CN106006798A - High efficiency water purification composite material and preparation method thereof - Google Patents
High efficiency water purification composite material and preparation method thereof Download PDFInfo
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- CN106006798A CN106006798A CN201610648222.3A CN201610648222A CN106006798A CN 106006798 A CN106006798 A CN 106006798A CN 201610648222 A CN201610648222 A CN 201610648222A CN 106006798 A CN106006798 A CN 106006798A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
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- Hydrology & Water Resources (AREA)
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- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
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- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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Abstract
The invention discloses a high efficiency water purification composite material and a preparation method thereof. The high efficiency water purification composite material is prepared from 85-95 parts by weight of an aluminum ferric chloride polymer, 55-65 parts by weight of polyacrylamide, 10-20 parts by weight of bentonite powder, 5-15 parts by weight of calcium lignin sulphonate, 6-10 parts by weight of basic aluminum chloride and 5-7 parts by weight of polyethylene glycol 400 and benzotriazole. A weight part ratio of polyethylene glycol 400 to benzotriazole is 4-6: 1. The high efficiency water purification composite material has excellent water purification performances and can effectively remove heavy metals in sewage. The preparation method of the high efficiency water purification composite material has simple processes and is suitable for large scale production.
Description
Technical field
The invention belongs to field of compound material, be specifically related to a kind of High-efficient Water and purify composite and preparation method thereof.
Background technology
Exhaust along with the water that conventional water resource is day by day rare, the quality of drinking water deteriorates in time and increases uses, cause salt
Water pollutes, and water treatment technology is quickly becoming the necessary aspect of Modern Live.Additionally, due to various activities, such as manufacturing industry and
The development of agricultural, the pollution of waterhead that additive and toxic heavy metal easily cause, these problems cause in water system and general, antibacterial,
Salt, the increase of heavy metal.These water sources are the most easily by sanitary sewage, industrial wastewater and agricultural by-products.In order to ensure water resource
Cleaning and safety, need antibacterial, virus and the sporangiocyst removal removing in water.Although passing through chemical disinfection or ultraviolet radiation energy will
Fractionated viral and removal of bacteria, but heavy metal and other class impurity can not be removed by these sterilization methods by absorption or reaction.
Summary of the invention
The first object of the present invention is to provide a kind of High-efficient Water to purify composite；
The present invention the second purpose is the preparation method providing above-mentioned High-efficient Water to purify composite.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of High-efficient Water purifies composite, is prepared from by the raw material of following weight portion: PAFC, 85～95 parts；
Polyacrylamide, 55～65 parts；Bentonite in powder, 10～20 parts；Calcium lignosulfonate, 5～15 parts；Aluminium chlorhydroxide, 6～10
Part；PEG400 and BTA totally 5～7 parts, the two weight part ratio is 4～6:1.
Further, described High-efficient Water is purified composite and is prepared from by the raw material of following weight portion: PAFC,
90 parts；Polyacrylamide, 60 parts；Bentonite in powder, 15 parts；Calcium lignosulfonate, 10 parts；Aluminium chlorhydroxide, 8 parts；
PEG400 and BTA totally 6 parts, the two weight part ratio is 5:1.
Further, described High-efficient Water is purified composite and is prepared from by the raw material of following weight portion: PAFC,
85 parts；Polyacrylamide, 55 parts；Bentonite in powder, 10 parts；Calcium lignosulfonate, 5 parts；Aluminium chlorhydroxide, 6 parts；Poly-
Ethylene glycol 400 and BTA totally 5 parts, the two weight part ratio is 4:1.
Further, described High-efficient Water is purified composite and is prepared from by the raw material of following weight portion: PAFC,
95 parts；Polyacrylamide, 65 parts；Bentonite in powder, 20 parts；Calcium lignosulfonate, 15 parts；Aluminium chlorhydroxide, 10 parts；
PEG400 and BTA totally 7 parts, the two weight part ratio is 6:1.
Further, the mean molecule quantity of described polyacrylamide is 160～1,800,000.
Above-mentioned High-efficient Water purifies the preparation method of composite, comprises the steps:
Step S1, weighs PAFC, polyacrylamide, bentonite in powder, calcium lignosulfonate and alkali formula chlorine by weight
Change aluminum, use wet ball-milling method to be mixed uniformly, be heated to 160～180 DEG C under vacuum, add PEG400
And BTA, mist projection granulating, compressing；
Step S2, under 550～650 DEG C of inert atmospheres, middle insulation i.e. obtains described High-efficient Water for 2～3 hours and purifies composite.
