CN106010065A - Surface treatment method for connecting device for modular buildings - Google Patents

Surface treatment method for connecting device for modular buildings Download PDF

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Publication number
CN106010065A
CN106010065A CN201610329368.1A CN201610329368A CN106010065A CN 106010065 A CN106010065 A CN 106010065A CN 201610329368 A CN201610329368 A CN 201610329368A CN 106010065 A CN106010065 A CN 106010065A
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attachment means
hours
silane coupling
coupling agent
modular architectural
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李海蓉
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BOCA HI-TECH PRECISION Ltd
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BOCA HI-TECH PRECISION Ltd
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Priority to CN201711092231.XA priority Critical patent/CN107828305A/en
Priority to CN201610329368.1A priority patent/CN106010065A/en
Publication of CN106010065A publication Critical patent/CN106010065A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/04—Anhydrides, e.g. cyclic anhydrides
    • C08F222/06—Maleic anhydride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/10—N-Vinyl-pyrrolidone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D135/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
    • C09D139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C09D139/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/38—Connections for building structures in general
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Electromagnetism (AREA)
  • Physics & Mathematics (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a surface treatment method for a connecting device for modular buildings. The method comprises the following steps: preparing a prepolymer from raw materials including acrylic acid, N-hydroxymethyl acrylamide, 1,4-cyclohexanedimethanol diacrylate, N-vinyl pyrrolidone, lauryl methacrylate, iso-tridecanol polyoxyethylene ether and resorcinol monobenzoate; preparing an adhesive from raw materials including 4,4'-di(trifluoromethoxy) azobenzene, dicumyl peroxide, tetraglycidyl ether tetraphenyl ethane, lauryl methacrylate, maleic anhydride and 4-dimethylaminopyridine; preparing primer from raw materials including hydroxyl silicon resin, dimethyl imidazole, solid amine, vinyl trimethoxy silane, copper phthalocyanine and vinyl cyclohexene dioxide; treating the connecting device and completing the surface treatment of the connecting device for the modular buildings.

Description

A kind of surface treatment method for modular architectural attachment means
Technical field
The present invention relates to body of wall equipment technical field, particularly relate to fill a kind of connection for modular architectural The surface treatment method put.
Background technology
Modular architectural is a kind of assembling technology, and it uses the most prefabricated modular structure, such as wall Body, is assembled into various house, and easy construction, assembling are flexibly.Modular structure is the most prefabricated, just In tissue industrialized production, improve work efficiency, reduce material consumption, little by seasonal effect.Modularity is built Build have that speed of application is fast, anti-seismic performance good, usable floor area is big, structural weight per square meter is light, easy construction, Assemble the features such as flexible, recruitment materials save, modular structure can design, therefore have in urban construction There is good using value.
One complete house, has the body of wall of load-bearing, girder construction and for connecting wall and elevator Between well, body of wall, the attachment means on body of wall and floor, it needs have high-strength tensile performance, with Time also need to have and dismount performance quickly and easily, the most quickly construct excellent meeting modular architectural Point.Steel are the main raw material(s)s preparing modular architectural attachment means, and it is processed, welding is the most square Just, it may have certain antirust function, but in each assembly junction still exist and lead because of getting rusty Cause to connect unstable situation, on the one hand have limitation due to the antirust ability of steel itself, be more mainly Because can destroy at two component touch steel surface process layer, such as install time or install after slightly During rolling dynamic friction, all contact surface can be caused interfacial failure.And it is not carried out by existing steel business Surface processes the ability of requirement meeting building module, specializes in what surface processed producer and lacks again machine The knowledge of tool configuration aspects, if using the raw material of higher level, then cost is the highest, it is impossible to throw in Market；So necessary exploitation is a kind of new is applicable between high intensity modular structure quickly connect device Surface treatment method, especially for exposed contact surface, need to have extraordinary antirust Ability.
Summary of the invention
It is an object of the invention to provide the surface process side of a kind of attachment means for modular architectural Method.In conjunction with metal machinery and Polymer Technology, by unique design, at unique macromolecule Reason technology, each parts surface in attachment means forms tamper-proof layer, protects material non-corrosive, eliminates Connect hidden danger；Be conducive to connecting elements stable performance, there is the stability of excellence, it is adaptable to modularity Building.
