CN106009979A - Environment-friendly battery conductive coating material - Google Patents

Environment-friendly battery conductive coating material Download PDF

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Publication number
CN106009979A
CN106009979A CN201610530167.8A CN201610530167A CN106009979A CN 106009979 A CN106009979 A CN 106009979A CN 201610530167 A CN201610530167 A CN 201610530167A CN 106009979 A CN106009979 A CN 106009979A
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CN
China
Prior art keywords
parts
conductive coating
environment
coating material
friendly type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610530167.8A
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Chinese (zh)
Inventor
陈平
陈一平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Baolai Battery Co
Original Assignee
Wuxi Baolai Battery Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Baolai Battery Co filed Critical Wuxi Baolai Battery Co
Priority to CN201610530167.8A priority Critical patent/CN106009979A/en
Publication of CN106009979A publication Critical patent/CN106009979A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

An environment-friendly battery conductive coating material is prepared from, by weight, 40-60 parts of a base material, 15-25 parts of a conductive additive, 10-18 parts of inorganic filler and 8-15 parts of a modified additive. According to the reasonable raw material ratio and a large number of experimental proofs, the environment-friendly battery conductive coating material has good adhesive force and low contact resistance, the consumption of an adhesive can be effectively lowered, and environmental protection performance of battery manufacturing is improved; the conductive coating contains no methylbenzene or xylene with high noxiousness and meanwhile is better in sealing effect.

Description

A kind of battery conductive coating material of environment-friendly type
Technical field
The present invention relates to battery rapidoprint technical field, be specifically related to the battery conductive coating material of a kind of environment-friendly type.
Background technology
Development along with ferric phosphate lithium cell; become the probability of automobile power cell because it has and constantly paid close attention to by each side; characteristic due to himself; rate LiFePO 4 material develops to nanorize, and this is allowed to poor processability, in order to improve its processing characteristics; reduce pole piece resistance or the internal resistance of cell; conductive coating technology starts to obtain the application of scale, and thus to more professional development, and extend to some other relevant industries.
Conductive coating is also referred to as precoated shet, is often referred to be coated on one layer of conductive coating of plus plate current-collecting body aluminium foil surface in lithium battery industry, and the aluminium foil of coating conductive coating is referred to as precoated shet aluminium foil or is called for short coated aluminum foil.Conductive coating can be effectively improved pole piece adhesive force in lithium battery, reduces the usage amount of binding agent, and the electrical property simultaneously for battery is also obviously improved.Turned out a prestigious institution along with the development of new forms of energy industry, particularly ferric phosphate lithium cell in recent years, became new technique very powerful and exceedingly arrogant in the industry or new material.The existing conductive coating materials feature of environmental protection is poor.
Summary of the invention
Not enough for prior art, the invention provides the battery conductive coating material of a kind of environment-friendly type.
The present invention solves the technical scheme of above-mentioned technical problem employing: the battery conductive coating material of a kind of environment-friendly type, is made up of the raw material of following parts by weight: matrix material 40 ~ 60 parts, conductive additive 15 ~ 25 parts, inorganic filler 10 ~ 18 parts and property-modifying additive 8 ~ 15 parts.
Further, described matrix material is ethylene propylene diene rubber and venamul, and its mass parts is than for 1:2 ~ 4.
Further, described conductive additive is graphite powder and argentum powder, and its mass parts ratio is 1 ~ 3:1.
Further, described inorganic filler is nanoscale Pulvis Talci, calcium carbonate, the mixture of nanoscale attapulgite.
Further, described property-modifying additive is antioxidant, dispersant, firming agent, light stabilizer and fire retardant.
The battery conductive coating material of above-mentioned a kind of environment-friendly type, after being on the waiting list raw material according to above-mentioned mass fraction, obtains the conductive coating materials of the present invention through physical method mixing, filtration and subsequent treatment.
Compared with prior art, what the present invention possessed has the beneficial effect that
The battery conductive coating material of a kind of environment-friendly type that the present invention provides, through rational proportioning raw materials and substantial amounts of it is experimentally confirmed that have good adhesive force and relatively low contact resistance, can effectively reduce the consumption of adhesive, improves the feature of environmental protection of battery manufacture;The conductive coating of the present invention does not contains the high toluene of toxicity and dimethylbenzene, and sealing effectiveness is preferable simultaneously.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: the battery conductive coating material of a kind of environment-friendly type, is made up of the raw material of following parts by weight: matrix material 50 parts, conductive additive 20 parts, inorganic filler 15 parts and property-modifying additive 12 parts.
Further, described matrix material is ethylene propylene diene rubber and venamul, and its mass parts is than for 1:3;Described conductive additive is graphite powder and argentum powder, and its mass parts is than for 2:1;Described inorganic filler is nanoscale Pulvis Talci, calcium carbonate, the mixture of nanoscale attapulgite;Described property-modifying additive is antioxidant, dispersant, firming agent, light stabilizer and fire retardant.
Embodiment 2: the battery conductive coating material of a kind of environment-friendly type, is made up of the raw material of following parts by weight: matrix material 40 parts, conductive additive 15 parts, inorganic filler 10 parts and property-modifying additive 8 parts.
Further, described matrix material is ethylene propylene diene rubber and venamul, and its mass parts is than for 1:4;Described conductive additive is graphite powder and argentum powder, and its mass parts is than for 1:1;Described inorganic filler is nanoscale Pulvis Talci, calcium carbonate, the mixture of nanoscale attapulgite;Described property-modifying additive is antioxidant, dispersant, firming agent, light stabilizer and fire retardant.
Embodiment 3: the battery conductive coating material of a kind of environment-friendly type, is made up of the raw material of following parts by weight: matrix material 60 parts, conductive additive 25 parts, inorganic filler 18 parts and property-modifying additive 15 parts.
Further, described matrix material is ethylene propylene diene rubber and venamul, and its mass parts is than for 1:2;Described conductive additive is graphite powder and argentum powder, and its mass parts is than for 3:1;Described inorganic filler is nanoscale Pulvis Talci, calcium carbonate, the mixture of nanoscale attapulgite;Described property-modifying additive is antioxidant, dispersant, firming agent, light stabilizer and fire retardant.
The battery conductive coating material of a kind of environment-friendly type described in above-described embodiment 1 ~ 3, after being on the waiting list raw material according to above-mentioned mass fraction, obtains the conductive coating materials of the present invention through physical method mixing, filtration and subsequent treatment.

