CN106010000A - Novel health-maintaining paint for building interior wall - Google Patents

Novel health-maintaining paint for building interior wall Download PDF

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Publication number
CN106010000A
CN106010000A CN201610486085.8A CN201610486085A CN106010000A CN 106010000 A CN106010000 A CN 106010000A CN 201610486085 A CN201610486085 A CN 201610486085A CN 106010000 A CN106010000 A CN 106010000A
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CN
China
Prior art keywords
novel health
health care
wall
agent
building
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Pending
Application number
CN201610486085.8A
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Chinese (zh)
Inventor
高武斌
魏立新
龙须
许志刚
石笃笃
田立新
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BEIJING SENIOR EXPERT TECHNOLOGY CENTER CHINESE ACADEMY OF SCIENCES
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BEIJING SENIOR EXPERT TECHNOLOGY CENTER CHINESE ACADEMY OF SCIENCES
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Priority to CN201610486085.8A priority Critical patent/CN106010000A/en
Publication of CN106010000A publication Critical patent/CN106010000A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides novel health-maintaining paint for a building interior wall. The novel health-maintaining paint has excellent weather fastness and water resistance of waterborne paint, is environmentally friendly and high in adhesive force, contains 2-10% of a piezo-electric crystal additive, has the unique function of releasing negative oxygen ions and high-radiation 4-18-micrometer far infrared rays, can effectively decompose indoor formaldehyde, arene and other volatile organic gas pollutants, kill bacteria, effectively lower indoor PM2.5 concentration and improve the living environment and has the health-maintaining effects of calming nerves, improving sleeping and blood circulation in the human body and enhancing metabolism.

