CN106012585A - Duplex printing method for chinlon 56 fiber/cotton blended fabric - Google Patents

Duplex printing method for chinlon 56 fiber/cotton blended fabric Download PDF

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Publication number
CN106012585A
CN106012585A CN201610437610.7A CN201610437610A CN106012585A CN 106012585 A CN106012585 A CN 106012585A CN 201610437610 A CN201610437610 A CN 201610437610A CN 106012585 A CN106012585 A CN 106012585A
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China
Prior art keywords
chinlon
duplex pringing
fiber
fabric
duplex
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CN201610437610.7A
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CN106012585B (en
Inventor
郝新敏
鞠景堂
赵鹏程
严欣宁
倪成涛
仇凯
陈晓
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Liaoning Sunichem Co Ltd
Quartermaster Research Institute of General Logistics Department of CPLA
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Liaoning Sunichem Co Ltd
Quartermaster Research Institute of General Logistics Department of CPLA
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Priority to CN201610437610.7A priority Critical patent/CN106012585B/en
Publication of CN106012585A publication Critical patent/CN106012585A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/22General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8219Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • D06P5/04After-treatment with organic compounds

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a duplex printing method for a chinlon 56 fiber/cotton blended fabric. The method comprises the following step that vat dyes are adopted for carrying out duplex printing on the chinlon 56 fiber/cotton blended fabric, wherein the chinlon 56 fiber/cotton blended fabric is the blended fabric of chinlon 56 fiber and cotton fiber. The duplex printing method for the chinlon 56 fiber/cotton blended fabric has the advantages that duplex printing for the chinlon 56 fiber and cotton blended fabric is achieved through the method, and the blended fabric subjected to duplex printing is made into ready-made clothes of which the front side and the reverse side can be worn alternately, and has higher practicability when used as camouflage clothing and outdoor garment fabric.

