CN106009902A - UV(ultraviolet) metal decorating offset print ink - Google Patents

UV(ultraviolet) metal decorating offset print ink Download PDF

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Publication number
CN106009902A
CN106009902A CN201610506721.9A CN201610506721A CN106009902A CN 106009902 A CN106009902 A CN 106009902A CN 201610506721 A CN201610506721 A CN 201610506721A CN 106009902 A CN106009902 A CN 106009902A
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China
Prior art keywords
light trigger
pigment
ink
photoinitiator
resin
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CN201610506721.9A
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Chinese (zh)
Inventor
王锐
王蕊
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TIANJIN ANGEL CHEMICALS GROUP CO Ltd
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TIANJIN ANGEL CHEMICALS GROUP CO Ltd
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Priority to CN201610506721.9A priority Critical patent/CN106009902A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/101Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

Abstract

The invention belongs to the technical field of ink printing, and particularly relates to UV(ultraviolet) metal decorating offset print ink. The UV metal decorating offset print ink is prepared from the following material components in parts by weight: 19 parts of polyester acrylate resin, 41-50 parts of special acrylic resin, 4-4.5 parts of talcum powder, 1.9-10.4 parts of SR9020, 5-6 parts of photoinitiator 907, 2-3 parts of photoinitiator ITX, 1 part of photoinitiator BDK, 0-3 parts of photoinitiator 369, 0.1 part of 510 accessory ingredient and 10.4-17.3 parts of colour pigment, wherein the colour pigment is one of pigments of four colors, the red pigment is a magenta pigment, the yellow pigment is a centrolecithal pigment, the sky blue pigment is a bocour blue pigment, and the black pigment is a mixture of the bocour blue pigment, a carbon black pigment and a purple pigment. The UV metal decorating offset print ink has the beneficial effects that good adhesive force is achieved, after one hundred tests, the print ink achieves a 5B level, i.e., no ink falling phenomena happen, meanwhile, post processing requirements are met, and an ink membrane does not crack through simple mechanical stretching.

Description

A kind of UV tin graphed sheet offset ink
Technical field
The invention belongs to ink-printing techniques field, particularly relate to a kind of UV tin graphed sheet offset ink.
Background technology
Currently, ultraviolet curing technology is owing to having efficiently, and the suitability is wide, economical, energy-conservation, environment Close friend, is described as green industry new technique geared to the 21st century.And domestic common tin printing ink uses and adds Hot roasting mode solidifies, and needs mass energy, does not meets national industry and adjusts policy.According to China The conservative estimation of mental package association, domestic existing tin graphed sheet production line 2000 is a plurality of, needs every year to consume stone Fluid activating QI 15000 ten thousand stere.Printing solidification needs to use rearmounted baker, and baker provides 130-210 Degree high temperature, leaflet needs to toast 15-20 minute in baker.UV ink instantaneous solidification need not greatly Amount energy resource consumption, according to measuring and calculating use UV ink will more energy-conservation than common tin printing ink 70%, energy-saving effect Substantially;UV cure system compact conformation general 5-10 rice simultaneously, and baking-curing system it is generally required to 20-30 rice, it is seen that UV cure system can save substantial amounts of production space;Improving production efficiency is The largest benefit of UV curing system, common tin printing ink needs to toast in baker 15-20 minute, very The difficult print speed printing speed improving printer, general tin graphed sheet printer machine speed is only 2000/hour, produces Efficiency is low, and energy expenditure is big.
Summary of the invention
In order to overcome above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of curing rate fast, Concentration is high, and transparency is good, steady quality, the UV tin graphed sheet offset ink that cost performance is high.
For achieving the above object, the technical solution used in the present invention is: a kind of UV tin graphed sheet offset ink, It is characterized in that: each material composition and weight percentage be: resin is 60-69, and activity is monomer 1.9-10.4, Pulvis Talci is 4-4.5, and initiator is 8-13, and auxiliary agent is 0.1, and color pigment is 10.4-17.3.
Preferably, described resin includes polyester acrylate resin and special acrylic acid resin;Described activity Monomer be SR9020, SR9020 be propoxylated glycerol triacrylate product code, be long-chain three official Energy degree monomer, as regulation ink viscosity monomer;Described initiator includes light trigger 907, light-initiated Agent ITX, photoinitiator b DK and light-initiated 369;Described auxiliary agent is auxiliary agent 510, is UV formula body The high-efficiency polymerization inhibitor of system, for ethylene-acrylic acid copolymer.
