CN106004494A - Water hydrogen power automobile and air conditioner system thereof - Google Patents

Water hydrogen power automobile and air conditioner system thereof Download PDF

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Publication number
CN106004494A
CN106004494A CN201610438233.9A CN201610438233A CN106004494A CN 106004494 A CN106004494 A CN 106004494A CN 201610438233 A CN201610438233 A CN 201610438233A CN 106004494 A CN106004494 A CN 106004494A
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China
Prior art keywords
hydrogen
gas
valve
methanol
container
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CN201610438233.9A
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Chinese (zh)
Inventor
向华
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Shanghai Hejide Dynamic Hydrogen Machine Co Ltd
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Shanghai Hejide Dynamic Hydrogen Machine Co Ltd
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Priority to CN201610438233.9A priority Critical patent/CN106004494A/en
Publication of CN106004494A publication Critical patent/CN106004494A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
    • B60L58/00—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles
    • B60L58/30—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles for monitoring or controlling fuel cells
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
    • B60L50/00—Electric propulsion with power supplied within the vehicle
    • B60L50/50—Electric propulsion with power supplied within the vehicle using propulsion power supplied by batteries or fuel cells
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
    • B60L58/00—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles
    • B60L58/30—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles for monitoring or controlling fuel cells
    • B60L58/32—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles for monitoring or controlling fuel cells for controlling the temperature of fuel cells, e.g. by controlling the electric load
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
    • B60L58/00—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles
    • B60L58/40—Methods or circuit arrangements for monitoring or controlling batteries or fuel cells, specially adapted for electric vehicles for controlling a combination of batteries and fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/60—Heating or cooling; Temperature control
    • H01M10/66—Heat-exchange relationships between the cells and other systems, e.g. central heating systems or fuel cells
    • H01M10/663—Heat-exchange relationships between the cells and other systems, e.g. central heating systems or fuel cells the system being an air-conditioner or an engine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Transportation (AREA)
  • Manufacturing & Machinery (AREA)
  • Power Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

The invention discloses a water hydrogen power automobile and an air conditioner system thereof. The water hydrogen power automobile comprises a methanol hydrogen production system, a hydrogen power generation system, a genemotor, a gearbox, an automobile body, a chassis and automobile wheels. The methanol hydrogen production system is connected with the hydrogen power generation system. The hydrogen power generation system is connected with the genemotor. High-temperature gas exhausted by hydrogen production equipment is used as a heat source of an automobile air conditioner heating, and heat is supplied to the automobile through a heat exchange device. The heat exchange device comprises a plurality of heat exchange pipelines, and circulating gas of an automobile air conditioner is in the heat exchange pipelines. The high-temperature gas exhausted by the hydrogen production equipment or high-temperature liquid heated by the high-temperature gas is located outside the heat exchange pipelines. According to the water hydrogen power automobile provided by the invention, methanol required by the power generation system can be generated by the automobile, and emission of carbon dioxide is avoided. Heat energy exhausted by the hydrogen production equipment is adopted by the automobile air conditioner system as heat energy for air conditioner warm air.

Description

A kind of water hydrogen car and air conditioning system thereof
Technical field
The invention belongs to electric vehicle engineering field, relate to a kind of electric automobile, particularly relate to a kind of carbon dioxide Circulating water hydrogen power electrical automobile；Meanwhile, the invention still further relates to the air conditioning system of this automobile.
Background technology
Auto industry is the second largest industry being only second to petrochemical industry in the world, and at present, major part automobile is all with vapour Oil, diesel oil are fuel, not only consume substantial amounts of petroleum resources, and nitrogen oxides contained in vehicle exhaust, Hydrocarbons, carbon monoxide etc. cause the severe contamination of air.In order to keep the sustainable development of national economy, Protection human residential environment and guarantee energy resource supply, countries in the world government puts into substantial amounts of human and material resources one after another and seeks Solve the various approach of certainly these problems.
Currently mainly having two kinds of energy-conservation approach, a kind of is the hybrid vehicle with Toyota as representative, another kind of It it is the pure electric automobile with tesla as representative.The starting of hybrid vehicle is slow, and fuel is still gasoline or bavin Oil, it is impossible to the problem inherently solving resource, pollution.Pure electric automobile needs specific charging pile, it is more difficult to Universal, and flying power is poor.
Fuel cell be a kind of without combustion process directly in electrochemical reaction mode by fuel and oxidant Chemical energy is changed into the efficient generating apparatus of electric energy, and its work process is not limited by Carnot cycle, and conversion efficiency is high, Almost without pollutant emission.FC-EV with fuel cell as power not only can protect environment but also Energy shortage can be alleviated and readjust the energy structure, it has also become one of important trend of future automobile development, being to work as Modern world energy sources and the focus of field of traffic exploitation.
Fuel cell can be divided into alkaline fuel cell, phosphoric acid fuel cell, fused carbonate to fire by electrolyte classification Five classes such as material battery, SOFC, Proton Exchange Membrane Fuel Cells.And automobile fuel battery Requirement be: can work at normal temperatures, electric current density is high, and non-maintaining property is good, and resistance to vibration is good with resistance to impact, High efficiency operating can be carried out from underload to high load capacity.Proton Exchange Membrane Fuel Cells (PEMFC) disclosure satisfy that These performance requirements, therefore become the most ripe vehicle fuel battery with fastest developing speed.Combustion based on PEMFC Material battery car need hydrogen as fuel, since fuel cell is born, hydrogen source problem and fuel cell itself It is the core technology of no less important, and the research and development of hydrogen source have become fuel cell car and moved towards business from demonstration The important step changed.
Summary of the invention
The technical problem to be solved is: provide a kind of water hydrogen car, available hydrogen from methyl alcohol system The tail gas that system is got rid of is used for providing the energy for vehicle air conditioning.
Additionally, the present invention also provides for the air conditioning system of a kind of automobile, the heat energy conduct that available hydrogen producer is discharged The heat energy of air conditioning warm air.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that
A kind of water hydrogen car, described circulating water hydrogen car includes: hydrogen production by methanol system, hydrogen are sent out Electricity system, methanol Preparation equipment, genemotor, change speed gear box, vehicle body, chassis, wheel, hydrogen from methyl alcohol system System is connected with hydrogen gas generating system, and hydrogen gas generating system is connected with methanol Preparation equipment；Methanol Preparation equipment, electricity The electric energy that dynamic electromotor is sent by hydrogen gas generating system works；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, system Hydrogen subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes that solid hydrogen stores and holds Device, storage container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described storage container includes: what container, the space mechanism being arranged in container were connected with space mechanism drives Motivation structure, control module, induction module；Container is at least divided into two spaces by described space mechanism；Two skies In between, a placing response liquid, opposite side arrange hydrogen gas generating system release, the liquid then compressed or The carbon dioxide of solid-state；Control module connects drive mechanism, induction module respectively；Described drive mechanism includes electricity Machine, induction module includes pressure transducer or/and liquid level sensor；Described induction module is in order to sense in container The amount of reaction liquid, sensing hydrogen gas generating system release simultaneously, the liquid then compressed or the titanium dioxide of solid-state The amount of carbon；And sensed data is sent to control module；The data that described control module senses according to induction module Control the drive mechanism action to space mechanism；Liquid in storing container reduces or carbon dioxide increases up to When imposing a condition, drive mechanism drives space mechanism action, reduces the volume of reaction liquid, increases carbon dioxide Volume；Described storage container also includes liquefying plant or/and solidification equipment, the carbon dioxide liquid that will collect Change or/and solidify；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, Separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen store container, store container respectively with hydrogen producer Connect；Store the first alcohol and water storing liquid in container；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes that first opens Dynamic device, the second starter；Described first starter includes the first heating arrangements, the first gasification pipe, The internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；Institute State one end of the first gasification pipe to connect and store container, by raw material conveying device, methanol sent into the first vapor lamp Lu Zhong；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition； Or, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, Methanol directly spontaneous combustion after the first gasification pipe output；Described second starter includes the second gasification pipe, the The main body of two gasification pipe is arranged at described reformer chamber, and the first gasification pipe is or/and the second gasification pipe exports Methanol be reformer chamber heating while heat the second gasification pipe, by the methanol gasifying in the second gasification pipe； Described reformer chamber inwall is provided with and adds pipe line, is placed with catalyst in adding pipe line；Described device for rapidly starting passes through Add described in heating pipe line attach most importance to whole room heating；After described hydrogen generating system starts, hydrogen generating system passes through hydrogen producer The hydrogen prepared provides the energy needed for running；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts module Including the solar panel being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts Module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual Electromotor, the electric energy sent is stored in battery by manual generator；
Described catalyst include the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, The oxide of Zn, rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for catalysis The 0.6%～1.8% of agent gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, and the oxide of Cu accounts for catalysis The 6%～12% of agent gross mass, the oxide of Fe accounts for the 3%～8% of catalyst gross mass, and the oxide of Zn accounts for catalysis The 8%～20% of agent gross mass, rare-earth oxide accounts for the 6%～40% of catalyst gross mass, and remaining is transition gold Belong to oxide；
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the CuO of 3-17 part, The Al of ZrO, 55-80 part of the ZnO of 3-18 part, 0.5-3 part2O3, the CeO of 1-3 part2, the La of 1-3 part2O3；
Described solid hydrogen stores and stores solid hydrogen in container, when hydrogen generating system starts, by gasification module Solid hydrogen is converted to gaseous hydrogen, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, The startup energy as hydrogen producer；
First alcohol and water in described storage container is delivered to heat exchanger heat exchange by raw material conveying device, and heat exchange is laggard Enter vaporizer gasification；Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with catalyst, Reformer chamber bottom and middle portion temperature are 300 DEG C～420 DEG C；The temperature on described reformer chamber top is 400 DEG C～570 DEG C； Reformer chamber is connected by connecting line with separation chamber, connecting line be completely or partially arranged at the upper of reformer chamber Portion, can continue the heating gas from reformer chamber output by the high temperature on reformer chamber top；Described connecting line conduct Buffering between reformer chamber and separation chamber so that from the temperature phase of the temperature of the gas of reformer chamber output with separation chamber Same or close；Temperature in described separation chamber is set as 350 DEG C～570 DEG C；Membrane separator it is provided with in separation chamber, Hydrogen is obtained from the aerogenesis end of membrane separator；
Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Described former Material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough Pressure；
After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is tieed up by burning Hold hydrogen producer to run；
The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and separates, and divides for separating the film of hydrogen Difference from the inside and outside pressure of device is more than or equal to 0.7M Pa；Described membrane separation device is true at porous ceramic surface The membrane separation device of empty plating palladium-silver, film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, silver accounts for 22%～25%；
Prepared hydrogen is passed through transfer conduit real-time Transmission to hydrogen gas generating system by described hydrogen manufacturing subsystem；Described Transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system Utilize the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
The high-temperature gas that described hydrogen producer is discharged, as the thermal source of air conditioning for automobiles heating installation, passes through heat-exchange device For Vehicle heating；Heat-exchange device includes some heat exchanging pipes, is the circulation gas of vehicle air conditioning in heat exchanging pipe Body, the high-temperature gas discharged for hydrogen producer outside heat exchanging pipe or the high-temp liquid after being heated by high-temperature gas；
Described heat-exchange device is provided with microprocessor, valve positioner, hot-gas temperature sensor, flow Sensor, microprocessor connecting valve controller, hot-gas temperature sensor, flow transducer, car respectively Air-conditioner controller, according to hot-gas temperature sensor, the temperature of the high-temperature gas of flow transducer sensing, The control state modulator valve positioner of flow and vehicle air conditioning, adjusts the size of valve by valve positioner, Thus adjust the flow of the high-temperature gas led in heat-exchange device；
Described air pressure adjustment subsystem include microprocessor, gas pressure sensor, valve positioner, air outlet valve, Outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the air pressure in transfer conduit Data, and the barometric information of sensing is sent to microprocessor；Described microprocessor will be from gas pressure sensor This barometric information received is compared with setting threshold interval；When the pressure data received is higher than setting threshold value Interval maximum, microprocessor control valve door controller is opened air outlet valve and is set the time so that in transfer conduit Air pressure is in set point, and one end of outlet pipe connects air outlet valve simultaneously, and the other end connects described hydrogen manufacturing subsystem System, is heated by the firing equipment that needs that burning is hydrogen manufacturing subsystem；When the pressure data received is less than setting Determining the minima of threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, divides from expellant gas Do not collect hydrogen, oxygen gas and water, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generation System uses, and the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycles；
Described Collection utilization subsystem includes that hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separate Device, oxygen check valve, by hydrogen and oxygen separation, be separated from water hydrogen, oxygen is separated from water the most respectively；
Described hydrogen producer also includes that electric energy estimation block, hydrogen prepare detection module, electric energy memory module；Institute State whether the electric energy that electric energy estimation block sends in real time in order to estimate hydrogen gas generation device can meet reformation, when separating Need the electric energy consumed；If it is satisfied, then closedown device for rapidly starting；
It is the most stable that hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer；If hydrogen producer The hydrogen of preparation is unstable, then control device for rapidly starting and be again started up, and the electric energy part obtained be stored in Electric energy memory module, uses when electric energy is not enough to the consumption providing hydrogen producer；
Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, electricity Heap；The gas of described gas supply device utilization compression is as power, in automatic transport to pile；Described pile Including some sub-fuel cell modules, each sub-fuel cell module includes at least one super capacitor；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas of described compression is predominantly Oxygen；Air enters pile with oxygen after mixing container mixing；
Described fuel cell system also includes gas regulating system；Described gas regulating system includes valve regulated control Device processed, and oxygen content sensor is or/and compressed gas compression ratio sensor；
Described oxygen content sensor mixes the air of mixing and the content of oxygen in oxygen in container in order to sense, And the data sensed are sent to valve regulated control device；
Described compressed gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data that will sense Send to valve regulated control device；
Described valve regulated controls device according to oxygen content sensor or/and compressed gas compression ratio sensor Sensing result regulation oxygen delivery valve door, air entrainment valve door, control compressed oxygen, the conveying ratio of air； Mixed gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container；
Described fuel cell system also includes humidification system, and humidification system includes that humidity exchanging container, humidity exchange Pipeline, humidity exchange pipeline is a part for air intake conduit；Gas through fuel cell reaction passes through Air pipe is delivered to humidity exchanging container；
The material of described humidity exchange pipeline is the most permeable airtight so that conveying gas carries out humidity with natural air Exchange, and cannot circulate between gas.
Described methanol Preparation equipment includes: nitrogen gas conveying device, hydrogen conveyor, carbon dioxide conveyer device, First blender, the second gaseous mixture, micro fixed-bed reactor, counterbalance valve, synthesis reactor, alcohol-water separation Device, chromatograph, methanol solution gasifying device, methanol collect container, main control module；Described carbon dioxide conveyer device Connect the side of described storage container collection carbon dioxide；The methanol prepared is delivered to store the methanol of container Water mixed liquid side；
Described nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline is provided with One stop valve, the first mass flowmenter；
Described carbon dioxide conveyer device includes carbon dioxide storage container, the second transfer pipeline, the second conveying pipe Road is provided with the second stop valve, the second mass flowmenter；
Described hydrogen conveyor includes hydrogen storage vessel, the 3rd transfer pipeline, the 4th transfer pipeline, the 3rd Transfer pipeline is provided with the 3rd stop valve, the 3rd mass flowmenter, the 4th transfer pipeline be provided with the 4th stop valve, Four mass flowmenters；
Described hydrogen storage vessel is connected by the 3rd transfer pipeline and the first transfer pipeline, the 3rd transfer pipeline and First transfer pipeline is intersected in one first three-way valve；
Described hydrogen storage vessel is connected by the 4th transfer pipeline and the second transfer pipeline, the 4th transfer pipeline and Second transfer pipeline is intersected in one first cross valve；
Described first three-way valve and the first blender connect, and the other end of the first blender and the second three-way valve are even Connect；Second three-way valve connects micro fixed-bed reactor by the 5th transfer pipeline, and the 5th transfer pipeline is provided with the Five mass flowmenters, pressure gage；
The other end of described micro fixed-bed reactor connects the 4th three-way valve, and the 4th three-way valve is also connected with back pressure Valve, the other end of counterbalance valve connects one second cross valve；
Described first cross valve and the second blender connect, and the other end of the second blender and the 3rd three-way valve are even Connect；Alcohol-water separation device, the second three-way valve connect the 3rd three-way valve, alcohol-water separation device, methanol solution gasifying device, color Spectrometer connects the second cross valve；Methanol solution gasifying device is collected container with methanol and is connected；
Described master control module controls all parts action, first controls high pure nitrogen and high-purity hydrogen with the ratio set Being emptied by beds after the first blender mixing, treating that catalyst reduction completes rear cutout ventilation body is hydrogen Gas and the gaseous mixture of carbon dioxide, gas boosts to certain pressure again through alcohol water by beds through counterbalance valve Separator isolates Methanol product and water, and unreacted gas continues through reactor after unstripped gas supplements and follows Ring reacts.
Described automobile also includes the second genemotor, energy storage units, kinetic energy converting unit, and kinetic energy is changed Unit, energy storage units, the second genemotor are sequentially connected with；Described kinetic energy converting unit is by braking automobile The energy of braking is converted to electric energy and is stored in energy storage units, provides electric energy for the second genemotor；
Described second genemotor is also connected with hydrogen gas generating system, hydrogen gas generating system be the second motor Machine provides the energy；
Described automobile also includes that road environment induction module, allocation database, hydrogen distribute module；Hydrogen distributes Module is connected with road environment induction module, allocation database respectively, according to the sensing of road environment induction module Data in data and allocation database are the hydrogen that the distribution of each genemotor is corresponding；
Described road environment induction module is in order to sense road congestion information, ground flat degree information；Congestion in road Information is according to automobile real-time speed, acceleration, deceleration frequency, and determines down time；Ground flat degree information Obliquity sensor according to arranging on automobile chassis determines；
Described allocation database stores some tables of data, tables of data records each road congestion information, ground Flatness information corresponding for genemotor, second genemotor distribution hydrogen data；Genemotor, In second genemotor, one is used for driving trailing wheel or/and front-wheel, another be used for driving front-wheel or/and after Wheel.
A kind of water hydrogen car, described water hydrogen car includes: hydrogen production by methanol system, hydrogen gas generating system, Genemotor, change speed gear box, vehicle body, chassis, wheel, hydrogen production by methanol system is connected with hydrogen gas generating system, Hydrogen gas generating system is connected with genemotor；
Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen is by being coated with palladium-silver Membrane separation device obtains highly purified hydrogen, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system；Described methanol system Hydrogen system includes hydrogen producer；
The high-temperature gas that described hydrogen producer is discharged, as the thermal source of air conditioning for automobiles heating installation, passes through heat-exchange device For Vehicle heating；Heat-exchange device includes some heat exchanging pipes, is the circulation gas of vehicle air conditioning in heat exchanging pipe Body, the high-temperature gas discharged for hydrogen producer outside heat exchanging pipe or the high-temp liquid after being heated by high-temperature gas.
As a preferred embodiment of the present invention, described heat-exchange device be provided with microprocessor, valve positioner, Hot-gas temperature sensor, flow transducer, microprocessor connecting valve controller, High Temperature Gas body temperature respectively Degree sensor, flow transducer, vehicle air conditioner controller, according to hot-gas temperature sensor, flow sensing The control state modulator valve positioner of the temperature of high-temperature gas, flow and the vehicle air conditioning of device sensing, passes through valve Door controller adjusts the size of valve, thus adjusts the flow of the high-temperature gas led in heat-exchange device.
As a preferred embodiment of the present invention, the middle part of described storage container is provided with dividing plate, and the side of dividing plate sets Putting reaction liquid, opposite side arranges hydrogen gas generating system release, the liquid then compressed or the titanium dioxide of solid-state Carbon；Dividing plate connects pushing mechanism, and the liquid in storing container reduces or carbon dioxide increases up to set bar During part, pushing mechanism drives dividing plate action, reduces the volume of storage reaction liquid regions, increases storage titanium dioxide The volume in carbon region.
