CN106009841A - Environmentally friendly nano coating and preparation method thereof - Google Patents

Environmentally friendly nano coating and preparation method thereof Download PDF

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Publication number
CN106009841A
CN106009841A CN201610570642.4A CN201610570642A CN106009841A CN 106009841 A CN106009841 A CN 106009841A CN 201610570642 A CN201610570642 A CN 201610570642A CN 106009841 A CN106009841 A CN 106009841A
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CN
China
Prior art keywords
paint
environment protective
parts
protective nano
content
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Pending
Application number
CN201610570642.4A
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Chinese (zh)
Inventor
翟彬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHU HAOXUAN NEW ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
Original Assignee
WUHU HAOXUAN NEW ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
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Application filed by WUHU HAOXUAN NEW ENVIRONMENTAL PROTECTION MATERIAL Co Ltd filed Critical WUHU HAOXUAN NEW ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
Priority to CN201610570642.4A priority Critical patent/CN106009841A/en
Publication of CN106009841A publication Critical patent/CN106009841A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an environmentally friendly nano coating and a preparation method thereof. The environmentally friendly nano coating consists of the following raw materials in parts by weight: 20-40 parts of water, 60-100 parts of emulsion, 10-20 parts of a coloring agent, 15-35 parts of packing, 5-10 parts of an adhesive, 1-5 parts of a diluent and 2-5 parts of a corrosion inhibitor relative to 20 parts of silicate ester. The environmentally friendly nano coating has the characteristics of environmental friendliness and harmlessness.