Further, step S1 is heated to 170 DEG C under vacuum, adds PEG400 and BTA, spray
Mist pelletize, compressing.
Further, it is incubated 2.5 hours during step S2 is under 600 DEG C of nitrogen protective effects and get final product.
Advantages of the present invention:
The High-efficient Water that the present invention provides purifies composite and has the Water warfare performance of excellence, especially can efficiently remove the weight in sewage
Metal；It is simple that this High-efficient Water purifies composite material preparation process, can be with large-scale production.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit scope with this.To the greatest extent
The present invention is explained in detail by pipe with reference to preferred embodiment, it will be understood by those within the art that, can be to the present invention
Technical scheme modify or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: High-efficient Water purifies the preparation of composite
Parts by weight of raw materials compares:
PAFC, 90 parts；Polyacrylamide, 60 parts；Bentonite in powder, 15 parts；Calcium lignosulfonate, 10 parts；
Aluminium chlorhydroxide, 8 parts；PEG400 and BTA totally 6 parts, the two weight part ratio is 5:1.
Preparation method:
Step S1, weighs PAFC, polyacrylamide, bentonite in powder, calcium lignosulfonate and alkali formula chlorine by weight
Change aluminum, use wet ball-milling method be mixed uniformly, be heated to 170 DEG C under vacuum, add PEG400 with
BTA, mist projection granulating, compressing；
Step S2, under 600 DEG C of nitrogen protective effects, middle insulation i.e. obtains described High-efficient Water for 2.5 hours and purifies composite.
Embodiment 2: High-efficient Water purifies the preparation of composite
Parts by weight of raw materials compares:
PAFC, 85 parts；Polyacrylamide, 55 parts；Bentonite in powder, 10 parts；Calcium lignosulfonate, 5 parts；Alkali
Formula aluminum chloride, 6 parts；PEG400 and BTA totally 5 parts, the two weight part ratio is 4:1.
Preparation method:
Step S1, weighs PAFC, polyacrylamide, bentonite in powder, calcium lignosulfonate and alkali formula chlorine by weight
Change aluminum, use wet ball-milling method be mixed uniformly, be heated to 170 DEG C under vacuum, add PEG400 with
BTA, mist projection granulating, compressing；
Step S2, under 600 DEG C of nitrogen protective effects, middle insulation i.e. obtains described High-efficient Water for 2.5 hours and purifies composite.
Embodiment 3: High-efficient Water purifies the preparation of composite
Parts by weight of raw materials compares:
PAFC, 95 parts；Polyacrylamide, 65 parts；Bentonite in powder, 20 parts；Calcium lignosulfonate, 15 parts；
Aluminium chlorhydroxide, 10 parts；PEG400 and BTA totally 7 parts, the two weight part ratio is 6:1.
Preparation method:
Step S1, weighs PAFC, polyacrylamide, bentonite in powder, calcium lignosulfonate and alkali formula chlorine by weight
Change aluminum, use wet ball-milling method be mixed uniformly, be heated to 170 DEG C under vacuum, add PEG400 with
BTA, mist projection granulating, compressing；
Step S2, under 600 DEG C of nitrogen protective effects, middle insulation i.e. obtains described High-efficient Water for 2.5 hours and purifies composite.
Embodiment 4: High-efficient Water purifies the preparation of composite
Parts by weight of raw materials compares:
PAFC, 90 parts；Polyacrylamide, 60 parts；Bentonite in powder, 15 parts；Calcium lignosulfonate, 10 parts；
Aluminium chlorhydroxide, 8 parts；PEG400 and BTA totally 6 parts, the two weight part ratio is 4:1.
Preparation method:
Step S1, weighs PAFC, polyacrylamide, bentonite in powder, calcium lignosulfonate and alkali formula chlorine by weight
Change aluminum, use wet ball-milling method be mixed uniformly, be heated to 170 DEG C under vacuum, add PEG400 with
BTA, mist projection granulating, compressing；
Step S2, under 600 DEG C of nitrogen protective effects, middle insulation i.e. obtains described High-efficient Water for 2.5 hours and purifies composite.
Embodiment 5: High-efficient Water purifies the preparation of composite
Parts by weight of raw materials compares:
PAFC, 90 parts；Polyacrylamide, 60 parts；Bentonite in powder, 15 parts；Calcium lignosulfonate, 10 parts；
Aluminium chlorhydroxide, 8 parts；PEG400 and BTA totally 6 parts, the two weight part ratio is 6:1.