The most each material composition and weight percentage be: polyester acrylate resin is 19, extraordinary third Olefin(e) acid resin is 41-50, Pulvis Talci be 4-4.5, SR9020 be 1.9-10.4, light trigger 907 is 5-6, light trigger ITX are 2-3, and photoinitiator b DK is 1, and light trigger 369 is 0-3,510 Auxiliary agent is 0.1, and color pigment is 10.4-17.3.
Described color pigment is red, yellow, sky blue, the one in black four kinds of colors, the pigment of red selection For fuchsin, the pigment that yellow is selected is middle yellow pigment, and the pigment that sky blue is selected is phthalocyanine blue, black The pigment selected is phthalocyanine blue, white carbon black and purple mixture.
Preferably, each material composition and weight percentage are: polyester acrylate resin is 19, extraordinary Acrylic resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, light trigger 907 Being 2-3 for 5-6, light trigger ITX, photoinitiator b DK is 1, and light trigger 369 is 0-3, 510 auxiliary agents are 0.1, and fuchsin is 10.4-17.3.
Preferably, each material composition and weight percentage are: polyester acrylate resin is 19, extraordinary Acrylic resin be 41-50, SR9020 be 1.9-10.4, light trigger 907 is 5-6, light trigger ITX is 2-3, and photoinitiator b DK is 1, and light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, in Huang is 10.4-17.3.
Preferably, each material composition and weight percentage are: polyester acrylate resin is 19, extraordinary Acrylic resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, light trigger 907 Being 2-3 for 5-6, light trigger ITX, photoinitiator b DK is 1, and light trigger 369 is 0-3, 510 auxiliary agents are 0.1, and phthalocyanine blue is 10.4-17.3.
Preferably, each material composition and weight percentage are: polyester acrylate resin is 19, extraordinary Acrylic resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, light trigger 907 Being 2-3 for 5-6, light trigger ITX, photoinitiator b DK is 1, and light trigger 369 is 0-3, 510 auxiliary agents are 0.1, and phthalocyanine blue is 0-3.1, and white carbon black is 10.4-14.1, and purple is 0-1.1.
Beneficial effects of the present invention: hundred tests reach 5B i.e. without falling ink phenomenon, are drawn by simple and mechanical Stretching ink film not ftracture, speed is fast, bright in luster, concentration is high, transparency good, site is clear admittedly to have light, The features such as adhesive force is high, ink film good toughness, meet the technological requirement of post-press finishing
Detailed description of the invention
Below in conjunction with specific embodiment the present invention made and further explaining.
The present invention provides: a kind of UV tin graphed sheet offset ink, it is characterised in that: each material composition and weight Percentage composition is: resin is 60-69, and activity is monomer 1.9-10.4, and Pulvis Talci is 4-4.5, initiator For 8-13, auxiliary agent is 0.1, and color pigment is 10.4-17.3.
Preferably, described resin includes polyester acrylate resin and special acrylic acid resin, in development process In, we as the alternative of raising adhesive force, test attached initially with polyurethane resin in test Put forth effort to improve significantly, also can meet requirement for post-treatment tensile property.But emulsifiability is poor, logical Crossing addition emulsion resistance auxiliary agent, emulsification rate decreases.Few in conjunction with tin graphed sheet printer damping roller, the water yield is difficult to The feature controlled, finally abandons this thinking, have selected with polyester acrylic and special acrylic acid resin As matrix resin in UV tin graphed sheet offset ink, special acrylic acid resin is on epoxy resin basis Blending part thermosetting acrylic resin, ink attachment is had very great help by this resin.Meanwhile, epoxy Resin curing rate is fast, becomes film hardness good.Post-treatment is stretched, and scratch resistant performance is helpful;
Described activated monomer be SR9020, SR9020 be propoxylated glycerol triacrylate product generation Code, is long-chain three-functionality-degree monomer, and as regulation ink viscosity monomer, SR9020 has reactivity Height, the feature such as film forming good toughness;
Described initiator includes light trigger 907, light trigger ITX, and photoinitiator b DK and light draw Send out 369;Described auxiliary agent is auxiliary agent 510, is the high-efficiency polymerization inhibitor of UV formula system, for ethylene-propylene Acid copolymer.