As a preferred embodiment of the present invention, described storage container also includes control module, induction module；Institute State drive mechanism and include that motor, induction module include pressure transducer or/and liquid level sensor；Described sensing mould Block in order to sense the amount of reaction liquid in container, sensing hydrogen gas generating system release simultaneously, the liquid then compressed The amount of the carbon dioxide of state or solid-state；And sensed data is sent to control module；Described control module is according to sense Answer the action to space mechanism of Data Control drive mechanism that module senses；Liquid in liquid storage container subtracts Less or time carbon dioxide increases up to impose a condition, drive mechanism drives space mechanism action, reaction liquid is reduced Volume, increase carbon dioxide volume；Described storage device also includes liquefying plant or/and solidification equipment, By the co 2 liquefaction collected or/and solidify.
As a preferred embodiment of the present invention, described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment Subsystem, Collection utilization subsystem, hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, collection Subsystem is utilized to be sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes that solid hydrogen stores and holds Device, storage container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, Separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen store container, store container respectively with hydrogen producer Connect；Store the first alcohol and water storing liquid in container；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes that first opens Dynamic device, the second starter；Described first starter includes the first heating arrangements, the first gasification pipe, The internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；Institute State one end of the first gasification pipe to connect and store container, by raw material conveying device, methanol sent into the first vapor lamp Lu Zhong；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition； Or, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, Methanol directly spontaneous combustion after the first gasification pipe output；Described second starter includes the second gasification pipe, the The main body of two gasification pipe is arranged at described reformer chamber, and the first gasification pipe is or/and the second gasification pipe exports Methanol be reformer chamber heating while heat the second gasification pipe, by the methanol gasifying in the second gasification pipe； Described reformer chamber inwall is provided with and adds pipe line, is placed with catalyst in adding pipe line；Described device for rapidly starting passes through Add described in heating pipe line attach most importance to whole room heating；After described hydrogen generating system starts, hydrogen generating system passes through hydrogen producer The hydrogen prepared provides the energy needed for running；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts module Including the solar panel being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts Module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual Electromotor, the electric energy sent is stored in battery by manual generator；
Described solid hydrogen stores and stores solid hydrogen in container, when hydrogen generating system starts, by gasification module Solid hydrogen is converted to gaseous hydrogen, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, The startup energy as hydrogen producer；
First alcohol and water in described storage container is delivered to heat exchanger heat exchange by raw material conveying device, and heat exchange is laggard Enter vaporizer gasification；Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with catalyst, Reformer chamber bottom and middle portion temperature are 300 DEG C～420 DEG C；The temperature on described reformer chamber top is 400 DEG C～570 DEG C； Reformer chamber is connected by connecting line with separation chamber, connecting line be completely or partially arranged at the upper of reformer chamber Portion, can continue the heating gas from reformer chamber output by the high temperature on reformer chamber top；Described connecting line conduct Buffering between reformer chamber and separation chamber so that from the temperature phase of the temperature of the gas of reformer chamber output with separation chamber Same or close；Temperature in described separation chamber is set as 350 DEG C～570 DEG C；Membrane separator it is provided with in separation chamber, Hydrogen is obtained from the aerogenesis end of membrane separator；
Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Described former Material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough Pressure；
After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is tieed up by burning Hold hydrogen producer to run；
The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and separates, and divides for separating the film of hydrogen Difference from the inside and outside pressure of device is more than or equal to 0.7M Pa；Described membrane separation device is true at porous ceramic surface The membrane separation device of empty plating palladium-silver, film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, silver accounts for 22%～25%；
Prepared hydrogen is passed through transfer conduit real-time Transmission to hydrogen gas generating system by described hydrogen manufacturing subsystem；Described Transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system Utilize the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
Described air pressure adjustment subsystem include microprocessor, gas pressure sensor, valve positioner, air outlet valve, Outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the air pressure in transfer conduit Data, and the barometric information of sensing is sent to microprocessor；Described microprocessor will be from gas pressure sensor This barometric information received is compared with setting threshold interval；When the pressure data received is higher than setting threshold value Interval maximum, microprocessor control valve door controller is opened air outlet valve and is set the time so that in transfer conduit Air pressure is in set point, and one end of outlet pipe connects air outlet valve simultaneously, and the other end connects described hydrogen manufacturing subsystem System, is heated by the firing equipment that needs that burning is hydrogen manufacturing subsystem；When the pressure data received is less than setting Determining the minima of threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, divides from expellant gas Do not collect hydrogen, oxygen gas and water, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generation System uses, and the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycles；
Described Collection utilization subsystem includes that hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separate Device, oxygen check valve, by hydrogen and oxygen separation, be separated from water hydrogen, oxygen is separated from water the most respectively；
Described hydrogen producer also includes that electric energy estimation block, hydrogen prepare detection module, electric energy memory module；Institute State whether the electric energy that electric energy estimation block sends in real time in order to estimate hydrogen gas generation device can meet reformation, when separating Need the electric energy consumed；If it is satisfied, then closedown device for rapidly starting；
It is the most stable that hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer；If hydrogen producer The hydrogen of preparation is unstable, then control device for rapidly starting and be again started up, and the electric energy part obtained be stored in Electric energy memory module, uses when electric energy is not enough to the consumption providing hydrogen producer；
Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, electricity Heap；The gas of described gas supply device utilization compression is as power, in automatic transport to pile；Described pile Including some sub-fuel cell modules, each sub-fuel cell module includes at least one super capacitor；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas of described compression is predominantly Oxygen；Air enters pile with oxygen after mixing container mixing；
Described fuel cell system also includes gas regulating system；Described gas regulating system includes valve regulated control Device processed, and oxygen content sensor is or/and compressed gas compression ratio sensor；
Described oxygen content sensor mixes the air of mixing and the content of oxygen in oxygen in container in order to sense, And the data sensed are sent to valve regulated control device；
Described compressed gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data that will sense Send to valve regulated control device；
Described valve regulated controls device according to oxygen content sensor or/and compressed gas compression ratio senses
Device sensing result regulation oxygen delivery valve door, air entrainment valve door, control compressed oxygen, air defeated
Send ratio；Mixed gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container；
Described fuel cell system also includes humidification system, and humidification system includes that humidity exchanging container, humidity exchange Pipeline, humidity exchange pipeline is a part for air intake conduit；Gas through fuel cell reaction passes through Air pipe is delivered to humidity exchanging container；
The material of described humidity exchange pipeline is the most permeable airtight so that conveying gas carries out humidity with natural air Exchange, and cannot circulate between gas.
As a preferred embodiment of the present invention, the initial start energy of described device for rapidly starting is some sun Can start module, solar energy starts solar panel, the solar energy-electric energy conversion electricity that module includes being sequentially connected with Road, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, described quickly open The initial start energy of dynamic device is manual generator, and the electric energy sent is stored in battery by manual generator.
As a preferred embodiment of the present invention, described catalyst include the oxide of Pt, the oxide of Pd, The oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide； Wherein, precious metals pt content accounts for the 0.6%～1.8% of catalyst gross mass, and Pd content accounts for catalyst gross mass The oxide of 1.1%～4%, Cu accounts for the 6%～12% of catalyst gross mass, and the oxide of Fe accounts for catalyst gross mass 3%～8%, the oxide of Zn accounts for the 8%～20% of catalyst gross mass, and it is total that rare-earth oxide accounts for catalyst The 6%～40% of quality, remaining is transition metal oxide；
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the CuO of 3-17 part, The Al of ZrO, 55-80 part of the ZnO of 3-18 part, 0.5-3 part2O3, the CeO of 1-3 part2, the La of 1-3 part2O3。
As a preferred embodiment of the present invention, described methanol Preparation equipment includes: nitrogen gas conveying device, hydrogen Conveyer device, carbon dioxide conveyer device, the first blender, the second gaseous mixture, micro fixed-bed reactor, Counterbalance valve, synthesis reactor, alcohol-water separation device, chromatograph, methanol solution gasifying device, methanol collect container, master Control module；Described carbon dioxide conveyer device connects the side of described storage container collection carbon dioxide；It is prepared into To methanol be delivered to store container methanol-water mixed liquor side；
Described nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline is provided with One stop valve, the first mass flowmenter；
Described carbon dioxide conveyer device includes carbon dioxide storage container, the second transfer pipeline, the second conveying pipe Road is provided with the second stop valve, the second mass flowmenter；
Described hydrogen conveyor includes hydrogen storage vessel, the 3rd transfer pipeline, the 4th transfer pipeline, the 3rd Transfer pipeline is provided with the 3rd stop valve, the 3rd mass flowmenter, the 4th transfer pipeline be provided with the 4th stop valve, Four mass flowmenters；
Described hydrogen storage vessel is connected by the 3rd transfer pipeline and the first transfer pipeline, the 3rd transfer pipeline and First transfer pipeline is intersected in one first three-way valve；
Described hydrogen storage vessel is connected by the 4th transfer pipeline and the second transfer pipeline, the 4th transfer pipeline and Second transfer pipeline is intersected in one first cross valve；
Described first three-way valve and the first blender connect, and the other end of the first blender and the second three-way valve are even Connect；Second three-way valve connects micro fixed-bed reactor by the 5th transfer pipeline, and the 5th transfer pipeline is provided with the Five mass flowmenters, pressure gage；
The other end of described micro fixed-bed reactor connects the 4th three-way valve, and the 4th three-way valve is also connected with back pressure Valve, the other end of counterbalance valve connects one second cross valve；
Described first cross valve and the second blender connect, and the other end of the second blender and the 3rd three-way valve are even Connect；Alcohol-water separation device, the second three-way valve connect the 3rd three-way valve, alcohol-water separation device, methanol solution gasifying device, color Spectrometer connects the second cross valve；Methanol solution gasifying device is collected container with methanol and is connected；
Described master control module controls all parts action, first controls high pure nitrogen and high-purity hydrogen with the ratio set Being emptied by beds after the first blender mixing, treating that catalyst reduction completes rear cutout ventilation body is hydrogen Gas and the gaseous mixture of carbon dioxide, gas boosts to certain pressure again through alcohol water by beds through counterbalance valve Separator isolates Methanol product and water, and unreacted gas continues through reactor after unstripped gas supplements and follows Ring reacts.