Preparation method:
Step S1, weighs PAFC, polyacrylamide, bentonite in powder, calcium lignosulfonate and alkali formula chlorine by weight
Change aluminum, use wet ball-milling method be mixed uniformly, be heated to 170 DEG C under vacuum, add PEG400 with
BTA, mist projection granulating, compressing；
Step S2, under 600 DEG C of nitrogen protective effects, middle insulation i.e. obtains described High-efficient Water for 2.5 hours and purifies composite.
Embodiment 6: comparative example
Parts by weight of raw materials compares:
PAFC, 90 parts；Polyacrylamide, 60 parts；Bentonite in powder, 15 parts；Calcium lignosulfonate, 10 parts；
Aluminium chlorhydroxide, 8 parts；PEG400 and BTA totally 6 parts, the two weight part ratio is 3:1.
Preparation method:
Step S1, weighs PAFC, polyacrylamide, bentonite in powder, calcium lignosulfonate and alkali formula chlorine by weight
Change aluminum, use wet ball-milling method be mixed uniformly, be heated to 170 DEG C under vacuum, add PEG400 with
BTA, mist projection granulating, compressing；
Step S2, under 600 DEG C of nitrogen protective effects, middle insulation i.e. obtains described High-efficient Water for 2.5 hours and purifies composite.
Embodiment 7: comparative example
Parts by weight of raw materials compares:
PAFC, 90 parts；Polyacrylamide, 60 parts；Bentonite in powder, 15 parts；Calcium lignosulfonate, 10 parts；
Aluminium chlorhydroxide, 8 parts；PEG400 and BTA totally 6 parts, the two weight part ratio is 7:1.
Preparation method:
Step S1, weighs PAFC, polyacrylamide, bentonite in powder, calcium lignosulfonate and alkali formula chlorine by weight
Change aluminum, use wet ball-milling method be mixed uniformly, be heated to 170 DEG C under vacuum, add PEG400 with
BTA, mist projection granulating, compressing；
Step S2, under 600 DEG C of nitrogen protective effects, middle insulation i.e. obtains described High-efficient Water for 2.5 hours and purifies composite.
Embodiment 8: effect example
The performance of the water purification material of testing example 1～7 preparation respectively.
Method of testing: arsenic in sewage (concentration is 0.2mg/L) and lead (concentration is 0.2mg/L) are gone by test water purification material
Except rate, every liter of sewage adds water purification material 50g, stands 20 minutes after stirring.
Result see table:
| Arsenic removal rate (%) | Lead clearance (%) | |
| Embodiment 1 | 99.8 | 99.8 |
| Embodiment 2 | 99.4 | 99.3 |
| Embodiment 3 | 99.5 | 99.4 |
| Embodiment 4 | 99.4 | 99.3 |
| Embodiment 5 | 99.5 | 99.4 |
| Embodiment 6 | 69.5 | 71.3 |
| Embodiment 7 | 68.6 | 70.2 |
The above results shows, the High-efficient Water that the present invention provides purifies composite and has the Water warfare performance of excellence, especially can be efficient
Remove the heavy metal in sewage.It is simple that this High-efficient Water purifies composite material preparation process, can be with large-scale production.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit protection scope of the present invention with this.
It will be understood by those within the art that, technical scheme can be modified or equivalent, and not take off
Essence and protection domain from technical solution of the present invention.
Claims (8)
1. a High-efficient Water purifies composite, it is characterised in that be prepared from by the raw material of following weight portion: polyaluminium
Ferro-aluminum, 85～95 parts；Polyacrylamide, 55～65 parts；Bentonite in powder, 10～20 parts；Calcium lignosulfonate, 5～15 parts；
Aluminium chlorhydroxide, 6～10 parts；PEG400 and BTA totally 5～7 parts, the two weight part ratio is 4～6:1.
High-efficient Water the most according to claim 1 purifies composite, it is characterised in that by the raw material system of following weight portion
For forming: PAFC, 90 parts；Polyacrylamide, 60 parts；Bentonite in powder, 15 parts；Calcium lignosulfonate, 10
Part；Aluminium chlorhydroxide, 8 parts；PEG400 and BTA totally 6 parts, the two weight part ratio is 5:1.