The most each material composition and weight percentage be: polyester acrylate resin is 19, extraordinary third Olefin(e) acid resin is 41-50, Pulvis Talci be 4-4.5, SR9020 be 1.9-10.4, light trigger 907 is 5-6, light trigger ITX are 2-3, and photoinitiator b DK is 1, and light trigger 369 is 0-3,510 Auxiliary agent is 0.1, and color pigment is 10.4-17.3.
Described color pigment is red, yellow, sky blue, the one in black four kinds of colors, the pigment of red selection For fuchsin, the pigment that yellow is selected is middle yellow pigment, and the pigment that sky blue is selected is phthalocyanine blue, black The pigment selected is phthalocyanine blue, white carbon black and purple mixture.
Preferably, each material composition and weight percentage are: polyester acrylate resin is 19, extraordinary Acrylic resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, light trigger 907 Being 2-3 for 5-6, light trigger ITX, photoinitiator b DK is 1, and light trigger 369 is 0-3, 510 auxiliary agents are 0.1, and fuchsin is 10.4-17.3.
Preferably, each material composition and weight percentage are: polyester acrylate resin is 19, extraordinary Acrylic resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, light trigger 907 Being 2-3 for 5-6, light trigger ITX, photoinitiator b DK is 1, and light trigger 369 is 0-3, 510 auxiliary agents are 0.1, and middle Huang is 10.4-17.3.
Preferably, each material composition and weight percentage are: polyester acrylate resin is 19, extraordinary Acrylic resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, light trigger 907 Being 2-3 for 5-6, light trigger ITX, photoinitiator b DK is 1, and light trigger 369 is 0-3, 510 auxiliary agents are 0.1, and phthalocyanine blue is 10.4-17.3.
Preferably, each material composition and weight percentage are: polyester acrylate resin is 19, extraordinary Acrylic resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, light trigger 907 Being 2-3 for 5-6, light trigger ITX, photoinitiator b DK is 1, and light trigger 369 is 0-3, 510 auxiliary agents are 0.1, and phthalocyanine blue is 0-3.1, and white carbon black is 10.4-14.1, and purple is 0-1.1.
Choosing of a kind of UV each material composition of tin graphed sheet offset ink
1, the choosing of resin
Resin is the heart of ink, and many performances of ink to be determined by resin.Used by UV ink Resin be different from the resin that common offset printing ink is used.It has the unsaturation of height, is ultraviolet The important component of line cured printing ink wink-dry.The quality of UV resin property is directly connected to UV ink Curing rate, resistance to emulsion, gloss, definition, adhesive force, toughness, rub resistance, adhesive force Etc. performance, and the moistening to pigment, make pigment have good transitivity, printing performance and film properties All have a great impact.Preferably UV resin is in addition to possessing the unsaturation of height, also should possess relatively Stability.It is readily transported, stores and the production of ink.
UV resin used in UV ink is typically esters of acrylic acid prepolymer, esters of acrylic acid Prepolymer is due to its excellent hydrolytic stability and light stability, and UV curing rate is fast, thus extensively In UV curing system.Conventional esters of acrylic acid prepolymer mainly has epoxy acrylic resin, poly- Urethane acrylate resin, polyester acrylate resin etc.
In development process, we initially with polyurethane resin as improve adhesive force alternative, Test is tested adhesive force and improves notable, also can meet requirement for post-treatment tensile property.But emulsifying Poor-performing, by adding emulsion resistance auxiliary agent, emulsification rate decreases.In conjunction with tin graphed sheet printer damping roller Few, the uppity feature of the water yield, finally abandon this thinking, have selected with polyester acrylic and spy Planting acrylic resin as matrix resin in UV tin graphed sheet offset ink, special acrylic acid resin is at ring Blending part thermosetting acrylic resin on the basis of epoxy resins, ink attachment is had very great help by this resin. Meanwhile, epoxy resin cure speed is fast, becomes film hardness good.Post-treatment is stretched, and scratch resistant performance Helpful.
2, the choosing of activated monomer
Resin viscosity owing to selecting is higher, therefore to add amount of activated monomer in ink formulations with fall The viscosity of low system, increases mobile performance.Simultaneously in order to make the curing rate of UV tin graphed sheet offset ink reach To design requirement, in addition it is also necessary to considering that monomer whose institute is double bond containing how much, activity size, monomer is to resin Dissolving power, the factor to aspects such as the corrosivity of printer rubber roll and blanket.
