CN106009356A - Anti-ultraviolet black master batch and preparation method thereof - Google Patents
Anti-ultraviolet black master batch and preparation method thereof Download PDFInfo
- Publication number
- CN106009356A CN106009356A CN201610342940.8A CN201610342940A CN106009356A CN 106009356 A CN106009356 A CN 106009356A CN 201610342940 A CN201610342940 A CN 201610342940A CN 106009356 A CN106009356 A CN 106009356A
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- China
- Prior art keywords
- uvioresistant
- black
- resin
- master batch
- black agglomerate
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Abstract
The invention relates to an anti-ultraviolet black master batch. The anti-ultraviolet black master batch comprises the following components in percentage by mass: 30% to 50% of carbon black, 25% to 45% of carrier resin, 0.5% to 8% of dispersant, 3% to 8% of high-temperature stabilizer, and 0.5% to 13% of anti-ultraviolet stabilizer. The invention also relates to a preparation method of the anti-ultraviolet black master batch. The preparation method comprises the following steps of weighing the components according to the weight proportion, respectively adding into a high-speed mixer, and stirring for 10-20min at the rotation speed of 1500-1800r/min; after uniform mixing, discharging the material, adding into a double-screw extruder, melting and mixing at the temperature of 180-260 DEG C, extruding and granulating, cooling, drying, and packaging, so as to obtain the required black master batch. The black master batch has the advantages that the anti-ultraviolet function is realized, and the use requirement is met.
Description
Technical field
The present invention relates to technical field of polymer materials, particularly relate to a kind of uvioresistant black agglomerate and preparation side thereof
Method.
Background technology
Black masterbatch is the one of Masterbatch, but its status is the most somewhat different with other Masterbatch.Black masterbatch is to mould
A kind of Masterbatch the most frequently used in glue processing, a kind of Masterbatch that also amount of being is maximum.Black masterbatch is by a high proportion of
Pigment or additive and thermoplastic resin, through the plastic colorant of fine dispersion, its selected resin pair
Coloring agent has good wet and peptizaiton, and has the good compatibility with being colored material, it may be assumed that face
Material+carrier+additive=Masterbatch.Black masterbatch is widely used in plastic processing industry, such as injection mo(u)lding, extrusion
Molding and blow molding etc..In actual life, it is widely used in the injection mo(u)lding of automotive plastic parts, moulds
In the extrusion molding of material tubing, in the production of farm-oriented mulch and earth working material.Prior art does not also have uvioresistant black
Master batch and preparation method thereof.
Summary of the invention
It is an object of the invention to for the above-mentioned problems in the prior art, it is provided that a kind of uvioresistant black agglomerate
And preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is: a kind of uvioresistant black agglomerate, its each group
The mass percent divided is:
White carbon black 30%-50%；
Vector resin 25%-45%；
Dispersant 0.5%-8%；
High-temperature stabilizer 3%-8%；
Uvioresistant stabilizer 0.5%-13%.
Further, described vector resin is acrylonitritrile-styrene resin, polystyrene resin, acrylonitrile
-BS, Merlon, acrylic resin, polyamide, poly terephthalic acid
More than one in glycol ester or polyvinyl resin.
Further, it is characterised in that: described dispersant be Polyethylene Glycol, calcium stearate, ultra-fine TAS-2A powder,
One in modified ethylene bis-fatty acid amides, pentaerythritol stearate, AClyn low-molecular-weight ionomer.
Further, it is characterised in that: described high-temperature stabilizer is Tissuemat E, polyester wax or N-4,4-
One in diphenyl methane dimaleimide.
Further, it is characterised in that: the model of described uvioresistant stabilizer be UV-3853S or
UV-3808PP5 or UV-3346 or UV-3529 or UV-2908.
Present invention also offers the preparation method of a kind of uvioresistant black agglomerate, comprise the following steps: join by weight
Ratio weighs each component, and is separately added in super mixer, stirs 10-20 under the rotating speed of 1500-1800r/min
Minute, rear discharging to be mixed adds in double screw extruder, passes through at a temperature of 180 DEG C～260 DEG C
Extruding pelletization after melting mixing, cools down, is dried, packs, and prepares required black masterbatch.
Compared with prior art, the beneficial effect comprise that: this black agglomerate has uvioresistant function,
Disclosure satisfy that use demand.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described:
Embodiment 1
A kind of uvioresistant black agglomerate, the mass percent of its each component is:
White carbon black 30%；
Acrylonitritrile-styrene resin 45%；
Calcium stearate 8%；
Tissuemat E 8%；
UV-3853S type uvioresistant stabilizer 9%.
The preparation method of a kind of uvioresistant black agglomerate, comprises the following steps: weigh each group by above-mentioned weight proportion
Point, and be separately added in super mixer, stir 20 minutes under the rotating speed of 1500r/min, to be mixed all
Even rear discharging adds in double screw extruder, in 260oAt a temperature of C after melting mixing extruding pelletization, cold
But, it is dried, packs, black masterbatch needed for preparing.
