CN106010332A - Decorative base material and preparation method thereof - Google Patents

Decorative base material and preparation method thereof Download PDF

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Publication number
CN106010332A
CN106010332A CN201610380603.8A CN201610380603A CN106010332A CN 106010332 A CN106010332 A CN 106010332A CN 201610380603 A CN201610380603 A CN 201610380603A CN 106010332 A CN106010332 A CN 106010332A
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base material
tackifying resin
preparation
polymerizable
dicoration base
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CN106010332B (en
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张小民
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Qingyuan Fast New Type Building Material Co Ltd
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Qingyuan Fast New Type Building Material Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5425—Silicon-containing compounds containing oxygen containing at least one C=C bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/544—Silicon-containing compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2451/00—Presence of graft polymer

Abstract

The invention discloses a preparation method of a decorative base material. The decorative base material comprises a base material body, and the method consists of: coating the undersurface of the base material body with organosilicon and polymerizable rosin modified acrylic ester tackifying resin, and then performing drying in a 50-110DEG C environment for 2-10min, thus obtaining the decorative base material with an adhesive layer at the bottom. At the same time, the invention also discloses the decorative base material. The decorative base material has the advantages of high adhesion, good peelability and good thermal stability.

Description

A kind of Dicoration base material and preparation method thereof
Technical field
The present invention relates to decorative plate field, particularly a kind of Dicoration base material with and preparation method thereof.
Background technology
CN201510979718.4 discloses a kind of decoration PVC film, is composed of the following raw materials by weight: PVC440 resin-oatmeal, nano titanium carbide, chitosan graft polyacrylic acid, polyoxyethylene sorbitan monostearate, butyl titanate, ethyl stearte, positive octadecanol, two (triethanolamine) metatitanic acid diisopropyl ester, saturated fatty alcohol multi-carboxylate, sodium metaantimonate, zinc chromate, plasticizer, stabilizer, antioxidant.This invention reasonable combination by formula, the PVC film of gained has aging resistance, toughness height, heat stability, the advantage of good flame resistance.Meanwhile, also there is the feature of acid-alkali-corrosive-resisting.
CN201410808818.6 discloses a kind of Environment-friendlywear-resistant wear-resistant PVC decorative material, and its raw material and raw material weight percentage composition are as follows: PVC75-85%；Plasticizer 3-5%；Lubricant 5-7%；Levelling agent 3-5%；Barium zinc stabilizer 2-3%；Antioxidant 1-3%；Aluminium powder 1-3%.It is additionally added 1～the Graphene of 3% of described PVC weight.The described a kind of Environment-friendlywear-resistant wear-resistant PVC decorative material of this invention and manufacture method thereof, pollution-free, environment and human body are not injured, in use will not produce the problems such as contractions, deformation, and after discarding to water quality, soil is the most pollution-free.
But above-mentioned technical scheme has problems in that, it is during decoration laminating, the defect such as adhesive force is inadequate, rippability is low, poor heat stability.The tack coat of the most traditional Dicoration base material needs to heat coating, and abnormal smells from the patient is greatly, affects environment.This glue need not to add thermal coating, the highest to the adhesive strength of polar material, heat-resisting ageing-resisting performance is the best, PUR pressure sensitive adhesive plasticizer-containing.
Summary of the invention
It is an object of the invention to provide a kind of Dicoration base material, between this Dicoration base material and wall or floor, adhesive force is big, and rippability is good, Heat stability is good.The present invention also provides for the preparation method of this resin simultaneously.