Generally UV offset ink monomer selects mostly to be polyfunctionality monomer, and this time tin printing ink, fully examines Considering and stretch factor to post-press finishing, have selected SR9020, SR9020 is long-chain three-functionality-degree monomer, As regulation ink viscosity monomer.Entitled (3) third oxidation glycerol three acrylic acid of chemistry of SR9020 The features such as ester, has reactivity high, film forming good toughness.
3, talcous determine
Pulvis Talci can improve hiding rare, improves adhesive force and weatherability, improves the suspension of ink Property dryness, water-resistance, printing resistance, there is good pigment ductility, it is possible to decrease other usage amounts 5-10%, Lightness to color, color and saturation product hardness are low, and the abrasion to equipment is little, have higher change Learning inertia and temperature tolerance, test determines that talcous weight percentage is 4-4.5.
4, the determination of light trigger
The determination light trigger of light trigger plays very important effect in ink.The dryness of ink Except by resin, monomer, outside the impact of pigment, it is often more important that the use of light trigger.To different The ink of color, owing to the absorption of pigment is different with the ability of reflection light, thus adds identical light Its speed being dried of initiator differs.In same color ink, only add a kind of light-initiated Agent tends not to make the dry of ink reach optimum state;Need to select the most of the same race according to different pigment The light trigger of class carries out reasonably combined, so that its efficiency of initiation reaches optimal.At ultraviolet cured printing In ink formulations design, due to selected resin and monomer, it is different from conventional material, comparatively speaking Curing rate is slow, therefore to reach to design requirement and be necessary for light trigger carrying out screening with rationally Compounding, thus ensure that curing rate reaches to design requirement.
In process of the test, we are different types of light-initiated for the ink variety adoption of different colours Agent carries out compounding use, and it is 5-6, light trigger ITX that weight percentage is respectively as follows: light trigger 907 Being 1 for 2-3, photoinitiator b DK, light trigger 369 is 0-3, makes up to optimum efficiency, from And ensure that assorted ink sample can reach to design requirement.
5, the choosing of auxiliary agent
Selection of auxiliary auxiliary agent 510, is the high-efficiency polymerization inhibitor of UV formula system, and Main Function is to prevent UV Coating, UV ink product occurs auto polymerization to react in storage process, extends the storage of UV formulation product Time.For the anti-settling property that ethylene-acrylic acid copolymer auxiliary agent is excellent, gel, it is easy to dispersion, It is prone to add, prevents pigment sedimentation or caking, the minimum that affects of viscosity is promoted that those are difficult to moisten Being uniformly distributed of wet metallic pigments.
6, the determination of pigment
Used by UV tin printing ink, pigment is affected by processing characteristic thereafter, pigment proposes many and newly wants Ask, the requirement such as including high temperature resistant, resistance to steaming and decocting.In order to realize above-mentioned new demand, we are oily at design fuchsin Mo Zhong, have collected several cochineal and carries out test of drawing a design, and finally we have selected L5B01 fuchsin face Material, its vividness is high, and good luster, transparency is good, disclosure satisfy that high-temperature discoloration is little, resistance to steaming and decocting simultaneously Etc. feature.
Phthalocyanine blue pigment, carbon black majority meets high temperature resistant, resistance to conditions of cooking, and focus is put by we Carry out, in terms of the whole toner selection of yellow pigment and tusche, its performance of experimental test of drawing a design.Yellow pigment is wished full The foot high grade of transparency, the features such as high-temperature discoloration is little, resistance to steaming and decocting, by experimental selection Shanghai Lai Bo pigment factory A middle yellow pigment.It is experimentally confirmed the black whole toner interpolation whole chromatic effect of purple good, purple kind More, form and aspect differ greatly, and finally No. 23 purples of selection are as whole toner pigment, effect that this pigment is high temperature resistant The best, the tusche concentration coordinating carbon black pigment and phthalocyanine blue pigment to make is high, and color is full.
Specific embodiment
Embodiment 1:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: resin is 60-69, Activity is monomer 1.9-10.4, and Pulvis Talci is 4-4.5, and initiator is 8-13, and auxiliary agent is 0.1, color Color pigment is 10.4-17.3.
Embodiment 2:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: polyester acrylic tree Fat is 19, and special acrylic acid resin is 41-50, Pulvis Talci be 4-4.5, SR9020 be 1.9-10.4, Light trigger 907 is 5-6, and light trigger ITX is 2-3, and photoinitiator b DK is 1, light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, and color pigment is 10.4-17.3.