For reaching above-mentioned purpose, the technical solution used in the present invention is: a kind of for modular architectural Attachment means surface treatment method, comprises the following steps:
(1) by acrylic acid, N hydroxymethyl acrylamide, 1,4-CHDM diacrylate, NVP, lauryl methacrylate, isomerous tridecanol polyoxyethylene ether, single benzene first Acid resorcinol is added to the water, dropping persulfate aqueous solution after stir 20～30 minutes, in 65～ 75 DEG C are reacted 1.5～2.5 hours, obtain performed polymer；
(2) 4,4 '-two trifluoromethoxy diphenyl diimides, cumyl peroxide are dissolved in N, N-dimethyl In Methanamide, add four glycidyl ether tetraphenyl ethane, after stirring 30 minutes, add methyl-prop Olefin(e) acid lauryl and maleic anhydride, add 4-dimethylamino pyrrole for 1～2 hour in 95～105 DEG C of reactions Pyridine, continues reaction 1～2 hour, obtains bonding agent；
(3) hydroxyl silicones, methylimidazole, solid amine are added in heptane, in 50～55 DEG C Stir 0.5～1 hour, be subsequently adding vinyltrimethoxy silane and CuPc, anti-in 90～95 DEG C Answer 1.5～2 hours, be subsequently adding VCH diepoxide, in 100～105 DEG C of reactions 1.5～2 hours, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, in 125～135 DEG C heating 1.5～ 2.5 hours, form silane coupling agent film on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, Heat 0.5～1 hour in 115～120 DEG C, form adhesive linkage on silane coupling agent film surface；Last bonding Layer surface-coated performed polymer, heats 1.5～2 hours in 95～110 DEG C, completes for modular architectural Attachment means surface process.
In the present invention, attachment means does not limit, refer generally to often and contacting external air for mould Massing builds the parts connected between each module, at L-type connector between such as body of wall, drift angle Barrier part between star connection, body of wall and elevator, these attachment means are the most exposed outside, have Subject and expose to the weather, surface is constantly etched, aoxidizes, especially for attachment means and main body it Between contact site, the inevitable Presence of an interface friction when installing/dismounting, the hardness one of material of main part As higher than attachment means, this produces irreversible damage to the surface of attachment means, and is installing , for skyscraper, there is micro-swing in Bi Hou, an entirety can swing entirety, each portion as one Junction between part becomes stress point, and two interfaces constantly rub, long time integration, connects boundary Face can be destroyed, and there is safety problem.
In the present invention, acrylic acid, N hydroxymethyl acrylamide, 1,4-CHDM diacrylate Ester, NVP, lauryl methacrylate, isomerous tridecanol polyoxyethylene ether, list Benzoic acid resorcinol, potassium peroxydisulfate, the mass ratio of water are (0.21～0.25): (0.1～0.15): (0.05～0.08): (0.24～0.26): (0.18～0.19): (0.25～0.28): (0.15～ 0.18): (0.01～0.011): 1；The concentration of potassium sulfate solution is 0.1g/mL；Dropping over cure During acid aqueous solutions of potassium, it is added dropwise to complete in 20～30 minutes.Acrylate copolymer has the weatherability of excellence, Consisting of and polymerization technique rational formula, the performed polymer viscosity of preparation is applicable to surface-coated, There is quick-setting ability simultaneously；It is covered in the outermost layer of steel attachment means, fine and close thin film The intrusion of moisture can be prevented effectively from, provide solid foundation for surface-treated layer protection steel.
In the present invention, 4,4 '-two trifluoromethoxy diphenyl diimides, cumyl peroxide, four (+)-2,3-Epoxy-1-propanols Ether tetraphenyl ethane, lauryl methacrylate, maleic anhydride, the quality of DMAP Than for (0.11～0.15): (0.0001～0.00015): 1: (0.28～0.32): (0.28～ 0.29): (0.05～0.08).Utilize multifunction group epoxy and hyperergic unsaturated double-bond, carry For the reactivity that adhesive linkage is excellent, thus on can react with acrylate prepolymer, lower can be with silicon tree Fat, silane form new key mapping, are the most successfully connected as a single entity by layers of material.