The technical scheme is that the preparation method of a kind of Dicoration base material, described Dicoration base material includes material main body, described method is: Abietyl modified to organosilicon and polymerizable acrylate tackifying resin is coated in the bottom surface of material main body, then in the environment of 50-110 DEG C, dry 2-10min, obtain the bottom Dicoration base material for mucigel；
Described organosilicon and polymerizable Abietyl modified acrylate tackifying resin are prepared by following parts by weight of component:
Self-control polymerizable Colophonium tackifying resin 3-5 part, Isooctyl acrylate monomer 140-155 part, methyl methacrylate 5-8 part, 2-(Acryloyloxy)ethanol 45-54 part, methacrylic acid 10-14 part, alkylphenol polyoxyethylene (op-10) 4-6 part, organosilicon 0.3-0.5 part, buffer agent 0.9-1.1 part, inorganic initiator 3.5-4.5 part, chain-transferring agent 0.9-1.1 part, deionized water 240-260 part；
Wherein, self-control polymerizable Colophonium tackifying resin is prepared by the following method and obtains: join in reactor by the ethylene glycol monobutyl ether of the liquid rosin ester of 7-10 part, the rosin glyceride of 9-15 part and 5-8 part, react 2-3 hour at 85 DEG C-90 DEG C, obtain polymerizable Colophonium tackifying resin.
In the preparation method of above-mentioned Dicoration base material, the organosilicon of bottom surface coating and the thickness of polymerizable Abietyl modified acrylate tackifying resin of material main body are 0.05-2mm.
In the preparation method of above-mentioned Dicoration base material, described organosilicon is: γ-methacryloxypropyl trimethoxy silane or γ-aminopropyltrimethoxysilane or γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane.
In the preparation method of above-mentioned Dicoration base material, described initiator is potassium peroxydisulfate or sodium peroxydisulfate or Ammonium persulfate..
In the preparation method of above-mentioned Dicoration base material, described buffer agent is the one in sodium bicarbonate, potassium bicarbonate.
In the preparation method of above-mentioned Dicoration base material, described chain-transferring agent is lauryl mercaptan or aliphatic mercaptan or isopropanol.
In the preparation method of above-mentioned Dicoration base material, described organosilicon and polymerizable Abietyl modified acrylate tackifying resin are prepared by the following method and obtain:
Alkylphenol polyoxyethylene (op-10) is added in the deionized water of 60-100 part and stir, add self-control polymerizable Colophonium tackifying resin, Isooctyl acrylate monomer, methyl methacrylate, 2-(Acryloyloxy)ethanol, methacrylic acid, organosilicon, chain-transferring agent, be uniformly mixing to obtain pre-emulsification emulsion；
Sodium bicarbonate is dissolved in the deionized water of 120-140 part, joins in reactor.Another configuration inorganic initiator is dissolved in the deionized water of 40-60 part, prepares initiator solution, when question response still is warming up to 78-82 DEG C, it is simultaneously added dropwise initiator solution and pre-emulsification emulsion, reacts 3-5 hour, after being added dropwise to complete, be warming up to 85-90 DEG C, after insulation a period of time, cooling discharge.
In the preparation method of above-mentioned Dicoration base material, PU layer that described material main body includes from top to bottom setting gradually, transparent wear, the printing bed of material, packed layer, initial bed.Transparent wear is mainly by PVC, stabilizer, and plasticizer forms；Packed layer and the main PVC of initial bed and calcium carbonate and auxiliary agent stabilizer, plasticizer forms, and wherein PVC and calcium carbonate are respectively 15-30% and 35-65%；The introduction of PVC calcium carbonate composite board has much in the art, introduces this most one by one.
In the preparation method of above-mentioned Dicoration base material, described method is additionally included in one layer of release paper of bottom surface laminating of mucigel, obtains Dicoration base material；
Described Dicoration base material is sheet material or coiled material.Coiled material can be homogeneous penetrating floor or be other kinds of coiled material floor.
The invention also discloses a kind of Dicoration base material simultaneously, prepared by above-mentioned method.
Beneficial effects of the present invention is as follows:
The Dicoration base material of the present invention uses unique mucigel, its concrete weatherability is good, high temperature resistant and the preferable advantage of resistance to low temperature, pliability is good simultaneously, removability is good, and material adhesive property that can be low to polar surfaces is preferable, and this mucigel not plasticizer-containing, water, as medium, can improve existing drying plant utilization rate at dry process.