The air conditioning system of a kind of water hydrogen car, described water hydrogen car includes: hydrogen production by methanol system, hydrogen Gas electricity generation system, hydrogen production by methanol system is connected with hydrogen gas generating system；
Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen is by being coated with palladium-silver Membrane separation device obtains highly purified hydrogen, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system；Described methanol system Hydrogen system includes hydrogen producer；
Described air conditioning system includes heat-exchange device；The high-temperature gas that described hydrogen producer is discharged is empty as automobile The thermal source of adjusting system heating installation, is Vehicle heating by heat-exchange device；
Described heat-exchange device includes some heat exchanging pipes, is the circulation gas of vehicle air conditioner in heat exchanging pipe Body, the high-temperature gas discharged for hydrogen producer outside heat exchanging pipe or the high-temp liquid after being heated by high-temperature gas.
The beneficial effects of the present invention is: the water hydrogen car of present invention proposition and air conditioning system thereof, can avoid The discharge of carbon dioxide, can utilize the carbon dioxide of collection to prepare methanol simultaneously；Automotive air-conditioning system of the present invention Utilize heat energy that hydrogen producer discharges as the heat energy of air conditioning warm air.
Accompanying drawing explanation
Fig. 1 is the composition schematic diagram of the present invention circulating water hydrogen car.
Fig. 2 is the composition schematic diagram of hydrogen production by methanol system in present system.
Fig. 3 is the structural representation of device for rapidly starting in hydrogen producer
Fig. 4 is hydrogen producer and the structural representation adding pipe line thereof.
Fig. 5 is the composition schematic diagram of the hydrogen producer being provided with relief valve.
Fig. 6 is the schematic diagram under the another kind of state of the hydrogen producer being provided with relief valve.
Fig. 7 is the composition schematic diagram of fuel cell system in present system.
Fig. 8 is the structural representation of liquid container.
Fig. 9 is the composition schematic diagram of methanol Preparation equipment in present system.
Detailed description of the invention
Describe the preferred embodiments of the present invention below in conjunction with the accompanying drawings in detail.
Embodiment one
Referring to Fig. 1, present invention is disclosed a kind of carbon dioxide recycle formula water hydrogen car, described water hydrogen moves Power automobile includes: hydrogen production by methanol system, hydrogen gas generating system, methanol Preparation equipment, genemotor, speed change Case, vehicle body, chassis, wheel, hydrogen production by methanol system is connected with hydrogen gas generating system, hydrogen gas generating system and first Alcohol Preparation equipment connects；The electric energy that methanol Preparation equipment, genemotor are sent by hydrogen gas generating system works.
In the present embodiment, referring to Fig. 2, hydrogen production by methanol system is small portable hydrogen producer, including: liquid Body stores container 10, raw material conveying device 50, device for rapidly starting 40, device for producing hydrogen 20, membrane separation device 30, hydrogen delivery tube road 60.
Referring to Fig. 8, the middle part of liquid container is provided with dividing plate 101, and the side of dividing plate 101 arranges reaction Liquid, opposite side arranges hydrogen gas generating system release, the liquid then compressed or the carbon dioxide of solid-state.Every Plate 101 connects drive mechanism, and the liquid in storing container reduces or carbon dioxide increases up to impose a condition Time, drive mechanism drives dividing plate action, reduces the volume of storage reaction liquid regions, increases storage carbon dioxide The volume in region.The carbon dioxide of release so while preparing hydrogen, can be collected, reduce carbon dioxide The discharge of gas, the carbon dioxide of collection is also used as the raw material of subsequent handling.The two ends of dividing plate 101 are arranged In chute 102, can slide along chute 102.
Described liquid container can also include control module, induction module；Described drive mechanism includes motor, Induction module includes pressure transducer or/and liquid level sensor；Described induction module is in order to react in sensing container The amount of liquid, the carbon dioxide of sensing hydrogen gas generating system release simultaneously, the liquid then compressed or solid-state Amount；And sensed data is sent to control module；The Data Control that described control module senses according to induction module The drive mechanism action to space mechanism；Liquid in liquid storage container reduces or carbon dioxide increases up to When imposing a condition, drive mechanism drives space mechanism action, reduces the volume of reaction liquid, increases carbon dioxide Volume.Described liquid container also can include liquefying plant or/and solidification equipment, two will collected Carbonoxide liquefaction is or/and solidify；
As it is shown on figure 3, described device for rapidly starting 40 includes housing 41, heating arrangements 42, gasification pipe 43, the internal diameter of gasification pipe 43 is 1～2mm, and gasification pipe 43 is wound on heating arrangements 42；Described add Heat engine structure can be electrically heated rod, utilizes alternating current or accumulator, aneroid battery.
One end of described gasification pipe 43 connects liquid container 10, is sent into by methanol in gasification pipe 43； The other end of gasification pipe 43 exports vaporized methanol, then by ignition mechanism ignition；Or, The other end of gasification pipe 43 exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, methanol Directly spontaneous combustion after gasification pipe 43 exports；Described device for rapidly starting 40 is that device for producing hydrogen is (the most whole Hydrogen producer) the startup energy is provided.
Refer to Fig. 4, in order to improve the firing rate of device for producing hydrogen, in the reformer chamber of described device for producing hydrogen 20 Inwall is provided with and adds pipe line 21, is placed with catalyst (as can be heating and temperature control existed in adding pipe line 21 380 DEG C～480 DEG C)；Described device for rapidly starting 40 heats for reformer chamber by adding pipe line 21 described in heating, The efficiency of heating surface can be improved.
As in figure 2 it is shown, device for producing hydrogen 20 can also arrange the second starter 70, described second starter 70 include that the second gasification pipe, the main body of the second gasification pipe are arranged at reformer chamber, and the second gasification pipe is Reformer chamber heating (can also be the heating of other unit of hydrogen producer).First gasification pipe is or/and the second vapor lamp The methanol of road output is to heat the second gasification pipe, by the methanol in the second gasification pipe while reformer chamber heats Gasification.When the second starter can persistently prepare gasification methanol after set the time, can close above-mentioned quickly Starter, thus reduce the dependence to extra powers such as electric energy further.
In addition, described device for producing hydrogen 20 includes heat exchanger, vaporizer, reformer chamber；Membrane separation device sets Being placed in separation chamber, separation chamber is arranged at the top of reformer chamber.Described liquid container is with device for producing hydrogen even Connect；Liquid container stores the first alcohol and water of liquid.
First alcohol and water in described liquid container is delivered to heat exchanger heat exchange, heat exchange by raw material conveying device Rear entrance vaporizer gasifies；Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with catalysis Agent, reformer chamber bottom and middle portion temperature are 300 DEG C～420 DEG C.The temperature on described reformer chamber top is 400 DEG C ～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, connecting line be completely or partially arranged at reformation The top of room, can continue the heating gas from reformer chamber output by the high temperature on reformer chamber top；Described connecting tube Road is as the buffering between reformer chamber and separation chamber so that from temperature and the separation chamber of the gas of reformer chamber output Temperature is identical or close.Temperature in described separation chamber is set as 350 DEG C～570 DEG C；It is provided with film in separation chamber to divide From device, obtain hydrogen from the aerogenesis end of membrane separator.By above-mentioned improvement, can ensure that reformer chamber is urged respectively The low temperature requirements of agent, and the high temperature requirement of separation chamber, and then improve hydrogen preparation efficiency；Meanwhile, this Bright preheating method (separation chamber is arranged at the top of reformer chamber) is the most convenient.
Described catalyst include the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, The oxide of Zn, rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for catalysis The 0.6%～1.8% of agent gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, and the oxide of Cu accounts for catalysis The 6%～12% of agent gross mass, the oxide of Fe accounts for the 3%～8% of catalyst gross mass, and the oxide of Zn accounts for catalysis The 8%～20% of agent gross mass, rare-earth oxide accounts for the 6%～40% of catalyst gross mass, and remaining is transition gold Belong to oxide；
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the CuO of 3-17 part, The Al of ZrO, 55-80 part of the ZnO of 3-18 part, 0.5-3 part2O3, the CeO of 1-3 part2, the La of 1-3 part2O3。
Additionally, described raw material conveying device provides power, the feedstock transportation in liquid container to hydrogen manufacturing is filled Put；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that device for producing hydrogen prepares There is enough pressure.The hydrogen that described device for producing hydrogen prepares is delivered to membrane separation device and separates, for dividing Difference from the inside and outside pressure of the membrane separation device of hydrogen is more than or equal to 0.7M Pa.By this improvement so that hydrogen manufacturing The hydrogen that device prepares has enough pressure, can improve hydrogen production efficiency and the purity of prepared hydrogen.
After described hydrogen producer starts, the hydrogen that hydrogen producer is prepared by device for producing hydrogen provides the energy needed for running Source；At this point it is possible to closedown device for rapidly starting.The hydrogen partial prepared due to device for producing hydrogen is or/and residual air is led to Crossing burning maintains hydrogen producer to run, such that it is able to reduce the dependence to extra power, adaptive ability is strong.
The high-temperature gas that described hydrogen producer is discharged, as the thermal source of air conditioning for automobiles heating installation, passes through heat-exchange device For Vehicle heating；Heat-exchange device includes some heat exchanging pipes, is the circulation gas of vehicle air conditioning in heat exchanging pipe Body, the high-temperature gas discharged for hydrogen producer outside heat exchanging pipe or the high-temp liquid after being heated by high-temperature gas.
Described heat-exchange device is provided with microprocessor, valve positioner, hot-gas temperature sensor, flow Sensor, microprocessor connecting valve controller, hot-gas temperature sensor, flow transducer, car respectively Air-conditioner controller, according to hot-gas temperature sensor, the temperature of the high-temperature gas of flow transducer sensing, The control state modulator valve positioner of flow and vehicle air conditioning, adjusts the size of valve by valve positioner, Thus adjust the flow of the high-temperature gas led in heat-exchange device.
Additionally, refer to Fig. 5, Fig. 6, described hydrogen delivery tube road 60 is provided with spring safety valve 61, spring Relief valve 61 includes valve body, spring mechanism, end of upspringing；Described raw material conveying device 50 includes delivery pump, End of upspringing arranges (certain raw material conveying device 50 can also be for other power set) near the switch of delivery pump, The switch of raw material conveying device can be disconnected when end of upspringing is upspring.By arranging machine security on hydrogen delivery tube road Valve, when air pressure reaches setting value, mechanical safety valve is opened, and can control raw material conveying device stopping transferring raw material. Such that it is able to improve the safety that equipment runs, prevent hydrogen leak and blast.
