CN114250037A - Wear-resistant and aging-resistant decorative material and preparation method thereof - Google Patents
Wear-resistant and aging-resistant decorative material and preparation method thereof Download PDFInfo
- Publication number
- CN114250037A CN114250037A CN202111385759.2A CN202111385759A CN114250037A CN 114250037 A CN114250037 A CN 114250037A CN 202111385759 A CN202111385759 A CN 202111385759A CN 114250037 A CN114250037 A CN 114250037A
- Authority
- CN
- China
- Prior art keywords
- resistant
- wear
- aging
- parts
- decorative material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 65
- 230000032683 aging Effects 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000010410 layer Substances 0.000 claims abstract description 82
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 54
- WRQUOKZRJAVFGC-UHFFFAOYSA-N 4-ethenyl-2,8-bis(trifluoromethyl)quinoline Chemical compound C1=CC=C(C(F)(F)F)C2=NC(C(F)(F)F)=CC(C=C)=C21 WRQUOKZRJAVFGC-UHFFFAOYSA-N 0.000 claims abstract description 34
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229920001577 copolymer Polymers 0.000 claims abstract description 16
- 239000003999 initiator Substances 0.000 claims abstract description 16
- 239000004743 Polypropylene Substances 0.000 claims abstract description 14
- -1 polypropylene Polymers 0.000 claims abstract description 14
- 229920001155 polypropylene Polymers 0.000 claims abstract description 14
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims abstract description 13
- BRTALTYTFFNPAC-UHFFFAOYSA-N boroxin Chemical compound B1OBOBO1 BRTALTYTFFNPAC-UHFFFAOYSA-N 0.000 claims abstract description 11
- ZKVGXVGEPRBBQV-UHFFFAOYSA-N CN1C(NC(N(C1=O)CC=C)=O)=O.C1CO1 Chemical compound CN1C(NC(N(C1=O)CC=C)=O)=O.C1CO1 ZKVGXVGEPRBBQV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 25
- 239000002904 solvent Substances 0.000 claims description 21
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 19
- NADYEWVQIJRXJM-UHFFFAOYSA-N 1,3-bis(oxiran-2-ylmethyl)-5-prop-2-enyl-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC=C)C(=O)N1CC1CO1 NADYEWVQIJRXJM-UHFFFAOYSA-N 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 14
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 14
- 239000011261 inert gas Substances 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 10
- 238000005299 abrasion Methods 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- SHBZGQGJTNGCBL-UHFFFAOYSA-N 1-(oxiran-2-ylmethyl)-3-prop-2-enyl-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC=C)C(=O)NC(=O)N1CC1OC1 SHBZGQGJTNGCBL-UHFFFAOYSA-N 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000012298 atmosphere Substances 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 7
- 238000003490 calendering Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 230000001376 precipitating effect Effects 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000001291 vacuum drying Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 229910052593 corundum Inorganic materials 0.000 claims description 4
- 239000010431 corundum Substances 0.000 claims description 4
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 4
- 229910052863 mullite Inorganic materials 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000001307 helium Substances 0.000 claims description 3
- 229910052734 helium Inorganic materials 0.000 claims description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052754 neon Inorganic materials 0.000 claims description 3
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 239000012752 auxiliary agent Substances 0.000 description 12
- 230000003712 anti-aging effect Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 3
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/08—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F271/00—Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00
- C08F271/02—Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00 on to polymers of monomers containing heterocyclic nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2451/00—Presence of graft polymer
- C09J2451/006—Presence of graft polymer in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a wear-resistant and aging-resistant decorative material which is characterized by sequentially comprising a release film layer, a pressure-sensitive adhesive layer and a functional film layer from top to bottom; the functional film layer is prepared from the following components in parts by weight: 50-60 parts of hyperbranched polypropylene, 20-30 parts of 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (ethylene oxide methyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer, 2-4 parts of poly-4-methylpentene, 3-5 parts of 2,4, 6-trivinyl boroxine, 8-12 parts of wear-resistant additive and 0.8-1.2 parts of initiator. The invention also discloses a preparation method of the wear-resistant and aging-resistant decorative material. The wear-resistant and aging-resistant decorative material disclosed by the invention has the advantages of sufficient wear-resistant and aging-resistant performance, good flame retardance and mechanical properties, good weather resistance and good decorative effect.
Description
Technical Field
The invention relates to the technical field of decorative materials, in particular to a wear-resistant and aging-resistant decorative material and a preparation method thereof.