Accompanying drawing explanation
The structural representation of 1 embodiment of the present invention 1 of accompanying drawing.
Detailed description of the invention
Below in conjunction with detailed description of the invention, technical scheme is described in further detail, but does not constitute any limitation of the invention.
Specific embodiment 1:
Prepare material main body, PU layer 1 that material main body includes from top to bottom setting gradually, transparent wear 2, the printing bed of material 3, packed layer 4,5 initial beds；Being provided with glass layer 8 in described packed layer 4, then coat organosilicon and polymerizable Abietyl modified acrylate tackifying resin on initial bed 5, thickness is 1mm, 5min is dried in the environment of 80 DEG C, obtain mucigel 6, be then covered by release paper 7, obtain Dicoration base material.
Described organosilicon and polymerizable Abietyl modified acrylate tackifying resin are prepared by the following method and obtain:
1, self-control polymerizable Colophonium tackifying resin: join in reactor by the ethylene glycol monobutyl ether of the liquid rosin esters of 7 parts, the rosin glyceride of 9 parts and 5 parts, reacts 2 hours at 85 DEG C, obtains polymerizable Colophonium tackifying resin.
2, alkylphenol polyoxyethylene (op-10) 6 parts is added in the deionized water of 80 parts and stir, add 5 parts of self-controls polymerizable Colophonium tackifying resin, 150 parts of Isooctyl acrylate monomers, 8 parts of methyl methacrylates, 54 parts of 2-(Acryloyloxy)ethanols, 14 parts of methacrylic acids, 0.5 part of methacryloxypropyl trimethoxy silane, 1 part of lauryl mercaptan, be uniformly mixing to obtain pre-emulsification emulsion.
3, the sodium bicarbonate of 1 part is dissolved in the deionized water of 120 parts, joins in reactor.Another configuration Ammonium persulfate. 4 parts is dissolved in the deionized water of 50 parts, prepares initiator.When question response still is warming up to 78-80 DEG C, it is simultaneously added dropwise initiator and pre-emulsification emulsion, reacts 3-5 hour, after being added dropwise to complete, be warming up to 85-90 DEG C, be incubated 1 hour, cooling discharge.
Specific embodiment 2
Prepare material main body, PU layer that material main body includes from top to bottom setting gradually, transparent wear, the printing bed of material, packed layer, initial bed, it is provided with glass layer in described packed layer, then on initial bed, coat organosilicon and polymerizable Abietyl modified acrylate tackifying resin, thickness is 0.2mm, in the environment of 60 DEG C, dry 3min, be then covered by release paper, obtain Dicoration base material.
Described organosilicon and polymerizable Abietyl modified acrylate tackifying resin are prepared by the following method and obtain:
1, self-control polymerizable Colophonium tackifying resin: join in reactor by the ethylene glycol monobutyl ether of the liquid rosin esters of 8 parts, the rosin glyceride of 15 parts and 5 parts, reacts 2.5 hours at 88 DEG C, obtains polymerizable Colophonium tackifying resin.
2, alkylphenol polyoxyethylene (op-10) 5 parts is added in the deionized water of 60 parts and stir, add 3 parts of self-controls polymerizable Colophonium tackifying resin, 155 parts of Isooctyl acrylate monomers, 7 parts of methyl methacrylates, 48 parts of 2-(Acryloyloxy)ethanols, 12 parts of methacrylic acids, 0.3 part of γ-aminopropyltrimethoxysilane, 1.1 parts of lauryl mercaptans, be uniformly mixing to obtain pre-emulsification emulsion.
3, the sodium bicarbonate of 0.9 part is dissolved in the deionized water of 140 parts, joins in reactor.Another configuration Ammonium persulfate. 3.5 parts is dissolved in the deionized water of 40 parts, prepares initiator.When question response still is warming up to 78-82 DEG C, it is simultaneously added dropwise initiator and pre-emulsification emulsion, reacts 4 hours, after being added dropwise to complete, be warming up to 85-90 DEG C, be incubated 1 hour, cooling discharge.
