CN106010375A - Water-based adhesive for antiskid pavement and preparation method thereof - Google Patents

Water-based adhesive for antiskid pavement and preparation method thereof Download PDF

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Publication number
CN106010375A
CN106010375A CN201610488390.0A CN201610488390A CN106010375A CN 106010375 A CN106010375 A CN 106010375A CN 201610488390 A CN201610488390 A CN 201610488390A CN 106010375 A CN106010375 A CN 106010375A
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component
parts
agent
skid surface
aqueous adhesives
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CN201610488390.0A
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CN106010375B (en
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谭宏伟
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Guangdong paolway environmental protection material Co., Ltd.
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Foshan City Granville Road Environmental Protection Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a water-based adhesive for an antiskid pavement and a preparation method thereof. The water-based adhesive is a dual-component adhesive consisting of a component A and a component B; and before use, the component A and the component B are uniformly mixed according to a mass ratio of 1:(4-6) for use. The component A comprises the following raw materials: an acrylic acid homopolymer emulsion, an anti-freezing agent, a crosslinking agent and deionized water; and the component B is powder and comprises the following raw materials: Portland cement, a hardening agent, a filler and a colorant. The water-based adhesive for the antiskid pavement, disclosed by the invention, meets the needs for road antiskid and greenway rapid construction and rapid traffic restoring in a wet weather environment, and thus the problem of unavailable construction of an oil-based adhesive in a wet weather is solved.

Description

A kind of anti-skid surface Aqueous Adhesives and preparation method thereof
Technical field
The invention belongs to anti-skid surface and stick with glue agent field, especially relate to a kind of anti-skid surface Aqueous Adhesives and Preparation method.
Background technology
Color anti-skid road surface can significantly increase road surface frictional resistance, and color anti-skid road surface is typically by the wear-resisting bone of adhesives and colour Material composition, adhesives plays the effect connected between colored abrasive aggregates and original road surface, makes antislip colour floor and original road Face becomes an entirety, it is ensured that it has longer service life, has good using effect within the period of service.Current domestic city The enamel adhesives of anti-skid surface of field has a variety of, wherein has Domestic Scientific Research institutes and producer's independent development, also have from The external product directly introduced.Summary is got up, and the more commonly used have a following two: modified bi-component epoxide-resin glue and bi-component Acrylic size;Both adhesive mostly are oily gum stick, are not appropriate for cannot constructing under wet weather, in moist sky Can not fast setting under compression ring border, it is impossible to meet that road is anti-skidding and the rapid construction of green road, the demand quickly let pass.
Summary of the invention
It is an object of the invention to provide a kind of anti-skid surface Aqueous Adhesives and preparation method thereof, it is possible to solve above-mentioned At least one in problem.
According to an aspect of the invention, it is provided a kind of anti-skid surface Aqueous Adhesives, including first component and second group Part, the mass ratio of first component and component B is 1:4~6;
In parts by weight, its raw material forms and includes following component first component:
Acrylate homopolymer emulsion 70~80 parts;
Cross-linking agent 7~10 parts;
Deionized water 5~10 parts;
Described component B, in parts by weight, its raw material forms and includes following components:
Portland cement 30~50 parts;
Hardening agent 15~20 parts;
Filler 20~25 parts.
In some embodiments, cross-linking agent is propylene glycol phenylate.Thus, improve anti-skid surface Aqueous Adhesives Elastic.
In some embodiments, first component also includes antifreezing agent 1~3 parts, and antifreezing agent is propylene glycol.Thus, improve Anti-skid surface Aqueous Adhesives freeze-proof so that the anti-skid surface Aqueous Adhesives finally given can be at lower temperature ring Use under border.
In some embodiments, silicate cement is 425 portland cements.
In some embodiments, Hardening agent is quartz sand.
In some embodiments, filler is calcium carbonate.
In some embodiments, second component also includes coloring agent 3~5 parts, and coloring agent is iron oxide red.Thus, improve Anti-skid surface Aqueous Adhesives is the vividness of color when laying, and plays mark action.
The anti-skid surface Aqueous Adhesives of the present invention provides the benefit that: acrylate homopolymer is principal monomer and the third two One class elastomer of alcohol phenylate cross-linking reaction, the composition such as combined high-strength portland cement, with water as disperse medium, solidification After product be organic inorganic hybridization body, fully combine organic material high resiliency and inorganic material high intensity, high pressure excellent Point, is particularly suitable for that road under wet weather environment is anti-skidding and the rapid construction of green road, and the demand quickly let pass solves oily gum The difficult problem that glutinous agent cannot be constructed under wet weather.
According to a further aspect in the invention, it is provided that the preparation method of a kind of above-mentioned anti-skid surface Aqueous Adhesives, bag Include following steps:
The manufacture method of first component: acrylate homopolymer emulsion is put into reactor, drips cross-linking agent third under stirring condition Glycol phenylate is to reacting complete;Adding antifreezing agent, add deionized water regulation viscosity and be extremely coated with-4 glasss 30~45 seconds, stirring is all Even;
The preparation method of component B: portland cement, Hardening agent, filler, coloring agent are put into successively, mix homogeneously.
This preparation method have the beneficial effect that first component and second component can be fabricated separately, the most again both are entered Row mixing, each component manufacturing process is simple, and is easy to transport respectively and store, and keeps the performance of each component.
Detailed description of the invention
The present invention is further detailed explanation below.
A kind of anti-skid surface Aqueous Adhesives provided by the present invention, for first, second Bi-component adhesive, is divided into first component With second component, before use, by first component and component B according to the quality of 1:4~6 than mix homogeneously after, can use.
Specifically, first component, in parts by weight, its raw material forms and includes following components:
Acrylate homopolymer emulsion 70~80 parts;
Propylene glycol phenylate 7~10 parts;
Propylene glycol 1~3 parts;
Deionized water 5~10 parts.
Component B is powder, and in parts by weight, its raw material forms and includes following components:
425 portland cements 30~50 parts;
Quartz sand 15~20 parts;
Calcium carbonate 20~25 parts;
Iron oxide red 3~5 parts.
Wherein, acrylate homopolymer emulsion is aqueous acrylic acid series polymer emulsion, has guarantor's light of excellence, colour retention, Cryogenic property is good, has high-adhesive-strength and shear strength and excellent non-oxidizability.Acrylate homopolymer emulsion is at this Mainly as elastomer in invention, improve tensile strength and the shear strength of adhesive.
Propylene glycol phenylate mainly as the cross-linking agent use of acrylate homopolymer emulsion, improves bullet in the present invention further The elasticity of gonosome and crosslink density, improve low temperature elasticity and the adhesion strength of adhesive.Propylene glycol in the present invention mainly as Antifreezing agent agent uses, and increases the low-temperature stability of elastomer, improves anti-freezing property and the low-temperature construction performance of adhesive.
Deionized water uses mainly as diluent in the present invention, has the effect of regulation adhesive viscosity, improves glue The workability of glutinous agent.
425 portland cements play reinforcing agent effect, enter by absorbing the moisture of the moisture in elastomer and substrate surface Row hydration and sclerosis reacts, and forms organic inorganic hybridization body, thus reaches strengthening action and substantially increase the comprcssive strength of adhesive And adhesion strength.
Quartz sand plays Hardening agent effect, improves hardness and the anti-wear performance of adhesive;Calcium carbonate plays the work of filler With, reduce the cost of adhesive and certain reinforcing property is provided;Iron oxide red uses mainly as coloring agent.
Also providing for the embodiment scheme of a kind of optimization in the present invention, the adhesive effect using this scheme is more apparent, wherein, The mass ratio of first component and component B is 1:5;
First component, in parts by weight, its raw material forms and includes following components:
Acrylate homopolymer emulsion 75 parts;
Propylene glycol phenylate 8 parts;
Propylene glycol 2 parts;
Deionized water 7 parts.
Component B is powder, and in parts by weight, its raw material forms and includes following components:
425 portland cements 40 parts;
Quartz sand 18 parts;
Calcium carbonate 23 parts;
Iron oxide red 4 parts.
The present invention also provides for the preparation method of a kind of anti-skid surface Aqueous Adhesives, comprises the following steps:
The preparation method of first component: acrylate homopolymer emulsion is put into reactor, is slowly added dropwise cross-linking agent third under stirring condition To reacting, complete (product is applied on glass plate be formed after drying the film of transparent and homogeneous and is then considered as reaction eventually glycol phenylate Only);Add antifreezing agent propylene glycol, add deionized water regulation viscosity and be extremely coated with-4 glasss 30~45 seconds, cooling dress after stirring Bucket is standby;
The preparation method of component B: 425 portland cements, quartz sand, calcium carbonate, iron oxide red are put into successively in agitator tank mixed Close uniformly pack standby.
Anti-skid surface Aqueous Adhesives provided by the present invention, is principal monomer and propylene glycol phenyl by acrylate homopolymer One class elastomer of ether cross-linking reaction, the composition such as combined high-strength portland cement, with water as disperse medium, after solidification Product is organic inorganic hybridization body, fully combines organic material high resiliency and inorganic material high intensity, high pressure advantage, spy It is not suitable for that road under wet weather environment is anti-skidding and the rapid construction of green road, the demand quickly let pass, solve oiliness adhesive The difficult problem cannot constructed under wet weather.
Below by way of specific embodiment, the present invention will be further described.
Embodiment 1
The preparation method of first component: 70kg acrylate homopolymer emulsion is put into reactor, is slowly added dropwise 7kg and hands under stirring condition Connection agent propylene glycol phenylate is to reacting complete;Add 1kg antifreezing agent propylene glycol, add the deionized water regulation viscosity of about 5kg To being coated with-4 glasss 30~45 seconds, barrelling of lowering the temperature after stirring is standby;
The preparation method of component B: 30kg 425 portland cement, 15kg quartz sand, 20kg calcium carbonate, 3kg iron oxide red are depended on In secondary input agitator tank, mix homogeneously pack is standby.
Before using, by first component and component B according to mass ratio 1:4 mix homogeneously, obtain anti-skid surface aqueous gluing Agent.
Owing to first component and component B are for separately to deposit, its excellent storage stability, can stably store more than 1 year.Preparation Obtained by anti-skid surface Aqueous Adhesives, there is good mechanical performance, and there is good wet viscosity and quickly Curing rate, all can be bonding under damp condition, about 6 hours hardening times.Colophonium, cement, plank, steel plate, ceramic tile, slabstone, glass Glass surface all can be bonding, has adhesive property widely.Having relatively low film-forming temperature, temperature more than 5 DEG C is curable.Glued membrane has There is preferable water-acid resistance, calcium hydroxide saturated solution soaks 24h in phenomenon without exception;Internal plasticization and surface tension Low, good weatherability.
Embodiment 2
The preparation method of first component: 80kg acrylate homopolymer emulsion is put into reactor, is slowly added dropwise 10kg under stirring condition Cross-linking agent propylene glycol phenylate is to reacting complete;Adding 3kg antifreezing agent propylene glycol, the deionized water regulation adding about 10kg is viscous Degree is to being coated with-4 glasss 30~45 seconds, and barrelling of lowering the temperature after stirring is standby;
The preparation method of component B: 50kg 425 portland cement, 20kg quartz sand, 25kg calcium carbonate, 5kg iron oxide red are depended on In secondary input agitator tank, mix homogeneously pack is standby.
Before using, by first component and component B according to mass ratio 1:6 mix homogeneously, obtain anti-skid surface aqueous gluing Agent.
The anti-skid surface Aqueous Adhesives obtained by this preparation method has effect in the same manner as in Example 1.
Embodiment 3
The preparation method of first component: 75kg acrylate homopolymer emulsion is put into reactor, is slowly added dropwise 8kg and hands under stirring condition Connection agent propylene glycol phenylate is to reacting complete;Add 2kg antifreezing agent propylene glycol, add the deionized water regulation viscosity of about 7kg To being coated with-4 glasss 30~45 seconds, barrelling of lowering the temperature after stirring is standby;
The preparation method of component B: 40kg 425 portland cement, 18kg quartz sand, 23kg calcium carbonate, 4kg iron oxide red are depended on In secondary input agitator tank, mix homogeneously packs standby mix homogeneously, obtains anti-skid surface Aqueous Adhesives.
The anti-skid surface Aqueous Adhesives obtained by this preparation method has effect in the same manner as in Example 1.
Testing example 1~3 prepares the property indices of gained anti-skid surface Aqueous Adhesives respectively, specifically tests The results are shown in Table shown in 1.Result shows, anti-skid surface Aqueous Adhesives of the present invention, and impact strength is good, bonding to concrete Power is good, water-fast good with alkali resistance, also has low-temperature cracking-resistance.
Table 1
To sum up, anti-skid surface Aqueous Adhesives provided by the present invention has a following performance characteristics:
1, there is good mechanical performance and bin stability, storage-stable more than 1 year;
2, there is good wet viscosity and curing rate quickly, all can be bonding under damp condition, hardening time about 6 is little Time;
3, having adhesive property widely, Colophonium, cement, plank, steel plate, ceramic tile, slabstone, glass surface all can be bonding;
4, there is relatively low film-forming temperature, temperature Celsius more than 5 degree curable;
5, glued membrane has preferable water-acid resistance, soaks 24h in phenomenon without exception in calcium hydroxide saturated solution;
6, internal plasticization and surface tension are low, good weatherability.
Above-described is only the preferred embodiment of the present invention, it is noted that for those of ordinary skill in the art For, without departing from the concept of the premise of the invention, it is also possible to make some deformation and improvement, these broadly fall into the present invention Protection domain.

Claims (8)

1. an anti-skid surface Aqueous Adhesives, it is characterised in that include first component and component B, first component and component B Mass ratio is 1:4~6;
In parts by weight, its raw material forms and includes following component first component:
Acrylate homopolymer emulsion 70~80 parts;
Cross-linking agent 7~10 parts;
Deionized water 5~10 parts;
Described component B, in parts by weight, its raw material forms and includes following components:
Portland cement 30~50 parts;
Hardening agent 15~20 parts;
Filler 20~25 parts.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described cross-linking agent is the third two Alcohol phenylate.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described first component also includes Antifreezing agent 1~3 parts, described antifreezing agent is propylene glycol.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described silicate cement is 425 portland cements.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described Hardening agent is quartz Sand.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described filler is carbonic acid Calcium.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described second component also includes Coloring agent 3~5 parts, described coloring agent is iron oxide red.
8. one kind as arbitrary in claim 1~7 as described in the preparation method of anti-skid surface Aqueous Adhesives, it is characterised in that Comprise the following steps:
The manufacture method of first component: acrylate homopolymer emulsion is put into reactor, drips cross-linking agent propylene glycol under stirring condition Phenylate is to reacting complete;Add antifreezing agent, add deionized water regulation viscosity and be extremely coated with-4 glasss 30~45 seconds, stir;
The preparation method of component B: portland cement, Hardening agent, filler, coloring agent are put into successively, mix homogeneously.
CN201610488390.0A 2016-06-24 2016-06-24 A kind of anti-skid surface Aqueous Adhesives and preparation method thereof Active CN106010375B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107760233A (en) * 2017-10-20 2018-03-06 天津市禹红建筑防水材料有限公司 The flexible adhesives and preparation method of a kind of polyethylene polypropylene fiber waterproof coiled material
CN111039623A (en) * 2019-12-25 2020-04-21 北京中研益工程技术开发中心有限公司 Water-based stone-like composite anti-skid pavement and manufacturing method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967049A (en) * 2010-04-02 2011-02-09 上海东方雨虹防水技术有限责任公司 Bi-component waterproof paint for roads and bridges and preparation method thereof
CN103275578A (en) * 2013-06-06 2013-09-04 厦门力嘉诚防水工程有限公司 Universal waterproof coating
CN103896530A (en) * 2013-09-17 2014-07-02 苏州弗克新型建材有限公司 Modified polymer cement-based waterproof material
CN104140728A (en) * 2014-08-08 2014-11-12 鳄鱼制漆(上海)有限公司 JS elastic waterproof coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967049A (en) * 2010-04-02 2011-02-09 上海东方雨虹防水技术有限责任公司 Bi-component waterproof paint for roads and bridges and preparation method thereof
CN103275578A (en) * 2013-06-06 2013-09-04 厦门力嘉诚防水工程有限公司 Universal waterproof coating
CN103896530A (en) * 2013-09-17 2014-07-02 苏州弗克新型建材有限公司 Modified polymer cement-based waterproof material
CN104140728A (en) * 2014-08-08 2014-11-12 鳄鱼制漆(上海)有限公司 JS elastic waterproof coating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107760233A (en) * 2017-10-20 2018-03-06 天津市禹红建筑防水材料有限公司 The flexible adhesives and preparation method of a kind of polyethylene polypropylene fiber waterproof coiled material
CN107760233B (en) * 2017-10-20 2020-02-14 天津市禹红建筑防水材料有限公司 Flexible adhesive for polyethylene polypropylene fiber waterproof coiled material and preparation method thereof
CN111039623A (en) * 2019-12-25 2020-04-21 北京中研益工程技术开发中心有限公司 Water-based stone-like composite anti-skid pavement and manufacturing method thereof

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