathing compound
CN105566814A (en) * 2016-03-16 2016-05-11 远东电缆有限公司 Environment-friendly transparent elastomer sheath material for intelligent video wires and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102336987A (en) * 2011-07-18 2012-02-01 苏州华盈塑化有限公司 High humidity tolerance, high electric performance and environment-friendly polyvinyl chloride insulation material for electric wires and cables
CN104761848A (en) * 2015-03-27 2015-07-08 和县电力电线电缆有限责任公司 Higher-performance flexible polyvinyl chloride (PVC) cable material and preparation method thereof
CN105131576A (en) * 2015-09-21 2015-12-09 安徽徽宁电器仪表集团有限公司 Halogen-free flame retardant environment-friendly flexible cable sheathing compound for portable power source and preparation method of sheathing compound
CN105566814A (en) * 2016-03-16 2016-05-11 远东电缆有限公司 Environment-friendly transparent elastomer sheath material for intelligent video wires and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106221077A (en) * 2016-08-31 2016-12-14 高亚莉 The anti-PVC material and preparation method thereof that fractures of environment-friendly type
CN106380736A (en) * 2016-08-31 2017-02-08 高亚莉 Environmentally-friendly anti-wear flexible PVC material and preparation method thereof
CN106398040A (en) * 2016-08-31 2017-02-15 高亚莉 Environment-friendly cold-resistant flame-retardant PVC material and preparation method thereof
CN108299995A (en) * 2017-08-17 2018-07-20 安徽卓越电力设备有限公司 A kind of cable special coating and preparation method thereof

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