Background
With the improvement of living standard of people, the decoration requirement on living environment is more and more, and the performance requirement on the decoration material is higher and higher. The ideal decorative material not only plays a role in decoration protection, but also needs to be wear-resistant, ageing-resistant, ultraviolet-proof and environment-friendly, so that the appearance of the product can be effectively improved, the aesthetic feeling is brought to people, the aesthetic comfort degree of people is improved, the personalized requirements of people on the decorative material are met, the service life of the decorative material is prolonged, and the cost is reduced.
The existing decorative materials are numerous, wherein the most common decorative material is a PVC (polyvinyl chloride) film material, the weather resistance and the high-temperature resistance of the material need to be further improved, the surface smoothness and the gloss are insufficient, the hand feeling of the surface of the film is rough, the environmental protection performance is poor, and the decorative effect is limited. Other decorative materials also have the defects of insufficient aging resistance, scratch resistance, abrasion resistance and dirt resistance, short service life and poor flame retardance.
In order to solve the above problems, chinese invention patent CN102617930B discloses an automobile decorative material and a manufacturing method thereof, wherein the decorative material comprises the following raw materials in parts by weight: 65-75 parts of polypropylene resin, 5-25 parts of thermoplastic polyurethane resin, 3-6 parts of nano titanium dioxide, 10-15 parts of toughening agent, 5-10 parts of nucleating agent, 5-10 parts of grafting compatilizer, 0.4-0.6 part of compound stabilizer and 0.3-0.7 part of coupling agent. Relates to a formula design of scratch resistance, wear resistance, dirt resistance, no peculiar smell, aging resistance and molding processability, and meets the aims of high requirements and low price of people for automotive interior trim. However, the flame retardancy and the performance stability are poor, and the mechanical properties, the wear resistance and the aging resistance are required to be further improved.
Therefore, it is necessary to find a more effective method for preparing a wear-resistant and aging-resistant decorative material with sufficient wear-resistant and aging-resistant properties, good flame retardance and mechanical properties, good weather resistance and good decorative effect.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides a wear-resistant and aging-resistant decorative material which has the advantages of sufficient wear-resistant and aging-resistant performance, good flame retardance and mechanical properties, good weather resistance, good decorative effect and good environmental protection, and a preparation method thereof.
The technical scheme adopted by the invention for solving the technical problem is as follows: the wear-resistant and aging-resistant decorative material is characterized by sequentially comprising a release film layer, a pressure-sensitive adhesive layer and a functional film layer from top to bottom; the functional film layer is prepared from the following components in parts by weight: 50-60 parts of hyperbranched polypropylene, 20-30 parts of 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (ethylene oxide methyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer, 2-4 parts of poly-4-methylpentene, 3-5 parts of 2,4, 6-trivinyl boroxine, 8-12 parts of wear-resistant additive and 0.8-1.2 parts of initiator.
Preferably, the release film layer is made of a release film, and the release film is any one of a PC release film, a PE release film, a PET release film and a PMMA release film; and the release film is coated with a low-silicon release agent.
Preferably, the pressure-sensitive adhesive layer is made of a pressure-sensitive adhesive, and the pressure-sensitive adhesive is at least one of a German Hehan high acrylic pressure-sensitive adhesive DURO-TAK8604-2, a KL-6600 organosilicon pressure-sensitive adhesive and a rubber pressure-sensitive adhesive HX 6012.
Preferably, the source of the hyperbranched polypropylene has no special requirement, and in one embodiment of the present invention, the hyperbranched polypropylene is prepared by the method in embodiment 1 of chinese patent CN 107187153B.
Preferably, the preparation method of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyltrimethoxysilane copolymer comprises the following steps: adding 4-vinyl-2, 8-bis (trifluoromethyl) quinoline (CAS:1031928-53-6), N-vinylcarbazole, 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, vinyltrimethoxysilane and azodiisobutyronitrile into a high-boiling-point solvent, stirring and reacting for 4-6 hours at 65-75 ℃ under an inert gas atmosphere, then precipitating in water, washing the precipitated polymer for 3-6 times by using ethanol, and finally drying in a vacuum drying oven at 80-90 ℃ to constant weight.
Preferably, the mass ratio of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline, the N-vinylcarbazole, the 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, the vinyltrimethoxysilane, the azobisisobutyronitrile and the high-boiling-point solvent is 1 (1-2): 0.3-0.5):0.4 (0.03-0.05): 9-15.
Preferably, the high boiling point solvent is at least one of dimethyl sulfoxide, N-dimethylformamide and N-methylpyrrolidone; the inert gas is any one of nitrogen, helium, neon and argon.
Preferably, the poly-4-methyl-1-pentene is
MX004。
Preferably, the wear-resistant auxiliary agent is at least one of corundum powder, graphene, mullite, silicon carbide and silicon nitride.
