CN106035345A - Compound for preventing and controlling apple budworms and preparation method thereof - Google Patents

Compound for preventing and controlling apple budworms and preparation method thereof Download PDF

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Publication number
CN106035345A
CN106035345A CN201610474728.7A CN201610474728A CN106035345A CN 106035345 A CN106035345 A CN 106035345A CN 201610474728 A CN201610474728 A CN 201610474728A CN 106035345 A CN106035345 A CN 106035345A
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Prior art keywords
parts
butyl acrylate
thiapronil
apple
synergist
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CN201610474728.7A
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Chinese (zh)
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叶松
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Individual
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02—Acyclic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a compound for preventing and controlling apple budworms and a preparation method thereof. The compound comprises the following raw materials in parts by weight: 20-30 parts of thiapronil, 10-20 parts of hinoki lactone, 130-150 parts of glycerol, 350-370 parts of water and 6-8 parts of synergist butyl acrylate and tartaric acid, wherein the weight ratio of butyl acrylate to tartaric acid is (5-7):1. The compound provided by the invention can be used for preventing and controlling apple budworms and can be prepared into pesticides for preventing and controlling apple budworms; the preventing and controlling effects are related to the weight ratio of the butyl acrylate to tartaric acid in the raw materials; when the weight ratio of the butyl acrylate to tartaric acid is (5-7):1, the preventing and controlling effects are optimal; and the spraying dosage of the compound provided by the invention is small and the compound is difficult to remain.