Specific embodiment 3
Prepare material main body, PU layer that material main body includes from top to bottom setting gradually, transparent wear, the printing bed of material, packed layer, initial bed；It is provided with glass layer in described packed layer.Then coating organosilicon and polymerizable Abietyl modified acrylate tackifying resin on initial bed, thickness is 2mm, dries 7min, be then covered by release paper, obtain Dicoration base material in the environment of 105 DEG C.
Described organosilicon and polymerizable Abietyl modified acrylate tackifying resin are prepared by the following method and obtain:
1, self-control polymerizable Colophonium tackifying resin: join in reactor by the ethylene glycol monobutyl ether of the liquid rosin esters of 10 parts, the rosin glyceride of 9 parts and 8 parts, reacts 3 hours at 90 DEG C, obtains polymerizable Colophonium tackifying resin.
2, alkylphenol polyoxyethylene (op-10) 4 parts is added in the deionized water of 90 parts and stir, add 4 parts of self-controls polymerizable Colophonium tackifying resin, 145 parts of Isooctyl acrylate monomers, 5 parts of methyl methacrylates, 45 parts of 2-(Acryloyloxy)ethanols, 14 parts of methacrylic acids, 0.4 part of γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane, 0.9 part of aliphatic mercaptan, be uniformly mixing to obtain pre-emulsification emulsion.
3, the potassium bicarbonate of 0.9 part is dissolved in the deionized water of 120 parts, joins in reactor.Another configuration sodium peroxydisulfate 3.5 parts is dissolved in the deionized water of 50 parts, prepares initiator.When question response still is warming up to 78-82 DEG C, it is simultaneously added dropwise initiator and pre-emulsification emulsion, reacts 5 hours, after being added dropwise to complete, be warming up to 85-90 DEG C, be incubated 1.5 hours, cooling discharge.
Organosilicon and polymerizable Abietyl modified acrylate tackifying resin performance test:
Initial bonding strength: according to GB/T4852-2002 standard (A), uses initial bonding strength tester to measure.
Peel strength, tensile bond intensity: according to GB/T2792-1998 standard, JC/T550-2008 standard, use universal testing machine to measure.
Heat stability: after making model, places 72 hours under the conditions of 80 DEG C-90 DEG C continuously, glue phenomenon of overflowing does not occurs, i.e. shows that heat stability is good.
Properties of product are tested:
1, polymerizable Colophonium tackifying resin is on initial bonding strength, the impact of open hour
On the premise of the holding of other conditions is constant, the Different adding amount self-control initial bonding strength of glue of polymerizable Colophonium tackifying resin, the impact of open hour such as following table one in embodiment 1:
Table one
Other conditions keep constant on the premise of, the self-control polymerizable Colophonium tackifying resin in embodiment 1 is changed into glue initial bonding strength, the impact of open hour such as following table two after independent adding liquid rosin ester:
Table two
Other conditions keep constant on the premise of, the self-control polymerizable Colophonium tackifying resin in embodiment 1 is changed into individually adding glue initial bonding strength, the impact of open hour such as following table three after rosin glyceride:
Table three
By table one it can be seen that the glue initial bonding strength initial stage increases along with the addition of tackifying resin and increases, and along with the addition of tackifying resin increases to certain phase, the vitrification point of glue itself gradually reduces, and initial bonding strength reduces therewith.Addition is when 3-6, and initial bonding strength and open hour keep comparing equilibrium.
By table two and three it can be seen that the tackifying resin initial bonding strength performance of adding liquid rosin ester is better than adding the tackifying resin of rosin glyceride.
By table one, table two and three it can be seen that the tackifying resin initial bonding strength performance adding self-control polymerizable Colophonium tackifying resin is better than adding liquid rosin ester and adds the tackifying resin of rosin glyceride.