Specifically, in the present embodiment, the switch of described delivery pump includes contact-segment 62 and three ports, three Port is respectively first port the 63, second port the 64, the 3rd port 65.One end of described contact-segment 62 can Being rotatably provided in the first port 63, the first port 63 connects delivery pump；The other end of contact-segment 62 can connect Touch the second port 64 or the 3rd port 65.
Described second port 64 connects power supply, when the first port 63 connects the second port 64, can control conveying Pump work.Described 3rd port 65 connects alarm transmitting device, when the first port connects three ports 65, Can control conveying air pump inoperative, alarm transmitting device sends warning message (as by the way of note) extremely simultaneously Corresponding server or client, can notify corresponding personnel.
Described hydrogen gas generation device connects hydrogen producer, and the Partial DC electricity sent is delivered to hydrogen producer；System Hydrogen storage equipment drives electromagnetic heater to be reformer chamber, separation chamber's heating by the unidirectional current oneself prepared；Meanwhile, Also the unidirectional current sent is delivered to the deep sea water extracting device of system, sea water purifying plant, oxygen conveying set Standby, water generation equipment, runs for these equipment, goes back hydrogen supply gas electric generating apparatus self-operating simultaneously.
Described hydrogen producer includes electromagnetic heater；Electromagnetic heater includes the reformation cylinder forming reformer chamber Body, the separation cylinder body of formation separation chamber, the first heating coil being arranged at outside reformation cylinder body, separate outside cylinder body Second heating coil, reformation cylinder body, the temperature sensor separated in cylinder body, pressure transducer, and electromagnetism control Device processed；Electromagnetic controller according to the Data Control first that temperature sensor, pressure transducer sense heat coil, The electric current of the second heating coil, can make reformer chamber, separation chamber moment reach design temperature.
Described hydrogen producer also includes that electric energy estimation block, hydrogen prepare detection module, electric energy memory module；Institute State whether the electric energy that electric energy estimation block sends in real time in order to estimate hydrogen gas generation device can meet reformation, when separating Need the electric energy consumed；If it is satisfied, then closedown device for rapidly starting.
It is the most stable that hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer；If hydrogen producer The hydrogen of preparation is unstable, then control device for rapidly starting and be again started up, and the electric energy part obtained be stored in Electric energy memory module, uses when electric energy is not enough to the consumption providing hydrogen producer.
Referring to Fig. 7, in the present embodiment, described hydrogen gas generation device 200 is fuel cell system, fuel electricity Cell system includes: gas supply device, pile 201；Described gas supply device utilizes the gas conduct of compression Power, in automatic transport to pile 201.
In the present embodiment, gas supply device is compressed gas feedway 202, and described compressed gas is delivered to Entering pile 201 after one mixing container 203, one end of mixing container 203 connects air；Compressed gas enters Natural air is reacted by the power produced after mixing container 203 in setting ratio inspiration pile, and regulation oxygen contains Amount.
Described fuel cell system also includes air intake conduit, outlet pipe, air intake conduit, escape pipe Road is all through humidification system 204.The gas of described compression is mainly oxygen (can also be for air)；Naturally empty Gas enters pile 201 with compressed oxygen after mixing container mixing.
Described fuel cell system also includes gas regulating system, and gas regulating system is arranged at mixing container 203 In；Described gas regulating system includes that valve regulated controls device, and oxygen content sensor is or/and compress Gas compression compares sensor.
Described oxygen content sensor mixes the air of mixing and the content of oxygen in oxygen in container in order to sense, And the data sensed are sent to valve regulated control device.
Described compressed gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data that will sense Send to valve regulated control device.
Described valve regulated controls device according to oxygen content sensor or/and compressed gas compression ratio sensor Sensing result regulation oxygen delivery valve door, air entrainment valve door, control compressed oxygen, the delivery ratio of natural air Example (if natural air ratio can be 0-70%)；The power that compressed oxygen produces after entering mixing container will be mixed Close gas and push to pile reaction, utilize natural air to do dilution decompression.
Described humidification system 204 includes that humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is air A part for air inlet pipeline；Gas through fuel cell reaction is delivered to humidity exchange by outlet pipe to be held Device.
The material of described humidity exchange pipeline is the most permeable airtight so that conveying gas carries out humidity with natural air Exchange, and cannot circulate between gas.Humidity exchange pipeline spiral in humidity exchanging container is arranged, Ke Yichong Divide and carry out humidity exchange.
Referring to Fig. 9, described methanol Preparation equipment includes: nitrogen gas conveying device A1, hydrogen conveyor A2, Carbon dioxide conveyer device A3, the first blender A4, the second gaseous mixture A5, micro fixed-bed reactor A7, Counterbalance valve A8, alcohol-water separation device A6, chromatograph A9, methanol solution gasifying device, methanol collect container, master control mould Block.
Described nitrogen gas conveying device A1 includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline sets There are the first stop valve A11, the first mass flowmenter A12.
Described carbon dioxide conveyer device A3 includes carbon dioxide storage container, the second transfer pipeline, and second is defeated Pipeline is sent to be provided with the second stop valve, the second mass flowmenter.
Described hydrogen conveyor A3 includes hydrogen storage vessel, the 3rd transfer pipeline, the 4th transfer pipeline, 3rd transfer pipeline is provided with the 3rd stop valve, the 3rd mass flowmenter, the 4th transfer pipeline be provided with the 4th stop valve, 4th mass flowmenter.
Described hydrogen storage vessel A3 is connected by the 3rd transfer pipeline and the first transfer pipeline, the 3rd conveying pipe Road and the first transfer pipeline are intersected in one first three-way valve A13.
Described hydrogen storage vessel is connected by the 4th transfer pipeline and the second transfer pipeline, the 4th transfer pipeline and Second transfer pipeline is intersected in one first cross valve A14.
Described first three-way valve A13 and the first blender A4 connects, the other end and second of the first blender A4 Three-way valve A15 connects；Second three-way valve A15 connects micro fixed-bed reactor A7 by the 5th transfer pipeline, 5th transfer pipeline is provided with the 5th mass flowmenter, pressure gage.
The other end of described micro fixed-bed reactor A7 connects the 4th three-way valve A16, the 4th three-way valve A16 The other end being also connected with counterbalance valve A8, counterbalance valve A8 connects one second cross valve A10.
Described first cross valve A14 and the second blender A5 connects, the other end and the 3rd of the second blender A5 Three-way valve A17 connects；Alcohol-water separation device A6, the second three-way valve A15 connect the 3rd three-way valve A17, alcohol moisture The second cross valve A10 is connected from device A6, methanol solution gasifying device, chromatograph A9；Methanol solution gasifying device and methanol Collection container connects.
Described master control module controls all parts action, first controls high pure nitrogen and high-purity hydrogen with the ratio set Being emptied by beds after the first blender mixing, treating that catalyst reduction completes rear cutout ventilation body is hydrogen Gas and the gaseous mixture of carbon dioxide, gas boosts to certain pressure again through alcohol water by beds through counterbalance valve Separator isolates Methanol product and water, and unreacted gas continues through reactor after unstripped gas supplements and follows Ring reacts.
Described methanol Preparation equipment also includes generating electricity by natural energy device, utilizes solar energy or/and wind energy is or/and give birth to Thing can generate electricity, and utilizes the electric energy sent water to be hydrolyzed to hydrogen and oxygen, by the hydrogen collected and carbon dioxide It is prepared as methanol.The energy that methanol Preparation equipment is used can be to utilize the natural energy resources such as solar energy, wind energy to turn The electric energy changed and come.
In the present embodiment, described automobile is automobile, and described automobile also includes that the second genemotor, energy store Unit, kinetic energy converting unit, kinetic energy converting unit, energy storage units, the second genemotor are sequentially connected with； The energy of automobile brake is converted to electric energy and is stored in energy storage units by described kinetic energy converting unit, for Second genemotor provides electric energy.
Described second genemotor is also connected with hydrogen gas generating system, hydrogen gas generating system be the second motor Machine provides the energy.
Described automobile also includes that road environment induction module, allocation database, hydrogen distribute module；Hydrogen distributes Module is connected with road environment induction module, allocation database respectively, according to the sensing of road environment induction module Data in data and allocation database are the hydrogen that the distribution of each genemotor is corresponding.
Described road environment induction module is in order to sense road congestion information, ground flat degree information；Congestion in road Information is according to automobile real-time speed, acceleration, deceleration frequency, and determines down time；Ground flat degree information Obliquity sensor according to arranging on automobile chassis determines.
Described allocation database stores some tables of data, tables of data records each road congestion information, ground Flatness information corresponding for genemotor, second genemotor distribution hydrogen data；Genemotor, In second genemotor, one is used for driving trailing wheel or/and front-wheel, another be used for driving front-wheel or/and after Wheel.
Embodiment two
The present embodiment is with the difference of embodiment one, and in the present embodiment, described hydrogen production by methanol system also includes gas Pressure regulon system, Collection utilization subsystem.
Described air pressure adjustment subsystem include microprocessor, gas pressure sensor, valve positioner, air outlet valve, Outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the air pressure in transfer conduit Data, and the barometric information of sensing is sent to microprocessor；Described microprocessor will be from gas pressure sensor This barometric information received is compared with setting threshold interval；When the pressure data received is higher than setting threshold value Interval maximum, microprocessor control valve door controller is opened air outlet valve and is set the time so that in transfer conduit Air pressure is in set point, and one end of outlet pipe connects air outlet valve simultaneously, and the other end connects described hydrogen manufacturing subsystem System, is heated by the firing equipment that needs that burning is hydrogen manufacturing subsystem；When the pressure data received is less than setting Determining the minima of threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material.
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, divides from expellant gas Do not collect hydrogen, oxygen gas and water, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generation System uses, and the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycles.Described Collection utilization System includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, will Hydrogen and oxygen separation, be separated from water hydrogen, oxygen is separated from water the most respectively.
Embodiment three
The air conditioning system of a kind of water hydrogen car, described water hydrogen car includes: hydrogen production by methanol system, hydrogen Gas electricity generation system, hydrogen production by methanol system is connected with hydrogen gas generating system.
Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen is by being coated with palladium-silver Membrane separation device obtains highly purified hydrogen, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system.
Described air conditioning system includes heat-exchange device；The high-temperature gas that described hydrogen producer is discharged is empty as automobile The thermal source of adjusting system heating installation, is Vehicle heating by heat-exchange device.
Described heat-exchange device includes some heat exchanging pipes, is the circulation gas of vehicle air conditioner in heat exchanging pipe Body, the high-temperature gas discharged for hydrogen producer outside heat exchanging pipe or the high-temp liquid after being heated by high-temperature gas.
In sum, the water hydrogen car of present invention proposition and air conditioning system thereof, the row of carbon dioxide can be avoided Put, the carbon dioxide of collection can be utilized to prepare methanol simultaneously；Automotive air-conditioning system of the present invention can utilize hydrogen manufacturing The heat energy that equipment is discharged is as the heat energy of air conditioning warm air.
Device for producing hydrogen volume of the present invention is little, utilizes distinctive catalyst formulation and palladium film to purify, and the hydrogen of preparation is fast Speed, stable, purity height, can be that automobile provides stable input energy sources.The methanol Preparation equipment of the present invention can Improve preparation efficiency, improve the concentration preparing methanol.
Here description of the invention and application is illustrative, is not wishing to limit the scope of the invention to above-mentioned reality Execute in example.The deformation of embodiments disclosed herein and change are possible, for the common skill of those this areas For art personnel, the various parts with equivalence of replacing of embodiment are known.It should be clear to a person skilled in the art that , in the case of without departing from the spirit or essential characteristics of the present invention, the present invention can in other forms, knot Structure, layout, ratio, and realize with other assembly, material and parts.Without departing from the scope of the invention and In the case of spirit, embodiments disclosed herein can be carried out other deformation and change.

Claims (10)

1. a water hydrogen car, it is characterised in that described automobile includes: hydrogen production by methanol system, hydrogen gas generation System, methanol Preparation equipment, genemotor, change speed gear box, vehicle body, chassis, wheel, hydrogen from methyl alcohol System is connected with hydrogen gas generating system, and hydrogen gas generating system is connected with methanol Preparation equipment；Genemotor, The electric energy that methanol Preparation equipment is sent by hydrogen gas generating system works；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, Hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes that solid hydrogen is stored up Deposit container, store container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described storage container includes: container, the space mechanism being arranged in container are connected with space mechanism Drive mechanism, control module, induction module；Container is at least divided into two spaces by described space mechanism； In two spaces, a placing response liquid, opposite side arranges hydrogen gas generating system release, is then pressed The liquid of contracting or the carbon dioxide of solid-state；Control module connects drive mechanism, induction module respectively；Described Drive mechanism includes that motor, induction module include pressure transducer or/and liquid level sensor；Described sensing mould Block, in order to sense the amount of reaction liquid in container, sensing hydrogen gas generating system release simultaneously, is then compressed Liquid or the amount of carbon dioxide of solid-state；And sensed data is sent to control module；Described control mould The Data Control drive mechanism that tuber senses according to the induction module action to space mechanism；In storing container Liquid reduce or carbon dioxide is when increasing up to impose a condition, drive mechanism drives space mechanism action, Reduce the volume of reaction liquid, increase the volume of carbon dioxide；Described storage container also includes liquefying plant Or/and solidification equipment, by the co 2 liquefaction collected or/and solidify；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged at separation chamber In, separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen store container, store container respectively with Hydrogen producer connects；Store the first alcohol and water storing liquid in container；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes One starter, the second starter；Described first starter includes the first heating arrangements, the first gas Changing pipeline, the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound in first and adds On heat engine structure；One end of described first gasification pipe connects storage container, by raw material conveying device by first Alcohol is sent in the first gasification pipe；The other end of the first gasification pipe exports vaporized methanol, then leads to Cross ignition mechanism ignition；Or, the other end of the first gasification pipe exports vaporized methanol, and The methanol temperature of output reaches self-ignition point, methanol directly spontaneous combustion after the first gasification pipe output；Described Two starters include that the second gasification pipe, the main body of the second gasification pipe are arranged at described reformer chamber, First gasification pipe is or/and the methanol of the second gasification pipe output is heating second while reformer chamber heating Gasification pipe, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, It is placed with catalyst in adding pipe line；Described device for rapidly starting is attached most importance to whole room by adding pipe line described in heating Heating；After described hydrogen generating system starts, hydrogen generating system is provided by the hydrogen that hydrogen producer prepares and runs institute The energy needed；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts Solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Too Sun can start module provides electric energy for the first heating arrangements；Or, initially opening of described device for rapidly starting Energy source is manual generator, and the electric energy sent is stored in battery by manual generator；
Described catalyst include the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, The oxide of Zn, rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for The 0.6%～1.8% of catalyst gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, the oxidation of Cu Thing accounts for the 6%～12% of catalyst gross mass, and the oxide of Fe accounts for the 3%～8% of catalyst gross mass, the oxygen of Zn Compound accounts for the 8%～20% of catalyst gross mass, and rare-earth oxide accounts for the 6%～40% of catalyst gross mass, Remaining is transition metal oxide；
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: 3-17 part The Al of ZrO, 55-80 part of the ZnO of CuO, 3-18 part, 0.5-3 part2O3, the CeO of 1-3 part2, 1-3 The La of part2O3；
Described solid hydrogen stores and stores solid hydrogen in container, when hydrogen generating system starts, by gasification Solid hydrogen is converted to gaseous hydrogen by module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer Start heat energy, as the startup energy of hydrogen producer；
First alcohol and water in described storage container is delivered to heat exchanger heat exchange, heat exchange by raw material conveying device Rear entrance vaporizer gasifies；Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with Catalyst, reformer chamber bottom and middle portion temperature are 300 DEG C～420 DEG C；The temperature on described reformer chamber top is 400 DEG C～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, completely or partially setting of connecting line It is placed in the top of reformer chamber, the heating gas from reformer chamber output can be continued by the high temperature on reformer chamber top； Described connecting line is as the buffering between reformer chamber and separation chamber so that from the gas of reformer chamber output Temperature is identical or close with the temperature of separation chamber；Temperature in described separation chamber is set as 350 DEG C～570 DEG C； It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator；
Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Institute State raw material conveying device and the pressure of 0.15～5MPa is provided to raw material so that the hydrogen tool that hydrogen producer prepares There is enough pressure；
After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is by burning Maintenance hydrogen producer runs；
The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and separates, for separating hydrogen The difference of the inside and outside pressure of membrane separation device is more than or equal to 0.7M Pa；Described membrane separation device is to make pottery in porous The membrane separation device of porcelain surface vacuum plating palladium-silver, film plating layer is palladium-silver, the quality of palladium-silver Percentage ratio palladium accounts for 75%～78%, and silver accounts for 22%～25%；
Prepared hydrogen is passed through transfer conduit real-time Transmission to hydrogen gas generating system by described hydrogen manufacturing subsystem； Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen Electricity generation system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
The high-temperature gas that described hydrogen producer is discharged, as the thermal source of air conditioning for automobiles heating installation, is exchanged by heat Device is Vehicle heating；Heat-exchange device includes some heat exchanging pipes, is vehicle air conditioning in heat exchanging pipe Circulated gases, the high-temperature gas discharged for hydrogen producer outside heat exchanging pipe or after being heated by high-temperature gas High-temp liquid；Or, it is the circulated gases of vehicle air conditioning outside heat exchanging pipe, for hydrogen manufacturing in heat exchanging pipe The high-temperature gas that equipment is discharged or the high-temp liquid after being heated by high-temperature gas；
Described heat-exchange device be provided with microprocessor, valve positioner, hot-gas temperature sensor, Flow transducer, microprocessor connecting valve controller respectively, hot-gas temperature sensor, flow pass Sensor, vehicle air conditioner controller, according to hot-gas temperature sensor, the high temperature of flow transducer sensing The control state modulator valve positioner of the temperature of gas, flow and vehicle air conditioning, passes through valve positioner Adjust the size of valve, thus adjust the flow leading to the high-temperature gas in or beyond heat-exchange device；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, goes out Air valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense transfer tube Barometric information in road, and the barometric information of sensing is sent to microprocessor；Described microprocessor will be from This barometric information that gas pressure sensor receives is compared with setting threshold interval；When the pressure received Force data is higher than the maximum of setting threshold interval, and microprocessor control valve door controller is opened air outlet valve and set Fixing time so that in transfer conduit, air pressure is in set point, one end connection of outlet pipe simultaneously is given vent to anger Valve, the other end connects described hydrogen manufacturing subsystem, is carried out by the firing equipment that needs that burning is hydrogen manufacturing subsystem Heating；When the pressure data received controls described less than the minima of setting threshold interval, microprocessor Hydrogen manufacturing subsystem accelerates the transporting velocity of raw material；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, from expellant gas Middle hydrogen, the oxygen gas and water of collecting respectively, utilizes the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen Gas electricity generation system uses, and the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycles；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water Separator, oxygen check valve, by hydrogen and oxygen separation, be separated from water hydrogen, oxygen the most respectively It is separated from water；
Described hydrogen producer also includes that electric energy estimation block, hydrogen prepare detection module, electric energy memory module； The electric energy that described electric energy estimation block sends in real time in order to estimate hydrogen gas generation device whether can meet reformation, The electric energy consumed is needed during separation；If it is satisfied, then closedown device for rapidly starting；
It is the most stable that hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer；If hydrogen manufacturing Hydrogen prepared by equipment is unstable, then control device for rapidly starting and be again started up, and the electric energy portion that will obtain Divide and be stored in electric energy memory module, use when electric energy is not enough to the consumption providing hydrogen producer；
Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, Pile；The gas of described gas supply device utilization compression is as power, in automatic transport to pile；Institute State pile and include that some sub-fuel cell modules, each sub-fuel cell module include at least one super electricity Hold；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas master of described compression Oxygen to be；Air enters pile with oxygen after mixing container mixing；
Described fuel cell system also includes gas regulating system；Described gas regulating system includes that valve is adjusted Joint controls device, and oxygen content sensor is or/and compressed gas compression ratio sensor；
Described oxygen content sensor is in order to sense the air of mixing and the containing of oxygen in oxygen in mixing container Amount, and the data sensed are sent to valve regulated control device；
Described compressed gas compression ratio sensor is in order to sensing the compression ratio of compressed oxygen, and will sense Data send to valve regulated control device；
Described valve regulated controls device according to oxygen content sensor or/and compressed gas compression ratio senses Device sensing result regulation oxygen delivery valve door, air entrainment valve door, control compressed oxygen, air defeated Send ratio；Mixed gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container；
Described fuel cell system also includes humidification system, and humidification system includes humidity exchanging container, humidity Exchange pipeline, humidity exchange pipeline is a part for air intake conduit；Gas through fuel cell reaction Body is delivered to humidity exchanging container by outlet pipe；
