CN106030875A - 电化学电池及其组件 - Google Patents

电化学电池及其组件 Download PDF

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Publication number
CN106030875A
CN106030875A CN201480075279.8A CN201480075279A CN106030875A CN 106030875 A CN106030875 A CN 106030875A CN 201480075279 A CN201480075279 A CN 201480075279A CN 106030875 A CN106030875 A CN 106030875A
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China
Prior art keywords
gas
electrode
anode
leaf
core element
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Pending
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CN201480075279.8A
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English (en)
Chinese (zh)
Inventor
G·F·斯维吉斯
D·J·考克斯
D·德拉克鲁斯
S·德拉克鲁斯
S·D·克洛斯
P·S-H·邱
F·W·汤普森
A·纳特斯塔德
D·安蒂奥霍斯
S·T·贝尔尼
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Aquahydrex Pty Ltd
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Aquahydrex Pty Ltd
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Filing date
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Priority claimed from AU2013904806A external-priority patent/AU2013904806A0/en
Application filed by Aquahydrex Pty Ltd filed Critical Aquahydrex Pty Ltd
Publication of CN106030875A publication Critical patent/CN106030875A/zh
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/002Shape, form of a fuel cell
    • H01M8/004Cylindrical, tubular or wound
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031Porous electrodes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • H01M4/8626Porous electrodes characterised by the form
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8636Inert electrodes with catalytic activity, e.g. for fuel cells with a gradient in another property than porosity
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H01M4/8668Binders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H01M4/8673Electrically conductive fillers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8803Supports for the deposition of the catalytic active composition
    • H01M4/8807Gas diffusion layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/023Porous and characterised by the material
    • H01M8/0232Metals or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/023Porous and characterised by the material
    • H01M8/0234Carbonaceous material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/023Porous and characterised by the material
    • H01M8/0239Organic resins; Organic polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/023Porous and characterised by the material
    • H01M8/0241Composites
    • H01M8/0243Composites in the form of mixtures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/023Porous and characterised by the material
    • H01M8/0241Composites
    • H01M8/0245Composites in the form of layered or coated products
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201Reactant storage and supply, e.g. means for feeding, pipes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04276Arrangements for managing the electrolyte stream, e.g. heat exchange
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2484Details of groupings of fuel cells characterised by external manifolds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8825Methods for deposition of the catalytic active composition
    • H01M4/8828Coating with slurry or ink
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04186Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Inert Electrodes (AREA)
  • Secondary Cells (AREA)
  • Hybrid Cells (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Fuel Cell (AREA)
CN201480075279.8A 2013-12-10 2014-12-10 电化学电池及其组件 Pending CN106030875A (zh)

Applications Claiming Priority (11)

Application Number Priority Date Filing Date Title
AU2013904802 2013-12-10
AU2013904806A AU2013904806A0 (en) 2013-12-10 Modular electrochemical cells
AU2013904804 2013-12-10
AU2013904802A AU2013904802A0 (en) 2013-12-10 Composite three-dimensional electrodes and methods of fabrication
AU2013904804A AU2013904804A0 (en) 2013-12-10 Method and electrochemical cell for managing electrochemical reactions
AU2013904807A AU2013904807A0 (en) 2013-12-10 Elements for spiral-wound electrochemical cells
AU2013904803 2013-12-10
AU2013904803A AU2013904803A0 (en) 2013-12-10 Electro-synthetic or electro-energy cell with industrially-beneficial electrodes
AU2013904807 2013-12-10
AU2013904806 2013-12-10
PCT/AU2014/050416 WO2015085369A1 (en) 2013-12-10 2014-12-10 Electrochemical cells and components thereof

Publications (1)

Publication Number Publication Date
CN106030875A true CN106030875A (zh) 2016-10-12

Family

ID=53370377

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480075279.8A Pending CN106030875A (zh) 2013-12-10 2014-12-10 电化学电池及其组件

Country Status (7)

Country Link
US (1) US20160322649A1 (enExample)
EP (1) EP3080855A4 (enExample)
JP (1) JP2017501542A (enExample)
CN (1) CN106030875A (enExample)
AU (1) AU2014361750A1 (enExample)
CA (1) CA2932293A1 (enExample)
WO (1) WO2015085369A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111511459A (zh) * 2017-11-07 2020-08-07 小利兰·斯坦福大学托管委员会 用于电催化的人造肺

Families Citing this family (13)