2, polymerizable Colophonium tackifying resin is on adhesive force, peel strength, the impact of tensile bond intensity
On the premise of the holding of other conditions is constant, the Different adding amount self-control adhesive force of glue of polymerizable Colophonium tackifying resin, peel strength, the impact such as following table four of tensile bond intensity in embodiment 1:
Table four
Other conditions keep constant on the premise of, the self-control polymerizable Colophonium tackifying resin in embodiment 1 is changed into glue glue adhesive force, peel strength, the impact such as following table five of tensile bond intensity after independent adding liquid rosin ester:
Table five
Other conditions keep constant on the premise of, the self-control polymerizable Colophonium tackifying resin in embodiment 1 is changed into individually adding glue glue adhesive force, peel strength, the impact such as following table six of tensile bond intensity after rosin glyceride:
Table six
Be can be seen that by table four, increase along with the addition of tackifying resin, glue mobility is also being continuously increased, and glue peel strength, tensile bond intensity reduce afterwards along with the addition of tackifying resin increases first to increase, in the case of the addition of tackifying resin 3-6, peel strength and the performance of tensile bond intensity are preferably.
By table five and six it can be seen that after individually adding rosin glyceride glue glue adhesive force, peel strength, tensile bond intensity be better than the glue after independent adding liquid rosin ester.
3, organosilicon is on heat stability and the impact of residue
On the premise of the holding of other conditions is constant, in the case of having added 5g tackifying resin, the organosilicon of Different adding amount is on glue heat stability, residue, the impact such as following table seven of peel strength:
Table seven
By table seven it can be seen that glue residue increases along with the addition of organosilicon and increases, and along with the addition of organosilicon increases, the heat stability of glue itself is the best；But peel strength dies down on the contrary along with the amount of organosilicon increases.Addition is when 0.4-0.5, and properties keeps comparing equilibrium.
Be can be seen that by table one to seven and be polymerized and under the existence condition of the organosilicon of suitable ingredients by the self-control polymerizable Colophonium tackifying resin of active component, acrylic acid/ester monomer, the modification acrylate tackifying resin simultaneously improving the indexs such as initial bonding strength, open hour, adhesive force, peel strength, tensile bond intensity, heat stability can be prepared.
Using above-mentioned modification acrylate tackifying resin as after the mucigel of the present invention, it has good adhesive force, rippability, heat stability after being arranged on material main body.
Above-described only presently preferred embodiments of the present invention, all any amendment, equivalent and improvement etc. made in the range of the spirit and principles in the present invention, should be included within the scope of the present invention.

Claims (10)

1. the preparation method of a Dicoration base material, it is characterised in that described Dicoration base material includes material main body, described method For: Abietyl modified to organosilicon and polymerizable acrylate tackifying resin is coated in the bottom surface of material main body, then at 50-110 DEG C Environment in dry 2-10min, obtain bottom for the Dicoration base material of mucigel；
Described organosilicon and polymerizable Abietyl modified acrylate tackifying resin are prepared by following parts by weight of component:
Self-control polymerizable Colophonium tackifying resin 3-5 part, Isooctyl acrylate monomer 140-155 part, methyl methacrylate 5-8 part, third Olefin(e) acid hydroxyl ethyl ester 45-54 part, methacrylic acid 10-14 part, alkylphenol polyoxyethylene (op-10) 4-6 part, organosilicon 0.3-0.5 Part, buffer agent 0.9-1.1 part, inorganic initiator 3.5-4.5 part, chain-transferring agent 0.9-1.1 part, deionized water 240-260 part；
Wherein, self-control polymerizable Colophonium tackifying resin is prepared by the following method and obtains: by the liquid rosin ester of 7-10 part, 9-15 The rosin glyceride of part and the ethylene glycol monobutyl ether of 5-8 part join in reactor, react 2-3 hour, obtain at 85 DEG C-90 DEG C Polymerizable Colophonium tackifying resin.
The preparation method of Dicoration base material the most according to claim 1, it is characterised in that having of the bottom surface coating of material main body The thickness of machine silicon and polymerizable Abietyl modified acrylate tackifying resin is 0.05-2mm.