The material of described humidity exchange pipeline is the most permeable airtight so that after reaction, gas enters with natural air Row humidity exchanges, and cannot circulate between gas；
Described automobile also includes the second genemotor, energy storage units, kinetic energy converting unit, kinetic energy Converting unit, energy storage units, the second genemotor are sequentially connected with；Described kinetic energy converting unit will The energy of automobile brake is converted to electric energy and is stored in energy storage units, is the second genemotor Electric energy is provided；
Described second genemotor is also connected with hydrogen gas generating system, hydrogen gas generating system be second electronic Electromotor provides the energy；
Described automobile also includes that road environment induction module, allocation database, hydrogen distribute module；Hydrogen Distribution module is connected with road environment induction module, allocation database respectively, senses mould according to road environment Data in the data of block sensing and allocation database are the hydrogen that the distribution of each genemotor is corresponding；
Described road environment induction module is in order to sense road congestion information, ground flat degree information；Road Congestion information is according to automobile real-time speed, acceleration, deceleration frequency, and determines down time；Ground is put down Whole degree information determines according to the obliquity sensor arranged on automobile chassis；
Described allocation database stores some tables of data, tables of data records each road congestion information, Ground flat degree information corresponding for genemotor, second genemotor distribution hydrogen data；Electricity In dynamic electromotor, the second genemotor, one is used for driving trailing wheel or/and front-wheel, and another is used for driving Front-wheel is or/and trailing wheel；
Described methanol Preparation equipment includes: nitrogen gas conveying device, hydrogen conveyor, carbon dioxide carry Device, the first blender, the second gaseous mixture, micro fixed-bed reactor, counterbalance valve, synthesis reactor, Alcohol-water separation device, chromatograph, methanol solution gasifying device, methanol collect container, main control module；Described dioxy Change carbon conveyer device and connect the side of described storage container collection carbon dioxide；The methanol conveying prepared To the methanol-water mixed liquor side storing container；
Described nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline sets There are the first stop valve, the first mass flowmenter；
Described carbon dioxide conveyer device includes carbon dioxide storage container, the second transfer pipeline, and second is defeated Pipeline is sent to be provided with the second stop valve, the second mass flowmenter；
Described hydrogen conveyor includes hydrogen storage vessel, the 3rd transfer pipeline, the 4th transfer pipeline, 3rd transfer pipeline is provided with the 3rd stop valve, the 3rd mass flowmenter, and the 4th transfer pipeline is provided with the 4th section Only valve, the 4th mass flowmenter；
Described hydrogen storage vessel is connected by the 3rd transfer pipeline and the first transfer pipeline, the 3rd conveying pipe Road and the first transfer pipeline are intersected in one first three-way valve；
Described hydrogen storage vessel is connected by the 4th transfer pipeline and the second transfer pipeline, the 4th conveying pipe Road and the second transfer pipeline are intersected in one first cross valve；
Described first three-way valve and the first blender connect, the other end of the first blender and the second three-way valve Connect；Second three-way valve connects micro fixed-bed reactor, the 5th transfer pipeline by the 5th transfer pipeline It is provided with the 5th mass flowmenter, pressure gage；
The other end of described micro fixed-bed reactor connects the 4th three-way valve, and the 4th three-way valve is also connected with the back of the body Pressure valve, the other end of counterbalance valve connects one second cross valve；
Described first cross valve and the second blender connect, the other end of the second blender and the 3rd three-way valve Connect；Alcohol-water separation device, the second three-way valve connect the 3rd three-way valve, and alcohol-water separation device, methanol solution are disguised Put, chromatograph connects the second cross valve；Methanol solution gasifying device is collected container with methanol and is connected；
Described master control module controls all parts action, first controls high pure nitrogen and high-purity hydrogen with setting Ratio is emptied by beds after the first blender mixing, switches after catalyst reduction completes Gas is the gaseous mixture of hydrogen and carbon dioxide, and gas is boosted to necessarily through counterbalance valve by beds Pressure isolates Methanol product and water through alcohol-water separation device again, and unreacted gas is after unstripped gas supplements Continue through reactor cycles reaction.
2. a water hydrogen car, it is characterised in that described water hydrogen car includes: hydrogen production by methanol system, Hydrogen gas generating system, genemotor, change speed gear box, vehicle body, chassis, wheel, hydrogen production by methanol system with Hydrogen gas generating system connects, and hydrogen gas generating system is connected with genemotor；
Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen closes by being coated with palladium-silver The membrane separation device of gold obtains highly purified hydrogen, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system；First Alcohol hydrogen generating system includes hydrogen producer；
The high-temperature gas that described hydrogen producer is discharged, as the thermal source of air conditioning for automobiles heating installation, is exchanged by heat Device is Vehicle heating；Heat-exchange device includes some heat exchanging pipes, is vehicle air conditioning in heat exchanging pipe Circulated gases, the high-temperature gas discharged for hydrogen producer outside heat exchanging pipe or after being heated by high-temperature gas High-temp liquid；Or, it is the circulated gases of vehicle air conditioning outside heat exchanging pipe, for hydrogen manufacturing in heat exchanging pipe The high-temperature gas that equipment is discharged or the high-temp liquid after being heated by high-temperature gas.
Water hydrogen car the most according to claim 2, it is characterised in that:
Described heat-exchange device be provided with microprocessor, valve positioner, hot-gas temperature sensor, Flow transducer, microprocessor connecting valve controller respectively, hot-gas temperature sensor, flow pass Sensor, vehicle air conditioner controller, according to hot-gas temperature sensor, the high temperature of flow transducer sensing The control state modulator valve positioner of the temperature of gas, flow and vehicle air conditioning, passes through valve positioner Adjust the size of valve, thus adjust the flow leading to the high-temperature gas in or beyond heat-exchange device.
Water hydrogen car the most according to claim 2, it is characterised in that:
Described hydrogen production by methanol system includes storing container, and the middle part storing container is provided with dividing plate, the one of dividing plate Side arranges reaction liquid, and opposite side arranges hydrogen gas generating system release, the liquid then compressed or solid-state Carbon dioxide；Dividing plate connects pushing mechanism, and the liquid in storing container reduces or carbon dioxide increases Adding when reaching to impose a condition, pushing mechanism drives dividing plate action, reduces the volume of storage reaction liquid regions, Increase the volume in storage carbon dioxide region；
Described storage container also includes control module, induction module；Described drive mechanism includes motor, sense Module is answered to include pressure transducer or/and liquid level sensor；Described induction module is in order to react in sensing container The amount of liquid, sensing hydrogen gas generating system release simultaneously, the liquid then compressed or the titanium dioxide of solid-state The amount of carbon；And sensed data is sent to control module；Described control module senses according to induction module The action to space mechanism of the Data Control drive mechanism；Liquid in liquid storage container reduces or dioxy When change carbon increases up to impose a condition, drive mechanism drives space mechanism action, reduces the appearance of reaction liquid Long-pending, increase the volume of carbon dioxide；Described storage device also includes liquefying plant or/and solidification equipment, incites somebody to action The co 2 liquefaction collected is or/and solidify.
Water hydrogen car the most according to claim 2, it is characterised in that:
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, Hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes that solid hydrogen is stored up Deposit container, store container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged at separation chamber In, separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen store container, store container respectively with Hydrogen producer connects；Store the first alcohol and water storing liquid in container；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes One starter, the second starter；Described first starter includes the first heating arrangements, the first gas Changing pipeline, the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound in first and adds On heat engine structure；One end of described first gasification pipe connects storage container, by raw material conveying device by first Alcohol is sent in the first gasification pipe；The other end of the first gasification pipe exports vaporized methanol, then leads to Cross ignition mechanism ignition；Or, the other end of the first gasification pipe exports vaporized methanol, and The methanol temperature of output reaches self-ignition point, methanol directly spontaneous combustion after the first gasification pipe output；Described Two starters include that the second gasification pipe, the main body of the second gasification pipe are arranged at described reformer chamber, First gasification pipe is or/and the methanol of the second gasification pipe output is heating second while reformer chamber heating Gasification pipe, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, It is placed with catalyst in adding pipe line；Described device for rapidly starting is attached most importance to whole room by adding pipe line described in heating Heating；After described hydrogen generating system starts, hydrogen generating system is provided by the hydrogen that hydrogen producer prepares and runs institute The energy needed；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts Solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Too Sun can start module provides electric energy for the first heating arrangements；Or, initially opening of described device for rapidly starting Energy source is manual generator, and the electric energy sent is stored in battery by manual generator；
Described solid hydrogen stores and stores solid hydrogen in container, when hydrogen generating system starts, by gasification Solid hydrogen is converted to gaseous hydrogen by module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer Start heat energy, as the startup energy of hydrogen producer；
First alcohol and water in described storage container is delivered to heat exchanger heat exchange, heat exchange by raw material conveying device Rear entrance vaporizer gasifies；Methanol vapor and steam after gasification enter reformer chamber, and reformer chamber is provided with Catalyst, reformer chamber bottom and middle portion temperature are 300 DEG C～420 DEG C；The temperature on described reformer chamber top is 400 DEG C～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, completely or partially setting of connecting line It is placed in the top of reformer chamber, the heating gas from reformer chamber output can be continued by the high temperature on reformer chamber top； Described connecting line is as the buffering between reformer chamber and separation chamber so that from the gas of reformer chamber output Temperature is identical or close with the temperature of separation chamber；Temperature in described separation chamber is set as 350 DEG C～570 DEG C； It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator；
Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Institute State raw material conveying device and the pressure of 0.15～5MPa is provided to raw material so that the hydrogen tool that hydrogen producer prepares There is enough pressure；
After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is by burning Maintenance hydrogen producer runs；
The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and separates, for separating hydrogen The difference of the inside and outside pressure of membrane separation device is more than or equal to 0.7M Pa；Described membrane separation device is to make pottery in porous The membrane separation device of porcelain surface vacuum plating palladium-silver, film plating layer is palladium-silver, the quality of palladium-silver Percentage ratio palladium accounts for 75%～78%, and silver accounts for 22%～25%；
Prepared hydrogen is passed through transfer conduit real-time Transmission to hydrogen gas generating system by described hydrogen manufacturing subsystem； Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen Electricity generation system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, goes out Air valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense transfer tube Barometric information in road, and the barometric information of sensing is sent to microprocessor；Described microprocessor will be from This barometric information that gas pressure sensor receives is compared with setting threshold interval；When the pressure received Force data is higher than the maximum of setting threshold interval, and microprocessor control valve door controller is opened air outlet valve and set Fixing time so that in transfer conduit, air pressure is in set point, one end connection of outlet pipe simultaneously is given vent to anger Valve, the other end connects described hydrogen manufacturing subsystem, is carried out by the firing equipment that needs that burning is hydrogen manufacturing subsystem Heating；When the pressure data received controls described less than the minima of setting threshold interval, microprocessor Hydrogen manufacturing subsystem accelerates the transporting velocity of raw material；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, from expellant gas Middle hydrogen, the oxygen gas and water of collecting respectively, utilizes the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen Gas electricity generation system uses, and the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycles；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water Separator, oxygen check valve, by hydrogen and oxygen separation, be separated from water hydrogen, oxygen the most respectively It is separated from water.
