CN106026339A

CN106026339A - Charging system for electric automobile

Info

Publication number: CN106026339A
Application number: CN201610438147.8A
Authority: CN
Inventors: 向华
Original assignee: Shanghai Hejide Dynamic Hydrogen Machine Co Ltd
Current assignee: Shanghai Hejide Dynamic Hydrogen Machine Co Ltd
Priority date: 2016-06-17
Filing date: 2016-06-17
Publication date: 2016-10-12

Abstract

The invention discloses a charging system for an electric automobile. The charging system comprises a self-powered ecological system and a charging terminal, wherein the self-powered ecological system is connected with the charging terminal for supplying power for the charging terminal; the charging terminal comprises a fixed station and a movable charging mechanism, the movable charging mechanism is used for charging through the fixed station and then is connected with the electric automobile for charging the electric automobile, so that unused batteries in the electric automobile can be charged when the electric automobile is driven, or batteries being used in the electric automobile can be charged. According to the charging system for the electric automobile provided by the invention, the electric automobile can be charged in the vehicle driving process, and the problem that charging for the electric automobile is slow is solved.

Description

Charging system for electric automobile

Technical field

The invention belongs to electric vehicle engineering field, relate to a kind of charging system, particularly relate to a kind of electric automobile Charging system.

Background technology

Auto industry is the second largest industry being only second to petrochemical industry in the world, and at present, major part automobile is all with vapour Oil, diesel oil are fuel, not only consume substantial amounts of petroleum resources, and nitrogen oxides contained in vehicle exhaust, Hydrocarbons, carbon monoxide etc. cause the severe contamination of air.In order to keep the sustainable development of national economy, Protection human residential environment and guarantee energy resource supply, countries in the world government puts into substantial amounts of human and material resources one after another and seeks Solve the various approach of certainly these problems.

Currently mainly having two kinds of energy-conservation approach, a kind of is the hybrid vehicle with Toyota as representative, another kind of It it is the pure electric automobile with tesla as representative.The starting of hybrid vehicle is slow, and fuel is still gasoline or bavin Oil, it is impossible to the problem inherently solving resource, pollution.Pure electric automobile needs specific charging pile, it is more difficult to Universal, and flying power is poor.

Fuel cell be a kind of without combustion process directly in electrochemical reaction mode by fuel and oxidant Chemical energy is changed into the efficient generating apparatus of electric energy, and its work process is not limited by Carnot cycle, and conversion efficiency is high, Almost without pollutant emission.FC-EV with fuel cell as power not only can protect environment but also Energy shortage can be alleviated and readjust the energy structure, it has also become one of important trend of future automobile development, being to work as Modern world energy sources and the focus of field of traffic exploitation.

Fuel cell can be divided into alkaline fuel cell, phosphoric acid fuel cell, fused carbonate to fire by electrolyte classification Five classes such as material battery, SOFC, Proton Exchange Membrane Fuel Cells.And automobile fuel battery Requirement be: can work at normal temperatures, electric current density is high, and non-maintaining property is good, and resistance to vibration is good with resistance to impact, High efficiency operating can be carried out from underload to high load capacity.Proton Exchange Membrane Fuel Cells (PEMFC) disclosure satisfy that These performance requirements, therefore become the most ripe vehicle fuel battery with fastest developing speed.Combustion based on PEMFC Material battery car need hydrogen as fuel, since fuel cell is born, hydrogen source problem and fuel cell itself It is the core technology of no less important, and the research and development of hydrogen source have become fuel cell car and moved towards business from demonstration The important step changed.

At present, domestic electric automobile (including plug-in hybrid vehicle, pure electric automobile) charging needs to consume Long period.Pure electric automobile generally cannot travel the long period；Plug-in hybrid vehicle travels long-time Time, also it is only capable of consuming gasoline.

In view of this, nowadays in the urgent need to designing a kind of new charging modes, in order to overcome existing charging modes to deposit Drawbacks described above.

Summary of the invention

The technical problem to be solved is: provides a kind of charging system for electric automobile, can travel at vehicle During be charging electric vehicle, solve the slow problem of charging electric vehicle.

For solving above-mentioned technical problem, the present invention adopts the following technical scheme that

A kind of charging system for electric automobile, described charging system includes: self-powered ecosystem, charging terminal； Self-powered ecosystem is connected with charging terminal, powers for charging terminal；

Described charging terminal includes fixed station, mobile charging mechanism, and mobile charging mechanism is filled by fixed station Electricity, then connecting electric automobile, for charging electric vehicle, can be when electric automobile during traveling electric automobile not The battery charging used, or the battery charging being currently in use for electric automobile；

Described self-powered ecosystem includes: wind-power generation unit, solar power generation unit, methanol generator unit, Rechargeable battery, charhing unit, biogas alcohol unit, electricity Hydrogen Unit, methanol Preparation equipment, main control unit；

Described main control unit connects wind-power generation unit, solar power generation unit, methanol generator unit respectively, fills Electricity battery, charhing unit, biogas alcohol unit, electricity Hydrogen Unit, methanol Preparation equipment, control unit Work；

Described wind-power generation unit, solar power generation unit, methanol generator unit connect electrical equipment respectively, directly Connect and power for electrical equipment；

Described wind-power generation unit, solar power generation unit, methanol generator unit connect charhing unit respectively, logical Overcharge unit is rechargeable battery charging；

Described main control unit is also in order to obtain the opening of electrical equipment, thus obtains real-time need for electricity number According to；Meanwhile, main control unit obtain wind-power generation unit, solar power generation unit, methanol generator unit real-time Generated energy data；

Described main control unit does corresponding control according to real-time need for electricity data, real-time generated energy data；Work as generating When amount data are more than need for electricity data, controlling charhing unit by unnecessary electric energy is rechargeable battery charging；Work as generating When amount data are less than need for electricity data, it is that electrical equipment is powered by starting rechargeable battery；

Prepared methanol, in order to biomass are prepared methanol by fermentation, is stored to first by described biogas alcohol unit Alcohol memory element；

Described methanol generator unit utilizes methanol to generate electricity, and generates carbon dioxide simultaneously, by defeated for the carbon dioxide generated Deliver to methanol Preparation equipment；

Described electricity Hydrogen Unit, in order to by water electrolysis, obtains hydrogen and oxygen, hydrogen is delivered to methanol preparation and sets Standby；Electricity Hydrogen Unit starts when generated energy remaining data reaches setting value, utilizes surplus electric energy hydrogen manufacturing；

Described methanol Preparation equipment prepares methanol in order to utilize hydrogen, carbon dioxide；Described methanol Preparation equipment exists Generated energy remaining data starts when reaching to set high level, prepares methanol；

Described methanol generator unit includes hydrogen production by methanol system, hydrogen gas generating system, hydrogen production by methanol system and hydrogen Electricity generation system connects；

Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, system Hydrogen subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；

Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes that solid hydrogen stores and holds Device, storage container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；

Described storage container includes: what container, the space mechanism being arranged in container were connected with space mechanism drives Motivation structure, control module, induction module；Container is at least divided into two spaces by described space mechanism；Two skies In between, a placing response liquid, opposite side arrange hydrogen gas generating system release, the liquid then compressed or The carbon dioxide of solid-state；Control module connects drive mechanism, induction module respectively；Described drive mechanism includes electricity Machine, induction module includes pressure transducer or/and liquid level sensor；Described induction module is in order to sense in container The amount of reaction liquid, sensing hydrogen gas generating system release simultaneously, the liquid then compressed or the titanium dioxide of solid-state The amount of carbon；And sensed data is sent to control module；The data that described control module senses according to induction module Control the drive mechanism action to space mechanism；Liquid in storing container reduces or carbon dioxide increases up to When imposing a condition, drive mechanism drives space mechanism action, reduces the volume of reaction liquid, increases carbon dioxide Volume；Described storage container also includes liquefying plant or/and solidification equipment, the carbon dioxide liquid that will collect Change or/and solidify；

Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, Separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen store container, store container respectively with hydrogen producer Connect；Store the first alcohol and water storing liquid in container；

Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes that first opens Dynamic device, the second starter；Described first starter includes the first heating arrangements, the first gasification pipe, The internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；Institute State one end of the first gasification pipe to connect and store container, by raw material conveying device, methanol sent into the first vapor lamp Lu Zhong；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition； Or, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, Methanol directly spontaneous combustion after the first gasification pipe output；Described second starter includes the second gasification pipe, the The main body of two gasification pipe is arranged at described reformer chamber, and the first gasification pipe is or/and the second gasification pipe exports Methanol be reformer chamber heating while heat the second gasification pipe, by the methanol gasifying in the second gasification pipe； Described reformer chamber inwall is provided with and adds pipe line, is placed with catalyst in adding pipe line；Described device for rapidly starting passes through Add described in heating pipe line attach most importance to whole room heating；After described hydrogen generating system starts, hydrogen generating system passes through hydrogen producer The hydrogen prepared provides the energy needed for running；

The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts module Including the solar panel being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts Module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual Electromotor, the electric energy sent is stored in battery by manual generator；

Described catalyst include the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, The oxide of Zn, rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for catalysis The 0.6%～1.8% of agent gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, and the oxide of Cu accounts for catalysis The 6%～12% of agent gross mass, the oxide of Fe accounts for the 3%～8% of catalyst gross mass, and the oxide of Zn accounts for catalysis The 8%～20% of agent gross mass, rare-earth oxide accounts for the 6%～40% of catalyst gross mass, and remaining is transition gold Belong to oxide；

Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the CuO of 3-17 part, The Al of ZrO, 55-80 part of the ZnO of 3-18 part, 0.5-3 part₂O₃, the CeO of 1-3 part₂, the La of 1-3 part₂O₃；

Described solid hydrogen stores and stores solid hydrogen in container, when hydrogen generating system starts, by gasification module Solid hydrogen is converted to gaseous hydrogen, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, The startup energy as hydrogen producer；

First alcohol and water in described storage container is delivered to heat exchanger heat exchange by raw material conveying device, and heat exchange is laggard Enter vaporizer gasification；Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with catalyst, Reformer chamber bottom and middle portion temperature are 300 DEG C～420 DEG C；The temperature on described reformer chamber top is 400 DEG C～570 DEG C； Reformer chamber is connected by connecting line with separation chamber, connecting line be completely or partially arranged at the upper of reformer chamber Portion, can continue the heating gas from reformer chamber output by the high temperature on reformer chamber top；Described connecting line conduct Buffering between reformer chamber and separation chamber so that from the temperature phase of the temperature of the gas of reformer chamber output with separation chamber Same or close；Temperature in described separation chamber is set as 350 DEG C～570 DEG C；Membrane separator it is provided with in separation chamber, Hydrogen is obtained from the aerogenesis end of membrane separator；

Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Described former Material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough Pressure；

After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is tieed up by burning Hold hydrogen producer to run；

The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and separates, and divides for separating the film of hydrogen Difference from the inside and outside pressure of device is more than or equal to 0.7MPa；Described membrane separation device is true at porous ceramic surface The membrane separation device of empty plating palladium-silver, film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, silver accounts for 22%～25%；

Prepared hydrogen is passed through transfer conduit real-time Transmission to hydrogen gas generating system by described hydrogen manufacturing subsystem；Described Transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system Utilize the hydrogen gas generation that hydrogen manufacturing subsystem prepares；

Described air pressure adjustment subsystem include microprocessor, gas pressure sensor, valve positioner, air outlet valve, Outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the air pressure in transfer conduit Data, and the barometric information of sensing is sent to microprocessor；Described microprocessor will be from gas pressure sensor This barometric information received is compared with setting threshold interval；When the pressure data received is higher than setting threshold value Interval maximum, microprocessor control valve door controller is opened air outlet valve and is set the time so that in transfer conduit Air pressure is in set point, and one end of outlet pipe connects air outlet valve simultaneously, and the other end connects described hydrogen manufacturing subsystem System, is heated by the firing equipment that needs that burning is hydrogen manufacturing subsystem；When the pressure data received is less than setting Determining the minima of threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material；

Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, divides from expellant gas Do not collect hydrogen, oxygen gas and water, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generation System uses, and the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycles；

Described Collection utilization subsystem includes that hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separate Device, oxygen check valve, by hydrogen and oxygen separation, be separated from water hydrogen, oxygen is separated from water the most respectively；

Described hydrogen gas generating system includes that fuel cell, fuel cell include some sub-fuel cell modules, each Sub-fuel cell module includes at least one super capacitor；

Described hydrogen producer also includes that electric energy estimation block, hydrogen prepare detection module, electric energy memory module；Institute State whether the electric energy that electric energy estimation block sends in real time in order to estimate hydrogen gas generating system can meet reformation, when separating Need the electric energy consumed；If it is satisfied, then closedown device for rapidly starting；

It is the most stable that hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer；If hydrogen producer The hydrogen of preparation is unstable, then control device for rapidly starting and be again started up, and the electric energy part obtained be stored in Electric energy memory module, uses when electric energy is not enough to the consumption providing hydrogen producer；

Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, electricity Heap；The gas of described gas supply device utilization compression is as power, in automatic transport to pile；

Described fuel cell system also includes air intake conduit, outlet pipe；The gas of described compression is predominantly Oxygen；Air enters pile with oxygen after mixing container mixing；

Described fuel cell system also includes gas regulating system；Described gas regulating system includes valve regulated control Device processed, and oxygen content sensor is or/and compressed gas compression ratio sensor；