The preparation method of Dicoration base material the most according to claim 1, it is characterised in that described organosilicon is: γ-methyl Acryloxypropyl trimethoxy silane or γ-aminopropyltrimethoxysilane or γ-(2,3-epoxy the third oxygen) propyl group front three TMOS.
The preparation method of Dicoration base material the most according to claim 1, it is characterised in that described initiator is potassium peroxydisulfate Or sodium peroxydisulfate or Ammonium persulfate..
The preparation method of Dicoration base material the most according to claim 1, it is characterised in that described buffer agent be sodium bicarbonate, One in potassium bicarbonate.
The preparation method of Dicoration base material the most according to claim 1, it is characterised in that described chain-transferring agent is dodecane Base mercaptan or aliphatic mercaptan or isopropanol.
The preparation method of Dicoration base material the most according to claim 1, it is characterised in that described organosilicon and polymerizable pine Fragrant modification acrylate tackifying resin is prepared by the following method and obtains:
Alkylphenol polyoxyethylene (op-10) being added in the deionized water of 60-100 part and stir, adding self-control can gather Close Colophonium tackifying resin, Isooctyl acrylate monomer, methyl methacrylate, 2-(Acryloyloxy)ethanol, methacrylic acid, organosilicon, Chain-transferring agent, is uniformly mixing to obtain pre-emulsification emulsion；
Sodium bicarbonate is dissolved in the deionized water of 120-140 part, joins in reactor.Another configuration inorganic initiator is dissolved in 40-60 In the deionized water of part, prepare initiator solution, when question response still is warming up to 78-82 DEG C, be simultaneously added dropwise initiator solution and pre-breast Change emulsion, react 3-5 hour, after being added dropwise to complete, be warming up to 85-90 DEG C, after insulation a period of time, cooling discharge.
The preparation method of Dicoration base material the most according to claim 1, it is characterised in that described material main body includes by upper The PU layer that sets gradually under and, transparent wear, the printing bed of material, packed layer, initial bed, be provided with glass in described packed layer Glass fibrous layer.
The preparation method of Dicoration base material the most according to claim 1, it is characterised in that described method is additionally included in viscose One layer of release paper of bottom surface laminating of layer, obtains Dicoration base material；
Described Dicoration base material is sheet material or coiled material.
10. a Dicoration base material, it is characterised in that prepared by the arbitrary described method of claim 1 to 9.
CN201610380603.8A 2016-05-31 2016-05-31 A kind of Dicoration base material and preparation method thereof Active CN106010332B (en)

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CN108198869A (en) * 2017-12-06 2018-06-22 中国乐凯集团有限公司 A kind of flexible solar battery encapsulating film
CN109438617A (en) * 2018-12-15 2019-03-08 深圳市益达兴科技股份有限公司 Height with rosin based tackifying monomer just glues development of Acrylate Emulsion Pressure-Sensitive Adhesive and preparation method thereof
CN113322018A (en) * 2021-05-26 2021-08-31 上海亥博胶粘材料有限公司 Adhesive tape with reliability-enhancing adhesive and application method
CN114250037A (en) * 2021-11-22 2022-03-29 田祝英 Wear-resistant and aging-resistant decorative material and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108198869A (en) * 2017-12-06 2018-06-22 中国乐凯集团有限公司 A kind of flexible solar battery encapsulating film
CN109438617A (en) * 2018-12-15 2019-03-08 深圳市益达兴科技股份有限公司 Height with rosin based tackifying monomer just glues development of Acrylate Emulsion Pressure-Sensitive Adhesive and preparation method thereof
CN109438617B (en) * 2018-12-15 2020-10-27 深圳市益达兴科技股份有限公司 High initial viscosity emulsion type acrylate pressure-sensitive adhesive with rosin-based viscous monomer and preparation method thereof
CN113322018A (en) * 2021-05-26 2021-08-31 上海亥博胶粘材料有限公司 Adhesive tape with reliability-enhancing adhesive and application method
CN114250037A (en) * 2021-11-22 2022-03-29 田祝英 Wear-resistant and aging-resistant decorative material and preparation method thereof

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