CN106046582A - Polystyrene imitation teak product and production method thereof - Google Patents
Polystyrene imitation teak product and production method thereof Download PDFInfo
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- CN106046582A CN106046582A CN201610408516.9A CN201610408516A CN106046582A CN 106046582 A CN106046582 A CN 106046582A CN 201610408516 A CN201610408516 A CN 201610408516A CN 106046582 A CN106046582 A CN 106046582A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2425/02—Homopolymers or copolymers of hydrocarbons
- C08J2425/04—Homopolymers or copolymers of styrene
- C08J2425/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2469/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
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Abstract
The invention discloses a polystyrene imitation teak product, made by mixing and extruding colorant particles and wood grain agents different in color, including 40-70 parts of brown particles and 30-60 parts of yellow particles, as well as 0.01-0.1 part of coffee wood grain agent, 0.005-0.05 part of black wood grain agent and 0.005-0.05 part of purple wood grain agent; the brown and yellow particles are made from the following materials according to parts by weight: 70-80 parts of polystyrene recycled material, 5-10 parts of modified polystyrene, 5-10 parts of foamed polystyrene, 1-5 parts of ABS (acrylonitrile butadiene styrene), 1-10 parts of filler, 0.1-1 part of an antioxidant, 0.1-1 part of a plasticizer, 0.1-1 part of a flame retardant, and 1-10 parts of a pigment; the wood grain agents are made from the following materials according to parts by weight: 20-80 parts of modified polystyrene, 20-80 parts of ABS, 1-10 parts of polycarbonate PC and 10-30 parts of pigments. The polystyrene foamed waste packaging recycled material is used to produce imitation teak products different in shape, size and specific weight, environmental pollution due to wastes is reduced, and human resources for treating wastes are also reduced.
Description
Technical field
The present invention relates to a kind of imitated wood material, especially relate to a kind of polystyrene imitating Tectona grandis L. F. product and preparation method thereof.
Background technology
Imitated wood material refers to that a class has and wood materials outward appearance, texture or even physical mechanics intensity, machining property
Close material, in household, the certain fields such as gardens construction, logistics can replace conventional wooden material.Tradition imitated wood material master
Reinforced concrete surface imitated wood material to be included, imitation wood tube material, Wood-plastic material etc., the many need of armored concrete imitated wood material are former
Wood material makees mould to obtain surface wood grain, and production cost is high, and this type of wood-imitated products, in appearance close to woodwork, is gathered around
There is inorganic metallic materials performance and non-wood moral character energy, be used for big-and-middle-sized building in the style of the ancients.Traditional Wood moulding material then needs to add
Wood materials more than or equal to more than 50%, the easy moisture absorption of goods, water resistance haves much room for improvement；For realizing imitative wood grain effect, one
As need to carry out after shaping surface moditied processing, operation is relatively cumbersome.
Foamed polystyrene is discarded to be packaged in and is processed the manpower and materials that upper waste is certain, and to environment, and
Foamed polystyrene being discarded recycling of packaging utilize, the preparation for imitated wood material rarely has report, for imitating the system of Tectona grandis L. F. material
Standby then less.The wooden exquisiteness of Tectona grandis L. F., wood body delicate fragrance.Tectona grandis L. F. has extremely important position on China's folk culture and faith, I
State's new Year scroll the earliest all make of Tectona grandis L. F. plate, and also known as peach wood charms against evil, for thousands of years, Tectona grandis L. F. just has what town calamity avoided evil spirits to say, is referred to as god
Wood.In the modern life, Tectona grandis L. F. exorcise evil spirits in order to relieve the people in stricken areas be used gradually few, but Tectona grandis L. F. color and luster is such as redwood, multiplex makees classic furniture,
Tectona grandis L. F. is increasingly favored by people in this respect, but, Tectona grandis L. F. yields poorly, if significantly cutting down and natural environment can being destroyed,
Therefore develop a kind of imitative Tectona grandis L. F. product to be of great immediate significance.
Summary of the invention
It is an object of the invention to provide a kind of polystyrene imitating Tectona grandis L. F. product and preparation method thereof, the method is with polyphenyl second
The discarded recycling of packaging material of alkene foaming is that primary raw material prepares imitative Tectona grandis L. F. product, has proportion, the wood exactly liked with natural Tectona grandis L. F.
Stricture of vagina, feel etc., but have more preferable resistance to water, mildew resistance, outdoor durable than natural Tectona grandis L. F., can substitute prepared by existing Tectona grandis L. F.
Furniture house ornamentation, and use out of doors and also have the biggest advantage.