Preferably, the particle size of the wear-resistant additive is 1000-1200 meshes.
Preferably, the initiator is at least one of di-tert-butyl peroxide, cumene hydroperoxide and tert-butyl peroxybenzoate.
The invention also aims to provide a preparation method of the wear-resistant and aging-resistant decorative material, which is characterized by comprising the following steps: uniformly mixing the components in parts by weight, adding the mixture into a double-screw extruder, melting the mixture at the temperature of 190-220 ℃, and sequentially passing the mixture through a clothes hanger type T-die, a chrome-plated calendering roller and a drying roller to obtain a functional film layer; forming a pressure-sensitive adhesive layer on the upper surface of the functional film layer; and then, a release film layer is attached to the pressure-sensitive adhesive layer to obtain the wear-resistant and aging-resistant decorative material.
Adopt the produced beneficial effect of above-mentioned technical scheme to lie in:
(1) the preparation method of the wear-resistant and aging-resistant decorative material provided by the invention is simple, convenient to operate and control, small in equipment dependence, low in energy consumption, low in capital investment, high in preparation efficiency and finished product qualification rate, and capable of simultaneously realizing better economic benefits, social benefits and ecological benefits.
(2) According to the wear-resistant anti-aging decorative material provided by the invention, the components of the functional film layer interact with each other and act synergistically, so that the prepared decorative material has the advantages of sufficient wear-resistant anti-aging performance, good flame retardance and mechanical properties, good weather resistance, good decorative effect and good environmental friendliness; in the melt processing process, under the initiation action of an initiator, vinyl on the vinyl-containing 2,4, 6-trivinyl boroxine can perform copolymerization grafting reaction with polyolefin main chains such as hyperbranched polypropylene, 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer and poly-4-methylpentene to form an interpenetrating network structure, so that the performances can be effectively improved, the prepared material has better comprehensive performance and performance stability, better durability and longer service life.
(3) According to the wear-resistant anti-aging decorative material provided by the invention, through mutual matching and combined action of the components, fluorine-containing quinoline, carbazole, triazone and boroxine structures are simultaneously introduced into a molecular chain of the decorative material, and under multiple actions of an electronic effect, a steric effect, a conjugate effect and the like, the wear resistance and the anti-aging performance of the material can be effectively improved, and the mechanical property, the flame retardance and the weather resistance of the material are improved; the polypropylene with the hyperbranched structure can improve the toughness of the material, and the poly-4-methylpentene can improve the adhesive force between the decorative material and the base material, thereby effectively prolonging the service life of the decorative material.
Detailed Description
In order to make the technical solutions of the present invention better understood and make the above features, objects, and advantages of the present invention more comprehensible, the present invention is further described with reference to the following examples. The examples are intended to illustrate the invention only and are not intended to limit the scope of the invention; the poly-4-methyl-1-pentene in the examples is
MX 004; the hyperbranched polypropylene is a product of Chinese invention patentCN107187153B prepared by the method in example 1.
Example 1
The wear-resistant and aging-resistant decorative material is characterized by sequentially comprising a release film layer, a pressure-sensitive adhesive layer and a functional film layer from top to bottom; the functional film layer is prepared from the following components in parts by weight: 50 parts of hyperbranched polypropylene, 20 parts of 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (ethylene oxide methyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer, 2 parts of poly-4-methylpentene, 3 parts of 2,4, 6-trivinyl boroxine, 8 parts of wear-resistant auxiliary agent and 0.8 part of initiator.
The release film layer is made of a release film, and the release film is a PC release film; and the release film is coated with a low-silicon release agent.
The pressure-sensitive adhesive layer is made of a pressure-sensitive adhesive, and the pressure-sensitive adhesive is a German Han high acrylic pressure-sensitive adhesive DURO-TAK 8604-2.
The preparation method of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer comprises the following steps: adding 4-vinyl-2, 8-bis (trifluoromethyl) quinoline, N-vinylcarbazole, 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, vinyltrimethoxysilane and azodiisobutyronitrile into a high-boiling-point solvent, stirring and reacting for 4 hours at 65 ℃ in an inert gas atmosphere, precipitating in water, washing the precipitated polymer for 3 times by using ethanol, and finally drying the polymer in a vacuum drying oven at 80 ℃ to constant weight; the mass ratio of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline to the N-vinylcarbazole to the 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione to the vinyltrimethoxysilane to the azodiisobutyronitrile to the high-boiling-point solvent is 1:1:0.3:0.4:0.03: 9; the high boiling point solvent is dimethyl sulfoxide; the inert gas is nitrogen.
