CN106011520A - Dry copper-base powder metallurgy friction material used for clutch and preparing method of dry copper-base powder metallurgy friction material - Google Patents

Dry copper-base powder metallurgy friction material used for clutch and preparing method of dry copper-base powder metallurgy friction material Download PDF

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Publication number
CN106011520A
CN106011520A CN201610518088.5A CN201610518088A CN106011520A CN 106011520 A CN106011520 A CN 106011520A CN 201610518088 A CN201610518088 A CN 201610518088A CN 106011520 A CN106011520 A CN 106011520A
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China
Prior art keywords
friction material
powder
powder metallurgy
copper
clutch
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CN201610518088.5A
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Chinese (zh)
Inventor
李专
张国洪
韩建国
许成法
戴国文
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Hangzhou Advance Gearbox Group Co Ltd
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Hangzhou Advance Gearbox Group Co Ltd
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Priority to CN201610518088.5A priority Critical patent/CN106011520A/en
Publication of CN106011520A publication Critical patent/CN106011520A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • B22F1/0003
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/06Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
    • B22F7/08Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools with one or more parts not made from powder
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/02Alloys containing less than 50% by weight of each constituent containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/04Alloys containing less than 50% by weight of each constituent containing tin or lead
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0005Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with at least one oxide and at least one of carbides, nitrides, borides or silicides as the main non-metallic constituents
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0084Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ carbon or graphite as the main non-metallic constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention discloses a dry copper-base powder metallurgy friction material used for a clutch and a preparing method of the dry copper-base powder metallurgy friction material. Cu and Fe are adopted as matrix components of the friction material, graphite is adopted as a lubrication component of the friction material, SiC and ZrSiO4 are adopted as friction components, and Ni and Sn alloy elements are added for strengthening a matrix. The powder metallurgy material includes, by weight percent, 45%-65% of copper powder, 5%-18% of iron powder, 5%-12% of graphite powder, 2%-8% of silicon carbide powder, 10%-20% of zircon sand powder, 0%-6% of nickel and 4%-10% of tin. The preparing method includes the steps that the above components are evenly mixed in a V-shaped material mixing machine and pressed into a blank, the blank is fixed to a supporting steel back, and the needed copper-base powder metallurgy friction material is obtained through high-temperature sintering. The copper-base powder metallurgy friction material has the beneficial effects that good friction stability and heat resistance are achieved, noise in the use process is low, the material is suitable for overall environments, and the performance of the material meets the requirement of dry clutch surfaces of tractors.

Description

A kind of clutch dry type copper based powder metallurgy friction material and preparation method thereof
Technical field
The present invention relates to a kind of clutch dry type copper based powder metallurgy friction material and preparation method thereof, especially one is used for drawing High-performance dry type copper based powder metallurgy friction material of machine clutch and preparation method thereof, belongs to friction material and technology of preparing neck thereof Territory.
Background technology
Tractor is irreplaceable dynamic power machine during agricultural modernization produces, and has and have been widely used in agricultural production.Tractor The main function of clutch is the power that escape engine transmits, so that change speed gear box is put into gear smoothly or shifts gears, compliantly engages power, Ensureing vehicle gentle start, during over loading, slipping of clutch is to protect part from damage.
According to the mode of transmission power, clutch is divided into friction-type and hydraulic type two kinds, and current friction-type is widely used.Until today, In the friction material of tractor clutch, majority or the material based on asbestos are worked out, and the dough sheet of this establishment is by stone Cotton fiber and copper wire or zinc filament winding are made asbestos cotton rope and are made.Asbestos fibre for the coefficient of friction of material, abrasion resistance, thermostability, Each performances such as intensity, modulus and hardness all serve certain improving effect, and raw material sources is extensive, cheap.But also deposit In some obvious shortcomings, first it is that the heat stability of asbestos is not good enough, thus results in the heat resistanceheat resistant of its clutch friction material strengthened Degenerative is bad, in general, starts substantially decline at 250 DEG C, is likely to occur inefficacy at 350 DEG C;Next to that it is to human body Injury, asbestos fibre is likely to result in the disease such as asbestosis, pulmonary carcinoma by sucking pulmonary in a large number.Powder metallurgy friction material is as clutch The friction sheets of device clutch plate, abroad from the 1950's, begins to use in engineering machinery and cargo vehicle.Due to The coefficient of friction of powder metallurgy friction sheets is higher than resin based friction plate, and the clutch of dress powder metallurgy friction sheets is relative to adopting For clutch with resin based friction plate, bigger moment of friction, the i.e. torque of clutch can be provided under same clamping load Capacity is big compared with biochip, or under identical torque capacity, clamping load used can be less, makes clutch engage softer, separating force Less.