The technical solution adopted for the present invention to solve the technical problems is: a kind of polystyrene imitating Tectona grandis L. F. product, by difference
The colored particle of color and wood grain agent mixing extrusion prepare, and described colored particle includes brown, yellow, the weight portion of each coloured particles
Number is: brown particle 40-70 part, yellow particle 30-60 part；Described wood grain agent includes coffee color, black, purple wood grain agent；Respectively
The parts by weight of color wood grain agent are coffee-like wood grain agent 0.01 0.1 parts, black wood grain agent 0.005 0.05 parts, purple wood grain
Agent 0.005 0.05 parts；
Brown, yellow color granule are made up of the raw material of following parts by weight: polystyrene reclaimed materials 70-80 part, modified polyphenyl
Ethylene 5-10 part, expanded polystyrene (EPS) 5-10 part, ABS1-5 part, filler 1-10 part, antioxidant 0.1-1 part, plasticizer 0.1-1
Part, fire retardant 0.1-1 part, pigment 1-10 part；
Described wood grain agent is made up of the raw material of following parts by weight: MPS 20-80 part, ABS 20-80 part, poly-carbon
PC 1-10 part, pigment 10-30 part.
Described filler is one or both in Pulvis Talci, fine particle calcium carbonate, triple superphosphate.
Brown is iron oxide brown, and yellow uitramarine is iron oxide yellow, and coffee-like pigment is prepared by titanium dioxide, carbon black, black
Color pigment is carbon black.
Described plasticizer is the one in phthalic acid ester, phosphate ester, PEPA, aliphatic, dibasic acid ester.
Described fire retardant is phosphate ester.
Described antioxidant is TINUVIN P, TINUVIN DF770, IRGANOX 1076, IRGAFOS 168,
In IRGANON 1010 any two kinds.
The preparation method of above-mentioned imitation wood product, comprises the steps:
S1) colored particle and the preparation of wood grain agent:
The preparation of colored particle: weigh the raw material of colored particle by weight, is mixed to get compound one, then by compound
One adds extruder, extruding pelletization under the conditions of 140 DEG C～180 DEG C, prepares the colored particle of different colours respectively；
The preparation of wood grain agent: weigh the raw material of wood grain agent by weight, mixes to obtain compound two, is then added by compound two
Enter extruder, extruding pelletization under the conditions of 160 DEG C～200 DEG C；Prepare the wood grain agent of different colours respectively；
S2) preparation of imitative Tectona grandis L. F. product:
Colored particle and the wood grain agent of the multiple color of step S1 gained are weighed by weight, are mixed to get compound three,
Then compound three is added extruder, extrusion molding under the conditions of 140 DEG C～180 DEG C；Then it is circulated spraying cooling, uses
Traction machine sync pulling, obtains preliminary section bar, is then used by cutting tool and is cut by the preliminary section bar obtained, makes type
Material；
S3) section bar inspection is put in storage or continues to be processed into finished product furniture.
The invention has the beneficial effects as follows:
(1) utilize foamed polystyrene to discard recycling of packaging material, produce difformity, size, the imitative Tectona grandis L. F. of different specific weight
Product, decreases the obsolete material pollution to environment, decreases the manpower processing obsolete material.
(2) the imitation wood product of this imitative Tectona grandis L. F. material manufacture have exactly like with natural Tectona grandis L. F. proportion, wood grain, feel etc., but
Having more preferable resistance to water, mildew resistance, outdoor durable than natural Tectona grandis L. F., using out of doors has the biggest advantage.
(3) this imitative Tectona grandis L. F. material is in order to prepare imitative Tectona grandis L. F. product, substitutes Tectona grandis L. F. material, can slow down the felling of forest.
(4) this imitative Tectona grandis L. F. material adds fire retardant, improves the imitative Tectona grandis L. F. product of use this imitative Tectona grandis L. F. material manufacture
Safety in utilization.
Accompanying drawing explanation
Fig. 1 is the process chart of the imitation wood product of the present invention.
Detailed description of the invention
Below with reference to accompanying drawing describe embodiment be exemplary, be only used for explain the present invention, and it is not intended that
Limitation of the present invention.
The present invention seeks to utilize the discarded recycling of packaging material using polystyrene as foaming raw material as primary raw material
Produce the goods such as the imitative furniture item of Tectona grandis L. F., section bar.Colored particle and wood grain agent mixing extrusion by different colours prepare, described
Colored particle includes that brown, yellow, the parts by weight of each coloured particles are: brown particle 40-70 part, yellow particle 30-60 part；Institute
State wood grain agent and include coffee color, black, purple wood grain agent；The parts by weight of assorted wood grain agent are coffee-like wood grain agent 0.01
0.1 part, black wood grain agent 0.005 0.05 parts, purple wood grain agent 0.005 0.05 parts；Brown, yellow color granule are by following
The raw material of parts by weight is made: polystyrene reclaimed materials 70-80 part, MPS 5-10 part, expanded polystyrene (EPS) 5-10
Part, ABS1-5 part, filler 1-10 part, antioxidant 0.1-1 part, plasticizer 0.1-1 part, fire retardant 0.1-1 part, pigment 1-10
Part；Described wood grain agent is made up of the raw material of following parts by weight: MPS 20-80 part, ABS 20-80 part, poly-carbon PC
1-10 part, pigment 10-30 part.