High-efficient Water the most according to claim 1 purifies composite, it is characterised in that by the raw material system of following weight portion
For forming: PAFC, 85 parts；Polyacrylamide, 55 parts；Bentonite in powder, 10 parts；Calcium lignosulfonate, 5 parts；
Aluminium chlorhydroxide, 6 parts；PEG400 and BTA totally 5 parts, the two weight part ratio is 4:1.
High-efficient Water the most according to claim 1 purifies composite, it is characterised in that by the raw material system of following weight portion
For forming: PAFC, 95 parts；Polyacrylamide, 65 parts；Bentonite in powder, 20 parts；Calcium lignosulfonate, 15
Part；Aluminium chlorhydroxide, 10 parts；PEG400 and BTA totally 7 parts, the two weight part ratio is 6:1.
5. purify composite according to the arbitrary described High-efficient Water of Claims 1 to 4, it is characterised in that: described polyacrylamide
Mean molecule quantity is 160～1,800,000.
6. the arbitrary described High-efficient Water of Claims 1 to 4 purifies the preparation method of composite, it is characterised in that comprise the steps:
Step S1, weighs PAFC, polyacrylamide, bentonite in powder, calcium lignosulfonate and alkali formula chlorine by weight
Change aluminum, use wet ball-milling method to be mixed uniformly, be heated to 160～180 DEG C under vacuum, add PEG400
And BTA, mist projection granulating, compressing；
Step S2, under 550～650 DEG C of inert atmospheres, middle insulation i.e. obtains described High-efficient Water for 2～3 hours and purifies composite.
Preparation method the most according to claim 6, it is characterised in that: step S1 is heated to 170 DEG C under vacuum,
Add PEG400 and BTA, mist projection granulating, compressing.
Preparation method the most according to claim 6, it is characterised in that: step S2 is middle under 600 DEG C of nitrogen protective effects protects
Temperature i.e. obtains described High-efficient Water for 2.5 hours and purifies composite.
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| CN201610648222.3A CN106006798B (en) | 2016-08-09 | 2016-08-09 | A kind of efficient Water warfare composite material and preparation method |
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| CN201610648222.3A CN106006798B (en) | 2016-08-09 | 2016-08-09 | A kind of efficient Water warfare composite material and preparation method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473403A (en) * | 2017-09-25 | 2017-12-15 | 芜湖恒杰膨润土科技有限公司 | A kind of purifying agent for polluted water |
| CN113772759A (en) * | 2021-09-16 | 2021-12-10 | 安徽庞海科技股份有限公司 | Efficient purifying material for floating liquid in space capsule and production process thereof |
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| CN104925969A (en) * | 2015-06-30 | 2015-09-23 | 青岛麦科三维高新技术有限公司 | Efficient water quality stabilizer |
| CN105129940A (en) * | 2015-08-28 | 2015-12-09 | 邓忆凯 | Novel industrial wastewater flocculating agent and preparation method thereof |
| CN105481116A (en) * | 2015-12-18 | 2016-04-13 | 宁波高新区夏远科技有限公司 | Circulating cooling water corrosion and scale inhibitor and preparation method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US6280628B1 (en) * | 1997-10-20 | 2001-08-28 | Cooperatie Cosun U.A. | Biodegradable complexing agents for heavy metals |
| CN104925969A (en) * | 2015-06-30 | 2015-09-23 | 青岛麦科三维高新技术有限公司 | Efficient water quality stabilizer |
| CN105129940A (en) * | 2015-08-28 | 2015-12-09 | 邓忆凯 | Novel industrial wastewater flocculating agent and preparation method thereof |
| CN105481116A (en) * | 2015-12-18 | 2016-04-13 | 宁波高新区夏远科技有限公司 | Circulating cooling water corrosion and scale inhibitor and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473403A (en) * | 2017-09-25 | 2017-12-15 | 芜湖恒杰膨润土科技有限公司 | A kind of purifying agent for polluted water |
| CN113772759A (en) * | 2021-09-16 | 2021-12-10 | 安徽庞海科技股份有限公司 | Efficient purifying material for floating liquid in space capsule and production process thereof |
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Effective date of registration: 20190729 Address after: 523000 Guangcheng Street Venture Community, Dongguan City, Guangdong Province 1309 Baida Center Office Building, No. 9 Guantai Road Patentee after: Dongguan Tianzheng Enterprise Management Consulting Co., Ltd. Address before: 523112 Guangdong province Dongguan City Bridge Village Yinzhu road Dongcheng District Dongcheng Street No. 26 Patentee before: Dongguan Crystal New Material Technology Co., Ltd. |