Embodiment 3:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: polyester acrylic tree Fat is 19, special acrylic acid resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, Light trigger 907 is 5-6, and light trigger ITX is 2-3, and photoinitiator b DK is 1, light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, and fuchsin is 10.4-17.3.
Embodiment 4:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: polyester acrylic tree Fat is 19, special acrylic acid resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, Light trigger 907 is 5-6, and light trigger ITX is 2-3, and photoinitiator b DK is 1, light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, and middle Huang is 10.4-17.3.
Embodiment 5:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: polyester acrylic tree Fat is 19, special acrylic acid resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, Light trigger 907 is 5-6, and light trigger ITX is 2-3, and photoinitiator b DK is 1, light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, and phthalocyanine blue is 10.4-17.3.
Embodiment 6:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: polyester acrylic tree Fat is 19, special acrylic acid resin be 41-50, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, Light trigger 907 is 5-6, and light trigger ITX is 2-3, and photoinitiator b DK is 1, light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, and phthalocyanine blue is 0-3.1, and white carbon black is 10.4-14.1, and purple is 0-1.1. Embodiment 7:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: polyester acrylic tree Fat is 19, and special acrylic acid resin is 41, and SR9020 is 10.4, and Pulvis Talci is 4.5, light trigger 907 is 5, and light trigger ITX is 3, photoinitiator b DK be 1,510 auxiliary agents be 0.1, fuchsin is 16。
Embodiment 8:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: polyester acrylic tree Fat is 19, and special acrylic acid resin is 50, and SR9020 is 7.5, and Pulvis Talci is 4, light trigger 907 Being 5, light trigger ITX is 3, photoinitiator b DK be 1,510 auxiliary agents be 0.1, middle Huang is 10.4.
Embodiment 9:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: polyester acrylic tree Fat is 19, and special acrylic acid resin is 44, and SR9020 is 7.5, and Pulvis Talci is 4, light trigger 907 Being 5, light trigger ITX is 3, photoinitiator b DK be 1,510 auxiliary agents be 0.1, phthalocyanine blue is 10.4-17.3。
Embodiment 10:
A kind of UV tin graphed sheet offset ink, each material composition and weight percentage be: polyester acrylic tree Fat is 19, and special acrylic acid resin is 45.7, and SR9020 is 1.9, and Pulvis Talci is 4, light trigger 907 is 6, and light trigger ITX is 2, and photoinitiator b DK is 1, and light trigger 369 is 3,510 Auxiliary agent is 0.1, and phthalocyanine blue is 3.1, and white carbon black is 14.1, and purple is 1.1.
Properties of product are tested
By substantial amounts of experimental work and the most perfect, the indices through detection ink reaches to set The requirement of meter.
By substantial amounts of experiment work and continuous modification and perfection, eventually pass through high-volume test produce, Detection, the indices of ink reaches to design requirement.Its testing result is as follows:
After UV tin graphed sheet offset ink is made, print on the HYP45B-3 metallic plate offset press of space Hua Use, machine speed 4900/hour, primary coat Bai Keding.After printing, user thinks that its adhesive force is good, dry Dry performance meets the requirement of printing, and ink color is bright-coloured, and site is clear, and transferability is good, and abnormal smells from the patient is low, By post-press finishing technique, ink meets technological requirement.
In sum, UV tin graphed sheet offset ink properties of product are excellent, and speed is fast, color is fresh admittedly to have light The feature such as gorgeous, concentration is high, transparency good, site is clear, and adhesive force is high, ink film good toughness, meets The technological requirement of post-press finishing.To strengthen from now on to marketing dynamics, carry out the propaganda work of product, Meet the market demand.
Above the example of the present invention is described in detail, but described content has been only the preferable of the present invention Embodiment, it is impossible to be considered the practical range for limiting the present invention.All according to the present patent application scope institute Impartial change and the improvement etc. made, within all should still belonging to the patent covering scope of the present invention.

Claims (8)

1. a UV tin graphed sheet offset ink, it is characterised in that: each material composition and weight percentage be: Resin is 60-69, and activity is monomer 1.9-10.4, and Pulvis Talci is 4-4.5, and initiator is 8-13, auxiliary agent Being 0.1, color pigment is 10.4-17.3.