Embodiment 2
A kind of uvioresistant black agglomerate, the mass percent of its each component is:
White carbon black 50%；
Merlon 33.5%；
Ultra-fine TAS-2A powder 0.5%；
N-4,4-diphenyl methane dimaleimide 3%；
UV-3529 type uvioresistant stabilizer 13%.
The preparation method of a kind of uvioresistant black agglomerate, comprises the following steps: weigh each group by above-mentioned weight proportion
Point, and be separately added in super mixer, stir 10 minutes under the rotating speed of 1800r/min, to be mixed all
Even rear discharging adds in double screw extruder, at a temperature of 180 DEG C after melting mixing extruding pelletization, cold
But, it is dried, packs, black masterbatch needed for preparing.
Embodiment 3
A kind of uvioresistant black agglomerate, the mass percent of its each component is:
White carbon black 50%；
Polyethylene terephthalate 33.5%；
AClyn low-molecular-weight ionomer 8%；
Polyester wax 8%；
UV-3346 type uvioresistant stabilizer 0.5%.
The preparation method of a kind of uvioresistant black agglomerate, comprises the following steps: weigh each group by above-mentioned weight proportion
Point, and be separately added in super mixer, stir 10 minutes under the rotating speed of 1800r/min, to be mixed all
Even rear discharging adds in double screw extruder, at a temperature of 180 DEG C after melting mixing extruding pelletization, cold
But, it is dried, packs, black masterbatch needed for preparing.
Embodiment 4
A kind of uvioresistant black agglomerate, the mass percent of its each component is:
White carbon black 50%；
Polyethylene terephthalate 25%；
AClyn low-molecular-weight ionomer 8%；
Polyester wax 8%；
UV-3346 type uvioresistant stabilizer 9%.
The preparation method of a kind of uvioresistant black agglomerate, comprises the following steps: weigh each group by above-mentioned weight proportion
Point, and be separately added in super mixer, stir 20 minutes under the rotating speed of 1500r/min, to be mixed all
Even rear discharging adds in double screw extruder, at a temperature of 180 DEG C after melting mixing extruding pelletization, cold
But, it is dried, packs, black masterbatch needed for preparing.
This black agglomerate has uvioresistant function, it is possible to meet use demand.
Above by embodiment, the present invention is described in detail, but described content has been only the preferable of the present invention
Embodiment, it is impossible to be considered the practical range for limiting the present invention.All according to the present patent application scope made equal
Deng change and improvement etc., within all should still belonging to the patent covering scope of the present invention.
Claims (6)
1. a uvioresistant black agglomerate, it is characterised in that the mass percent of its each component is:
White carbon black 25%-50%；
Vector resin 25%-45%；
Dispersant 0.5%-8%；
High-temperature stabilizer 3%-8%；
Uvioresistant stabilizer 0.5%-13%.
Uvioresistant black agglomerate the most according to claim 1, it is characterised in that: described vector resin is
Acrylonitritrile-styrene resin, polystyrene resin, acrylonitrile-butadiene-styrene copolymer, poly-carbon
One in acid esters, acrylic resin, polyamide, polyethylene terephthalate or polyvinyl resin
Above.
Uvioresistant black agglomerate the most according to claim 1, it is characterised in that: described dispersant is poly-
Ethylene glycol, calcium stearate, ultra-fine TAS-2A powder, modified ethylene bis-fatty acid amides, tetramethylolmethane stearic acid
One in ester, AClyn low-molecular-weight ionomer.
Uvioresistant black agglomerate the most according to claim 1, it is characterised in that: described high-temperature stabilizer
For Tissuemat E, polyester wax or N-4, the one in 4-diphenyl methane dimaleimide.
Uvioresistant black agglomerate the most according to claim 1, it is characterised in that: described uvioresistant is steady
The model determining agent is UV-3853S or UV-3808PP5 or UV-3346 or UV-3529 or UV-2908.