Description

Environment protective nano-paint and preparation method thereof
Technical field
The present invention relates to coating prepare, be specifically related to environment protective nano-paint and preparation method thereof.
Background technology
Coating is a kind of material, and this material can be coated in by different construction technologies and be protected or filled The body surface of decorations, and can be formed with coated article adhere to firmly, to have some strength, continuous print solid-state thin Film.The thin film common name film formed, also known as paint film or coating.Coating is typically with resin, oil, emulsion Being main, coordinate pigment, other preparations such as additive, with the formulated mixture of organic solvent or water. At present, present on market, coating formula is unreasonable, and environmental pollution is serious, harm organism healthy and Preparation method is complex, and preparation technology is loaded down with trivial details.
Summary of the invention
It is an object of the invention to provide environment protective nano-paint and preparation method thereof, the painting prepared by the method Material has environmentally friendly effect.
To achieve these goals, the invention provides a kind of environment protective nano-paint, be made up of following raw material: Water, emulsion, coloring agent, filler, adhesive, diluent, corrosion inhibiter and esters of silicon acis；In parts by weight, Wherein, relative to 20 parts of esters of silicon acis, the content of described water be 20-40 part, the content of emulsion be 60-100 Part, the content of coloring agent be 10-20 part, the content of filler be 15-35 part, the content of adhesive be 5-10 Part, the content of diluent be 1-5 part, the content of corrosion inhibiter be 2-5 part.
Present invention also offers the preparation method of above-mentioned environment protective nano-paint, the method includes: by 20-40 Part water, 60-100 part emulsion, 10-20 part coloring agent, 15-35 part filler, 5-10 part adhesive, 1-5 Part diluent, 2-5 part corrosion inhibiter and 20 parts of esters of silicon acis stirring mixing, prepare environment protective nano-paint.
By technique scheme, the present invention is by stirring the raw material of each weight portion in reaction vessel Mixing mixing, be under agitation in close contact between material, react generation synergism each other, thus Prepare environment protective nano-paint.The method is a kind of with low cost, mild condition, environmental protection and operation letter Single stirring means, prepared environment protective nano-paint has environmentally friendly characteristic.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that this place is retouched The detailed description of the invention stated is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides a kind of environment protective nano-paint, be made up of following raw material: water, emulsion, coloring agent, Filler, adhesive, diluent, corrosion inhibiter and esters of silicon acis；In parts by weight, wherein, relative to 20 Part esters of silicon acis, the content of described water be 20-40 part, the content of emulsion be 60-100 part, the containing of coloring agent Amount is 10-20 part, the content of filler is 15-35 part, the content of adhesive is 5-10 part, diluent Content be 1-5 part, the content of corrosion inhibiter be 2-5 part.
In above-mentioned environment protective nano-paint, the concrete kind of emulsion used can select in wide scope, But in order to improve the environmentally friendly characteristic of environment protective nano-paint further, it is preferable that emulsion is selected from methyl One or more in acrylic acid methyl ester., acrylic emulsion, acrylic acid ester emulsion, ethylbenzene latex.
In above-mentioned environment protective nano-paint, the concrete kind of coloring agent used can be selected in wide scope Select, but in order to improve the environmentally friendly characteristic of environment protective nano-paint further, it is preferable that coloring agent selects One or more in titanium dioxide, chrome yellow, Cinnabaris.
In above-mentioned environment protective nano-paint, the concrete kind of filler used can select in wide scope, But prepare productivity in order to improve environment protective nano-paint further, it is preferable that filler selected from calcium carbonate, One or more in Pulvis Talci, laterite.
In above-mentioned environment protective nano-paint, the concrete kind of adhesive used can be selected in wide scope Select, but in order to improve the environmentally friendly characteristic of environment protective nano-paint further, it is preferable that adhesive selects One or more in polyvinyl acetate, cellulose esters, polyvinyl acetate, polyvinyl alcohol.
In above-mentioned environment protective nano-paint, the concrete kind of diluent used can be selected in wide scope Select, but in order to improve the environmentally friendly characteristic of environment protective nano-paint further, it is preferable that diluent selects One or more in dimethylbenzene, n-butyl alcohol, styrene, ethyl acetate.
In above-mentioned environment protective nano-paint, used by have the concrete kind of corrosion inhibiter can select in wide scope Select, but in order to improve the environmentally friendly characteristic of environment protective nano-paint further, it is preferable that corrosion inhibiter selects One in lead naphthenate, zinc naphthenate, petroleum sodium sulfonate, barium mahogany sulfonate, calcium mahogany sulfonate or Multiple.
Present invention also offers the preparation method of above-mentioned environment protective nano-paint, the method includes: Jiang Shui, breast Liquid, coloring agent, filler, adhesive, diluent, corrosion inhibiter and esters of silicon acis stirring mixing are with prepared environmental protection Nano paint.
In above-mentioned preparation method, speed and the time of stirring mixing can select in wide scope, but It is to prepare productivity in order to improve environment protective nano-paint further, it is preferable that the speed of stirring is 3000-4000rpm, the time of stirring is 5-15h.
In above-mentioned preparation method, there is no particular limitation for the temperature mixing stirring, can be in heating Under the conditions of carry out, it is also possible to carry out under conditions of not heating, from environment protective nano-paint prepare productivity and Consider on environmental angle, it is preferable that the temperature of stirring is 20-35 DEG C.
Hereinafter will be described the present invention by embodiment.
Embodiment 1
At 20 DEG C, select a reaction vessel, by the raw material of following weight portion: 20 parts of water, 60 parts of first Base acrylic acid methyl ester., 10 parts of titanium dioxides, 15 parts of calcium carbonate, 5 parts of polyvinyl acetate adhesives, 1 part two Toluene, 2 parts of lead naphthenates and 20 parts of esters of silicon acis are added thereto, and under the rotating speed of 3000rpm, stirring is mixed Close reaction 15h, prepare environment protective nano-paint A1.
Embodiment 2
At 35 DEG C, select a reaction vessel, by the raw material of following weight portion: 40 parts of water, 100 part third Olefin(e) acid emulsion, 20 parts of chrome yellow, 35 parts of Pulvis Talci, 10 parts of cellulose esters, 5 parts of n-butyl alcohol, 5 parts of cycloalkanes Acid zinc and 20 parts of esters of silicon acis are added thereto, and under the rotating speed of 4000rpm, stir hybrid reaction 5h, system Obtain environment protective nano-paint A2.
Embodiment 3
At 25 DEG C, select a reaction vessel, by the raw material of following weight portion: 30 parts of water, 80 part third Olefin(e) acid ester emulsion, 15 parts of Cinnabaris, 30 parts of laterite, 8 parts of polyvinyl acetate, 3 parts of styrene, 3 parts Petroleum sodium sulfonate and 20 parts of esters of silicon acis are added thereto, and under the rotating speed of 3500rpm, stir hybrid reaction 10h prepares environment protective nano-paint A3.
Embodiment 4
At 22 DEG C, select a reaction vessel, by the raw material of following weight portion: 25 parts of water, 75 parts of second Atrolactamide, 15 parts of titanium dioxides, 25 parts of Pulvis Talci, 6 parts of cellulose esters, 2 parts of dimethylbenzene, 4 parts of oil Sulfoacid calcium and 20 parts of esters of silicon acis are added thereto, and under the rotating speed of 3200rpm, stir hybrid reaction 12h, Prepare environment protective nano-paint A4.
Embodiment 5
At 28 DEG C, select a reaction vessel, by the raw material of following weight portion: 35 parts of water, 85 part third Olefin(e) acid ester emulsion, 17 parts of chrome yellow, 30 parts of calcium carbonate, 5 parts of polyvinyl alcohol, 5 parts of styrene, 3 parts of stones Oil barium sulfonate and 20 parts of esters of silicon acis are added thereto, and under the rotating speed of 3700rpm, stir hybrid reaction 8h, Prepare environment protective nano-paint A5.
Comparative example 1
Coating B1 is prepared relative to embodiment 1, except that, add the consumption of methyl methacrylate Being 20 weight portions, the consumption of titanium dioxide is 5 weight portions.
Comparative example 2
Coating B2 is prepared relative to embodiment 2, except that, adding talcous consumption is 50 weights Amount part, the consumption of cellulose esters is 15 weight portions.
Comparative example 3
Coating B3 is prepared relative to embodiment 3, except that, except that, add oil sulfonic acid The consumption of sodium is 10 weight portions.
Detection example 1
The method that the coating preparing above-described embodiment and comparative example specifies according to GB 18582-2008 standard Detecting relevant parameter, concrete outcome is shown in Table 1.
Table 1
A1 A2 A3 A4 A5 B1 B2 B3
VOC content Meet Meet Meet Meet Meet Do not meet Meet Do not meet
Limit the use of solvent Meet Meet Meet Meet Meet Do not meet Do not meet Do not meet
Content of beary metal Meet Meet Meet Meet Meet Do not meet Meet Meet
Free formaldehyde content Meet Meet Meet Meet Meet Do not meet Do not meet Meet
Benzene content Meet Meet Meet Meet Meet Meet Meet Do not meet
Wherein, VOC represents VOC；By above-mentioned detection example, the present invention carries The environment protective nano-paint of confession meets GB 18582-2008 standard, has environmentally friendly effect, and preparation Method is simple.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited to above-mentioned reality Execute the detail in mode, in the technology concept of the present invention, can be to the technical side of the present invention Case carries out multiple simple variant, and these simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technology described in above-mentioned detailed description of the invention is special Levy, in the case of reconcilable, can be combined by any suitable means, in order to avoid need not The repetition wanted, various possible compound modes are illustrated by the present invention the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as its Without prejudice to the thought of the present invention, by the raw material of each weight portion being stirred in reaction vessel mixing, Under agitation being in close contact between material, react generation synergism each other, thus obtains environmental protection Nano paint, it should be considered as content disclosed in this invention equally.