In the present invention, hydroxyl silicones, methylimidazole, solid amine, vinyltrimethoxy silane, CuPc, the mass ratio of VCH diepoxide are 1: (0.001～0.0015): (0.05～0.08): (0.54～0.56): (0.00018～0.00019): (0.31～0.35). Polymeric film and steel belong to foreign materials, and both sides are the most incompatible, particularly the strongest the gathering of functionalization Compound such as weatherability, corrosion resistance are very strong, more repel dissimilar materials, in order to solve this problem, The present invention first forms primer layer, the silicones in silane coupling agent, silane energy on steel attachment means surface Form adhesion with steel surface the most well, add epoxide simultaneously, and with double bond, can To form reaction with other polymer, obtain interpenetrating structure, thus ensure that polymer treatment layer and steel The attachment stability of basal layer processed, provides safeguard for effectively processing of attachment means.
In the present invention, preheat attachment means in 110 DEG C.The temperature of reaction and time are to the present invention very Important, each individual system of the present invention is in continuous course of reaction, forms the film layer of stable homogeneous； Especially bonding agent, silane coupling agent has stronger reactivity.The present invention by matrix resin, firming agent, Promote effective cooperation of component and active small molecular, control reaction temperature, the extent of reaction can be obtained The highest process film layer；Especially three groups of polymeric systems of the present invention, reaction temperature is variant, with Process step is consistent, and temperature gradually reduces, and effectively prevent the subsequent heat destruction to front road polymer, The most not only layers of material polymer degree is good, and the whole process film layer extent of reaction is the highest, and processes Layer is the strongest with the adhesive force of attachment means, can effectively protect attachment means.
In the present invention, little molecule improves the wet-hot aging performance of matrix resin such as epoxy resin, by instead The polar group in resin matrix molecular structure should be reduced, make resin matrix reduce with the interaction of water, Thus reduce the water absorption rate of resin matrix；Optimize composite bed simultaneously and process technique, reduce composite bed and becoming During type, the micropore of generation, micro-crack, free volume etc. also can improve its wet-hot aging performance；Introduce Curing accelerator coordinates with little molecules immobilized dose, increases the degree of cross linking, introduces heat-resisting group and such as introduce aryl Deng, and the humidity resistance processing layer is also improved by multiple macromolecule formation interpenetrating polymer networks； Success solve macromolecule membranous layer humidity resistance be macromolecule play protection steel surface performance basis with Crucial.
In the present invention, the thickness of silane coupling agent film is 380～450 nanometers, and thickness of adhibited layer is 220～250 Nanometer；Adhesive linkage is the thinnest, and beneficially it is as bridge joint component, so that reaction is more thorough；For third The thickness of olefin(e) acid performed polymer film layer is not particularly limited, and arranges according to actual needs.
The invention also discloses the attachment means for modular architectural prepared according to said method and Its application in modular architectural.
Owing to technique scheme is used, the present invention compared with prior art has the advantage that
The present invention, by unique macromolecule treatment technology, processes film in the formation of existing attachment means surface Layer, efficiently solves the erosion that existing attachment means exists and gets rusty and the safety problem that causes；And locate Reason film layer is strong with steel substrate adhesive force；Attachment means after process is suitable to industrialization module application.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment one
(1) by 210g acrylic acid, 100gN-n-methylolacrylamide, 50g1,4-cyclohexanedimethanol Diacrylate, 240gN-vinyl pyrrolidone, 180g lauryl methacrylate, 250g isomery Tridecanol polyoxyethylene ether, 150g mono-benzoic acid resorcinol adds in 1000g water, stirs 30 Drip the persulfate aqueous solution of 100mL0.1g/mL after minute, be added dropwise to complete in 20 minutes, in 75 DEG C reaction 1.5 hours, obtain performed polymer；
(2) by 110g4,4 '-two trifluoromethoxy diphenyl diimides, 0.1g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs Add 280g lauryl methacrylate and 280g maleic anhydride after mixing 30 minutes, react 2 in 95 DEG C Hour add 50g4-dimethylamino naphthyridine, continue reaction 1 hour, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1g methylimidazole, 50g solid amine are added 600g heptan In alkane, stir 0.5 hour in 50 DEG C, be subsequently adding 540g vinyltrimethoxy silane and 0.18g CuPc, reacts 1.5 hours in 90 DEG C, is subsequently adding 310g vinyl bad hexene diepoxide, React 2 hours in 100 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 1.5 hours in 135 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 120 DEG C heating 0.5 hour, silane coupling agent film surface formed adhesive linkage；Last pre-in adhesive linkage surface-coated Aggressiveness, heats 1.5 hours in 110 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.