Described oxygen content sensor mixes the air of mixing and the content of oxygen in oxygen in container in order to sense, And the data sensed are sent to valve regulated control device；

Described compressed gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data that will sense Send to valve regulated control device；

Described valve regulated controls device according to oxygen content sensor or/and compressed gas compression ratio sensor Sensing result regulation oxygen delivery valve door, air entrainment valve door, control compressed oxygen, the conveying ratio of air； Mixed gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container；

Described fuel cell system also includes humidification system, and humidification system includes that humidity exchanging container, humidity exchange Pipeline, humidity exchange pipeline is a part for air intake conduit；Gas through fuel cell reaction passes through Air pipe is delivered to humidity exchanging container；

The material of described humidity exchange pipeline is the most permeable airtight so that after reaction, gas carries out wet with natural air Degree exchange, and cannot circulate between gas；

Described methanol Preparation equipment includes: nitrogen gas conveying device, hydrogen conveyor, carbon dioxide conveyer device, First blender, the second blender, micro fixed-bed reactor, counterbalance valve, alcohol-water separation device, chromatograph, Methanol solution gasifying device, methanol collect container, main control module；Described carbon dioxide conveyer device connects described storage The side of container collection carbon dioxide；The methanol prepared is delivered to store the methanol-water mixed liquor one of container Side；

Described nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline is provided with One stop valve, the first mass flowmenter；

Described carbon dioxide conveyer device includes carbon dioxide storage container, the second transfer pipeline, the second conveying pipe Road is provided with the second stop valve, the second mass flowmenter；

Described hydrogen conveyor includes hydrogen storage vessel, the 3rd transfer pipeline, the 4th transfer pipeline, the 3rd Transfer pipeline is provided with the 3rd stop valve, the 3rd mass flowmenter, the 4th transfer pipeline be provided with the 4th stop valve, Four mass flowmenters；

Described hydrogen storage vessel is connected by the 3rd transfer pipeline and the first transfer pipeline, the 3rd transfer pipeline and First transfer pipeline is intersected in one first three-way valve；

Described hydrogen storage vessel is connected by the 4th transfer pipeline and the second transfer pipeline, the 4th transfer pipeline and Second transfer pipeline is intersected in one first cross valve；

Described first three-way valve and the first blender connect, and the other end of the first blender and the second three-way valve are even Connect；Second three-way valve connects micro fixed-bed reactor by the 5th transfer pipeline, and the 5th transfer pipeline is provided with the Five mass flowmenters, pressure gage；

The other end of described micro fixed-bed reactor connects the 4th three-way valve, and the 4th three-way valve is also connected with back pressure Valve, the other end of counterbalance valve connects one second cross valve；

Described first cross valve and the second blender connect, and the other end of the second blender and the 3rd three-way valve are even Connect；Alcohol-water separation device, the second three-way valve connect the 3rd three-way valve, alcohol-water separation device, methanol solution gasifying device, color Spectrometer connects the second cross valve；Methanol solution gasifying device is collected container with methanol and is connected；

Described master control module controls all parts action, first controls high pure nitrogen and high-purity hydrogen with the ratio set Being emptied by beds after the first blender mixing, treating that catalyst reduction completes rear cutout ventilation body is hydrogen Gas and the gaseous mixture of carbon dioxide, gas boosts to certain pressure again through alcohol water by beds through counterbalance valve Separator isolates Methanol product and water, and unreacted gas continues through reactor after unstripped gas supplements and follows Ring reacts.

Described charging terminal includes fixed station, mobile charging mechanism, and mobile charging mechanism is filled by fixed station Electricity, then connecting electric automobile, for charging electric vehicle, can be when electric automobile during traveling electric automobile not The battery charging used, or the battery charging being currently in use for electric automobile.

As a preferred embodiment of the present invention, described self-powered ecosystem includes: methanol generator unit, fill Electricity battery, charhing unit, methanol Preparation equipment, main control unit；

Described main control unit connects methanol generator unit, rechargeable battery, charhing unit, methanol Preparation equipment respectively, Control the work of unit；

Described methanol generator unit connects electrical equipment, powers for electrical equipment；Described methanol generator unit is respectively Connect charhing unit, be that rechargeable battery charges by charhing unit；

Described main control unit is also in order to obtain the opening of electrical equipment, thus obtains real-time need for electricity number According to；Meanwhile, main control unit obtains the real-time generated energy data of methanol generator unit；

Described methanol Preparation equipment prepares methanol in order to utilize hydrogen, carbon dioxide；Described methanol Preparation equipment exists Generated energy remaining data starts when reaching to set high level, prepares methanol.

As a preferred embodiment of the present invention, described self-powered ecosystem also includes wind-power generation unit, too Sun can generator unit, biogas alcohol unit, electricity Hydrogen Unit；

Described electricity Hydrogen Unit, in order to by water electrolysis, obtains hydrogen and oxygen, hydrogen is delivered to methanol preparation and sets Standby；Electricity Hydrogen Unit starts when generated energy remaining data reaches setting value, utilizes surplus electric energy hydrogen manufacturing.

As a preferred embodiment of the present invention, described methanol generator unit includes that hydrogen production by methanol system, hydrogen are sent out Electricity system, hydrogen production by methanol system is connected with hydrogen gas generating system；

As a preferred embodiment of the present invention, described hydrogen gas generating system includes fuel cell, fuel cell bag Including some sub-fuel cell modules, each sub-fuel cell module includes at least one super capacitor；

The material of described humidity exchange pipeline is the most permeable airtight so that after reaction, gas carries out wet with natural air Degree exchange, and cannot circulate between gas.

As a preferred embodiment of the present invention, described methanol Preparation equipment includes: nitrogen gas conveying device, hydrogen Conveyer device, carbon dioxide conveyer device, the first blender, the second blender, micro fixed-bed reactor, Counterbalance valve, alcohol-water separation device, chromatograph, methanol solution gasifying device, methanol collect container, main control module；Described Carbon dioxide conveyer device connects the side of described storage container collection carbon dioxide；The methanol conveying prepared To the methanol-water mixed liquor side storing container；

The beneficial effects of the present invention is: the charging system for electric automobile that the present invention proposes, can run at vehicle Journey is charging electric vehicle, solves the problem that charging electric vehicle is slow.

Accompanying drawing explanation

Fig. 1 is the composition schematic diagram of charging system for electric automobile of the present invention.

Fig. 2 is the composition schematic diagram of hydrogen production by methanol system in present system.

Fig. 3 is the structural representation of device for rapidly starting in hydrogen producer

Fig. 4 is hydrogen producer and the structural representation adding pipe line thereof.

Fig. 5 is the composition schematic diagram of the hydrogen producer being provided with relief valve.

Fig. 6 is the schematic diagram under the another kind of state of the hydrogen producer being provided with relief valve.

Fig. 7 is the composition schematic diagram of fuel cell system in present system.