As it is shown in figure 1, the preparation method of above-mentioned imitative Tectona grandis L. F. product comprises the steps:
S1: granule and the preparation of wood grain agent:
The preparation of granule: weigh particulate material by above-mentioned percentage by weight, is mixed to obtain compound one, then by compound
One adds extruder, extruding pelletization under the conditions of 140 DEG C～180 DEG C, prepares the granule of different colours respectively；
The preparation of wood grain agent: weigh wood grain agent raw material by above-mentioned percentage by weight, is mixed to obtain compound two, then will be mixed
Close material two addition extruder, extruding pelletization under the conditions of 160 DEG C～200 DEG C；Prepare the wood grain agent of different colours respectively；
S2: the preparation of imitation wood product:
Weigh imitative Tectona grandis L. F. products material by above-mentioned percentage by weight, be mixed to obtain compound three, then by compound Acanthopanan trifoliatus (L.) Merr.
Enter extruder, extrusion molding under the conditions of 140 DEG C～180 DEG C；Then it is circulated spraying cooling, uses traction machine sync pulling,
Obtain preliminary section bar, be then used by cutting tool and the preliminary section bar obtained is cut, make section bar, if section bar does not continues to add
Work, then check warehouse-in, if continuing processing, then makes finished product furniture.
Hereinafter, the formula of multiple colored particle of illustration composition compound one:
1, brown particle:
| Formula one | Formula two | Formula three | |
| Polystyrene reclaimed materials | 80 parts | 77 parts | 78 parts |
| MPS | 10 parts | 10 parts | 9 parts |
| Expanded polystyrene (EPS) | 8 parts | 8 parts | 10 parts |
| ABS | 4 parts | 3 parts | 4 parts |
| Filler | 5 parts | 8 parts | 9 parts |
| Antioxidant | 0.6 part | 0.5 part | 0.6 part |
| Plasticizer | 0.2 part | 0.18 part | 0.17 part |
| Fire retardant phosphate ester | 0.9 part | 0.7 part | 0.9 part |
| Iron oxide brown | 5 parts | 5 parts | 8 parts |
2, yellow particle
| Formula one | Formula two | Formula three | |
| Polystyrene reclaimed materials | 80 parts | 77 parts | 78 parts |
| MPS | 10 parts | 10 parts | 9 parts |
| Expanded polystyrene (EPS) | 8 parts | 8 parts | 10 parts |
| ABS | 4 parts | 3 parts | 4 parts |
| Filler | 5 parts | 8 parts | 7 parts |
| Antioxidant | 0.3 part | 0.5 part | 0.6 part |
| Plasticizer | 0.18 part | 0.18 part | 0.11 part |
| Fire retardant phosphate ester | 0.5 part | 0.7 part | 0.9 part |
| Iron oxide yellow | 6 parts | 6 parts | 7 parts |
In above-mentioned formula, filler is one or both in Pulvis Talci, fine particle calcium carbonate, triple superphosphate.Plasticizer is phthalic acid ester, phosphoric acid
One in ester, PEPA, aliphatic, dibasic acid ester.Antioxidant is TINUVIN P, TINUVIN DF770,
In IRGANOX 1076, IRGAFOS 168, IRGANON 1010 any two kinds.
The formula of multiple wood grain agent of composition compound two:
3, coffee-like wood grain agent
| Formula one | Formula two | Formula three | |
| MPS | 40 parts | 45 parts | 39 parts |
| ABS | 20 parts | 30 parts | 35 parts |
| Poly-carbon PC | 5 parts | 6 parts | 7 parts |
| Carbon black | 5 parts | 11 parts | 15 parts |
| Titanium white | 6 | 9 | 13 |
4, black wood grain agent
| Formula one | Formula two | Formula three | |
| MPS | 40 parts | 45 parts | 35 parts |
| ABS | 30 parts | 38 parts | 45 parts |
| Poly-carbon PC | 5 parts | 6 parts | 7 parts |
| Carbon black | 10 parts | 20 parts | 30 parts |
5, purple wood grain agent
| Formula one | Formula two | Formula three | |
| MPS | 42 parts | 45 parts | 38 parts |
| ABS | 30 parts | 30 parts | 45 parts |
| Poly-carbon PC | 5 parts | 6 parts | 7 parts |
| Violet pigment P-29 | 10 parts | 20 parts | 30 parts |
The formula of composition compound three:
| Formula one | Formula two | Formula three | |
| Brown particle | 42 parts | 53 parts | 68 parts |
| Yellow particle | 33 parts | 45 parts | 56 parts |
| Black wood grain agent | 0.005 part | 0.045 part | 0.01 part |
| Coffee-like wood grain agent | 0.05 part | 0.09 part | 0.1 part |
| Purple wood grain agent | 0.005 part | 0.045 part | 0.01 part |
Although an embodiment of the present invention has been shown and described, it will be understood by those within the art that: without departing from
These embodiments can be carried out multiple change in the case of the principle of the present invention and objective, revise, replace and modification, the present invention
Scope limited by claim and equivalent thereof, without creative work improvements introduced etc., should be included in this
Within the protection domain of invention.