Embodiment two
(1) by 250g acrylic acid, 150gN-n-methylolacrylamide, 80g1,4-cyclohexanedimethanol Diacrylate, 260gN-vinyl pyrrolidone, 190g lauryl methacrylate, 280g isomery Tridecanol polyoxyethylene ether, 180g mono-benzoic acid resorcinol adds in 1000g water, stirs 30 Drip the persulfate aqueous solution of 110mL0.1g/mL after minute, be added dropwise to complete in 30 minutes, in 75 DEG C reaction 2.5 hours, obtain performed polymer；
(2) by 150g4,4 '-two trifluoromethoxy diphenyl diimides, 0.15g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs Add 320g lauryl methacrylate and 290g maleic anhydride after mixing 30 minutes, react 2 in 95 DEG C Hour add 80g4-dimethylamino naphthyridine, continue reaction 2 hours, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1.5g methylimidazole, 80g solid amine are added 600g In heptane, stir 0.5 hour in 50 DEG C, be subsequently adding 560g vinyltrimethoxy silane and 0.19g CuPc, reacts 1.5 hours in 95 DEG C, is subsequently adding 350g VCH diepoxide, React 1.5 hours in 105 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 1.5 hours in 135 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 120 DEG C heating 1 hour, silane coupling agent film surface formed adhesive linkage；Last in adhesive linkage surface-coated pre-polymerization Body, heats 2 hours in 95 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.
Embodiment three
(1) by 210g acrylic acid, 100gN-n-methylolacrylamide, 50g1,4-cyclohexanedimethanol Diacrylate, 240gN-vinyl pyrrolidone, 180g lauryl methacrylate, 250g isomery Tridecanol polyoxyethylene ether, 150g mono-benzoic acid resorcinol adds in 1000g water, stirs 30 Drip the persulfate aqueous solution of 100mL0.1g/mL after minute, be added dropwise to complete in 20 minutes, in 75 DEG C reaction 2.5 hours, obtain performed polymer；
(2) by 150g4,4 '-two trifluoromethoxy diphenyl diimides, 0.15g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs 320g lauryl methacrylate and 290g maleic anhydride is added, in 105 DEG C of reactions after mixing 30 minutes Within 1 hour, add 80g4-dimethylamino naphthyridine, continue reaction 1 hour, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1.5g methylimidazole, 80g solid amine are added 600g In heptane, stir 1 hour in 50 DEG C, be subsequently adding 560g vinyltrimethoxy silane and 0.19g CuPc, reacts 2 hours in 90 DEG C, is subsequently adding 350g VCH diepoxide, React 2 hours in 100 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 1.5 hours in 135 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 120 DEG C heating 0.5 hour, silane coupling agent film surface formed adhesive linkage；Last pre-in adhesive linkage surface-coated Aggressiveness, heats 1.5 hours in 110 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.
Embodiment four
(1) by 210g acrylic acid, 100gN-n-methylolacrylamide, 50g1,4-cyclohexanedimethanol Diacrylate, 240gN-vinyl pyrrolidone, 180g lauryl methacrylate, 250g isomery Tridecanol polyoxyethylene ether, 150g mono-benzoic acid resorcinol adds in 1000g water, stirs 30 Drip the persulfate aqueous solution of 100mL0.1g/mL after minute, be added dropwise to complete in 20 minutes, in 75 DEG C reaction 1.5 hours, obtain performed polymer；
(2) by 110g4,4 '-two trifluoromethoxy diphenyl diimides, 0.1g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs 280g lauryl methacrylate and 280g maleic anhydride is added, in 105 DEG C of reactions after mixing 30 minutes Within 1 hour, add 50g4-dimethylamino naphthyridine, continue reaction 2 hours, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1.5g methylimidazole, 80g solid amine are added 600g In heptane, stir 1 hour in 55 DEG C, be subsequently adding 560g vinyltrimethoxy silane and 0.19g CuPc, reacts 1.5 hours in 95 DEG C, is subsequently adding 350g VCH diepoxide, React 1.5 hours in 105 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 1.5 hours in 135 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 115～ 120 DEG C are heated 0.5 hour, form adhesive linkage on silane coupling agent film surface；Last in adhesive linkage surface-coated Performed polymer, heats 1.5 hours in 110 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.