Fig. 8 is the structural representation of liquid container.

Fig. 9 is the composition schematic diagram of methanol Preparation equipment in present system.

Detailed description of the invention

Describe the preferred embodiments of the present invention below in conjunction with the accompanying drawings in detail.

Embodiment one

Referring to Fig. 1, present invention is disclosed a kind of charging system for electric automobile, described charging system includes: from Power supply ecosystem, charging terminal；Self-powered ecosystem is connected with charging terminal, powers for charging terminal.

Described self-powered ecosystem includes: wind-power generation unit, solar power generation unit, methanol generator unit, Rechargeable battery, charhing unit, biogas alcohol unit, electricity Hydrogen Unit, methanol Preparation equipment, main control unit.

Described main control unit connects wind-power generation unit, solar power generation unit, methanol generator unit respectively, fills Electricity battery, charhing unit, biogas alcohol unit, electricity Hydrogen Unit, methanol Preparation equipment, control unit Work.

Described wind-power generation unit, solar power generation unit, methanol generator unit connect electrical equipment respectively, directly Connect and power for electrical equipment.Described wind-power generation unit, solar power generation unit, methanol generator unit connect respectively Connect charhing unit, be that rechargeable battery charges by charhing unit.

Described main control unit also in order to obtain electrical equipment (equipment that charging terminal is charging can be included, and Self-powered ecosystem self) opening, thus obtain real-time need for electricity data；Meanwhile, master control list Unit obtains wind-power generation unit, solar power generation unit, the real-time generated energy data of methanol generator unit.

Described main control unit does corresponding control according to real-time need for electricity data, real-time generated energy data；Work as generating When amount data are more than need for electricity data, controlling charhing unit by unnecessary electric energy is rechargeable battery charging；Work as generating When amount data are less than need for electricity data, it is that electrical equipment is powered by starting rechargeable battery.

Prepared methanol, in order to biomass are prepared methanol by fermentation, is stored to first by described biogas alcohol unit Alcohol memory element.

Described methanol generator unit utilizes methanol to generate electricity, and generates carbon dioxide simultaneously, by defeated for the carbon dioxide generated Deliver to methanol Preparation equipment.

Described methanol generator unit includes hydrogen production by methanol system, hydrogen gas generating system, hydrogen production by methanol system and hydrogen Electricity generation system connects.

In the present embodiment, referring to Fig. 2, hydrogen production by methanol system is small portable hydrogen producer, including: liquid Body stores container 10, raw material conveying device 50, device for rapidly starting 40, device for producing hydrogen 20, membrane separation device 30, hydrogen delivery tube road 60.

Referring to Fig. 8, the middle part of liquid container is provided with dividing plate 101, and the side of dividing plate 101 arranges reaction Liquid, opposite side arranges hydrogen gas generating system release, the liquid then compressed or the carbon dioxide of solid-state.Every Plate 101 connects drive mechanism, and the liquid in storing container reduces or carbon dioxide increases up to impose a condition Time, drive mechanism drives dividing plate action, reduces the volume of storage reaction liquid regions, increases storage carbon dioxide The volume in region.The carbon dioxide of release so while preparing hydrogen, can be collected, reduce carbon dioxide The discharge of gas, the carbon dioxide of collection is also used as the raw material of subsequent handling.The two ends of dividing plate 101 are arranged In chute 102, can slide along chute 102.

Described liquid container can also include control module, induction module；Described drive mechanism includes motor, Induction module includes pressure transducer or/and liquid level sensor；Described induction module is in order to react in sensing container The amount of liquid, the carbon dioxide of sensing hydrogen gas generating system release simultaneously, the liquid then compressed or solid-state Amount；And sensed data is sent to control module；The Data Control that described control module senses according to induction module The drive mechanism action to space mechanism；Liquid in liquid storage container reduces or carbon dioxide increases up to When imposing a condition, drive mechanism drives space mechanism action, reduces the volume of reaction liquid, increases carbon dioxide Volume.Described liquid container also can include liquefying plant or/and solidification equipment, two will collected Carbonoxide liquefaction is or/and solidify；

As it is shown on figure 3, described device for rapidly starting 40 includes housing 41, heating arrangements 42, gasification pipe 43, the internal diameter of gasification pipe 43 is 1～2mm, and gasification pipe 43 is wound on heating arrangements 42；Described add Heat engine structure can be electrically heated rod, utilizes alternating current or accumulator, aneroid battery.

One end of described gasification pipe 43 connects liquid container 10, is sent into by methanol in gasification pipe 43； The other end of gasification pipe 43 exports vaporized methanol, then by ignition mechanism ignition；Or, The other end of gasification pipe 43 exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, methanol Directly spontaneous combustion after gasification pipe 43 exports；Described device for rapidly starting 40 is that device for producing hydrogen is (the most whole Hydrogen producer) the startup energy is provided.

Refer to Fig. 4, in order to improve the firing rate of device for producing hydrogen, in the reformer chamber of described device for producing hydrogen 20 Inwall is provided with and adds pipe line 21, is placed with catalyst (as can be heating and temperature control existed in adding pipe line 21 380 DEG C～480 DEG C)；Described device for rapidly starting 40 heats for reformer chamber by adding pipe line 21 described in heating, The efficiency of heating surface can be improved.

As in figure 2 it is shown, device for producing hydrogen 20 can also arrange the second starter 70, described second starter 70 include that the second gasification pipe, the main body of the second gasification pipe are arranged at reformer chamber, and the second gasification pipe is Reformer chamber heating (can also be the heating of other unit of hydrogen producer).First gasification pipe is or/and the second vapor lamp The methanol of road output is to heat the second gasification pipe, by the methanol in the second gasification pipe while reformer chamber heats Gasification.When the second starter can persistently prepare gasification methanol after set the time, can close above-mentioned quickly Starter, thus reduce the dependence to extra powers such as electric energy further.

In addition, described device for producing hydrogen 20 includes heat exchanger, vaporizer, reformer chamber；Membrane separation device sets Being placed in separation chamber, separation chamber is arranged at the top of reformer chamber.Described liquid container is with device for producing hydrogen even Connect；Liquid container stores the first alcohol and water of liquid.

First alcohol and water in described liquid container is delivered to heat exchanger heat exchange, heat exchange by raw material conveying device Rear entrance vaporizer gasifies；Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with catalysis Agent, reformer chamber bottom and middle portion temperature are 300 DEG C～420 DEG C.The temperature on described reformer chamber top is 400 DEG C ～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, connecting line be completely or partially arranged at reformation The top of room, can continue the heating gas from reformer chamber output by the high temperature on reformer chamber top；Described connecting tube Road is as the buffering between reformer chamber and separation chamber so that from temperature and the separation chamber of the gas of reformer chamber output Temperature is identical or close.Temperature in described separation chamber is set as 350 DEG C～570 DEG C；It is provided with film in separation chamber to divide From device, obtain hydrogen from the aerogenesis end of membrane separator.By above-mentioned improvement, can ensure that reformer chamber is urged respectively The low temperature requirements of agent, and the high temperature requirement of separation chamber, and then improve hydrogen preparation efficiency；Meanwhile, this Bright preheating method (separation chamber is arranged at the top of reformer chamber) is the most convenient.

Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the CuO of 3-17 part, The Al of ZrO, 55-80 part of the ZnO of 3-18 part, 0.5-3 part₂O₃, the CeO of 1-3 part₂, the La of 1-3 part₂O₃。

Additionally, described raw material conveying device provides power, the feedstock transportation in liquid container to hydrogen manufacturing is filled Put；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that device for producing hydrogen prepares There is enough pressure.The hydrogen that described device for producing hydrogen prepares is delivered to membrane separation device and separates, for dividing Difference from the inside and outside pressure of the membrane separation device of hydrogen is more than or equal to 0.7MPa.By this improvement so that hydrogen manufacturing The hydrogen that device prepares has enough pressure, can improve hydrogen production efficiency and the purity of prepared hydrogen.

After described hydrogen producer starts, the hydrogen that hydrogen producer is prepared by device for producing hydrogen provides the energy needed for running Source；At this point it is possible to closedown device for rapidly starting.The hydrogen partial prepared due to device for producing hydrogen is or/and residual air is led to Crossing burning maintains hydrogen producer to run, such that it is able to reduce the dependence to extra power, adaptive ability is strong.

The high-temperature gas that described hydrogen producer is discharged, as the thermal source of air conditioning for automobiles heating installation, passes through heat-exchange device For Vehicle heating；Heat-exchange device includes some heat exchanging pipes, is the circulation gas of vehicle air conditioning in heat exchanging pipe Body, the high-temperature gas discharged for hydrogen producer outside heat exchanging pipe or the high-temp liquid after being heated by high-temperature gas.

Described heat-exchange device is provided with microprocessor, valve positioner, hot-gas temperature sensor, flow Sensor, microprocessor connecting valve controller, hot-gas temperature sensor, flow transducer, car respectively Air-conditioner controller, according to hot-gas temperature sensor, the temperature of the high-temperature gas of flow transducer sensing, The control state modulator valve positioner of flow and vehicle air conditioning, adjusts the size of valve by valve positioner, Thus adjust the flow of the high-temperature gas led in heat-exchange device.

Additionally, refer to Fig. 5, Fig. 6, described hydrogen delivery tube road 60 is provided with spring safety valve 61, spring Relief valve 61 includes valve body, spring mechanism, end of upspringing；Described raw material conveying device 50 includes delivery pump, End of upspringing arranges (certain raw material conveying device 50 can also be for other power set) near the switch of delivery pump, The switch of raw material conveying device can be disconnected when end of upspringing is upspring.By arranging machine security on hydrogen delivery tube road Valve, when air pressure reaches setting value, mechanical safety valve is opened, and can control raw material conveying device stopping transferring raw material. Such that it is able to improve the safety that equipment runs, prevent hydrogen leak and blast.

Specifically, in the present embodiment, the switch of described delivery pump includes contact-segment 62 and three ports, three Port is respectively first port the 63, second port the 64, the 3rd port 65.One end of described contact-segment 62 can Being rotatably provided in the first port 63, the first port 63 connects delivery pump；The other end of contact-segment 62 can connect Touch the second port 64 or the 3rd port 65.

Described second port 64 connects power supply, when the first port 63 connects the second port 64, can control conveying Pump work.Described 3rd port 65 connects alarm transmitting device, when the first port connects three ports 65, Can control conveying air pump inoperative, alarm transmitting device sends warning message (as by the way of note) extremely simultaneously Corresponding server or client, can notify corresponding personnel.

Described hydrogen gas generation device connects hydrogen producer, and the Partial DC electricity sent is delivered to hydrogen producer；System Hydrogen storage equipment drives electromagnetic heater to be reformer chamber, separation chamber's heating by the unidirectional current oneself prepared；Meanwhile, Also the unidirectional current sent is delivered to the deep sea water extracting device of system, sea water purifying plant, oxygen conveying set Standby, water generation equipment, runs for these equipment, goes back hydrogen supply gas electric generating apparatus self-operating simultaneously.

Described hydrogen producer includes electromagnetic heater；Electromagnetic heater includes the reformation cylinder forming reformer chamber Body, the separation cylinder body of formation separation chamber, the first heating coil being arranged at outside reformation cylinder body, separate outside cylinder body Second heating coil, reformation cylinder body, the temperature sensor separated in cylinder body, pressure transducer, and electromagnetism control Device processed；Electromagnetic controller according to the Data Control first that temperature sensor, pressure transducer sense heat coil, The electric current of the second heating coil, can make reformer chamber, separation chamber moment reach design temperature.

Described hydrogen producer also includes that electric energy estimation block, hydrogen prepare detection module, electric energy memory module；Institute State whether the electric energy that electric energy estimation block sends in real time in order to estimate hydrogen gas generation device can meet reformation, when separating Need the electric energy consumed；If it is satisfied, then closedown device for rapidly starting.

It is the most stable that hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer；If hydrogen producer The hydrogen of preparation is unstable, then control device for rapidly starting and be again started up, and the electric energy part obtained be stored in Electric energy memory module, uses when electric energy is not enough to the consumption providing hydrogen producer.

Referring to Fig. 7, in the present embodiment, described hydrogen gas generation device 200 is fuel cell system, fuel electricity Cell system includes: gas supply device, pile 201；Described gas supply device utilizes the gas conduct of compression Power, in automatic transport to pile 201.

In the present embodiment, gas supply device is compressed gas feedway 202, and described compressed gas is delivered to Entering pile 201 after one mixing container 203, one end of mixing container 203 connects air；Compressed gas enters Natural air is reacted by the power produced after mixing container 203 in setting ratio inspiration pile, and regulation oxygen contains Amount.

Described fuel cell system also includes air intake conduit, outlet pipe, air intake conduit, escape pipe Road is all through humidification system 204.The gas of described compression is mainly oxygen (can also be for air)；Naturally empty Gas enters pile 201 with compressed oxygen after mixing container mixing.

Described fuel cell system also includes gas regulating system, and gas regulating system is arranged at mixing container 203 In；Described gas regulating system includes that valve regulated controls device, and oxygen content sensor is or/and compress Gas compression compares sensor.

Described oxygen content sensor mixes the air of mixing and the content of oxygen in oxygen in container in order to sense, And the data sensed are sent to valve regulated control device.

Described compressed gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data that will sense Send to valve regulated control device.