Description

A kind of inner wall of building novel health care coating
Technical field
The invention belongs to the crossing domain of novel environment friendly building and ornament materials and chemical technology, relate to inner wall of building aqueous The preparation method of coating, is specifically related to a kind of to have permanent releasing negative oxygen ion, radiate the health preserving coating of high far infrared Formula and preparation method thereof.
Background technology
People stay in every day in room and vehicles space for up to 20 hours, therefore, in space residing for us The quality of air quality is one of key factor of quality affecting our quality of life in all one's life, but, along with modern industry Development, China's city atmospheric environment situation is the most pessimistic, and this causes negative effect greatly to the improvement of IAQ (indoor air quality)； Secondly, the volatile organic contaminant such as formaldehyde that house decorative material, furniture etc. discharge, aromatic hydrocarbons, badly influence people especially IAQ (indoor air quality).
Inner wall of building coating is as a kind of decorative material, outside beautifying and decorating home environment effect, by its merit Energyization is modified, can give it and possess permanent releasing negative oxygen ion, radiation infrared ability so that it is have construction health care Effect of living environment.Building in health care's living environment, effect of negative oxygen ion and far infrared is wide by medical science institute General confirmation, the negative oxygen ion concentration in air is defined as evaluating the major criterion of air quality grade, negative oxygen ion by WHO especially Can effectively decompose the volatile organic gaseous contamination thing such as indoor formaldehyde, aromatic hydrocarbons, kill pathogenic bacteria, effectively reduce indoor PM2.5's Concentration, improves living environment, and negative oxygen ion has stable nerve simultaneously, improves the health maintenance effect of sleep；Far infrared has relatively Strong penetration, penetrates at human body skin and subcutaneous tissue deep layer, produces resonance effect with the hydrone in human body cell, to changing Kind blood circulation of human body, activates biomacromolecule, strengthens metabolism, has the health maintenance effect prevented and cured diseases.
Water paint is that one develops the man of environmental protection faster coatings, by carrying out function modified to it so that be coated with it The living environment of dress has degradation of formaldehyde, reduces outside the purification functions such as indoor PM2.5 concentration, has more effect of health preserving, and this will One new developing direction of function man coatings can be become.
Summary of the invention
It is an object of the invention to provide a kind of can forever releasing negative oxygen ion, radiate high far infrared inner wall of building use Novel health care coating and preparation method thereof.
The basic conception of the present invention is the pressure introducing ultra-fine pressure and temperature sensitivity during preparing water paint Electric crystal material powder body, and make it dispersed in water paint, thus obtain inner wall of building novel health care coating.Foundation Piezoquartz material, under the pressure and temperature concussion effect of air, makes crystalline solid positive and negative charge migrate toward two ends and causes electromotive force Produce electric discharge, make surrounding air produce ionization, water that the electron attachment hit is closed on and oxygen molecule and make it be converted into air Negative oxygen ion, the negative oxygen ion of generation migrates in atmosphere, be able to continuously to space releasing negative oxygen ion；Simultaneously at environment Under minor variations, i.e. there is strong vibration in crystals, and dipole moment then occurs violent change, just produces " light of life ", Wavelength is the far infrared of 4-18 μm, matches with human body far infrared wave length, provides energy to life, improves microcirculation in human body.
Technical scheme: a kind of inner wall of building novel health care coating, its material component and part by weight be: pressure Electric crystal additive: 2-10%, deionized water 15-30%, polyacrylate dispersion: 18-35%, titanium dioxide: 15-30%, heavy carbonic Calcium: 10-18%, blanc fixe: 8-15%, dispersant: 0.2-0.8%, wetting agent: 0.05-0.08%, defoamer: 1.5-2.5%, Levelling agent: 0.5-0.6%, coalescents: 0.05-0.06%, antibacterial: 0.2-0.8%, thickening agent: appropriate, pH adjusting agent: suitable Amount.
Preferably raw material weight percentage ratio: piezoquartz additive: 4.5%, deionized water 23%, polyacrylate dispersion: 25%, titanium dioxide: 18%, calcium bicarbonate: 14%, blanc fixe: 12%, dispersant: 0.6%, wetting agent: 0.05%, defoamer: 2%, levelling agent: 0.5%, coalescents: 0.05%, antifungus agent: 0.3%, thickening agent: appropriate, pH adjusting agent: appropriate.
Health preserving coating of the present invention, wherein said piezoquartz additive is opal: gull rock: hexacyclic ring stone=2-5:2-5: Two or three mixture in 2-3, granularity reaches 2000 mesh.
Health preserving coating of the present invention, wherein said titanium dioxide is nanometer titanium dioxide: the mixture of Detitanium-ore-type titanium dioxide=1:5.
Inner wall of building novel health care preparation method for coating of the present invention, comprises the following steps: 1. by deionized water, dispersion Agent, wetting agent are sequentially added in reactor, and low rate mixing fully dissolves for 15-30 minute；2. by titanium dioxide, calcium bicarbonate, precipitation Barium sulfate, piezoquartz additive are sequentially added in aforesaid reaction vessel, and high speed dispersion 20-40 minute；3. by acrylic resin Emulsion, defoamer, levelling agent, coalescents are sequentially added in aforesaid reaction vessel, and mixing 15-30 minute at a slow speed, by equal for dispersion Even serosity carries out sand milling, makes fineness reach 20-50 μm；4. under moderate rotation, it is sequentially added into antibacterial, thickening agent, pH regulator Agent adjusts viscosity and reaches 0.8-1.5 Pa.s, and pH value, when 7.5-9, i.e. can be made into inner wall of building novel health care coating.
The novel health care coating obtained detects, and shows that its appearance of film is smooth, uniform color, and negative oxygen ion produces Amount is more than 3200/cm3* min, under 25 DEG C of room temperatures, 4-18 μm normal direction far infrared emissivity reaches 0.91.
Detailed description of the invention
Below by being embodied as example, further illustrate inner wall of building novel health care preparation method for coating of the present invention Details, but illustrated embodiment is not as limitation of the present invention.
Embodiment 1-3: the formula such as following table institute of raw material weight percentage ratio pressed by inner wall of building novel health care coating Show:
Preparation process is:
(1) dispersant of said ratio, wetting agent are gradually added in deionized water under the stirring of 300 r/min successively Carry out disperseing and dissolving, then mixing speed is brought up to 1000 r/min, stir 15-30 min；
(2) by the titanium dioxide of proportioning, calcium bicarbonate, blanc fixe, piezoquartz additive, (example 1 is opal: gull rock =2:3；Example 2 is gull rock: hexacyclic ring stone=2:1；Example 3 is opal: gull rock: hexacyclic ring stone=3:4:3) 300 r/min's It is gradually added successively under stirring in the liquid described in step (1) and disperses, then by aforesaid liquid and at 1000-1500 20-40 min is stirred under the rotating speed of r/min；
(3) emulsion acrylic resin, defoamer, levelling agent, coalescents are sequentially added under the stirring of 500 r/min In above-mentioned serosity, at the lower at a slow speed mixing 15-30 min of 400 r/min, after serosity is mixed thoroughly, serosity is pumped into Sand milling tank is ground, after fineness reaches 20-50 μm in pumped back agitator tank；
(4) be sequentially added under the moderate rotation of 800-1200 r/min antibacterial, thickening agent, pH adjusting agent adjust viscosity reach 0.8-1.5 Pa.s, pH value, when 7.5-9, i.e. can be made into inner wall of building novel health care coating.