Claims (10)

1. an environment protective nano-paint, it is characterised in that be made up of following raw material: water, emulsion, Toner, filler, adhesive, diluent, corrosion inhibiter and esters of silicon acis；
In parts by weight, wherein, relative to 20 parts of esters of silicon acis, the content of described water is 20-40 part, The content of described emulsion is 60-100 part, and the content of described coloring agent is 10-20 part, containing of described filler Amount is 15-35 part, and the content of described adhesive is 5-10 part, and the content of described diluent is 1-5 part, The content of described corrosion inhibiter is 2-5 part.
Environment protective nano-paint the most according to claim 1, wherein, described emulsion is selected from methyl-prop One or more in e pioic acid methyl ester, acrylic emulsion, acrylic acid ester emulsion and ethylbenzene latex.
Environment protective nano-paint the most according to claim 1, wherein, described coloring agent is selected from titanium white One or more in powder, chrome yellow and Cinnabaris.
Environment protective nano-paint the most according to claim 1, wherein, described filler selected from calcium carbonate, One or more in Pulvis Talci and laterite.
Environment protective nano-paint the most according to claim 1, wherein, described adhesive is selected from poly-vinegar One or more in acid ethylene, cellulose esters, polyvinyl acetate and polyvinyl alcohol.
Environment protective nano-paint the most according to claim 1, wherein, described diluent is selected from diformazan One or more in benzene, n-butyl alcohol, styrene and ethyl acetate.
Environment protective nano-paint the most according to claim 1, wherein, described corrosion inhibiter is selected from cycloalkanes One or more in lead plumbate, zinc naphthenate, petroleum sodium sulfonate, barium mahogany sulfonate and calcium mahogany sulfonate.
8. a preparation method for the environment protective nano-paint as described in any one in claim 1-7, It is characterized in that, described preparation method includes: by described water, emulsion, coloring agent, filler, adhesive, Diluent, corrosion inhibiter and esters of silicon acis mixing, prepare described environment protective nano-paint.
The preparation method of environment protective nano-paint the most according to claim 8, wherein, described mixing Temperature be 20-35 DEG C, the time of described mixing is 5-15h.
The preparation method of environment protective nano-paint the most according to claim 8, wherein, described mixing Mode for stirring, the speed of described stirring is 3000-4000rpm.
CN201610570642.4A 2016-07-20 2016-07-20 Environmentally friendly nano coating and preparation method thereof Pending CN106009841A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
CN106009841A true CN106009841A (en) 2016-10-12

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107793795A (en) * 2017-10-26 2018-03-13 铜仁市万山区天下红实业发展有限责任公司 A kind of cinnabar embossment paint and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104231817A (en) * 2014-08-22 2014-12-24 青岛保利康新材料有限公司 Resin-type coating
CN105440836A (en) * 2015-12-15 2016-03-30 青岛宏宇环保空调设备有限公司 High efficiency waterproof coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104231817A (en) * 2014-08-22 2014-12-24 青岛保利康新材料有限公司 Resin-type coating
CN105440836A (en) * 2015-12-15 2016-03-30 青岛宏宇环保空调设备有限公司 High efficiency waterproof coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107793795A (en) * 2017-10-26 2018-03-13 铜仁市万山区天下红实业发展有限责任公司 A kind of cinnabar embossment paint and preparation method thereof

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Application publication date: 20161012