Described valve regulated controls device according to oxygen content sensor or/and compressed gas compression ratio sensor Sensing result regulation oxygen delivery valve door, air entrainment valve door, control compressed oxygen, the delivery ratio of natural air Example (if natural air ratio can be 0-70%)；The power that compressed oxygen produces after entering mixing container will be mixed Close gas and push to pile reaction, utilize natural air to do dilution decompression.

Described humidification system 204 includes that humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is air A part for air inlet pipeline；Gas through fuel cell reaction is delivered to humidity exchange by outlet pipe to be held Device.

The material of described humidity exchange pipeline is the most permeable airtight so that after reaction, gas carries out wet with natural air Degree exchange, and cannot circulate between gas.Humidity exchange pipeline spiral in humidity exchanging container is arranged, permissible Fully carry out humidity exchange.

Referring to Fig. 9, described methanol Preparation equipment includes: nitrogen gas conveying device A1, hydrogen conveyor A2, Carbon dioxide conveyer device A3, the first blender A4, the second gaseous mixture A5, micro fixed-bed reactor A7, Counterbalance valve A8, alcohol-water separation device A6, chromatograph A9, methanol solution gasifying device, methanol collect container, master control mould Block.

Described nitrogen gas conveying device A1 includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline sets There are the first stop valve A11, the first mass flowmenter A12.

Described carbon dioxide conveyer device A3 includes carbon dioxide storage container, the second transfer pipeline, and second is defeated Pipeline is sent to be provided with the second stop valve, the second mass flowmenter.

Described hydrogen conveyor A3 includes hydrogen storage vessel, the 3rd transfer pipeline, the 4th transfer pipeline, 3rd transfer pipeline is provided with the 3rd stop valve, the 3rd mass flowmenter, the 4th transfer pipeline be provided with the 4th stop valve, 4th mass flowmenter.

Described hydrogen storage vessel A3 is connected by the 3rd transfer pipeline and the first transfer pipeline, the 3rd conveying pipe Road and the first transfer pipeline are intersected in one first three-way valve A13.

Described hydrogen storage vessel is connected by the 4th transfer pipeline and the second transfer pipeline, the 4th transfer pipeline and Second transfer pipeline is intersected in one first cross valve A14.

Described first three-way valve A13 and the first blender A4 connects, the other end and second of the first blender A4 Three-way valve A15 connects；Second three-way valve A15 connects micro fixed-bed reactor A7 by the 5th transfer pipeline, 5th transfer pipeline is provided with the 5th mass flowmenter, pressure gage.

The other end of described micro fixed-bed reactor A7 connects the 4th three-way valve A16, the 4th three-way valve A16 The other end being also connected with counterbalance valve A8, counterbalance valve A8 connects one second cross valve A10.

Described first cross valve A14 and the second blender A5 connects, the other end and the 3rd of the second blender A5 Three-way valve A17 connects；Alcohol-water separation device A6, the second three-way valve A15 connect the 3rd three-way valve A17, alcohol moisture The second cross valve A10 is connected from device A6, methanol solution gasifying device, chromatograph A9；Methanol solution gasifying device and methanol Collection container connects.

The use principle of charging system of the present invention is: when electric automobile needs charging, obtains from setting charging station Mobile charging mechanism (can be with advanced deposits or the identification user that swipes the card), mobile charging mechanism can be placed in car, Charge when vehicle moves.After charging complete, mobile charging mechanism is given back setting website and (can not be and take The website walked).Mobile charging mechanism can be in the way of being similar high capacity cell, it is also possible to is to utilize methanol system The equipment of hydrogen generating.

Embodiment two

The present embodiment is with the difference of embodiment one, and in the present embodiment, described hydrogen production by methanol system also includes gas Pressure regulon system, Collection utilization subsystem.

Described air pressure adjustment subsystem include microprocessor, gas pressure sensor, valve positioner, air outlet valve, Outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the air pressure in transfer conduit Data, and the barometric information of sensing is sent to microprocessor；Described microprocessor will be from gas pressure sensor This barometric information received is compared with setting threshold interval；When the pressure data received is higher than setting threshold value Interval maximum, microprocessor control valve door controller is opened air outlet valve and is set the time so that in transfer conduit Air pressure is in set point, and one end of outlet pipe connects air outlet valve simultaneously, and the other end connects described hydrogen manufacturing subsystem System, is heated by the firing equipment that needs that burning is hydrogen manufacturing subsystem；When the pressure data received is less than setting Determining the minima of threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material.

Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, divides from expellant gas Do not collect hydrogen, oxygen gas and water, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generation System uses, and the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycles.Described Collection utilization System includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, will Hydrogen and oxygen separation, be separated from water hydrogen, oxygen is separated from water the most respectively.

Embodiment three

A kind of charging system for electric automobile, described charging system includes: methanol generator unit, charging terminal；First Alcohol generator unit is connected with charging terminal, powers for charging terminal.

In sum, the charging system for electric automobile that the present invention proposes, can be electronic vapour in vehicle travel process Car charges, and solves the problem that charging electric vehicle is slow.

Here description of the invention and application is illustrative, is not wishing to limit the scope of the invention to above-mentioned reality Execute in example.The deformation of embodiments disclosed herein and change are possible, for the common skill of those this areas For art personnel, the various parts with equivalence of replacing of embodiment are known.It should be clear to a person skilled in the art that , in the case of without departing from the spirit or essential characteristics of the present invention, the present invention can in other forms, knot Structure, layout, ratio, and realize with other assembly, material and parts.Without departing from the scope of the invention and In the case of spirit, embodiments disclosed herein can be carried out other deformation and change.

Claims

1. a charging system for electric automobile, it is characterised in that described charging system includes: self-powered ecosystem, charging terminal；Self-powered ecosystem is connected with charging terminal, powers for charging terminal；

Described charging terminal includes fixed station, mobile charging mechanism, mobile charging mechanism is charged by fixed station, then connecting electric automobile, for charging electric vehicle, can be the untapped battery charging of electric automobile when electric automobile during traveling, or the battery charging being currently in use for electric automobile；

Described main control unit connects wind-power generation unit, solar power generation unit, methanol generator unit, rechargeable battery, charhing unit, biogas alcohol unit, electricity Hydrogen Unit, methanol Preparation equipment respectively, controls the work of unit；

Described wind-power generation unit, solar power generation unit, methanol generator unit connect electrical equipment respectively, directly power for electrical equipment；

Described wind-power generation unit, solar power generation unit, methanol generator unit connect charhing unit respectively, are that rechargeable battery charges by charhing unit；

Described main control unit is also in order to obtain the opening of electrical equipment, thus obtains real-time need for electricity data；Meanwhile, main control unit obtains wind-power generation unit, solar power generation unit, the real-time generated energy data of methanol generator unit；

Described main control unit does corresponding control according to real-time need for electricity data, real-time generated energy data；When generated energy data are more than need for electricity data, controlling charhing unit by unnecessary electric energy is rechargeable battery charging；When generated energy data are less than need for electricity data, it is that electrical equipment is powered by starting rechargeable battery；