Embodiment five
(1) by 250g acrylic acid, 150gN-n-methylolacrylamide, 80g1,4-cyclohexanedimethanol Diacrylate, 260gN-vinyl pyrrolidone, 190g lauryl methacrylate, 280g isomery Tridecanol polyoxyethylene ether, 180g mono-benzoic acid resorcinol adds in 1000g water, stirs 25 Drip the persulfate aqueous solution of 110mL0.1g/mL after minute, be added dropwise to complete in 25 minutes, in 70 DEG C reaction 1.5～2.5 hours, obtain performed polymer；
(2) by 110g4,4 '-two trifluoromethoxy diphenyl diimides, 0.1g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs 280g lauryl methacrylate and 280g maleic anhydride is added, in 100 DEG C of reactions after mixing 30 minutes Within 1 hour, add 50g4-dimethylamino naphthyridine, continue reaction 1 hour, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1g methylimidazole, 50g solid amine are added 600g heptan In alkane, stir 1 hour in 55 DEG C, be subsequently adding 540g vinyltrimethoxy silane and 0.18g CuPc, reacts 1.5 hours in 95 DEG C, is subsequently adding 310g VCH diepoxide, React 2 hours in 100 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 1.5 hours in 135 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 120 DEG C heating 0.5 hour, silane coupling agent film surface formed adhesive linkage；Last pre-in adhesive linkage surface-coated Aggressiveness, heats 1.5 hours in 110 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.
Embodiment six
(1) by 250g acrylic acid, 150gN-n-methylolacrylamide, 80g1,4-cyclohexanedimethanol Diacrylate, 260gN-vinyl pyrrolidone, 190g lauryl methacrylate, 280g isomery Tridecanol polyoxyethylene ether, 180g mono-benzoic acid resorcinol adds in 1000g water, stirs 30 Drip the persulfate aqueous solution of 110mL0.1g/mL after minute, be added dropwise to complete in 20 minutes, in 75 DEG C reaction 2.5 hours, obtain performed polymer；
(2) by 150g4,4 '-two trifluoromethoxy diphenyl diimides, 0.15g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs Add 320g lauryl methacrylate and 290g maleic anhydride after mixing 30 minutes, react 2 in 95 DEG C Hour add 80g4-dimethylamino naphthyridine, continue reaction 2 hours, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1g methylimidazole, 50g solid amine are added 600g heptan In alkane, stir 0.5 hour in 55 DEG C, be subsequently adding 540g vinyltrimethoxy silane and 0.18g CuPc, reacts 1.5 hours in 95 DEG C, is subsequently adding 310g VCH diepoxide, React 1.5 hours in 105 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 2.5 hours in 125 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 120 DEG C heating 0.5 hour, silane coupling agent film surface formed adhesive linkage；Last pre-in adhesive linkage surface-coated Aggressiveness, heats 1.5 hours in 110 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.
Embodiment seven
(1) by 230g acrylic acid, 130gN-n-methylolacrylamide, 60g1,4-cyclohexanedimethanol Diacrylate, 250gN-vinyl pyrrolidone, 185g lauryl methacrylate, 260g isomery Tridecanol polyoxyethylene ether, 170g mono-benzoic acid resorcinol adds in 1000g water, stirs 30 Drip the persulfate aqueous solution of 100mL0.1g/mL after minute, be added dropwise to complete in 20 minutes, in 75 DEG C reaction 2.5 hours, obtain performed polymer；
(2) by 130g4,4 '-two trifluoromethoxy diphenyl diimides, 0.12g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs 290g lauryl methacrylate and 280g maleic anhydride is added, in 105 DEG C of reactions after mixing 30 minutes Within 1 hour, add 70g4-dimethylamino naphthyridine, continue reaction 2 hours, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1.2g methylimidazole, 70g solid amine are added 600g In heptane, stir 1 hour in 50 DEG C, be subsequently adding 550g vinyltrimethoxy silane and 0.18g CuPc, reacts 1.5 hours in 95 DEG C, is subsequently adding 330g VCH diepoxide, React 1.5 hours in 105 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 2.5 hours in 130 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 120 DEG C heating 0.5 hour, silane coupling agent film surface formed adhesive linkage；Last pre-in adhesive linkage surface-coated Aggressiveness, heats 1.5 hours in 110 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.