Claims (6)

1. an inner wall of building novel health care coating, it is characterised in that its raw material includes following component by weight: piezo crystals Body additives: 2-10%, deionized water 15-30%, polyacrylate dispersion: 18-35%, titanium dioxide: 15-30%, calcium bicarbonate: 10-18%, blanc fixe: 8-15%, dispersant: 0.2-0.8%, wetting agent: 0.05-0.08%, defoamer: 1.5-2.5%, stream Flat agent: 0.5-0.6%, coalescents: 0.05-0.06%, antibacterial: 0.2-0.8%, thickening agent: appropriate, pH adjusting agent: appropriate.
2. according to the inner wall of building novel health care coating described in claims 1, it is characterised in that: have and forever discharge people The negative oxygen ion that body is useful；There is the decomposition volatile organic gaseous contamination thing such as indoor formaldehyde, aromatic hydrocarbons, kill pathogenic bacteria, effectively drop The effects such as the concentration of low indoor PM2.5, improve indoor air environment.
3. according to the inner wall of building novel health care coating described in claims 1, it is characterised in that: radiate and high be prone to human body The 4-18 μm far infrared absorbed；There is stable nerve, improve sleep, improve blood circulation of human body, strengthen metabolic supporting Raw effect.
4. according to the inner wall of building novel health care coating described in claims 1, it is characterised in that: described piezoquartz adds Agent is opal: gull rock: two or three mixture in hexacyclic ring stone=2-5:2-5:2-3, and granularity reaches 2000 mesh.
5. according to the inner wall of building novel health care coating described in claims 1, it is characterised in that: described titanium dioxide is nanometer Titanium dioxide: the mixture of Detitanium-ore-type titanium dioxide=1:5.
6. the preparation method of novel health care coating of the inner wall of building described in claims 1, it is characterised in that: by claim The formulation weight of book 1 is carried out than by following steps:
1. deionized water, dispersant, wetting agent are sequentially added in reactor, low rate mixing 15-30 minute；
2. titanium dioxide, calcium bicarbonate, blanc fixe, piezoquartz additive are sequentially added in aforesaid reaction vessel, and at a high speed Disperse 20-40 minute；
3. emulsion acrylic resin, defoamer, levelling agent, coalescents are sequentially added in aforesaid reaction vessel, and mix at a slow speed 15-30 minute, finely dispersed serosity is carried out sand milling, make fineness reach 20-50 μm；
4. be sequentially added under moderate rotation antibacterial, thickening agent, pH adjusting agent adjust viscosity reach 0.8-1.5 Pa.s, pH value When 7.5-9, i.e. can be made into inner wall of building novel health care coating.
CN201610486085.8A 2016-06-29 2016-06-29 Novel health-maintaining paint for building interior wall Pending CN106010000A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610486085.8A CN106010000A (en) 2016-06-29 2016-06-29 Novel health-maintaining paint for building interior wall

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Application Number Priority Date Filing Date Title
CN201610486085.8A CN106010000A (en) 2016-06-29 2016-06-29 Novel health-maintaining paint for building interior wall

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CN106010000A true CN106010000A (en) 2016-10-12

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108441064A (en) * 2018-01-30 2018-08-24 东莞市佳乾新材料科技有限公司 A kind of inner wall of building fire retarding epoxide resin coating and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108441064A (en) * 2018-01-30 2018-08-24 东莞市佳乾新材料科技有限公司 A kind of inner wall of building fire retarding epoxide resin coating and preparation method thereof

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Application publication date: 20161012