The wear-resistant auxiliary agent is corundum powder; the particle size of the wear-resistant auxiliary agent is 1000 meshes; the initiator is di-tert-butyl peroxide.
The preparation method of the wear-resistant and aging-resistant decorative material is characterized by comprising the following steps: uniformly mixing the components in parts by weight, adding the mixture into a double-screw extruder, melting the mixture at 190 ℃, and sequentially passing the mixture through a coat hanger type T-die, a chrome-plated calendering roller and a drying roller to obtain a functional film layer; forming a pressure-sensitive adhesive layer on the upper surface of the functional film layer; and then, a release film layer is attached to the pressure-sensitive adhesive layer to obtain the wear-resistant and aging-resistant decorative material.
Example 2
The wear-resistant and aging-resistant decorative material is characterized by sequentially comprising a release film layer, a pressure-sensitive adhesive layer and a functional film layer from top to bottom; the functional film layer is prepared from the following components in parts by weight: 53 parts of hyperbranched polypropylene, 22 parts of 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (ethylene oxide methyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer, 2.5 parts of poly-4-methylpentene, 3.5 parts of 2,4, 6-trivinyl boroxine, 9 parts of an abrasion-resistant assistant and 0.9 part of an initiator.
The release film layer is made of a release film, and the release film is a PE release film; coating a low-silicon release agent on the release film; the pressure-sensitive adhesive layer is made of a pressure-sensitive adhesive, and the pressure-sensitive adhesive is a KL-6600 organic silicon pressure-sensitive adhesive.
The preparation method of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer comprises the following steps: adding 4-vinyl-2, 8-bis (trifluoromethyl) quinoline, N-vinylcarbazole, 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, vinyltrimethoxysilane and azodiisobutyronitrile into a high-boiling-point solvent, stirring and reacting for 4.5 hours at 67 ℃ in an inert gas atmosphere, then precipitating in water, washing the precipitated polymer for 4 times by using ethanol, and finally drying in a vacuum drying oven at 83 ℃ to constant weight; the mass ratio of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline to the N-vinylcarbazole to the 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione to the vinyltrimethoxysilane to the azobisisobutyronitrile to the high-boiling-point solvent is 1:1.3:0.35:0.4:0.035: 11; the high boiling point solvent is N, N-dimethylformamide; the inert gas is helium.
The wear-resistant auxiliary agent is graphene; the particle size of the wear-resistant auxiliary agent is 1050 meshes; the initiator is tert-butyl peroxybenzoate.
The preparation method of the wear-resistant and aging-resistant decorative material is characterized by comprising the following steps: uniformly mixing the components in parts by weight, adding the mixture into a double-screw extruder, melting the mixture at the temperature of 200 ℃, and sequentially passing the mixture through a clothes-hanger type T-die, a chrome-plated calendering roller and a drying roller to obtain a functional film layer; forming a pressure-sensitive adhesive layer on the upper surface of the functional film layer; and then, a release film layer is attached to the pressure-sensitive adhesive layer to obtain the wear-resistant and aging-resistant decorative material.
Example 3
The wear-resistant and aging-resistant decorative material is characterized by sequentially comprising a release film layer, a pressure-sensitive adhesive layer and a functional film layer from top to bottom; the functional film layer is prepared from the following components in parts by weight: 55 parts of hyperbranched polypropylene, 25 parts of 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (ethylene oxide methyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer, 3 parts of poly-4-methylpentene, 4 parts of 2,4, 6-trivinyl boroxine, 10 parts of an abrasion-resistant assistant and 1 part of an initiator.
The release film layer is made of a release film, and the release film is a PET release film; coating a low-silicon release agent on the release film; the pressure-sensitive adhesive layer is made of a pressure-sensitive adhesive, and the pressure-sensitive adhesive is rubber pressure-sensitive adhesive HX 6012.
The preparation method of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer comprises the following steps: adding 4-vinyl-2, 8-bis (trifluoromethyl) quinoline, N-vinylcarbazole, 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, vinyltrimethoxysilane and azodiisobutyronitrile into a high-boiling-point solvent, stirring and reacting for 5 hours at 70 ℃ in an inert gas atmosphere, then precipitating in water, washing the precipitated polymer for 5 times by using ethanol, and finally drying in a vacuum drying oven at 85 ℃ to constant weight; the mass ratio of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline to the N-vinylcarbazole to the 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione to the vinyltrimethoxysilane to the azobisisobutyronitrile to the high-boiling-point solvent is 1:1.5:0.4:0.4:0.04: 12; the high boiling point solvent is N-methyl pyrrolidone; the inert gas is neon.