Description

A kind of duplex pringing method of chinlon 56 fibers/cotton blended spinning face fabric
Technical field
The present invention relates to a kind of duplex pringing method of chinlon 56 fibers/cotton blended spinning face fabric.
Background technology
Nylon fibre is the first synthetic fibers occurred in the world, and the kind that chinlon is typically commonly used has: nylon-6 for poly-own Lactams, nylon-66 is that hexamethylene diamine is polymerized with adipic acid, and chinlon 56 is a kind of novel Fypro, with Chinlon 66 uses petroleum different, and the raw material that it uses is biological raw material, by biological engineering method from each kind of starch Prepare pentanediamine with fermentation in stalk cellulose, owing to batch is big, low cost, therefore can substitute for hexamethylene diamine.Bio-based Fiber has that green, environmental friendliness, raw material be renewable and the good characteristic such as biodegradation, contributes to solving current complete Serious resource that ball socio-economic development is faced and energy shortage, and the problem such as environmental pollution.
Chinlon 56 has many excellent characteristics, and intensity is close to chinlon 66, and higher than terylene, density is less than terylene;Inhale Moist height, antistatic behaviour is good;Pliability is close to Pilus Caprae seu Ovis;Vitrification point is less than chinlon 66, chinlon 56 vitrification temperature Degree is 46 DEG C, far below terylene, it is ensured that lower temperature resistance under cold conditions;Softness, wearability is good.
Various fibers, whether natural fiber or staple fibre and synthetic fibers are all respectively arranged with advantage.General natural fibre Dimension such as Cotton Gossypii, Pilus Caprae seu Ovis hygroscopicity are relatively good, and comfortable and easy to wear, the general wearability of synthetic fibers is good, and strength is high, but inhale Moist difference, breathability is bad.Various fibers, natural, artificial, synthesis carry out different proportion blending, just Can fully use the feature of various fiber, learn from other's strong points to offset one's weaknesses, the wearability of reinforced fabric.Brocade/cotton, chinlon/viscose glue Blend fabric good hand touch, strength is high, proportion is little, high abrasion, resistance to mould, moth-resistant, because it is comfortable and easy to wear, good permeability, Increasingly welcome by consumer, be widely used in industry, civilian and national defence.
Chinlon 56 fiber and cellulosic fibre blend fabric duplex pringing, can change with positive and negative after making ready-made clothes and wear, Especially for army's camouflage color more practicality, camouflage color is generally divided into forest land camouflage color, desert camouflage, city camouflage color, sea Ocean camouflage color.Corresponding camouflage color can be selected to wear along with environmental change.Chinlon 56 fiber and cellulosic fibre blend face Material duplex pringing method has no the disclosure of correlation technique.
Summary of the invention
It is an object of the invention to provide a kind of duplex pringing method of chinlon 56 fibers/cotton blended spinning face fabric, the present invention can be real The now duplex pringing to chinlon 56 fiber Yu the blended yarn weaved fabric of cotton fiber different proportion.
The duplex pringing method of chinlon 56 fibers/cotton blended spinning face fabric that the present invention provides, comprises the steps:
Use reducing dye that chinlon 56 fibers/cotton blended spinning face fabric is carried out duplex pringing;
Described chinlon 56 fibers/cotton blended spinning face fabric is the blended yarn weaved fabric of chinlon 56 fiber and cotton fiber.
In above-mentioned duplex pringing method, described duplex pringing comprises the steps:
(1) preparation printing paste, the composition of the described printing paste of every 100 mass parts is as follows:
Thickening agent 5 parts, and the water of surplus;
(2) adding reducing dye in described printing paste, after stirring, the front to described blended yarn weaved fabric is justified Wire mark flower;Be padded in reducing solution after drying, more successively through evaporating, wash, aoxidize, soaping, water-proofing treatment and Sizing i.e. realizes the front stamp to described blended yarn weaved fabric;
(3) step repeat ROTARY SCREAM PRINTING in step (2), evaporating, wash, aoxidize and soaping is to described blending face The reverse side of material carries out stamp, and the sizing of last drying i.e. realizes the duplex pringing to described blended yarn weaved fabric.
In above-mentioned duplex pringing method, described thickening agent can be sodium alginate or many carboxyls high molecular polymer, such as: FS-80E is a kind of many carboxyls high molecular polymer thickening agent, its have good level-dyeing property, embrace aqueous good, do not carry on the back the spy oozed Point, makes the pattern contour of printing have the features such as desizing is easy, soft more finely, simultaneously, can be permanent by Liaoning Star Fine Chemical Co., Ltd provides.
In above-mentioned duplex pringing method, the addition of described reducing dye can be the 2%~8% of described printing paste quality, Concretely 4%.
In above-mentioned duplex pringing method, in step (2) and (3), the temperature of described drying can be 130~135 DEG C, The time of described drying can be 2~3 minutes, specifically can dry 2 minutes under conditions of 130 DEG C.
In above-mentioned duplex pringing method, in step (2) (3), described in the temperature evaporated can be 125 DEG C~165 DEG C, The described time evaporated can be 10~40s.