In use, there is heat resistance on the low side in tractor clutch powder metallurgy friction sheets of the prior art, abrasion is relatively Big problem so that slipping of clutch and shaking, and the noise phenomenon during clutch highlights.
In order to solve above-mentioned deficiency, it is necessary to use principle of optimality and computer technology to carry out the optimization design of material, thus obtain The composition proportion of best performance.At present, copper base friction material and iron-based friction material remain the two big main of powder metallurgy friction material Series.Generally use copper base friction material under conditions of lighter load, its can be used for dry friction or have hydrodynamic lubrication working condition in, Than iron-based powder metallurgy friction material, there is more preferable combination property, and there is the braking effect of excellence;Heavy load or overweight load Under the conditions of frequently with iron-based friction material, its low cost of manufacture, typically under dry friction use.
Summary of the invention
It is an object of the invention to the deficiency overcoming prior art to exist, and it is on the low side to provide one can effectively solve heat resistance, abrasion Bigger problem, during using, noise is few simultaneously, and the change of temperature and weather is little on frictional behaviour impact, free from environmental pollution from Clutch dry type copper based powder metallurgy friction material and preparation method thereof.
It is an object of the invention to complete by following technical solution, a kind of clutch dry type copper based powder metallurgy friction material, Described friction material uses Cu, Fe to be matrix constituent element, and graphite is lubricant component, and SiC, ZrSiO4 are friction component, adds Ni, Sn alloying element strengthening matrix;Each composition of described powdered metallurgical material according to following percentage by weight is: copper powder 45-65%, iron powder 5-18%, graphite powder 5-12%, carborundum powder 2-8%, zircon flour 10-20%, nickel 0-6%, stannum 4-10%.
As preferably: each composition of described friction material according to following percentage by weight is: copper powder 56%, iron powder 10%, Graphite powder 8%, carborundum powder 4%, zircon flour 10%, nickel 4%, stannum 8%.
The preparation method of a kind of clutch dry type copper based powder metallurgy friction material as above, described preparation method is: will Above-mentioned composition, at V-arrangement batch mixer mix homogeneously, is pressed into base, this pressed compact is fixed on supporting steel back, passes through high temperature sintering Obtain required copper based powder metallurgy friction material, specifically:
By above-mentioned constituent at V-arrangement batch mixer mixing 2-4h, and compacting obtains pressed compact under 500-600MPa pressure, and pressed compact is close Degree 4.5-5.5g/cm3, this pressed compact is fixed on supporting steel back, in 840-960 DEG C of sintering in clock hood type furnace, pressure is 1.0-3.0 MPa, sinters under hydrogen shield, is incubated 2-4 h, and insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, obtain required powder Powder metallurgy material.
As preferably: described preparation method is: by above-mentioned constituent at V-arrangement batch mixer mixing 3h, and at 550MPa pressure Lower compacting obtains pressed compact, green density 5.0g/cm3, this pressed compact is fixed on supporting steel back, in 900 DEG C of sintering in clock hood type furnace, Pressure is 2.0MPa, sinters under hydrogen shield, is incubated 3h, and insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, obtain required Powdered metallurgical material.
The present invention has good friction stability and thermostability, and during use, noise is few, and full ambient engine is suitable for, and performance meets dilatory The features such as the requirement of machine dry clutch dough sheet.
Accompanying drawing explanation
Fig. 1 is tractor clutch dry type copper-base powder metallurgy friction sheets figure prepared by the present invention;
Fig. 2 is the metallography microscope shape appearance figure of copper based powder metallurgy friction material prepared by the present invention.
Detailed description of the invention
The invention will be further described with embodiment below in conjunction with the accompanying drawings.A kind of clutch dry type copper-base powder metallurgy friction material Material, described friction material uses Cu, Fe to be matrix constituent element, and graphite is lubricant component, and SiC, ZrSiO4 are friction component, add Enter Ni, Sn alloying element strengthening matrix;Each composition of described powdered metallurgical material according to following percentage by weight is: copper powder 45-65%, iron powder 5-18%, graphite powder 5-12%, carborundum powder 2-8%, zircon flour 10-20%, nickel 0-6%, stannum 4-10%.