Embodiment eight
(1) by 250g acrylic acid, 150gN-n-methylolacrylamide, 80g1,4-cyclohexanedimethanol Diacrylate, 260gN-vinyl pyrrolidone, 190g lauryl methacrylate, 280g isomery Tridecanol polyoxyethylene ether, 180g mono-benzoic acid resorcinol adds in 1000g water, stirs 30 Drip the persulfate aqueous solution of 110mL0.1g/mL after minute, be added dropwise to complete in 20 minutes, in 75 DEG C reaction 2.5 hours, obtain performed polymer；
(2) by 130g4,4 '-two trifluoromethoxy diphenyl diimides, 0.12g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs 290g lauryl methacrylate and 280g maleic anhydride is added, in 105 DEG C of reactions after mixing 30 minutes Within 1 hour, add 70g4-dimethylamino naphthyridine, continue reaction 2 hours, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1.5g methylimidazole, 80g solid amine are added 600g In heptane, stir 1 hour in 50 DEG C, be subsequently adding 560g vinyltrimethoxy silane and 0.19g CuPc, reacts 2 hours in 90 DEG C, is subsequently adding 350g VCH diepoxide, React 1.5 hours in 105 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 1.5 hours in 135 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 120 DEG C heating 0.5 hour, silane coupling agent film surface formed adhesive linkage；Last pre-in adhesive linkage surface-coated Aggressiveness, heats 1.5 hours in 110 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.
Embodiment nine
(1) by 210g acrylic acid, 100gN-n-methylolacrylamide, 50g1,4-cyclohexanedimethanol Diacrylate, 240gN-vinyl pyrrolidone, 180g lauryl methacrylate, 250g isomery Tridecanol polyoxyethylene ether, 150g mono-benzoic acid resorcinol adds in 1000g water, stirs 30 Drip the persulfate aqueous solution of 100mL0.1g/mL after minute, be added dropwise to complete in 20 minutes, in 75 DEG C reaction 2.5 hours, obtain performed polymer；
(2) by 130g4,4 '-two trifluoromethoxy diphenyl diimides, 0.12g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs 290g lauryl methacrylate and 280g maleic anhydride is added, in 105 DEG C of reactions after mixing 30 minutes Within 1 hour, add 70g4-dimethylamino naphthyridine, continue reaction 2 hours, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1g methylimidazole, 50g solid amine are added 600g heptan In alkane, stir 0.5 hour in 55 DEG C, be subsequently adding 540g vinyltrimethoxy silane and 0.18g CuPc, reacts 1.5 hours in 95 DEG C, is subsequently adding 310g VCH diepoxide, React 2 hours in 100 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 1.5 hours in 135 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 120 DEG C heating 0.5 hour, silane coupling agent film surface formed adhesive linkage；Last pre-in adhesive linkage surface-coated Aggressiveness, heats 1.5 hours in 110 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.
Embodiment ten
(1) by 250g acrylic acid, 150gN-n-methylolacrylamide, 80g1,4-cyclohexanedimethanol Diacrylate, 260gN-vinyl pyrrolidone, 190g lauryl methacrylate, 280g isomery Tridecanol polyoxyethylene ether, 180g mono-benzoic acid resorcinol adds in 1000g water, stirs 30 Drip the persulfuric acid clock aqueous solution of 110mL0.1g/mL after minute, be added dropwise to complete in 20 minutes, in 75 DEG C reaction 2.5 hours, obtain performed polymer；
(2) by 130g4,4 '-two trifluoromethoxy diphenyl diimides, 0.12g cumyl peroxide dissolve in 400gN, in dinethylformamide, adds 1000g tetra-glycidyl ether tetraphenyl ethane, stirs 290g lauryl methacrylate and 280g maleic anhydride is added, in 105 DEG C of reactions after mixing 30 minutes Within 1 hour, add 70g4-dimethylamino naphthyridine, continue reaction 2 hours, obtain bonding agent；
(3) 1000g hydroxyl silicones, 1g methylimidazole, 50g solid amine are added 600g heptan In alkane, stir 1 hour in 50 DEG C, be subsequently adding 540g vinyltrimethoxy silane and 0.18g CuPc, reacts 2 hours in 90 DEG C, is subsequently adding 310g VCH diepoxide, React 1.5 hours in 100 DEG C, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, heats 2.5 hours in 135 DEG C, Silane coupling agent film is formed on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, in 120 DEG C heating 0.5 hour, silane coupling agent film surface formed adhesive linkage；Last pre-in adhesive linkage surface-coated Aggressiveness, heats 1.5 hours in 95 DEG C, completes to process for the surface of modular architectural attachment means.
Through test, inorganic agent film adhesion be more than 5B, water boiling resistance more than 8 minutes, thermal deformation temperature Degree is more than 95 DEG C.