In above-mentioned duplex pringing method, in step (2), organic fluorine waterproof agent that described water-proofing treatment is used or Waterproofing agent of organosilicon, such as organic fluoro water proofing agent TG-581, can be fluorinated Gong Zhong Co., Ltd by great Jin provides, described anti- Water step can prevent from carrying on the back, during reverse side stamp, the generation oozed, and its consumption is 10~40g/l, and pick-up is 50~80%.
In above-mentioned duplex pringing method, in step (2), the temperature of described sizing can be 150~170 DEG C, such as 165 DEG C;
In step (3), the temperature of described drying and shaping can be 160 DEG C~180 DEG C, such as 170 DEG C.
In above-mentioned duplex pringing method, described in described chinlon 56 fibers/cotton blended spinning face fabric, the blending ratio of chinlon 56 can It is 15~85%, concretely 50%.
The duplex pringing method of chinlon 56 fibers/cotton blended spinning face fabric that the present invention provides, has the advantage that
By the duplex pringing method of the present invention, it is achieved that chinlon 56 fiber and the duplex pringing of cotton blended spinning face fabric, will The blended yarn weaved fabric of duplex pringing can change with positive and negative after making ready-made clothes and dress, especially for camouflage color and outdoor wear face Expect more practicality.
Detailed description of the invention
Experimental technique used in following embodiment if no special instructions, is conventional method.
Material used in following embodiment, reagent etc., if no special instructions, the most commercially obtain.
Thickening agent FS-80 used in following embodiment is purchased from Liaoning Sunichem Co., Ltd..
Reducing dye used in following embodiment can be the black FBL of wheat Shillong that Hensel Man produces.
Embodiment 1, chinlon 56 fiber and cotton fiber blending reducing dye duplex pringing
Technological process is as follows:
Brocade is cotton 50/50,29.5/29.5,472/276 × 160 fabric turn over a margin to seam → and singe → move back and boil drift → mercerising → sizing → front stamp → dry → roll reducing solution → evaporate → wash oxidation is soaped drying → upper waterproof → sizing → reverse side stamp → dry → roll reducing solution → evaporate → wash oxidation and soap drying → drying and shaping → finished product.
(1) seam is turned over
Chinlon 56 fiber and cotton fiber carry out blending by the quality proportioning of 50/50 and obtain blended yarn weaved fabric, it is necessary to positive and negative unanimously, Margin to seam must put down, directly, jail, neat.
(2 singe
Gassing frame speed 110m/min, positive and negative twice.
(3) move back and boil drift
First crawler belt: temperature is 102 DEG C, and the time is 60 minutes, rolling alkali concn is 21g/L, open washing 1#, 2# bath temperature Degree is 80 DEG C, and 3# bath temperature degree is 70 DEG C, and 4# groove is that cold water is washed.
Second crawler belt: hydrogen peroxide 7g/L, the pH=10.5 steam temperature of 30% is 102 DEG C, and the time is 30 minutes.
(4) mercerising
Using half mercerising, speed is 40m/min, and NaOH concentration is 200g/L, and light alkali concn controls at 30g/L, pH=7.
(5) sizing
Speed is 40m/min, and temperature is 180 DEG C.
(6) front stamp
Thickening agent FS-80 and water accomplish fluently slurry, and both mass ratioes are 5:95, add through ground Hensel Man The reducing dye (the 4% of printing paste quality) produced, stirs, for circular screen printer stamp.
(7) dry
Drying temperature is 130 DEG C, and drying time is 2min.
(8) reducing solution is rolled
38Be ° of NaOH is 120g/L, and 85% sodium hydrosulfite is 150g/L, and pick-up is 70%.
(9) evaporate
Speed: 48m/min;Drying room temperature: 150 DEG C;Evaporate the time: 6min;Ring is long: 85%;Link nozzle pressure Power: 2bar;Circulating fan: 100%.
(10) washing oxidation is soaped drying
Tank 1~3#: temperature room temperature, roll compacting 0.2Mpa, spray is opened;
Tank 4~5#: temperature room temperature, roll compacting 0.2Mpa, spray not open;
Hydrogen peroxide: 4kg+2kg/10min;
Tank 6~7#: temperature 90~95 DEG C, roll compacting 0.2Mpa, spray is opened little;
Soaping agent BP:4kg+2kg/10min;
Tank 8~10#: temperature 90 DEG C, roll compacting 0.2Mpa, spray is opened.
(11) upper waterproof sizing
Waterproofing agent TG-581 (great Jin is fluorinated Gong Zhong Co., Ltd) 30g/L, setting temperature is 170 DEG C.
(12) this blended yarn weaved fabric reverse side stamp, dry, evaporate, technique is soaped in water oxidation, same to above-mentioned steps (5), (6), (7), (8) and (9).
(13) drying and shaping
Setting temperature 175 DEG C, speed is duplex pringing every color fastness index of 35m/min the present embodiment blended yarn weaved fabric As shown in table 1.
By data in table 1 it can be seen that after duplex pringing every fastness reach requirement.
Table 1 nylon fibre and duplex pringing method every color fastness index of cellulosic fibre blend fabric
Name of an article project Embodiment 1
Dry friction color fastness 4.5
Wet friction color fastness 4.5
Color fastness to water 5
Color fastness to chlorine 5
Color fastness to sea water 5
Alkaline-resisting PERSPIRATION COLOR FASTNESS 4.5
Colour fasteness to sunlight 7
Fastness to soaping 4.5
In table 1, the assay method of each index is as follows:
1, soaping fastness is tested by GB GB/T3921.4-1997.
2, dry and wet crock fastness presses GB/3920 execution.
3, resistance to (alkali) PERSPIRATION COLOR FASTNESS presses ISO105-E04:2008 execution.
4, chlorine-resistant drift color fastness presses ISO105E03:2010 execution.
5, color fastness to sea water presses AATCC106-2002 execution.
6, color fastness to water presses JIS (37 ± 2) DEG C × 4h.
7, colour fasteness to sunlight presses ISO105B02-1994 execution.