The wear-resistant auxiliary agent is mullite; the particle size of the wear-resistant auxiliary agent is 1100 meshes; the initiator is cumene hydroperoxide.
The preparation method of the wear-resistant and aging-resistant decorative material is characterized by comprising the following steps: uniformly mixing the components in parts by weight, adding the mixture into a double-screw extruder, melting the mixture at 205 ℃, and sequentially passing the mixture through a coat hanger type T-die, a chrome-plated calendering roller and a drying roller to obtain a functional film layer; forming a pressure-sensitive adhesive layer on the upper surface of the functional film layer; and then, a release film layer is attached to the pressure-sensitive adhesive layer to obtain the wear-resistant and aging-resistant decorative material.
Example 4
The wear-resistant and aging-resistant decorative material is characterized by sequentially comprising a release film layer, a pressure-sensitive adhesive layer and a functional film layer from top to bottom; the functional film layer is prepared from the following components in parts by weight: 58 parts of hyperbranched polypropylene, 28 parts of 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (ethylene oxide methyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer, 3.5 parts of poly-4-methylpentene, 4.5 parts of 2,4, 6-trivinyl boroxine, 11 parts of wear-resistant assistant and 1.1 parts of initiator.
The release film layer is made of a release film, and the release film is a PMMA release film; coating a low-silicon release agent on the release film; the pressure-sensitive adhesive layer is made of a pressure-sensitive adhesive, and the pressure-sensitive adhesive is a German Han high acrylic pressure-sensitive adhesive DURO-TAK 8604-2.
The preparation method of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer comprises the following steps: adding 4-vinyl-2, 8-bis (trifluoromethyl) quinoline, N-vinylcarbazole, 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, vinyltrimethoxysilane and azodiisobutyronitrile into a high-boiling-point solvent, stirring and reacting for 5.5 hours at 73 ℃ in an inert gas atmosphere, then precipitating in water, washing the precipitated polymer for 5 times by using ethanol, and finally drying in a vacuum drying oven at 88 ℃ to constant weight; the mass ratio of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline to the N-vinylcarbazole to the 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione to the vinyltrimethoxysilane to the azodiisobutyronitrile to the high-boiling-point solvent is 1:1.8:0.45:0.4:0.045: 14; the high-boiling-point solvent is a mixture formed by mixing dimethyl sulfoxide, N-dimethylformamide and N-methylpyrrolidone according to the mass ratio of 1:3: 5; the inert gas is argon.
The wear-resistant auxiliary agent is a mixture formed by mixing corundum powder, graphene, mullite, silicon carbide and silicon nitride according to a mass ratio of 1:1:3:2: 3; the particle size of the wear-resistant additive is 1150 meshes; the initiator is a mixture formed by mixing di-tert-butyl peroxide, cumene hydroperoxide and tert-butyl peroxybenzoate according to a mass ratio of 1:3: 5.
The preparation method of the wear-resistant and aging-resistant decorative material is characterized by comprising the following steps: uniformly mixing the components in parts by weight, adding the mixture into a double-screw extruder, melting the mixture at 210 ℃, and sequentially passing the mixture through a clothes-hanger-type T-die, a chrome-plated calendering roller and a drying roller to obtain a functional film layer; forming a pressure-sensitive adhesive layer on the upper surface of the functional film layer; and then, a release film layer is attached to the pressure-sensitive adhesive layer to obtain the wear-resistant and aging-resistant decorative material.
Example 5
The wear-resistant and aging-resistant decorative material is characterized by sequentially comprising a release film layer, a pressure-sensitive adhesive layer and a functional film layer from top to bottom; the functional film layer is prepared from the following components in parts by weight: 60 parts of hyperbranched polypropylene, 30 parts of 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (ethylene oxide methyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer, 4 parts of poly-4-methylpentene, 5 parts of 2,4, 6-trivinyl boroxine, 12 parts of wear-resistant auxiliary agent and 1.2 parts of initiator.
The release film layer is made of a release film, and the release film is a PC release film; coating a low-silicon release agent on the release film; the pressure-sensitive adhesive layer is made of a pressure-sensitive adhesive, and the pressure-sensitive adhesive is a KL-6600 organic silicon pressure-sensitive adhesive.
The preparation method of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer comprises the following steps: adding 4-vinyl-2, 8-bis (trifluoromethyl) quinoline, N-vinylcarbazole, 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, vinyltrimethoxysilane and azodiisobutyronitrile into a high-boiling-point solvent, stirring and reacting for 6 hours at 75 ℃ in an inert gas atmosphere, precipitating in water, washing the precipitated polymer for 6 times by using ethanol, and finally drying the polymer in a vacuum drying oven at 90 ℃ to constant weight; the mass ratio of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline to the N-vinylcarbazole to the 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione to the vinyltrimethoxysilane to the azobisisobutyronitrile to the high-boiling-point solvent is 1:2:0.5:0.4:0.05: 15; the high boiling point solvent is dimethyl sulfoxide; the inert gas is nitrogen.