Claims (10)

1. the surface treatment method for modular architectural attachment means, it is characterised in that include Following steps:
(1) by acrylic acid, N hydroxymethyl acrylamide, 1,4-CHDM diacrylate, NVP, lauryl methacrylate, isomerous tridecanol polyoxyethylene ether, single benzoic acid Resorcinol is added to the water, and drips persulfate aqueous solution, in 65～75 after stirring 20～30 minutes DEG C reaction 1.5～2.5 hours, obtain performed polymer；
(2) 4,4 '-two trifluoromethoxy diphenyl diimides, cumyl peroxide are dissolved in N, N-dimethyl methyl In amide, add four glycidyl ether tetraphenyl ethane, after stirring 30 minutes, add metering system Acid lauryl and maleic anhydride, add DMAP in 1～2 hour in 95～105 DEG C of reactions, Continue reaction 1～2 hour, obtain bonding agent；
(3) hydroxyl silicones, methylimidazole, solid amine are added in heptane, stir in 50～55 DEG C Mix 0.5～1 hour, be subsequently adding vinyltrimethoxy silane and CuPc, in 90～95 DEG C of reactions 1.5～2 hours, be subsequently adding VCH diepoxide, in 100～105 DEG C reaction 1.5～ 2 hours, obtain silane coupling agent；
(4) attachment means surface-coated silane coupling agent after preheat, in 125～135 DEG C heating 1.5～ 2.5 hours, form silane coupling agent film on attachment means surface；Then at silane coupling agent film surface spraying bonding agent, Heat 0.5～1 hour in 115～120 DEG C, form adhesive linkage on silane coupling agent film surface；Last bonding Layer surface-coated performed polymer, heats 1.5～2 hours in 95～110 DEG C, completes for modular architectural The surface of attachment means processes.
The most according to claim 1 for the surface treatment method of modular architectural attachment means, its It is characterised by: acrylic acid, N hydroxymethyl acrylamide, 1,4-CHDM diacrylate, N- Between vinyl pyrrolidone, lauryl methacrylate, isomerous tridecanol polyoxyethylene ether, single benzoic acid Benzodiazepines ester, potassium peroxydisulfate, the mass ratio of water are (0.21～0.25): (0.1～0.15): (0.05～ 0.08): (0.24～0.26): (0.18～0.19): (0.25～0.28): (0.15～0.18): (0.01～0.011): 1.
The most according to claim 1 for the surface treatment method of modular architectural attachment means, its It is characterised by: the concentration of potassium sulfate solution is 0.1g/mL.
The most according to claim 1 for the surface treatment method of modular architectural attachment means, its It is characterised by: 4,4 '-two trifluoromethoxy diphenyl diimides, cumyl peroxide, four glycidyl ethers four Diphenylphosphino ethane, lauryl methacrylate, maleic anhydride, the mass ratio of DMAP be (0.11～ 0.15): (0.0001～0.00015): 1: (0.28～0.32): (0.28～0.29): (0.05～ 0.08)。
The most according to claim 1 for the surface treatment method of modular architectural attachment means, its It is characterised by: hydroxyl silicones, methylimidazole, solid amine, vinyltrimethoxy silane, phthalocyanine Copper, the mass ratio of VCH diepoxide are 1: (0.001～0.0015): (0.05～ 0.08): (0.54～0.56): (0.00018～0.00019): (0.31～0.35).
The most according to claim 1 for the surface treatment method of modular architectural attachment means, its It is characterised by: preheat attachment means in 110 DEG C.
The most according to claim 1 for the surface treatment method of modular architectural attachment means, its It is characterised by: during dropping persulfate aqueous solution, be added dropwise to complete in 20～30 minutes.
The most according to claim 1 for the surface treatment method of modular architectural attachment means, its It is characterised by: the thickness of silane coupling agent film is 380～450 nanometers；Thickness of adhibited layer is 220～250 nanometers.
Method the most according to claim 1 prepare for modular architectural attachment means.
10. for the application in modular architectural of the modular architectural attachment means described in claim 9.
CN201610329368.1A 2016-05-17 2016-05-17 Surface treatment method for connecting device for modular buildings Pending CN106010065A (en)

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JP2011157475A (en) * 2010-02-01 2011-08-18 Mitsubishi Rayon Co Ltd Method for producing aqueous coating material
CN201841715U (en) * 2010-09-15 2011-05-25 中国石油天然气集团公司 Steel plate with solvent-free epoxy antistatic coating
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