Description

A kind of compositions of control of lesser apple-worn and preparation method thereof
Technical field
The invention belongs to pesticide field, be specifically related to compositions of a kind of control of lesser apple-worn and preparation method thereof.
Background technology
Lessor apple-worm has another name called Fructus Mali pumilae little moth moth.Fruit tree pest insect.Become polypide length 4.5～5 millimeters, wing expanse 10～11 milli Rice.All dun purplish metallic luster, protoloma has about 10 to white twill, and there is white flakes finned surface end.Hind wing Taupe.Larva body length 6～9 millimeters, pale red, polypide the metastomium 3～8 joint back side is respectively arranged with 2 pink bands.It is distributed in China Northeast, North China, northwest and Jiangsu etc. save, and occur heavier with South Liaoning and Fructus Mali pumilae producing region, the Shandong Peninsula.Also Japan and court are seen Fresh.Poor to the adaptive faculty of high temperature, limit its distribution south.
Have not yet to see thiapronil and Cupressus funebris alicyclic lactone and work in coordination with the report of control of lesser apple-worn.
Summary of the invention
It is an object of the invention to provide a kind of containing thiapronil with the combination of the control of lesser apple-worn of Cupressus funebris alicyclic lactone Thing and the application in pesticide thereof.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of compositions of control of lesser apple-worn, including the raw material of following weight portion: thiapronil, 20～30 parts；Flat Platycladus orientalis (L.) Franco (Biota orientalis (L.) Endl.) lactone, 10～20 parts；Glycerol, 130～150 parts；Water, 350～370 parts；Synergist butyl acrylate and tartaric acid totally 6～ 8 parts, butyl acrylate and tartaric weight ratio are 5～7:1.
Further, the compositions of described control of lesser apple-worn includes the raw material of following weight portion: thiapronil, 25 Part；Cupressus funebris alicyclic lactone, 15 parts；Glycerol, 140 parts；Water, 360 parts；Totally 7 parts of synergist butyl acrylate and tartaric acid, acrylic acid fourth Ester and tartaric weight ratio are 6:1.
Further, the compositions of described control of lesser apple-worn includes the raw material of following weight portion: thiapronil, 20 Part；Cupressus funebris alicyclic lactone, 10 parts；Glycerol, 130 parts；Water, 350 parts；Totally 6 parts of synergist butyl acrylate and tartaric acid, acrylic acid fourth Ester and tartaric weight ratio are 5:1.
Further, the compositions of described control of lesser apple-worn includes the raw material of following weight portion: thiapronil, 30 Part；Cupressus funebris alicyclic lactone, 20 parts；Glycerol, 150 parts；Water, 370 parts；Totally 8 parts of synergist butyl acrylate and tartaric acid, acrylic acid fourth Ester and tartaric weight ratio are 7:1.
The preparation method of above-mentioned composition, comprises the steps:
Step S1, dissolves thiapronil, Cupressus funebris alicyclic lactone and synergist butyl acrylate G & W；
Step S2, by tartaric acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Advantages of the present invention:
The compositions that the present invention provides with control of lesser apple-worn, can develop into the agriculture of control of lesser apple-worn Medicine.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit the present invention with this and protect model Enclose.Although the present invention being explained in detail with reference to preferred embodiment, it will be understood by those within the art that, can be right Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: the preparation of the compositions of control of lesser apple-worn
Parts by weight of raw materials compares:
Thiapronil, 25 parts；Cupressus funebris alicyclic lactone, 15 parts；Glycerol, 140 parts；Water, 360 parts；Synergist butyl acrylate and wine Stone acid totally 7 parts, butyl acrylate and tartaric weight ratio are 6:1.
Preparation method:
Step S1, dissolves thiapronil, Cupressus funebris alicyclic lactone and synergist butyl acrylate G & W；
Step S2, by tartaric acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 2: the preparation of the compositions of control of lesser apple-worn
Parts by weight of raw materials compares:
Thiapronil, 20 parts；Cupressus funebris alicyclic lactone, 10 parts；Glycerol, 130 parts；Water, 350 parts；Synergist butyl acrylate and wine Stone acid totally 6 parts, butyl acrylate and tartaric weight ratio are 5:1.
Preparation method:
Step S1, dissolves thiapronil, Cupressus funebris alicyclic lactone and synergist butyl acrylate G & W；
Step S2, by tartaric acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 3: the preparation of the compositions of control of lesser apple-worn
Parts by weight of raw materials compares:
Thiapronil, 30 parts；Cupressus funebris alicyclic lactone, 20 parts；Glycerol, 150 parts；Water, 370 parts；Synergist butyl acrylate and wine Stone acid totally 8 parts, butyl acrylate and tartaric weight ratio are 7:1.
Preparation method:
Step S1, dissolves thiapronil, Cupressus funebris alicyclic lactone and synergist butyl acrylate G & W；
Step S2, by tartaric acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 4: the preparation of the compositions of control of lesser apple-worn
Parts by weight of raw materials compares:
Thiapronil, 25 parts；Cupressus funebris alicyclic lactone, 15 parts；Glycerol, 140 parts；Water, 360 parts；Synergist butyl acrylate and wine Stone acid totally 7 parts, butyl acrylate and tartaric weight ratio are 5:1.
Preparation method:
Step S1, dissolves thiapronil, Cupressus funebris alicyclic lactone and synergist butyl acrylate G & W；
Step S2, by tartaric acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 5: the preparation of the compositions of control of lesser apple-worn
Parts by weight of raw materials compares:
Thiapronil, 25 parts；Cupressus funebris alicyclic lactone, 15 parts；Glycerol, 140 parts；Water, 360 parts；Synergist butyl acrylate and wine Stone acid totally 7 parts, butyl acrylate and tartaric weight ratio are 7:1.
Preparation method:
Step S1, dissolves thiapronil, Cupressus funebris alicyclic lactone and synergist butyl acrylate G & W；
Step S2, by tartaric acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 6: comparative example, butyl acrylate and tartaric weight ratio are 4:1
Parts by weight of raw materials compares:
Thiapronil, 25 parts；Cupressus funebris alicyclic lactone, 15 parts；Glycerol, 140 parts；Water, 360 parts；Synergist butyl acrylate and wine Stone acid totally 7 parts, butyl acrylate and tartaric weight ratio are 4:1.
Preparation method:
Step S1, dissolves thiapronil, Cupressus funebris alicyclic lactone and synergist butyl acrylate G & W；
Step S2, by tartaric acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 7: comparative example, butyl acrylate and tartaric weight ratio are 8:1
Parts by weight of raw materials compares:
Thiapronil, 25 parts；Cupressus funebris alicyclic lactone, 15 parts；Glycerol, 140 parts；Water, 360 parts；Synergist butyl acrylate and wine Stone acid totally 7 parts, butyl acrylate and tartaric weight ratio are 8:1.
Preparation method:
Step S1, dissolves thiapronil, Cupressus funebris alicyclic lactone and synergist butyl acrylate G & W；
Step S2, by tartaric acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 8: effect example
Use the field test compositions that respectively prepared by the testing example 1～7 preventing and treating effective percentage to lessor apple-worm (%).
Test sets chemicals treatment group 1～7 and blank group, and chemicals treatment group 1～7 is sprayed embodiment 1～7 respectively and prepared Compositions, blank group spray clear water.Chemicals treatment group agent fountain height 50g/hm in terms of thiapronil2.Plot area is 50m2, random district group arranges.It is repeated 4 times.Use workers and peasants-16 aerosol apparatus spray medicine, spouting liquid 750kg/hm2.With reference to Ministry of Agriculture field Test of pesticide effectiveness criterion, 15d after medicine, calculate preventing and treating effective percentage (%).
Result such as following table.
Preventing and treating effective percentage (%)
Embodiment 1 98
Embodiment 4 92
Embodiment 5 93
Embodiment 6 63
Embodiment 7 61
The effect of embodiment 2,3 is basically identical with embodiment 4,5.
The above results shows, the compositions that the present invention provides can develop into preventing and treating Herba Marsileae Quadrifoliae with control of lesser apple-worn The really pesticide of Grapholita spp, prevention effect is relevant with synergist butyl acrylate in raw material and tartaric weight ratio, and third When olefin(e) acid butyl ester and tartaric weight ratio are 5～7:1, prevention effect is best.If without Cupressus funebris alicyclic lactone, the present invention The preventing and treating effective percentage of compositions is less than 50%.And, it is little that the present composition sprays dose, is difficult to residual.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit the protection of the present invention with this Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent, Essence and protection domain without deviating from technical solution of the present invention.