Water hydrogen car the most according to claim 5, it is characterised in that:
Described hydrogen producer also includes that electric energy estimation block, hydrogen prepare detection module, electric energy memory module； The electric energy that described electric energy estimation block sends in real time in order to estimate hydrogen gas generation device whether can meet reformation, The electric energy consumed is needed during separation；If it is satisfied, then closedown device for rapidly starting；
It is the most stable that hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer；If hydrogen manufacturing Hydrogen prepared by equipment is unstable, then control device for rapidly starting and be again started up, and the electric energy portion that will obtain Divide and be stored in electric energy memory module, use when electric energy is not enough to the consumption providing hydrogen producer；
Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, Pile；The gas of described gas supply device utilization compression is as power, in automatic transport to pile；Institute State pile and include that some sub-fuel cell modules, each sub-fuel cell module include at least one super electricity Hold；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas master of described compression Oxygen to be；Air enters pile with oxygen after mixing container mixing；
Described fuel cell system also includes gas regulating system；Described gas regulating system includes that valve is adjusted Joint controls device, and oxygen content sensor is or/and compressed gas compression ratio sensor；
Described oxygen content sensor is in order to sense the air of mixing and the containing of oxygen in oxygen in mixing container Amount, and the data sensed are sent to valve regulated control device；
Described compressed gas compression ratio sensor is in order to sensing the compression ratio of compressed oxygen, and will sense Data send to valve regulated control device；
Described valve regulated controls device according to oxygen content sensor or/and compressed gas compression ratio senses Device sensing result regulation oxygen delivery valve door, air entrainment valve door, control compressed oxygen, air defeated Send ratio；Mixed gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container；
Described fuel cell system also includes humidification system, and humidification system includes humidity exchanging container, humidity Exchange pipeline, humidity exchange pipeline is a part for air intake conduit；Gas through fuel cell reaction Body is delivered to humidity exchanging container by outlet pipe；
The material of described humidity exchange pipeline is the most permeable airtight so that conveying gas is carried out with natural air Humidity exchanges, and cannot circulate between gas；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts Solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Too Sun can start module provides electric energy for the first heating arrangements；Or, initially opening of described device for rapidly starting Energy source is manual generator, and the electric energy sent is stored in battery by manual generator；
Described catalyst include the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, The oxide of Zn, rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for The 0.6%～1.8% of catalyst gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, the oxidation of Cu Thing accounts for the 6%～12% of catalyst gross mass, and the oxide of Fe accounts for the 3%～8% of catalyst gross mass, the oxygen of Zn Compound accounts for the 8%～20% of catalyst gross mass, and rare-earth oxide accounts for the 6%～40% of catalyst gross mass, Remaining is transition metal oxide；
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: 3-17 part The Al of ZrO, 55-80 part of the ZnO of CuO, 3-18 part, 0.5-3 part2O3, the CeO of 1-3 part2, 1-3 The La of part2O3。
Water hydrogen car the most according to claim 2, it is characterised in that:
Described automobile includes that methanol Preparation equipment, methanol Preparation equipment include: hydrogen conveyor, second Conveyer device, synthesis reactor；Described second conveyer device is carbon dioxide conveyer device or/and an oxidation Carbon conveyer device；Described hydrogen conveyor, the second conveyer device are connected with synthesis reactor respectively；Institute State hydrogen and carbon dioxide or reaction of carbon monoxide in synthesis reactor, generate methanol and water.
Water hydrogen car the most according to claim 7, it is characterised in that:
Described methanol Preparation equipment includes: nitrogen gas conveying device, hydrogen conveyor, carbon dioxide carry Device, the first blender, the second gaseous mixture, micro fixed-bed reactor, counterbalance valve, synthesis reactor, Alcohol-water separation device, chromatograph, methanol solution gasifying device, methanol collect container, main control module；Described dioxy Change carbon conveyer device and connect the side of described storage container collection carbon dioxide；The methanol conveying prepared To the methanol-water mixed liquor side storing container；
Described nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline sets There are the first stop valve, the first mass flowmenter；
Described carbon dioxide conveyer device includes carbon dioxide storage container, the second transfer pipeline, and second is defeated Pipeline is sent to be provided with the second stop valve, the second mass flowmenter；
Described hydrogen conveyor includes hydrogen storage vessel, the 3rd transfer pipeline, the 4th transfer pipeline, 3rd transfer pipeline is provided with the 3rd stop valve, the 3rd mass flowmenter, and the 4th transfer pipeline is provided with the 4th section Only valve, the 4th mass flowmenter；
Described hydrogen storage vessel is connected by the 3rd transfer pipeline and the first transfer pipeline, the 3rd conveying pipe Road and the first transfer pipeline are intersected in one first three-way valve；
Described hydrogen storage vessel is connected by the 4th transfer pipeline and the second transfer pipeline, the 4th conveying pipe Road and the second transfer pipeline are intersected in one first cross valve；
Described first three-way valve and the first blender connect, the other end of the first blender and the second three-way valve Connect；Second three-way valve connects micro fixed-bed reactor, the 5th transfer pipeline by the 5th transfer pipeline It is provided with the 5th mass flowmenter, pressure gage；
The other end of described micro fixed-bed reactor connects the 4th three-way valve, and the 4th three-way valve is also connected with the back of the body Pressure valve, the other end of counterbalance valve connects one second cross valve；
Described first cross valve and the second blender connect, the other end of the second blender and the 3rd three-way valve Connect；Alcohol-water separation device, the second three-way valve connect the 3rd three-way valve, and alcohol-water separation device, methanol solution are disguised Put, chromatograph connects the second cross valve；Methanol solution gasifying device is collected container with methanol and is connected；
Described master control module controls all parts action, first controls high pure nitrogen and high-purity hydrogen with setting Ratio is emptied by beds after the first blender mixing, switches after catalyst reduction completes Gas is the gaseous mixture of hydrogen and carbon dioxide, and gas is boosted to necessarily through counterbalance valve by beds Pressure isolates Methanol product and water through alcohol-water separation device again, and unreacted gas is after unstripped gas supplements Continue through reactor cycles reaction.
Water hydrogen car the most according to claim 2, it is characterised in that:
Described automobile also includes the second genemotor, energy storage units, kinetic energy converting unit, kinetic energy Converting unit, energy storage units, the second genemotor are sequentially connected with；Described kinetic energy converting unit will The energy of automobile brake is converted to electric energy and is stored in energy storage units, is the second genemotor Electric energy is provided；
Described second genemotor is also connected with hydrogen gas generating system, hydrogen gas generating system be second electronic Electromotor provides the energy；
Described automobile also includes that road environment induction module, allocation database, hydrogen distribute module；Hydrogen Distribution module is connected with road environment induction module, allocation database respectively, senses mould according to road environment Data in the data of block sensing and allocation database are the hydrogen that the distribution of each genemotor is corresponding；
Described road environment induction module is in order to sense road congestion information, ground flat degree information；Road Congestion information is according to automobile real-time speed, acceleration, deceleration frequency, and determines down time；Ground is put down Whole degree information determines according to the obliquity sensor arranged on automobile chassis；
Described allocation database stores some tables of data, tables of data records each road congestion information, Ground flat degree information corresponding for genemotor, second genemotor distribution hydrogen data；Electricity In dynamic electromotor, the second genemotor, one is used for driving trailing wheel or/and front-wheel, and another is used for driving Front-wheel is or/and trailing wheel.
10. the air conditioning system of a water hydrogen car, it is characterised in that described water hydrogen car includes: first Alcohol hydrogen generating system, hydrogen gas generating system, hydrogen production by methanol system is connected with hydrogen gas generating system；
Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen closes by being coated with palladium-silver The membrane separation device of gold obtains highly purified hydrogen, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system；First Alcohol hydrogen generating system includes hydrogen producer；
Described air conditioning system includes heat-exchange device；The high-temperature gas that described hydrogen producer is discharged is as vapour The thermal source of car air conditioning system heating installation, is Vehicle heating by heat-exchange device；
Described heat-exchange device includes some heat exchanging pipes, is the stream of vehicle air conditioner in heat exchanging pipe Ventilation body, for the high-temperature gas of hydrogen producer discharge or the height after being heated by high-temperature gas outside heat exchanging pipe Geothermal liquid；Or, it is the circulated gases of vehicle air conditioning outside heat exchanging pipe, is hydrogen producer in heat exchanging pipe The high-temperature gas discharged or the high-temp liquid after being heated by high-temperature gas.
CN201610438233.9A 2016-06-17 2016-06-17 Water hydrogen power automobile and air conditioner system thereof Pending CN106004494A (en)

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