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Publication number Priority date Publication date Assignee Title
RU2603772C2 (ru) 2012-06-12 2016-11-27 Монаш Юниверсити Воздухопроницаемый электрод и способ применения в расщеплении воды
BR112016002269A2 (pt) 2013-07-31 2017-08-01 Aquahydrex Pty Ltd método e célula eletroquímica para gerenciar reações eletroquímicas
EP3259794B1 (en) * 2015-02-17 2022-04-06 Evoqua Water Technologies LLC Reduced volume electrochlorination cells
WO2017100847A1 (en) * 2015-12-14 2017-06-22 Aquahydrex Pty Ltd Electrochemical cell and components thereof capable of operating at high current density
MX2019002264A (es) * 2016-09-07 2019-07-04 Colgate Palmolive Co Contenedor de producto con dispositivo electroquimico.
US20230021737A1 (en) * 2017-12-22 2023-01-26 Lyten, Inc. Carbon-enhanced fuel cells
JP2022519575A (ja) 2019-02-01 2022-03-24 アクアハイドレックス, インコーポレイテッド 閉じ込められた電解質を有する電気化学システム
EP3699323A1 (en) * 2019-02-20 2020-08-26 Hymeth ApS Electrode system
WO2022190671A1 (ja) * 2021-03-08 2022-09-15 セイコーインスツル株式会社 電気化学セル
JP7426357B2 (ja) * 2021-08-11 2024-02-01 プライムプラネットエナジー&ソリューションズ株式会社 電池の製造方法
WO2023069947A2 (en) 2021-10-18 2023-04-27 The Regents Of The University Of California Seawater electrolysis enables mg(oh)2 production and co2 mineralization
WO2025125209A1 (de) * 2023-12-13 2025-06-19 Verein für das Forschungsinstitut für Edelmetalle und Metallchemie e.V. Polymerelektrolyt-brennstoffzelle, verfahren zu deren herstellung und verfahren zu deren betrieb sowie modul aus mehreren solcher polymerelektrolyt-brennstoffzellen
CN222126585U (zh) * 2024-03-27 2024-12-06 惠州亿纬锂能股份有限公司 一种集流体系统及液冷系统

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US4048383A (en) * 1976-02-09 1977-09-13 Battelle Memorial Institute Combination cell
US4586999A (en) * 1984-10-29 1986-05-06 The Dow Chemical Company Three layer carbon based electrode
US4722773A (en) * 1984-10-17 1988-02-02 The Dow Chemical Company Electrochemical cell having gas pressurized contact between laminar, gas diffusion electrode and current collector
US4865925A (en) * 1987-12-14 1989-09-12 Hughes Aircraft Company Gas permeable electrode for electrochemical system
WO2013185170A1 (en) * 2012-06-12 2013-12-19 University Of Wollongong Gas permeable electrodes and electrochemical cells

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US3697410A (en) * 1971-02-08 1972-10-10 Cci Aerospace Corp Electrodialysis demineralization apparatus
DE2611901C3 (de) * 1975-03-31 1980-05-22 Union Carbide Corp., New York, N.Y. (V.St.A.) Wasserfreie galvanische Zelle
EP0570341B1 (de) * 1992-05-15 1996-09-18 Christ AG Vorrichtung zur kontinuierlichen elektrochemischen Entsalzung wässriger Lösungen
WO2002014224A1 (en) * 2000-08-11 2002-02-21 Ionics, Incorporated Device and method for electrodialysis
JP3954793B2 (ja) * 2000-12-04 2007-08-08 三洋電機株式会社 燃料電池用ガス拡散層およびその製法
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JP4513393B2 (ja) * 2004-04-22 2010-07-28 セイコーエプソン株式会社 燃料電池およびその製造方法
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US4048383A (en) * 1976-02-09 1977-09-13 Battelle Memorial Institute Combination cell
US4722773A (en) * 1984-10-17 1988-02-02 The Dow Chemical Company Electrochemical cell having gas pressurized contact between laminar, gas diffusion electrode and current collector
US4586999A (en) * 1984-10-29 1986-05-06 The Dow Chemical Company Three layer carbon based electrode
US4865925A (en) * 1987-12-14 1989-09-12 Hughes Aircraft Company Gas permeable electrode for electrochemical system
WO2013185170A1 (en) * 2012-06-12 2013-12-19 University Of Wollongong Gas permeable electrodes and electrochemical cells

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111511459A (zh) * 2017-11-07 2020-08-07 小利兰·斯坦福大学托管委员会 用于电催化的人造肺

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WO2015085369A1 (en) 2015-06-18
EP3080855A1 (en) 2016-10-19
EP3080855A4 (en) 2017-07-26
AU2014361750A1 (en) 2016-06-09
US20160322649A1 (en) 2016-11-03
CA2932293A1 (en) 2015-06-18
JP2017501542A (ja) 2017-01-12

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Application publication date: 20161012