A kind of UV tin graphed sheet offset ink the most according to claim 1, it is characterised in that: described tree Fat includes polyester acrylate resin and special acrylic acid resin;
Described activated monomer is SR9020;
Described initiator includes light trigger 907, light trigger ITX, and photoinitiator b DK and light draw Send out 369;
Described auxiliary agent is auxiliary agent 510.
A kind of UV tin graphed sheet offset ink the most according to claim 2, it is characterised in that: each material Component and weight percentage be: polyester acrylate resin is 19, and special acrylic acid resin is 41-50, Pulvis Talci be 4-4.5, SR9020 be 1.9-10.4, Pulvis Talci is 4-4.5, and light trigger 907 is 5-6, Light trigger ITX is 2-3, and photoinitiator b DK is 1, and light trigger 369 is 0-3,510 auxiliary agents Being 0.1, color pigment is 10.4-17.3.
A kind of UV tin graphed sheet offset ink the most according to claim 3, it is characterised in that: described coloured silk Color pigment is red, yellow, sky blue, the one in black four kinds of colors, and the pigment of red selection is fuchsin, yellow The pigment that color is selected is middle yellow pigment, and the pigment that sky blue is selected is phthalocyanine blue, the pigment that black is selected For phthalocyanine blue, white carbon black and purple mixture.
A kind of UV tin graphed sheet offset ink the most according to claim 4, it is characterised in that: each material Component and weight percentage be: polyester acrylate resin is 19, and special acrylic acid resin is 41-50, SR9020 is 1.9-10.4, and Pulvis Talci is 4-4.5, and light trigger 907 is 5-6, light trigger ITX Being 1 for 2-3, photoinitiator b DK, light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, and fuchsin is 10.4-17.3。
A kind of UV tin graphed sheet offset ink the most according to claim 4, it is characterised in that: each material Component and weight percentage be: polyester acrylate resin is 19, and special acrylic acid resin is 41-50, SR9020 is 1.9-10.4, and Pulvis Talci is 4-4.5, and light trigger 907 is 5-6, light trigger ITX Being 1 for 2-3, photoinitiator b DK, light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, and middle Huang is 10.4-17.3。
A kind of UV tin graphed sheet offset ink the most according to claim 4, it is characterised in that: each thing Matter component and weight percentage be: polyester acrylate resin is 19, and special acrylic acid resin is 41-50, SR9020 is 1.9-10.4, and Pulvis Talci is 4-4.5, and light trigger 907 is 5-6, light trigger ITX Being 1 for 2-3, photoinitiator b DK, light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, phthalocyanine blue For 10.4-17.3.
A kind of UV tin graphed sheet offset ink the most according to claim 4, it is characterised in that: each thing Matter component and weight percentage be: polyester acrylate resin is 19, and special acrylic acid resin is 41-50, SR9020 is 1.9-10.4, and Pulvis Talci is 4-4.5, and light trigger 907 is 5-6, light trigger ITX Being 1 for 2-3, photoinitiator b DK, light trigger 369 is 0-3, and 510 auxiliary agents are 0.1, phthalocyanine blue For 0-3.1, white carbon black is 10.4-14.1, and purple is 0-1.1.
CN201610506721.9A 2016-06-30 2016-06-30 UV(ultraviolet) metal decorating offset print ink Pending CN106009902A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107011722A (en) * 2017-06-02 2017-08-04 广州市尤特新材料有限公司 A kind of universal metal ink of ultraviolet light solidification and preparation method thereof
CN114990907A (en) * 2022-06-10 2022-09-02 苏州康丽达精密电子有限公司 Surface blackening process for conductive cloth

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104830211A (en) * 2015-05-18 2015-08-12 惠州德斯坤实业有限公司 UV (ultraviolet) offset printing gloss oil and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104830211A (en) * 2015-05-18 2015-08-12 惠州德斯坤实业有限公司 UV (ultraviolet) offset printing gloss oil and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
凌云星等: "《油墨技术手册 上》", 31 May 2009, 印刷工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107011722A (en) * 2017-06-02 2017-08-04 广州市尤特新材料有限公司 A kind of universal metal ink of ultraviolet light solidification and preparation method thereof
CN114990907A (en) * 2022-06-10 2022-09-02 苏州康丽达精密电子有限公司 Surface blackening process for conductive cloth

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Application publication date: 20161012