Preferred embodiment is: each composition of described friction material according to following percentage by weight is: copper powder 56%, iron powder 10%, graphite powder 8%, carborundum powder 4%, zircon flour 10%, nickel 4%, stannum 8%.
The preparation method of a kind of clutch dry type copper based powder metallurgy friction material as above, described preparation method is: will Above-mentioned composition, at V-arrangement batch mixer mix homogeneously, is pressed into base, this pressed compact is fixed on supporting steel back, passes through high temperature sintering Obtain required copper based powder metallurgy friction material, specifically:
By above-mentioned constituent at V-arrangement batch mixer mixing 2-4h, and compacting obtains pressed compact under 500-600MPa pressure, and pressed compact is close Degree 4.5-5.5g/cm3, this pressed compact is fixed on supporting steel back, in 840-960 DEG C of sintering in clock hood type furnace, pressure is 1.0-3.0 MPa, sinters under hydrogen shield, is incubated 2-4 h, and insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, obtain required powder Powder metallurgy material.
As preferred embodiment it is: described preparation method is: by above-mentioned constituent at V-arrangement batch mixer mixing 3h, and Under 550MPa pressure, compacting obtains pressed compact, green density 5.0g/cm3, this pressed compact is fixed on supporting steel back, in clock hood type furnace in 900 DEG C of sintering, pressure is 2.0MPa, sinters under hydrogen shield, is incubated 3h, and insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, Obtain required powdered metallurgical material.
Embodiment 1:
Each component is prepared: include copper powder 60% according to weight ratio, iron powder 6%, graphite powder 8%, carborundum powder 4%, zircon flour 14%, Nickel 0%, stannum 8%;By above-mentioned constituent at V-arrangement batch mixer mixing 2h, and compacting obtains pressed compact, pressed compact under 600MPa pressure Density 5.0g/cm3, this pressed compact is fixed on supporting steel back, in 840 DEG C of sintering in clock hood type furnace, pressure is 2.0 MPa, hydrogen Sintering under gas shielded, be incubated 3.5h, insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, obtain required Cu-base powder smelting Gold friction material.
It is on MM-3000 type friction wear testing machine, carry out friction test, copper-base powder metallurgy friction with steel alloy mating plate Test ring size: external diameter is 75mm, internal diameter is 53 mm, and thickness is 12 mm.Before test, friction test ring surface break-in is surveyed after 80% Fixed 20 times, end product is averaged.Test parameter is: brake percentage pressure 0.60Mpa, rotator inertia 0.35 kg m2, sample face Long-pending 20.0cm2, friction linear velocity is respectively 6500r/min and 8000r/min.Result of the test is as shown in table 1.
The MM-3000 friction and wear behavior of table 1 copper based powder metallurgy friction material
Embodiment 2:
Each component is prepared: include copper powder 56% according to weight ratio, iron powder 10%, graphite powder 8%, carborundum powder 4%, zircon flour 10%, Nickel 4%, stannum 8%;By above-mentioned constituent at V-arrangement batch mixer mix homogeneously, and compacting obtains pressed compact under 580MPa pressure, pressure Base density 5.1g/cm3, this pressed compact is fixed on supporting steel back, in 900 DEG C of sintering in clock hood type furnace, pressure is 3.0 MPa, Sintering under hydrogen shield, be incubated 4 h, insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, obtain required Cu-base powder smelting Gold friction material.
With rotating speed 400~600r/min on DM-S constant speed formula frictional testing machine, pressure 0.49MPa, by GB/T5764 vapour Car clutch surface regulation test method carries out friction and wear behavior detection, and experimental result is as shown in table 1.Testing result shows: copper The average friction coefficient of based powder metallurgy friction material is 0.50, and wear rate is only 0.12 × 10-7cm3·J-1, noise is few.
The DM-S constant speed friction and wear behavior of table 2 copper based powder metallurgy friction material
Embodiment 3:
Each component is prepared: include copper powder 45%, iron powder 18%, graphite powder 12%, carborundum powder 4%, zircon flour according to weight ratio 15%, nickel 2%, stannum 4%;By above-mentioned constituent at V-arrangement batch mixer mix homogeneously, and pressed under 600MPa pressure Base, green density 5.2g/cm3, this pressed compact is fixed on supporting steel back, in 960 DEG C of sintering in clock hood type furnace, pressure is 1.0 MPa, Sintering under hydrogen shield, be incubated 3 h, insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, obtain required Cu-base powder smelting Gold friction material.The hardness of the copper based powder metallurgy material prepared according to above-mentioned technique is 60HB, and comprcssive strength is 203MPa.