The wear-resistant auxiliary agent is silicon carbide; the particle size of the wear-resistant auxiliary agent is 1200 meshes; the initiator is di-tert-butyl peroxide.
The preparation method of the wear-resistant and aging-resistant decorative material is characterized by comprising the following steps: uniformly mixing the components in parts by weight, adding the mixture into a double-screw extruder, melting the mixture at 220 ℃, and sequentially passing the mixture through a coat hanger type T-die, a chrome-plated calendering roller and a drying roller to obtain a functional film layer; forming a pressure-sensitive adhesive layer on the upper surface of the functional film layer; and then, a release film layer is attached to the pressure-sensitive adhesive layer to obtain the wear-resistant and aging-resistant decorative material.
Comparative example 1
The formula and the preparation method of the wear-resistant and aging-resistant decorative material are basically the same as those in example 1, except that 2,4, 6-trivinyl boroxine is not added.
Comparative example 2
A wear-resistant and aging-resistant decorative material, whose formulation and preparation method are substantially the same as those of example 1, except that 4-vinyl-2, 8-bis (trifluoromethyl) quinoline (CAS:1031928-53-6) is not added.
The wear-resistant and aging-resistant decorative material samples described in examples 1 to 5 and comparative examples 1 to 2 were subjected to performance tests, the test results are shown in table 1, and the test methods are as follows: the abrasion resistance was measured in terms of abrasion loss and was measured with reference to CN 102124056B, specifically, according to ASTM D4060, a 10cm × 10cm sample and two circular aluminum pieces having a diameter of 5cm were prepared, and then the abrasion loss was measured by a Taber abrasion tester at a rotation speed of 90rpm and 10,000 cycles of abrasion; the aging resistance test is measured by the retention rate of tensile strength after the sample is placed in a heat aging box at 90 ℃ for 96 hours; tensile strength was tested according to GB/T1040-2018. Limiting oxygen index was performed according to GB/T2406-1993.
TABLE 1
As can be seen from table 1, the wear-resistant and aging-resistant decorative material disclosed in the embodiment of the present invention has better and excellent wear resistance, mechanical properties, aging resistance and flame retardancy compared with the comparative product, which is a result of the synergistic effect of the components.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are merely illustrative of the principles of the invention, but that various changes and modifications may be made without departing from the spirit and scope of the invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (10)
1. The wear-resistant and aging-resistant decorative material is characterized by sequentially comprising a release film layer, a pressure-sensitive adhesive layer and a functional film layer from top to bottom; the functional film layer is prepared from the following components in parts by weight: 50-60 parts of hyperbranched polypropylene, 20-30 parts of 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (ethylene oxide methyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyl trimethoxy silane copolymer, 2-4 parts of poly-4-methylpentene, 3-5 parts of 2,4, 6-trivinyl boroxine, 8-12 parts of wear-resistant additive and 0.8-1.2 parts of initiator.
2. The wear-resistant and aging-resistant decorating material as claimed in claim 1, wherein the release film layer is made of a release film, and the release film is any one of a PC release film, a PE release film, a PET release film and a PMMA release film; and the release film is coated with a low-silicon release agent.
3. A wear-resistant and aging-resistant decorative material as claimed in claim 1, wherein said pressure-sensitive adhesive layer is made of pressure-sensitive adhesive, said pressure-sensitive adhesive is at least one of german han acrylic pressure-sensitive adhesive DURO-TAK8604-2, KL-6600 silicone pressure-sensitive adhesive, rubber pressure-sensitive adhesive HX 6012.
4. The wear-resistant and aging-resistant decorative material of claim 1, wherein the preparation method of the 4-vinyl-2, 8-bis (trifluoromethyl) quinoline/N-vinylcarbazole/1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione/vinyltrimethoxysilane copolymer comprises the following steps: adding 4-vinyl-2, 8-bis (trifluoromethyl) quinoline (CAS:1031928-53-6), N-vinylcarbazole, 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, vinyltrimethoxysilane and azodiisobutyronitrile into a high-boiling-point solvent, stirring and reacting for 4-6 hours at 65-75 ℃ under an inert gas atmosphere, then precipitating in water, washing the precipitated polymer for 3-6 times by using ethanol, and finally drying in a vacuum drying oven at 80-90 ℃ to constant weight.