Claims (9)

1. a duplex pringing method for chinlon 56 fibers/blended yarn weaved fabric, comprises the steps:
Use reducing dye that chinlon 56 fibers/cotton blended spinning face fabric is carried out duplex pringing;
Described chinlon 56 fibers/cotton blended spinning face fabric is the blended yarn weaved fabric of chinlon 56 fiber and cotton fiber.
Duplex pringing method the most according to claim 1, it is characterised in that: described duplex pringing includes as follows Step:
(1) preparation printing paste, the composition of the described printing paste of every 100 mass parts is as follows:
Thickening agent 5 parts, and the water of surplus;
(2) adding reducing dye in described printing paste, after stirring, the front to described blended yarn weaved fabric is justified Wire mark flower;Be padded in reducing solution after drying, more successively through evaporating, wash, aoxidize, soaping, water-proofing treatment and Sizing i.e. realizes the front stamp to described blended yarn weaved fabric;
(3) step repeat ROTARY SCREAM PRINTING in step (2), evaporating, wash, aoxidize and soaping is to described blending face The reverse side of material carries out stamp, and the sizing of last drying i.e. realizes the duplex pringing to described blended yarn weaved fabric.
Duplex pringing method the most according to claim 1 and 2, it is characterised in that: described thickening agent is Sargassum Acid sodium or many carboxyls high molecular polymer.
4. according to the duplex pringing method according to any one of claim 1-3, it is characterised in that: described reducing dye Addition is described printing paste quality 2%~8%.
5. according to the duplex pringing method according to any one of claim 1-4, it is characterised in that: step (2) and (3), in, the temperature of described drying is 130 DEG C~135 DEG C, and the time of described drying is 2~3 minutes.
6. according to the duplex pringing method according to any one of claim 1-5, it is characterised in that: step (2) (3) In, described in the temperature evaporated be 125 DEG C~165 DEG C, described in time of evaporating be 10~40s.
7. according to the duplex pringing method according to any one of claim 1-6, it is characterised in that: in step (2), The waterproofing agent that described water-proofing treatment is used is organic fluorine waterproof agent or waterproofing agent of organosilicon.
8. according to the duplex pringing method according to any one of claim 1-7, it is characterised in that: in step (2), The temperature of described sizing is 150 DEG C~170 DEG C;
The temperature of described drying and shaping is 160 DEG C~180 DEG C.
9. according to the duplex pringing method according to any one of claim 1-8, it is characterised in that: described chinlon 56 The blending ratio of chinlon 56 described in fiber/cotton blended spinning face fabric is 15~85%.
CN201610437610.7A 2016-06-17 2016-06-17 A kind of duplex pringing method of 56 fibers of polyamide fibre/cotton blended spinning face fabric Active CN106012585B (en)

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CN106968114A (en) * 2017-03-16 2017-07-21 江苏工程职业技术学院 A kind of printing method of cotton graphene polyamide fibre interwoven fabric
WO2018197925A1 (en) * 2017-04-26 2018-11-01 Lucia Russo A method for double-sided printing on tissue
CN109137211A (en) * 2018-07-13 2019-01-04 浙江盛发纺织印染有限公司 A kind of duplex pringing camouflage inflaming retarding fabric
CN109554939A (en) * 2017-09-27 2019-04-02 上海凯赛生物技术研发中心有限公司 A kind of 56 fiber of polyamide or the indigo dyeing method of 56/ cotton blended spinning face fabric of polyamide and products thereof
CN111058316A (en) * 2019-12-31 2020-04-24 军事科学院系统工程研究院军需工程技术研究所 Alkaline pad dyeing method for chinlon 56 and cellulose fiber blended fabric
CN111172785A (en) * 2020-02-04 2020-05-19 军事科学院系统工程研究院军需工程技术研究所 Alkaline printing method for nylon 56 and cellulose fiber blended fabric
CN111235911A (en) * 2020-02-07 2020-06-05 军事科学院系统工程研究院军需工程技术研究所 Alkaline rapid printing method for chinlon 56 fiber and fabric

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106968114A (en) * 2017-03-16 2017-07-21 江苏工程职业技术学院 A kind of printing method of cotton graphene polyamide fibre interwoven fabric
WO2018197925A1 (en) * 2017-04-26 2018-11-01 Lucia Russo A method for double-sided printing on tissue
CN109554939A (en) * 2017-09-27 2019-04-02 上海凯赛生物技术研发中心有限公司 A kind of 56 fiber of polyamide or the indigo dyeing method of 56/ cotton blended spinning face fabric of polyamide and products thereof
CN109554939B (en) * 2017-09-27 2021-03-16 上海凯赛生物技术股份有限公司 Indigo dyeing method of polyamide 56 fiber or polyamide 56/cotton blended fabric and product thereof
CN109137211A (en) * 2018-07-13 2019-01-04 浙江盛发纺织印染有限公司 A kind of duplex pringing camouflage inflaming retarding fabric
CN111058316A (en) * 2019-12-31 2020-04-24 军事科学院系统工程研究院军需工程技术研究所 Alkaline pad dyeing method for chinlon 56 and cellulose fiber blended fabric
CN111172785A (en) * 2020-02-04 2020-05-19 军事科学院系统工程研究院军需工程技术研究所 Alkaline printing method for nylon 56 and cellulose fiber blended fabric
CN111235911A (en) * 2020-02-07 2020-06-05 军事科学院系统工程研究院军需工程技术研究所 Alkaline rapid printing method for chinlon 56 fiber and fabric

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