Embodiment 4:
Each component is prepared: include copper powder 62% according to weight ratio, iron powder 5%, graphite powder 5%, carborundum powder 8%, zircon flour 10%, Nickel 0%, stannum 10%;By above-mentioned constituent at V-arrangement batch mixer mix homogeneously, and compacting obtains pressed compact under 500MPa pressure, Green density 4.9g/cm3, this pressed compact is fixed on supporting steel back, in 880 DEG C of sintering in clock hood type furnace, pressure is 1.5 MPa, Sintering under hydrogen shield, be incubated 2 h, insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, obtain required Cu-base powder smelting Gold friction material.The hardness of the copper based powder metallurgy material prepared according to above-mentioned technique is 50HB, and comprcssive strength is 168MPa.
As can be seen here, the hardness of the copper based powder metallurgy friction material obtained by this preparation method up to 60HB, comprcssive strength up to 203MPa, the test result surface on MM-3000 type friction wear testing machine and DM-S constant speed formula frictional testing machine, have excellent Good friction and wear behavior and friction stability, heat resistance is good, and noise is few, can meet tractor dry clutch rubbing surface The technology requirement of sheet.
In above-described embodiment, the group element ratio of copper based powder metallurgy friction material, pressing pressure and sintering temperature etc. are only tools of the present invention Body embodiment, but protection scope of the present invention is not limited thereto.Any those of ordinary skill in the art the invention discloses In technical scope, the change that can readily occur in or replacement, all should contain within protection scope of the present invention.

Claims (4)

1. a clutch dry type copper based powder metallurgy friction material, it is characterised in that described friction material uses Cu, Fe to be matrix constituent element, and graphite is lubricant component, and SiC, ZrSiO4 are friction component, adds Ni, Sn alloying element strengthening matrix;Each composition of described powdered metallurgical material according to following percentage by weight is: copper powder 45-65%, iron powder 5-18%, graphite powder 5-12%, carborundum powder 2-8%, zircon flour 10-20%, nickel 0-6%, stannum 4-10%.
Clutch dry type copper based powder metallurgy friction material the most according to claim 1, it is characterised in that each composition of described friction material according to following percentage by weight is: copper powder 56%, iron powder 10%, graphite powder 8%, carborundum powder 4%, zircon flour 10%, nickel 4%, stannum 8%.
3. the preparation method of a clutch dry type copper based powder metallurgy friction material as claimed in claim 1 or 2, it is characterized in that described preparation method is: by above-mentioned composition at V-arrangement batch mixer mix homogeneously, it is pressed into base, this pressed compact is fixed on supporting steel back, required copper based powder metallurgy friction material is obtained, specifically by high temperature sintering:
By above-mentioned constituent at V-arrangement batch mixer mixing 2-4h, and compacting obtains pressed compact, green density 4.5 5.5g/cm under 500 600MPa pressure3, this pressed compact is fixed on supporting steel back, in 840 960 DEG C of sintering in clock hood type furnace, pressure is 1.0-3.0 MPa, sinters under hydrogen shield, is incubated 2-4 h, and insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, obtain required powdered metallurgical material.
The preparation method of clutch dry type copper based powder metallurgy friction material the most according to claim 3, it is characterized in that described preparation method is: by above-mentioned constituent at V-arrangement batch mixer mixing 3h, and compacting obtains pressed compact, green density 5.0g/cm under 550MPa pressure3, this pressed compact is fixed on supporting steel back, in 900 DEG C of sintering in clock hood type furnace, pressure is 2.0MPa, sinters under hydrogen shield, is incubated 3h, and insulation hangs stove air cooling to water-cooled after 500 DEG C after terminating, obtain required powdered metallurgical material.
CN201610518088.5A 2016-06-28 2016-06-28 Dry copper-base powder metallurgy friction material used for clutch and preparing method of dry copper-base powder metallurgy friction material Pending CN106011520A (en)

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CN106702204A (en) * 2017-02-17 2017-05-24 盐城工学院 Copper-based powder metallurgy friction material and preparation method thereof
CN107012358A (en) * 2017-03-27 2017-08-04 北京市瑞飞摩擦材料科技有限公司 A kind of brake pad powder metallurgy friction material and preparation technology
CN107142392A (en) * 2017-04-26 2017-09-08 湖南博科瑞新材料有限责任公司 A kind of friction materials for high-speed train braking and preparation method thereof, bullet train brake shoes and bullet train brake lining
CN107267800A (en) * 2017-07-05 2017-10-20 北京科技大学 A kind of preparation method of the equally distributed copper base friction material of Fe phases
CN107321983A (en) * 2017-07-05 2017-11-07 北京科技大学 A kind of method for adjusting powder metallurgy copper base friction material porosity and pore structure
CN107326205A (en) * 2017-07-05 2017-11-07 北京科技大学 A kind of method that powder metallurgy copper base friction material is prepared with cohesion technique
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CN107855516A (en) * 2017-10-20 2018-03-30 广西银英生物质能源科技开发股份有限公司 A kind of copper based powder metallurgy material and preparation method thereof
RU2666203C1 (en) * 2017-07-04 2018-09-06 Государственное научное учреждение "Институт порошковой металлургии" Copper-based sintered friction material
CN109136627A (en) * 2018-10-16 2019-01-04 北京天宜上佳高新材料股份有限公司 Magnetic suspension train friction material and its preparation method and application
CN109468487A (en) * 2018-12-30 2019-03-15 郑州轻工业学院 A kind of tungsten carbide enhancing copper based powder metallurgy friction material and preparation method thereof
CN110102754A (en) * 2019-05-20 2019-08-09 中南大学 A kind of heavy-duty vehicle dry clutch copper based powder metallurgy friction material and preparation method thereof
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CN106702204A (en) * 2017-02-17 2017-05-24 盐城工学院 Copper-based powder metallurgy friction material and preparation method thereof
CN106702204B (en) * 2017-02-17 2018-09-14 盐城工学院 Copper based powder metallurgy friction material and preparation method thereof
CN107012358A (en) * 2017-03-27 2017-08-04 北京市瑞飞摩擦材料科技有限公司 A kind of brake pad powder metallurgy friction material and preparation technology
CN110650812A (en) * 2017-04-07 2020-01-03 日本制铁株式会社 Sintered friction material
CN110650812B (en) * 2017-04-07 2022-04-05 日本制铁株式会社 Sintered friction material
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CN107142392A (en) * 2017-04-26 2017-09-08 湖南博科瑞新材料有限责任公司 A kind of friction materials for high-speed train braking and preparation method thereof, bullet train brake shoes and bullet train brake lining
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CN107326205A (en) * 2017-07-05 2017-11-07 北京科技大学 A kind of method that powder metallurgy copper base friction material is prepared with cohesion technique
CN107267800B (en) * 2017-07-05 2019-03-26 北京科技大学 A kind of preparation method of the equally distributed copper base friction material of Fe phase
CN107321983A (en) * 2017-07-05 2017-11-07 北京科技大学 A kind of method for adjusting powder metallurgy copper base friction material porosity and pore structure
CN107267800A (en) * 2017-07-05 2017-10-20 北京科技大学 A kind of preparation method of the equally distributed copper base friction material of Fe phases
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CN109468487A (en) * 2018-12-30 2019-03-15 郑州轻工业学院 A kind of tungsten carbide enhancing copper based powder metallurgy friction material and preparation method thereof
CN109468487B (en) * 2018-12-30 2020-07-07 郑州轻工业学院 Tungsten carbide reinforced copper-based powder metallurgy friction material and preparation method thereof
CN110102754B (en) * 2019-05-20 2020-04-24 中南大学 Copper-based powder metallurgy friction material for dry clutch of heavy-duty vehicle and preparation method thereof
CN110102754A (en) * 2019-05-20 2019-08-09 中南大学 A kind of heavy-duty vehicle dry clutch copper based powder metallurgy friction material and preparation method thereof
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CN112593112A (en) * 2020-10-23 2021-04-02 淮阴工学院 Multiphase friction-reducing resistance-increasing copper alloy and preparation method thereof
CN112593112B (en) * 2020-10-23 2021-09-24 淮阴工学院 Multiphase friction-reducing resistance-increasing copper alloy and preparation method thereof
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