Prepared methanol, in order to biomass are prepared methanol by fermentation, is stored to methanol memory element by described biogas alcohol unit；

Described methanol generator unit utilizes methanol to generate electricity, and generates carbon dioxide simultaneously, and the carbon dioxide of generation is delivered to methanol Preparation equipment；

Described electricity Hydrogen Unit, in order to by water electrolysis, obtains hydrogen and oxygen, hydrogen is delivered to methanol Preparation equipment；Electricity Hydrogen Unit starts when generated energy remaining data reaches setting value, utilizes surplus electric energy hydrogen manufacturing；

Described methanol Preparation equipment prepares methanol in order to utilize hydrogen, carbon dioxide；Described methanol Preparation equipment starts when generated energy remaining data reaches to set high level, prepares methanol；

Described methanol generator unit includes hydrogen production by methanol system, hydrogen gas generating system, and hydrogen production by methanol system is connected with hydrogen gas generating system；

Described hydrogen production by methanol system includes that hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；

Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes that solid hydrogen stores container, stores container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；

Described storage container includes: drive mechanism that container, the space mechanism being arranged in container are connected with space mechanism, control module, induction module；Container is at least divided into two spaces by described space mechanism；In two spaces, a placing response liquid, opposite side arranges hydrogen gas generating system release, the liquid then compressed or the carbon dioxide of solid-state；Control module connects drive mechanism, induction module respectively；Described drive mechanism includes that motor, induction module include pressure transducer or/and liquid level sensor；Described induction module in order to sense the amount of reaction liquid in container, the amount of the carbon dioxide of sensing hydrogen gas generating system release simultaneously, the liquid then compressed or solid-state；And sensed data is sent to control module；The Data Control drive mechanism that described control module senses according to the induction module action to space mechanism；When the liquid stored in container reduces or carbon dioxide increases up to impose a condition, drive mechanism drives space mechanism action, reduces the volume of reaction liquid, increases the volume of carbon dioxide；Described storage container also includes liquefying plant or/and solidification equipment, by the co 2 liquefaction collected or/and solidification；

Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen stores container, storage container is connected with hydrogen producer respectively；Store the first alcohol and water storing liquid in container；

Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first starter, the second starter；Described first starter includes the first heating arrangements, the first gasification pipe, and the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；One end of described first gasification pipe connects storage container, is sent in the first gasification pipe by methanol by raw material conveying device；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition；Or, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, methanol directly spontaneous combustion after the first gasification pipe output；Described second starter includes the second gasification pipe, the main body of the second gasification pipe is arranged at described reformer chamber, first gasification pipe is or/and the methanol of the second gasification pipe output is to heat the second gasification pipe, by the methanol gasifying in the second gasification pipe while reformer chamber heats；Described reformer chamber inwall is provided with and adds pipe line, is placed with catalyst in adding pipe line；Described device for rapidly starting by heating described in add pipe line attach most importance to whole room heat；After described hydrogen generating system starts, the hydrogen that hydrogen generating system is prepared by hydrogen producer provides the energy needed for running；

The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator；

Described catalyst includes the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for the 0.6%～1.8% of catalyst gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, the oxide of Cu accounts for the 6%～12% of catalyst gross mass, the oxide of Fe accounts for the 3%～8% of catalyst gross mass, the oxide of Zn accounts for the 8%～20% of catalyst gross mass, and rare-earth oxide accounts for the 6%～40% of catalyst gross mass, and remaining is transition metal oxide；

Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the Al of ZrO, 55-80 part of ZnO, 0.5-3 part of the CuO of 3-17 part, 3-18 part₂O₃, the CeO of 1-3 part₂, the La of 1-3 part₂O₃；

Described solid hydrogen stores and stores solid hydrogen in container, when hydrogen generating system starts, by gasification module, solid hydrogen is converted to gaseous hydrogen, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, as the startup energy of hydrogen producer；

First alcohol and water in described storage container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Methanol vapor and steam after gasification enter reformer chamber, and it is 300 DEG C～420 DEG C that reformer chamber is provided with catalyst, reformer chamber bottom and middle portion temperature；The temperature on described reformer chamber top is 400 DEG C～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, the top being completely or partially arranged at reformer chamber of connecting line, can continue the heating gas from reformer chamber output by the high temperature on reformer chamber top；Described connecting line is as the buffering between reformer chamber and separation chamber so that identical or close with the temperature of separation chamber from the temperature of the gas of reformer chamber output；Temperature in described separation chamber is set as 350 DEG C～570 DEG C；It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator；

Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough pressure；

After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air maintains hydrogen producer to run by burning；

The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and separates, for separating the difference of the inside and outside pressure of the membrane separation device of hydrogen more than or equal to 0.7M Pa；Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%；

Prepared hydrogen is passed through transfer conduit real-time Transmission to hydrogen gas generating system by described hydrogen manufacturing subsystem；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；

Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；This barometric information received from gas pressure sensor is compared by described microprocessor with setting threshold interval；When the pressure data received is higher than the maximum setting threshold interval, microprocessor control valve door controller is opened air outlet valve and is set the time, air pressure in transfer conduit is made to be in set point, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, is heated by the firing equipment that needs that burning is hydrogen manufacturing subsystem；When the pressure data received controls described hydrogen manufacturing subsystem accelerate the transporting velocity of raw material less than the minima of setting threshold interval, microprocessor；

Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, hydrogen, oxygen gas and water is collected respectively from expellant gas, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generating system, the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycles；

Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, by hydrogen and oxygen separation, is separated from water by hydrogen the most respectively, oxygen is separated from water；

Described hydrogen gas generating system includes that fuel cell, fuel cell include that some sub-fuel cell modules, each sub-fuel cell module include at least one super capacitor；

Described hydrogen producer also includes that electric energy estimation block, hydrogen prepare detection module, electric energy memory module；The electric energy that when whether the electric energy that described electric energy estimation block sends in real time in order to estimate hydrogen gas generating system can meet reformation, separation, needs consume；If it is satisfied, then closedown device for rapidly starting；

It is the most stable that hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer；If hydrogen prepared by hydrogen producer is unstable, then controls device for rapidly starting and be again started up, and the electric energy part obtained is stored in electric energy memory module, use when electric energy is not enough to the consumption providing hydrogen producer；

Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, pile；The gas of described gas supply device utilization compression is as power, in automatic transport to pile；

Described fuel cell system also includes air intake conduit, outlet pipe；The gas of described compression is mainly oxygen；Air enters pile with oxygen after mixing container mixing；

Described fuel cell system also includes gas regulating system；Described gas regulating system includes that valve regulated controls device, and oxygen content sensor is or/and compressed gas compression ratio sensor；