The preparation method of a kind of uvioresistant black agglomerate the most according to claim 1, it is characterised in that
Comprise the following steps: weigh each component by weight ratio, and be separately added in super mixer,
Stirring 10-20 minute under the rotating speed of 1500-1800r/min, rear discharging to be mixed adds double screw extruder
In, at a temperature of 180 DEG C～260 DEG C after melting mixing extruding pelletization, cool down, be dried, pack,
Prepare required black masterbatch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610342940.8A CN106009356A (en) | 2016-05-23 | 2016-05-23 | Anti-ultraviolet black master batch and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610342940.8A CN106009356A (en) | 2016-05-23 | 2016-05-23 | Anti-ultraviolet black master batch and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN106009356A true CN106009356A (en) | 2016-10-12 |
Family
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| CN201610342940.8A Pending CN106009356A (en) | 2016-05-23 | 2016-05-23 | Anti-ultraviolet black master batch and preparation method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151389A (en) * | 2017-07-06 | 2017-09-12 | 盐城瑞泽色母粒有限公司 | Ultra-dispersed Masterbatch of a kind of special bright black of polypropylene spunbondeds and preparation method thereof |
| CN107163398A (en) * | 2017-07-06 | 2017-09-15 | 盐城瑞泽色母粒有限公司 | A kind of polypropylene color masterbatch of graphene-containing and preparation method thereof |
| CN107200981A (en) * | 2017-07-19 | 2017-09-26 | 成都新柯力化工科技有限公司 | A kind of antiultraviolet plastic matrix and preparation method |
| CN107286467A (en) * | 2017-07-06 | 2017-10-24 | 盐城瑞泽色母粒有限公司 | A kind of polypropylene water repellent non-woven fabrics special color master batch and preparation method thereof |
| CN107286466A (en) * | 2017-07-06 | 2017-10-24 | 盐城瑞泽色母粒有限公司 | A kind of polypropylene color masterbatch of the toner containing nanometer and preparation method thereof |
| CN109852014A (en) * | 2019-01-11 | 2019-06-07 | 深圳市金志成塑胶科技有限公司 | A kind of anti-UV agglomerate material of BOPET and its preparation process |
| CN111534881A (en) * | 2020-04-23 | 2020-08-14 | 张为凤 | Uvioresistant polyester filament yarn and production method thereof |
| CN111849142A (en) * | 2020-07-29 | 2020-10-30 | 余姚市和众塑料有限公司 | Semiconductive PC black master batch and preparation method thereof |
| CN113563715A (en) * | 2021-07-20 | 2021-10-29 | 南京聚隆科技股份有限公司 | High-glass-fiber weather-resistant black nylon material |
| CN114573959A (en) * | 2022-03-22 | 2022-06-03 | 上海金发科技发展有限公司 | PET composition and application thereof |
| CN116461008A (en) * | 2023-06-15 | 2023-07-21 | 山东壹贰叁塑胶有限公司 | Method and equipment for preparing carbon black master batch |
-
2016
- 2016-05-23 CN CN201610342940.8A patent/CN106009356A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286466A (en) * | 2017-07-06 | 2017-10-24 | 盐城瑞泽色母粒有限公司 | A kind of polypropylene color masterbatch of the toner containing nanometer and preparation method thereof |
| CN107163398A (en) * | 2017-07-06 | 2017-09-15 | 盐城瑞泽色母粒有限公司 | A kind of polypropylene color masterbatch of graphene-containing and preparation method thereof |
| CN107151389A (en) * | 2017-07-06 | 2017-09-12 | 盐城瑞泽色母粒有限公司 | Ultra-dispersed Masterbatch of a kind of special bright black of polypropylene spunbondeds and preparation method thereof |
| CN107286467A (en) * | 2017-07-06 | 2017-10-24 | 盐城瑞泽色母粒有限公司 | A kind of polypropylene water repellent non-woven fabrics special color master batch and preparation method thereof |
| CN107200981B (en) * | 2017-07-19 | 2019-06-11 | 浙江乍浦塑料制品有限公司 | A kind of antiultraviolet plastic matrix and preparation method |
| CN107200981A (en) * | 2017-07-19 | 2017-09-26 | 成都新柯力化工科技有限公司 | A kind of antiultraviolet plastic matrix and preparation method |
| CN109852014A (en) * | 2019-01-11 | 2019-06-07 | 深圳市金志成塑胶科技有限公司 | A kind of anti-UV agglomerate material of BOPET and its preparation process |
| CN111534881A (en) * | 2020-04-23 | 2020-08-14 | 张为凤 | Uvioresistant polyester filament yarn and production method thereof |
| CN111849142A (en) * | 2020-07-29 | 2020-10-30 | 余姚市和众塑料有限公司 | Semiconductive PC black master batch and preparation method thereof |
| CN113563715A (en) * | 2021-07-20 | 2021-10-29 | 南京聚隆科技股份有限公司 | High-glass-fiber weather-resistant black nylon material |
| CN113563715B (en) * | 2021-07-20 | 2023-11-10 | 南京聚隆科技股份有限公司 | High-glass-fiber weather-resistant black nylon material |
| CN114573959A (en) * | 2022-03-22 | 2022-06-03 | 上海金发科技发展有限公司 | PET composition and application thereof |
| CN114573959B (en) * | 2022-03-22 | 2023-10-10 | 上海金发科技发展有限公司 | PET composition and application thereof |
| CN116461008A (en) * | 2023-06-15 | 2023-07-21 | 山东壹贰叁塑胶有限公司 | Method and equipment for preparing carbon black master batch |
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Legal Events
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161012 |