Claims (5)

1. the battery conductive coating material of an environment-friendly type, it is characterised in that be made up of the raw material of following parts by weight: matrix material 40 ~ 60 parts, conductive additive 15 ~ 25 parts, inorganic filler 10 ~ 18 parts and property-modifying additive 8 ~ 15 parts.
The battery conductive coating material of a kind of environment-friendly type the most according to claim 1, it is characterised in that: described matrix material is ethylene propylene diene rubber and venamul, and its mass parts is than for 1:2 ~ 4.
The battery conductive coating material of a kind of environment-friendly type the most according to claim 1, it is characterised in that: described conductive additive is graphite powder and argentum powder, and its mass parts ratio is 1 ~ 3:1.
The battery conductive coating material of a kind of environment-friendly type the most according to claim 1, it is characterised in that: described inorganic filler is nanoscale Pulvis Talci, calcium carbonate, the mixture of nanoscale attapulgite.
The battery conductive coating material of a kind of environment-friendly type the most according to claim 1, it is characterised in that: described property-modifying additive is antioxidant, dispersant, firming agent, light stabilizer and fire retardant.
CN201610530167.8A 2016-07-07 2016-07-07 Environment-friendly battery conductive coating material Pending CN106009979A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610530167.8A CN106009979A (en) 2016-07-07 2016-07-07 Environment-friendly battery conductive coating material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610530167.8A CN106009979A (en) 2016-07-07 2016-07-07 Environment-friendly battery conductive coating material

Publications (1)

Publication Number Publication Date
CN106009979A true CN106009979A (en) 2016-10-12

Family

ID=57107455

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610530167.8A Pending CN106009979A (en) 2016-07-07 2016-07-07 Environment-friendly battery conductive coating material

Country Status (1)

Country Link
CN (1) CN106009979A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1730571A (en) * 2005-08-18 2006-02-08 上海天鑫环境科技有限公司 Aqueous electrically-conducting paint and its preparation method
CN101457131A (en) * 2009-01-12 2009-06-17 成都茵地乐电源科技有限公司 Water binding agent for lithium ionic cell electric pole material and preparation method thereof
CN102648546A (en) * 2009-09-25 2012-08-22 大金工业株式会社 Positive electrode current collector laminate for lithium secondary battery
KR101423812B1 (en) * 2011-08-31 2014-07-25 주식회사 엘지화학 Lithium secondary battery comprising an oxygen scavenger
CN104716377A (en) * 2013-12-17 2015-06-17 远景能源(江苏)有限公司 Alternating current charging and discharging cell
CN105470522A (en) * 2014-08-29 2016-04-06 比亚迪股份有限公司 Conductive coating for lithium ion battery electrode and preparation method for conductive coating, lithium ion battery positive plate and preparation method therefor, and lithium ion battery

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1730571A (en) * 2005-08-18 2006-02-08 上海天鑫环境科技有限公司 Aqueous electrically-conducting paint and its preparation method
CN101457131A (en) * 2009-01-12 2009-06-17 成都茵地乐电源科技有限公司 Water binding agent for lithium ionic cell electric pole material and preparation method thereof
CN102648546A (en) * 2009-09-25 2012-08-22 大金工业株式会社 Positive electrode current collector laminate for lithium secondary battery
KR101423812B1 (en) * 2011-08-31 2014-07-25 주식회사 엘지화학 Lithium secondary battery comprising an oxygen scavenger
CN104716377A (en) * 2013-12-17 2015-06-17 远景能源(江苏)有限公司 Alternating current charging and discharging cell
CN105470522A (en) * 2014-08-29 2016-04-06 比亚迪股份有限公司 Conductive coating for lithium ion battery electrode and preparation method for conductive coating, lithium ion battery positive plate and preparation method therefor, and lithium ion battery

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Application publication date: 20161012

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