Described oxygen content sensor is in order to sense the air of mixing and the content of oxygen in oxygen in mixing container, and sends the data sensed to valve regulated control device；

Described compressed gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and sends the data sensed to valve regulated control device；

Described valve regulated controls device according to oxygen content sensor or/and sensing result regulation oxygen delivery valve door, the air entrainment valve door of compressed gas compression ratio sensor, controls compressed oxygen, the conveying ratio of air；Mixed gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container；

Described fuel cell system also includes humidification system, and humidification system includes that humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；Gas through fuel cell reaction is delivered to humidity exchanging container by outlet pipe；

The material of described humidity exchange pipeline is the most permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas；

Described methanol Preparation equipment includes: nitrogen gas conveying device, hydrogen conveyor, carbon dioxide conveyer device, the first blender, the second blender, micro fixed-bed reactor, counterbalance valve, alcohol-water separation device, chromatograph, methanol solution gasifying device, methanol collect container, main control module；Described carbon dioxide conveyer device connects the side of described storage container collection carbon dioxide；The methanol prepared is delivered to store the methanol-water mixed liquor side of container；

Described nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline is provided with the first stop valve, the first mass flowmenter；

Described carbon dioxide conveyer device includes carbon dioxide storage container, the second transfer pipeline, and the second transfer pipeline is provided with the second stop valve, the second mass flowmenter；

Described hydrogen conveyor includes hydrogen storage vessel, the 3rd transfer pipeline, the 4th transfer pipeline, and the 3rd transfer pipeline is provided with the 3rd stop valve, the 3rd mass flowmenter, and the 4th transfer pipeline is provided with the 4th stop valve, the 4th mass flowmenter；

Described hydrogen storage vessel is connected by the 3rd transfer pipeline and the first transfer pipeline, and the 3rd transfer pipeline and the first transfer pipeline are intersected in one first three-way valve；

Described hydrogen storage vessel is connected by the 4th transfer pipeline and the second transfer pipeline, and the 4th transfer pipeline and the second transfer pipeline are intersected in one first cross valve；

Described first three-way valve and the first blender connect, and the other end of the first blender and the second three-way valve connect；Second three-way valve connects micro fixed-bed reactor by the 5th transfer pipeline, and the 5th transfer pipeline is provided with the 5th mass flowmenter, pressure gage；

The other end of described micro fixed-bed reactor connects the 4th three-way valve, and the 4th three-way valve is also connected with counterbalance valve, and the other end of counterbalance valve connects one second cross valve；

Described first cross valve and the second blender connect, and the other end of the second blender and the 3rd three-way valve connect；Alcohol-water separation device, the second three-way valve connect the 3rd three-way valve, and alcohol-water separation device, methanol solution gasifying device, chromatograph connect the second cross valve；Methanol solution gasifying device is collected container with methanol and is connected；

Described master control module controls all parts action, first control high pure nitrogen and high-purity hydrogen to be emptied by beds after the first blender mixing with the ratio set, treat that catalyst reduction completes the gaseous mixture that rear cutout ventilation body is hydrogen and carbon dioxide, gas boosts to certain pressure by beds through counterbalance valve and isolates Methanol product and water through alcohol-water separation device again, and unreacted gas continues through reactor cycles reaction after unstripped gas supplements.

2. a charging system for electric automobile, it is characterised in that described charging system includes: methanol generator unit, charging terminal；Methanol generator unit is connected with charging terminal, powers for charging terminal；

Described charging terminal includes fixed station, mobile charging mechanism, mobile charging mechanism is charged by fixed station, then connecting electric automobile, for charging electric vehicle, can be the untapped battery charging of electric automobile when electric automobile during traveling, or the battery charging being currently in use for electric automobile.

Charging system for electric automobile the most according to claim 2, it is characterised in that:

Described hydrogen production by methanol system includes that hydrogen manufacturing subsystem, described hydrogen manufacturing subsystem utilize methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes raw material conveying device, hydrogen producer, membrane separation device；Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at reformer chamber.

Described charging system also includes self-powered ecosystem；Described self-powered ecosystem includes: described methanol generator unit, rechargeable battery, charhing unit, methanol Preparation equipment, main control unit；

Described main control unit connects methanol generator unit, rechargeable battery, charhing unit, methanol Preparation equipment respectively, controls the work of unit；

Described methanol generator unit connects electrical equipment, powers for electrical equipment；Described methanol generator unit connects charhing unit respectively, is that rechargeable battery charges by charhing unit；

Described main control unit is also in order to obtain the opening of electrical equipment, thus obtains real-time need for electricity data；Meanwhile, main control unit obtains the real-time generated energy data of methanol generator unit；

Described methanol Preparation equipment prepares methanol in order to utilize hydrogen, carbon dioxide；Described methanol Preparation equipment starts when generated energy remaining data reaches to set high level, prepares methanol.

Charging system for electric automobile the most according to claim 4, it is characterised in that:

Described self-powered ecosystem also includes wind-power generation unit, solar power generation unit, biogas alcohol unit, electricity Hydrogen Unit；

Described wind-power generation unit, solar power generation unit connect electrical equipment respectively, directly power for electrical equipment；

Described wind-power generation unit, solar power generation unit connect charhing unit respectively, are that rechargeable battery charges by charhing unit；

Described electricity Hydrogen Unit, in order to by water electrolysis, obtains hydrogen and oxygen, hydrogen is delivered to methanol Preparation equipment；Electricity Hydrogen Unit starts when generated energy remaining data reaches setting value, utilizes surplus electric energy hydrogen manufacturing.

Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, by hydrogen and oxygen separation, is separated from water by hydrogen the most respectively, oxygen is separated from water.

Charging system for electric automobile the most according to claim 6, it is characterised in that:

The material of described humidity exchange pipeline is the most permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas.

Described storage container includes: drive mechanism that container, the space mechanism being arranged in container are connected with space mechanism, control module, induction module；Container is at least divided into two spaces by described space mechanism；In two spaces, a placing response liquid, opposite side arranges hydrogen gas generating system release, the liquid then compressed or the carbon dioxide of solid-state；Control module connects drive mechanism, induction module respectively；Described drive mechanism includes that motor, induction module include pressure transducer or/and liquid level sensor；Described induction module in order to sense the amount of reaction liquid in container, the amount of the carbon dioxide of sensing hydrogen gas generating system release simultaneously, the liquid then compressed or solid-state；And sensed data is sent to control module；The Data Control drive mechanism that described control module senses according to the induction module action to space mechanism；When the liquid stored in container reduces or carbon dioxide increases up to impose a condition, drive mechanism drives space mechanism action, reduces the volume of reaction liquid, increases the volume of carbon dioxide；Described storage container also includes liquefying plant or/and solidification equipment, by the co 2 liquefaction collected or/and solidification.

Charging system for electric automobile the most according to claim 3, it is characterised in that: