CN106010375A - Water-based adhesive for antiskid pavement and preparation method thereof - Google Patents
Water-based adhesive for antiskid pavement and preparation method thereof Download PDFInfo
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- CN106010375A CN106010375A CN201610488390.0A CN201610488390A CN106010375A CN 106010375 A CN106010375 A CN 106010375A CN 201610488390 A CN201610488390 A CN 201610488390A CN 106010375 A CN106010375 A CN 106010375A
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- aqueous adhesives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a water-based adhesive for an antiskid pavement and a preparation method thereof. The water-based adhesive is a dual-component adhesive consisting of a component A and a component B; and before use, the component A and the component B are uniformly mixed according to a mass ratio of 1:(4-6) for use. The component A comprises the following raw materials: an acrylic acid homopolymer emulsion, an anti-freezing agent, a crosslinking agent and deionized water; and the component B is powder and comprises the following raw materials: Portland cement, a hardening agent, a filler and a colorant. The water-based adhesive for the antiskid pavement, disclosed by the invention, meets the needs for road antiskid and greenway rapid construction and rapid traffic restoring in a wet weather environment, and thus the problem of unavailable construction of an oil-based adhesive in a wet weather is solved.
Description
Technical field
The invention belongs to anti-skid surface and stick with glue agent field, especially relate to a kind of anti-skid surface Aqueous Adhesives and
Preparation method.
Background technology
Color anti-skid road surface can significantly increase road surface frictional resistance, and color anti-skid road surface is typically by the wear-resisting bone of adhesives and colour
Material composition, adhesives plays the effect connected between colored abrasive aggregates and original road surface, makes antislip colour floor and original road
Face becomes an entirety, it is ensured that it has longer service life, has good using effect within the period of service.Current domestic city
The enamel adhesives of anti-skid surface of field has a variety of, wherein has Domestic Scientific Research institutes and producer's independent development, also have from
The external product directly introduced.Summary is got up, and the more commonly used have a following two: modified bi-component epoxide-resin glue and bi-component
Acrylic size；Both adhesive mostly are oily gum stick, are not appropriate for cannot constructing under wet weather, in moist sky
Can not fast setting under compression ring border, it is impossible to meet that road is anti-skidding and the rapid construction of green road, the demand quickly let pass.
Summary of the invention
It is an object of the invention to provide a kind of anti-skid surface Aqueous Adhesives and preparation method thereof, it is possible to solve above-mentioned
At least one in problem.
According to an aspect of the invention, it is provided a kind of anti-skid surface Aqueous Adhesives, including first component and second group
Part, the mass ratio of first component and component B is 1:4～6；
In parts by weight, its raw material forms and includes following component first component:
Acrylate homopolymer emulsion 70～80 parts；
Cross-linking agent 7～10 parts；
Deionized water 5～10 parts；
Described component B, in parts by weight, its raw material forms and includes following components:
Portland cement 30～50 parts；
Hardening agent 15～20 parts；
Filler 20～25 parts.
In some embodiments, cross-linking agent is propylene glycol phenylate.Thus, improve anti-skid surface Aqueous Adhesives
Elastic.
In some embodiments, first component also includes antifreezing agent 1～3 parts, and antifreezing agent is propylene glycol.Thus, improve
Anti-skid surface Aqueous Adhesives freeze-proof so that the anti-skid surface Aqueous Adhesives finally given can be at lower temperature ring
Use under border.
In some embodiments, silicate cement is 425 portland cements.
In some embodiments, Hardening agent is quartz sand.
In some embodiments, filler is calcium carbonate.
In some embodiments, second component also includes coloring agent 3～5 parts, and coloring agent is iron oxide red.Thus, improve
Anti-skid surface Aqueous Adhesives is the vividness of color when laying, and plays mark action.
The anti-skid surface Aqueous Adhesives of the present invention provides the benefit that: acrylate homopolymer is principal monomer and the third two
One class elastomer of alcohol phenylate cross-linking reaction, the composition such as combined high-strength portland cement, with water as disperse medium, solidification
After product be organic inorganic hybridization body, fully combine organic material high resiliency and inorganic material high intensity, high pressure excellent
Point, is particularly suitable for that road under wet weather environment is anti-skidding and the rapid construction of green road, and the demand quickly let pass solves oily gum
The difficult problem that glutinous agent cannot be constructed under wet weather.
According to a further aspect in the invention, it is provided that the preparation method of a kind of above-mentioned anti-skid surface Aqueous Adhesives, bag
Include following steps:
The manufacture method of first component: acrylate homopolymer emulsion is put into reactor, drips cross-linking agent third under stirring condition
Glycol phenylate is to reacting complete；Adding antifreezing agent, add deionized water regulation viscosity and be extremely coated with-4 glasss 30～45 seconds, stirring is all
Even；
The preparation method of component B: portland cement, Hardening agent, filler, coloring agent are put into successively, mix homogeneously.
This preparation method have the beneficial effect that first component and second component can be fabricated separately, the most again both are entered
Row mixing, each component manufacturing process is simple, and is easy to transport respectively and store, and keeps the performance of each component.
Detailed description of the invention
The present invention is further detailed explanation below.
A kind of anti-skid surface Aqueous Adhesives provided by the present invention, for first, second Bi-component adhesive, is divided into first component
With second component, before use, by first component and component B according to the quality of 1:4～6 than mix homogeneously after, can use.
Specifically, first component, in parts by weight, its raw material forms and includes following components:
Acrylate homopolymer emulsion 70～80 parts；
Propylene glycol phenylate 7～10 parts；
Propylene glycol 1～3 parts；
Deionized water 5～10 parts.
Component B is powder, and in parts by weight, its raw material forms and includes following components:
425 portland cements 30～50 parts；
Quartz sand 15～20 parts；
Calcium carbonate 20～25 parts；
Iron oxide red 3～5 parts.
Wherein, acrylate homopolymer emulsion is aqueous acrylic acid series polymer emulsion, has guarantor's light of excellence, colour retention,
Cryogenic property is good, has high-adhesive-strength and shear strength and excellent non-oxidizability.Acrylate homopolymer emulsion is at this
Mainly as elastomer in invention, improve tensile strength and the shear strength of adhesive.
Propylene glycol phenylate mainly as the cross-linking agent use of acrylate homopolymer emulsion, improves bullet in the present invention further
The elasticity of gonosome and crosslink density, improve low temperature elasticity and the adhesion strength of adhesive.Propylene glycol in the present invention mainly as
Antifreezing agent agent uses, and increases the low-temperature stability of elastomer, improves anti-freezing property and the low-temperature construction performance of adhesive.
Deionized water uses mainly as diluent in the present invention, has the effect of regulation adhesive viscosity, improves glue
The workability of glutinous agent.
425 portland cements play reinforcing agent effect, enter by absorbing the moisture of the moisture in elastomer and substrate surface
Row hydration and sclerosis reacts, and forms organic inorganic hybridization body, thus reaches strengthening action and substantially increase the comprcssive strength of adhesive
And adhesion strength.
Quartz sand plays Hardening agent effect, improves hardness and the anti-wear performance of adhesive；Calcium carbonate plays the work of filler
With, reduce the cost of adhesive and certain reinforcing property is provided；Iron oxide red uses mainly as coloring agent.
Also providing for the embodiment scheme of a kind of optimization in the present invention, the adhesive effect using this scheme is more apparent, wherein,
The mass ratio of first component and component B is 1:5；
First component, in parts by weight, its raw material forms and includes following components:
Acrylate homopolymer emulsion 75 parts；
Propylene glycol phenylate 8 parts；
Propylene glycol 2 parts；
Deionized water 7 parts.
Component B is powder, and in parts by weight, its raw material forms and includes following components:
425 portland cements 40 parts；
Quartz sand 18 parts；
Calcium carbonate 23 parts；
Iron oxide red 4 parts.
The present invention also provides for the preparation method of a kind of anti-skid surface Aqueous Adhesives, comprises the following steps:
The preparation method of first component: acrylate homopolymer emulsion is put into reactor, is slowly added dropwise cross-linking agent third under stirring condition
To reacting, complete (product is applied on glass plate be formed after drying the film of transparent and homogeneous and is then considered as reaction eventually glycol phenylate
Only)；Add antifreezing agent propylene glycol, add deionized water regulation viscosity and be extremely coated with-4 glasss 30～45 seconds, cooling dress after stirring
Bucket is standby；
The preparation method of component B: 425 portland cements, quartz sand, calcium carbonate, iron oxide red are put into successively in agitator tank mixed
Close uniformly pack standby.
Anti-skid surface Aqueous Adhesives provided by the present invention, is principal monomer and propylene glycol phenyl by acrylate homopolymer
One class elastomer of ether cross-linking reaction, the composition such as combined high-strength portland cement, with water as disperse medium, after solidification
Product is organic inorganic hybridization body, fully combines organic material high resiliency and inorganic material high intensity, high pressure advantage, spy
It is not suitable for that road under wet weather environment is anti-skidding and the rapid construction of green road, the demand quickly let pass, solve oiliness adhesive
The difficult problem cannot constructed under wet weather.
Below by way of specific embodiment, the present invention will be further described.
Embodiment 1
The preparation method of first component: 70kg acrylate homopolymer emulsion is put into reactor, is slowly added dropwise 7kg and hands under stirring condition
Connection agent propylene glycol phenylate is to reacting complete；Add 1kg antifreezing agent propylene glycol, add the deionized water regulation viscosity of about 5kg
To being coated with-4 glasss 30～45 seconds, barrelling of lowering the temperature after stirring is standby；
The preparation method of component B: 30kg 425 portland cement, 15kg quartz sand, 20kg calcium carbonate, 3kg iron oxide red are depended on
In secondary input agitator tank, mix homogeneously pack is standby.
Before using, by first component and component B according to mass ratio 1:4 mix homogeneously, obtain anti-skid surface aqueous gluing
Agent.
Owing to first component and component B are for separately to deposit, its excellent storage stability, can stably store more than 1 year.Preparation
Obtained by anti-skid surface Aqueous Adhesives, there is good mechanical performance, and there is good wet viscosity and quickly
Curing rate, all can be bonding under damp condition, about 6 hours hardening times.Colophonium, cement, plank, steel plate, ceramic tile, slabstone, glass
Glass surface all can be bonding, has adhesive property widely.Having relatively low film-forming temperature, temperature more than 5 DEG C is curable.Glued membrane has
There is preferable water-acid resistance, calcium hydroxide saturated solution soaks 24h in phenomenon without exception；Internal plasticization and surface tension
Low, good weatherability.
Embodiment 2
The preparation method of first component: 80kg acrylate homopolymer emulsion is put into reactor, is slowly added dropwise 10kg under stirring condition
Cross-linking agent propylene glycol phenylate is to reacting complete；Adding 3kg antifreezing agent propylene glycol, the deionized water regulation adding about 10kg is viscous
Degree is to being coated with-4 glasss 30～45 seconds, and barrelling of lowering the temperature after stirring is standby；
The preparation method of component B: 50kg 425 portland cement, 20kg quartz sand, 25kg calcium carbonate, 5kg iron oxide red are depended on
In secondary input agitator tank, mix homogeneously pack is standby.
Before using, by first component and component B according to mass ratio 1:6 mix homogeneously, obtain anti-skid surface aqueous gluing
Agent.
The anti-skid surface Aqueous Adhesives obtained by this preparation method has effect in the same manner as in Example 1.
Embodiment 3
The preparation method of first component: 75kg acrylate homopolymer emulsion is put into reactor, is slowly added dropwise 8kg and hands under stirring condition
Connection agent propylene glycol phenylate is to reacting complete；Add 2kg antifreezing agent propylene glycol, add the deionized water regulation viscosity of about 7kg
To being coated with-4 glasss 30～45 seconds, barrelling of lowering the temperature after stirring is standby；
The preparation method of component B: 40kg 425 portland cement, 18kg quartz sand, 23kg calcium carbonate, 4kg iron oxide red are depended on
In secondary input agitator tank, mix homogeneously packs standby mix homogeneously, obtains anti-skid surface Aqueous Adhesives.
The anti-skid surface Aqueous Adhesives obtained by this preparation method has effect in the same manner as in Example 1.
Testing example 1～3 prepares the property indices of gained anti-skid surface Aqueous Adhesives respectively, specifically tests
The results are shown in Table shown in 1.Result shows, anti-skid surface Aqueous Adhesives of the present invention, and impact strength is good, bonding to concrete
Power is good, water-fast good with alkali resistance, also has low-temperature cracking-resistance.
Table 1
To sum up, anti-skid surface Aqueous Adhesives provided by the present invention has a following performance characteristics:
1, there is good mechanical performance and bin stability, storage-stable more than 1 year；
2, there is good wet viscosity and curing rate quickly, all can be bonding under damp condition, hardening time about 6 is little
Time；
3, having adhesive property widely, Colophonium, cement, plank, steel plate, ceramic tile, slabstone, glass surface all can be bonding；
4, there is relatively low film-forming temperature, temperature Celsius more than 5 degree curable；
5, glued membrane has preferable water-acid resistance, soaks 24h in phenomenon without exception in calcium hydroxide saturated solution；
6, internal plasticization and surface tension are low, good weatherability.
Above-described is only the preferred embodiment of the present invention, it is noted that for those of ordinary skill in the art
For, without departing from the concept of the premise of the invention, it is also possible to make some deformation and improvement, these broadly fall into the present invention
Protection domain.
Claims (8)
1. an anti-skid surface Aqueous Adhesives, it is characterised in that include first component and component B, first component and component B
Mass ratio is 1:4～6；
In parts by weight, its raw material forms and includes following component first component:
Acrylate homopolymer emulsion 70～80 parts；
Cross-linking agent 7～10 parts；
Deionized water 5～10 parts；
Described component B, in parts by weight, its raw material forms and includes following components:
Portland cement 30～50 parts；
Hardening agent 15～20 parts；
Filler 20～25 parts.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described cross-linking agent is the third two
Alcohol phenylate.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described first component also includes
Antifreezing agent 1～3 parts, described antifreezing agent is propylene glycol.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described silicate cement is
425 portland cements.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described Hardening agent is quartz
Sand.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described filler is carbonic acid
Calcium.
A kind of anti-skid surface Aqueous Adhesives the most according to claim 1, it is characterised in that described second component also includes
Coloring agent 3～5 parts, described coloring agent is iron oxide red.
8. one kind as arbitrary in claim 1～7 as described in the preparation method of anti-skid surface Aqueous Adhesives, it is characterised in that
Comprise the following steps:
The manufacture method of first component: acrylate homopolymer emulsion is put into reactor, drips cross-linking agent propylene glycol under stirring condition
Phenylate is to reacting complete；Add antifreezing agent, add deionized water regulation viscosity and be extremely coated with-4 glasss 30～45 seconds, stir；
The preparation method of component B: portland cement, Hardening agent, filler, coloring agent are put into successively, mix homogeneously.
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| CN201610488390.0A CN106010375B (en) | 2016-06-24 | 2016-06-24 | A kind of anti-skid surface Aqueous Adhesives and preparation method thereof |
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| CN201610488390.0A CN106010375B (en) | 2016-06-24 | 2016-06-24 | A kind of anti-skid surface Aqueous Adhesives and preparation method thereof |
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| CN106010375B CN106010375B (en) | 2017-11-21 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760233A (en) * | 2017-10-20 | 2018-03-06 | 天津市禹红建筑防水材料有限公司 | The flexible adhesives and preparation method of a kind of polyethylene polypropylene fiber waterproof coiled material |
| CN111039623A (en) * | 2019-12-25 | 2020-04-21 | 北京中研益工程技术开发中心有限公司 | Water-based stone-like composite anti-skid pavement and manufacturing method thereof |
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| CN101967049A (en) * | 2010-04-02 | 2011-02-09 | 上海东方雨虹防水技术有限责任公司 | Bi-component waterproof paint for roads and bridges and preparation method thereof |
| CN103275578A (en) * | 2013-06-06 | 2013-09-04 | 厦门力嘉诚防水工程有限公司 | Universal waterproof coating |
| CN103896530A (en) * | 2013-09-17 | 2014-07-02 | 苏州弗克新型建材有限公司 | Modified polymer cement-based waterproof material |
| CN104140728A (en) * | 2014-08-08 | 2014-11-12 | 鳄鱼制漆(上海)有限公司 | JS elastic waterproof coating |
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2016
- 2016-06-24 CN CN201610488390.0A patent/CN106010375B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967049A (en) * | 2010-04-02 | 2011-02-09 | 上海东方雨虹防水技术有限责任公司 | Bi-component waterproof paint for roads and bridges and preparation method thereof |
| CN103275578A (en) * | 2013-06-06 | 2013-09-04 | 厦门力嘉诚防水工程有限公司 | Universal waterproof coating |
| CN103896530A (en) * | 2013-09-17 | 2014-07-02 | 苏州弗克新型建材有限公司 | Modified polymer cement-based waterproof material |
| CN104140728A (en) * | 2014-08-08 | 2014-11-12 | 鳄鱼制漆(上海)有限公司 | JS elastic waterproof coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760233A (en) * | 2017-10-20 | 2018-03-06 | 天津市禹红建筑防水材料有限公司 | The flexible adhesives and preparation method of a kind of polyethylene polypropylene fiber waterproof coiled material |
| CN107760233B (en) * | 2017-10-20 | 2020-02-14 | 天津市禹红建筑防水材料有限公司 | Flexible adhesive for polyethylene polypropylene fiber waterproof coiled material and preparation method thereof |
| CN111039623A (en) * | 2019-12-25 | 2020-04-21 | 北京中研益工程技术开发中心有限公司 | Water-based stone-like composite anti-skid pavement and manufacturing method thereof |
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| Publication number | Publication date |
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| CN106010375B (en) | 2017-11-21 |
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