5. A wear-resistant and aging-resistant decorative material as set forth in claim 4, wherein the mass ratio of 4-vinyl-2, 8-bis (trifluoromethyl) quinoline, N-vinylcarbazole, 1, 3-bis (oxiranylmethyl) -5- (2-propenyl) -1,3, 5-triazine-2, 4,6(1H,3H,5H) -trione, vinyltrimethoxysilane, azobisisobutyronitrile and high-boiling solvent is 1 (1-2): 0.3-0.5):0.4 (0.03-0.05): 9-15.
6. A wear-resistant and aging-resistant decorative material according to claim 4, wherein said high boiling point solvent is at least one of dimethylsulfoxide, N-dimethylformamide, N-methylpyrrolidone; the inert gas is any one of nitrogen, helium, neon and argon.
7. A wear and aging resistant decorative material as claimed in claim 1, wherein said poly-4-methyl-1-pentene is
MX004。
8. A wear-resistant and aging-resistant decorative material as claimed in claim 1, wherein the wear-resistant auxiliary is at least one of corundum powder, graphene, mullite, silicon carbide and silicon nitride; the particle size of the wear-resistant additive is 1000-1200 meshes.
9. An abrasion and aging resistant decorative material as set forth in claim 1, wherein said initiator is at least one of di-t-butyl peroxide, cumene hydroperoxide and t-butyl peroxybenzoate.
10. A method for preparing a wear-resistant and ageing-resistant decorative material according to any one of claims 1 to 9, comprising the steps of: uniformly mixing the components in parts by weight, adding the mixture into a double-screw extruder, melting the mixture at the temperature of 190-220 ℃, and sequentially passing the mixture through a clothes hanger type T-die, a chrome-plated calendering roller and a drying roller to obtain a functional film layer; forming a pressure-sensitive adhesive layer on the upper surface of the functional film layer; and then, a release film layer is attached to the pressure-sensitive adhesive layer to obtain the wear-resistant and aging-resistant decorative material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111385759.2A CN114250037A (en) | 2021-11-22 | 2021-11-22 | Wear-resistant and aging-resistant decorative material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111385759.2A CN114250037A (en) | 2021-11-22 | 2021-11-22 | Wear-resistant and aging-resistant decorative material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114250037A true CN114250037A (en) | 2022-03-29 |
Family
ID=80792815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111385759.2A Pending CN114250037A (en) | 2021-11-22 | 2021-11-22 | Wear-resistant and aging-resistant decorative material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114250037A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116655327A (en) * | 2023-06-07 | 2023-08-29 | 湖南省勘测设计院有限公司 | High-strength waterproof concrete and preparation method thereof |
| CN115926480B (en) * | 2023-01-09 | 2023-09-29 | 江苏众成羽绒科技有限公司 | Down composite thermal insulation material and preparation method thereof |
| CN118218597A (en) * | 2024-03-24 | 2024-06-21 | 扬州宏佳新材料有限公司 | Compression-resistant powder metallurgy gear and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617930A (en) * | 2012-03-23 | 2012-08-01 | 重庆嘉良塑胶制品有限责任公司 | Decorative material for automobiles and manufacturing method for decorative material |
| CN106010332A (en) * | 2016-05-31 | 2016-10-12 | 清远市快地新型建材有限公司 | Decorative base material and preparation method thereof |
| CN110181896A (en) * | 2019-06-12 | 2019-08-30 | 湖南七纬科技有限公司 | A kind of decoration membrane material and preparation method thereof |
| CN209780089U (en) * | 2019-01-28 | 2019-12-13 | 深圳恩特材料科技有限公司 | Decorative paster |
| CN111234380A (en) * | 2020-03-16 | 2020-06-05 | 刘超 | Environment-friendly automotive interior composite material and preparation method thereof |
| CN111303607A (en) * | 2020-02-23 | 2020-06-19 | 邓华斌 | Wear-resistant high-temperature-resistant high-strength composite material |
| CN112194900A (en) * | 2020-10-12 | 2021-01-08 | 合肥坤擎机械科技有限公司 | Silicon rubber mold for integral molding of composite skirt and preparation method thereof |
| CN112538263A (en) * | 2020-11-04 | 2021-03-23 | 泗县硕友机电设备有限公司 | High-weather-resistance environment-friendly high polymer material and preparation method thereof |
| CN113004818A (en) * | 2021-04-01 | 2021-06-22 | 大正新型材料(肇庆)有限公司 | Self-adhesion type polypropylene decoration film |
-
2021
- 2021-11-22 CN CN202111385759.2A patent/CN114250037A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617930A (en) * | 2012-03-23 | 2012-08-01 | 重庆嘉良塑胶制品有限责任公司 | Decorative material for automobiles and manufacturing method for decorative material |