Claims (5)

1. the compositions of a control of lesser apple-worn, it is characterised in that include the raw material of following weight portion: thiapronil, 20 ～30 parts；Cupressus funebris alicyclic lactone, 10～20 parts；Glycerol, 130～150 parts；Water, 350～370 parts；Synergist butyl acrylate and wine Stone acid totally 6～8 parts, butyl acrylate and tartaric weight ratio are 5～7:1.
The compositions of control of lesser apple-worn the most according to claim 1, it is characterised in that include following weight portion Raw material: thiapronil, 25 parts；Cupressus funebris alicyclic lactone, 15 parts；Glycerol, 140 parts；Water, 360 parts；Synergist butyl acrylate and tartaric acid Totally 7 parts, butyl acrylate and tartaric weight ratio are 6:1.
The compositions of control of lesser apple-worn the most according to claim 1, it is characterised in that include following weight portion Raw material: thiapronil, 20 parts；Cupressus funebris alicyclic lactone, 10 parts；Glycerol, 130 parts；Water, 350 parts；Synergist butyl acrylate and tartaric acid Totally 6 parts, butyl acrylate and tartaric weight ratio are 5:1.
The compositions of control of lesser apple-worn the most according to claim 1, it is characterised in that include following weight portion Raw material: thiapronil, 30 parts；Cupressus funebris alicyclic lactone, 20 parts；Glycerol, 150 parts；Water, 370 parts；Synergist butyl acrylate and tartaric acid Totally 8 parts, butyl acrylate and tartaric weight ratio are 7:1.
5. the preparation method of the arbitrary described compositions of Claims 1 to 4, it is characterised in that comprise the steps:
Step S1, dissolves thiapronil, Cupressus funebris alicyclic lactone and synergist butyl acrylate G & W；
Step S2, by tartaric acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
CN201610474728.7A 2016-06-22 2016-06-22 Compound for preventing and controlling apple budworms and preparation method thereof Pending CN106035345A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610474728.7A CN106035345A (en) 2016-06-22 2016-06-22 Compound for preventing and controlling apple budworms and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610474728.7A CN106035345A (en) 2016-06-22 2016-06-22 Compound for preventing and controlling apple budworms and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106035345A true CN106035345A (en) 2016-10-26

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Country Status (1)

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Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
刘国军 等: "苹果小食心虫的防治措施", 《农村科技》 *
刘红翼 等: "噻丙腈的合成与生物活性", 《精细与专用化学品》 *
叶凤梅 等: "贡山八角枝叶化学成分研究", 《天然产物研究与开发》 *
宋玉泉 等: "新杀虫剂研究进展", 《现代农药》 *

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