Claims (7)
1. a polystyrene imitating Tectona grandis L. F. product, colored particle and wood grain agent mixing extrusion by different colours are prepared, its feature
Being, described colored particle includes that brown, yellow, the parts by weight of each coloured particles are: brown particle 40-70 part, yellow particle
30-60 part；Described wood grain agent includes coffee color, black, purple wood grain agent；The parts by weight of assorted wood grain agent are coffee-like wood grains
Agent 0.01 0.1 parts, black wood grain agent 0.005 0.05 parts, purple wood grain agent 0.005 0.05 parts；
Brown, yellow color granule are made up of the raw material of following parts by weight: polystyrene reclaimed materials 70-80 part, modified polyphenyl
Ethylene 5-10 part, expanded polystyrene (EPS) 5-10 part, ABS1-5 part, filler 1-10 part, antioxidant 0.1-1 part, plasticizer 0.1-1
Part, fire retardant 0.1-1 part, pigment 1-10 part；
Described wood grain agent is made up of the raw material of following parts by weight: MPS 20-80 part, ABS 20-80 part, poly-carbon
PC 1-10 part, pigment 10-30 part.
Imitation wood product the most according to claim 1, it is characterised in that: described filler is the one in Pulvis Talci, fine particle calcium carbonate, triple superphosphate
Or two kinds.
Imitation wood product the most according to claim 2, it is characterised in that: brown is iron oxide brown, and yellow uitramarine is oxidation
Iron oxide yellow, coffee-like pigment is prepared by titanium dioxide, carbon black, and black pigment is carbon black.
Imitation wood product the most according to claim 3, it is characterised in that: described plasticizer is phthalic acid ester, phosphate ester, gathers
One in ester polyol, aliphatic, dibasic acid ester.
Imitation wood product the most according to claim 4, it is characterised in that: described fire retardant is phosphate ester.
Imitation wood product the most according to claim 5, it is characterised in that: described antioxidant is TINUVIN P, TINUVIN
In DF770, IRGANOX 1076, IRGAFOS 168, IRGANON 1010 any two kinds.
7. the preparation method according to the imitation wood product described in claim 1-6 any claim, it is characterised in that include
Following steps:
S1) colored particle and the preparation of wood grain agent:
The preparation of colored particle: weigh the raw material of colored particle by weight, is mixed to get compound one, then by compound
One adds extruder, extruding pelletization under the conditions of 140 DEG C～180 DEG C, prepares the colored particle of different colours respectively；
The preparation of wood grain agent: weigh the raw material of wood grain agent by weight, mixes to obtain compound two, is then added by compound two
Enter extruder, extruding pelletization under the conditions of 160 DEG C～200 DEG C；Prepare the wood grain agent of different colours respectively；
S2) preparation of imitative Tectona grandis L. F. product:
Colored particle and the wood grain agent of the multiple color of step S1 gained are weighed by weight, are mixed to get compound three,
Then compound three is added extruder, extrusion molding under the conditions of 140 DEG C～180 DEG C；Then it is circulated spraying cooling, uses
Traction machine sync pulling, obtains preliminary section bar, is then used by cutting tool and is cut by the preliminary section bar obtained, makes type
Material；
S3) section bar inspection is put in storage or continues to be processed into finished product furniture.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610408516.9A CN106046582A (en) | 2016-06-13 | 2016-06-13 | Polystyrene imitation teak product and production method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610408516.9A CN106046582A (en) | 2016-06-13 | 2016-06-13 | Polystyrene imitation teak product and production method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112159567A (en) * | 2020-10-22 | 2021-01-01 | 广东顺德博舍环保家具股份有限公司 | Polystyrene imitation black walnut product and preparation method thereof |
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| CN103665630A (en) * | 2012-09-24 | 2014-03-26 | 领亿新材料(福建)科技有限公司 | Production process and preparation method of wood-plastic product with natural wood grains on whole body |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112159567A (en) * | 2020-10-22 | 2021-01-01 | 广东顺德博舍环保家具股份有限公司 | Polystyrene imitation black walnut product and preparation method thereof |
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