| CN106010332A (en) * | 2016-05-31 | 2016-10-12 | 清远市快地新型建材有限公司 | Decorative base material and preparation method thereof |
| CN209780089U (en) * | 2019-01-28 | 2019-12-13 | 深圳恩特材料科技有限公司 | Decorative paster |
| CN110181896A (en) * | 2019-06-12 | 2019-08-30 | 湖南七纬科技有限公司 | A kind of decoration membrane material and preparation method thereof |
| CN111303607A (en) * | 2020-02-23 | 2020-06-19 | 邓华斌 | Wear-resistant high-temperature-resistant high-strength composite material |
| CN111234380A (en) * | 2020-03-16 | 2020-06-05 | 刘超 | Environment-friendly automotive interior composite material and preparation method thereof |
| CN112194900A (en) * | 2020-10-12 | 2021-01-08 | 合肥坤擎机械科技有限公司 | Silicon rubber mold for integral molding of composite skirt and preparation method thereof |
| CN112538263A (en) * | 2020-11-04 | 2021-03-23 | 泗县硕友机电设备有限公司 | High-weather-resistance environment-friendly high polymer material and preparation method thereof |
| CN113004818A (en) * | 2021-04-01 | 2021-06-22 | 大正新型材料(肇庆)有限公司 | Self-adhesion type polypropylene decoration film |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115926480B (en) * | 2023-01-09 | 2023-09-29 | 江苏众成羽绒科技有限公司 | Down composite thermal insulation material and preparation method thereof |
| CN116655327A (en) * | 2023-06-07 | 2023-08-29 | 湖南省勘测设计院有限公司 | High-strength waterproof concrete and preparation method thereof |
| CN116655327B (en) * | 2023-06-07 | 2024-04-16 | 湖南省勘测设计院有限公司 | High-strength waterproof concrete and preparation method thereof |
| CN118218597A (en) * | 2024-03-24 | 2024-06-21 | 扬州宏佳新材料有限公司 | Compression-resistant powder metallurgy gear and preparation method thereof |
| CN118218597B (en) * | 2024-03-24 | 2024-09-10 | 扬州宏佳新材料有限公司 | Compression-resistant powder metallurgy gear and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN114250037A (en) | Wear-resistant and aging-resistant decorative material and preparation method thereof | |
| CN101768320B (en) | Heat-resisting ABS modified material and preparation method thereof for plating | |
| JP7122083B2 (en) | Thermoplastic resin composition containing silsesquioxane composite polymer | |
| CN108504089B (en) | High-strength wear-resistant plastic material and preparation method thereof | |
| CN1198451A (en) | Laminated sheet material or laminated film and moulded products thereof | |
| JP2013537252A (en) | Weather-resistant dyed molded body with improved gloss and abrasion resistance | |
| TW200902621A (en) | Moulding compositions for matt polyacrylate mouldings | |
| TW200909506A (en) | Resinous compositions and articles made therefrom | |
| EP3130637B1 (en) | Acrylic resin composition, acrylic resin film, and molded body | |
| CN108699315B (en) | Thermoplastic resin composition, method for preparing the same, and molded article prepared using the same | |
| JPWO2014162868A1 (en) | Aqueous surface treatment agent and article using the same | |
| TW200902623A (en) | Moulding compositions for matt PMMI mouldings | |
| CN112538263A (en) | High-weather-resistance environment-friendly high polymer material and preparation method thereof | |
| CN101525455B (en) | Resin combination and the products and method thereof | |
| WO2015058419A1 (en) | Environmentally friendly garment leather and preparation method thereof | |
| EP3700983A1 (en) | Tile containing primer coated substrates with good adhesion | |
| CN114381126A (en) | Organic silicon synthetic leather and preparation method thereof | |
| KR20050034605A (en) | Polyolefin powder, processes for making and using and slush molded articles made from the same | |
| CN104672756A (en) | ABS composite flame resistant material and preparation method thereof | |
| CN110863365B (en) | Lightweight flame-retardant organic silicon synthetic leather and preparation method thereof | |
| KR20020037752A (en) | Polymer compositions | |
| CN107641977A (en) | A kind of graphene glass wall base cloth and preparation method thereof | |
| CN101705620A (en) | Water-based PU bright surface brush clear varnish for synthetic leather | |
| CN106084571A (en) | A kind of embossing bronze printing polychlorovinyl sheet material and foaming method thereof | |
| CN114605575B (en) | Antibacterial acrylic plate and preparation method thereof and bathtub |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220329 |
|
| RJ01 | Rejection of invention patent application after publication |