CN104843809A - Coking sewage treatment agent and preparing method thereof - Google Patents

Coking sewage treatment agent and preparing method thereof Download PDF

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Publication number
CN104843809A
CN104843809A CN201510258563.5A CN201510258563A CN104843809A CN 104843809 A CN104843809 A CN 104843809A CN 201510258563 A CN201510258563 A CN 201510258563A CN 104843809 A CN104843809 A CN 104843809A
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parts
flocculation agent
coking
sewage treatment
agent
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CN104843809B (en
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杜小卫
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Shenzhen Environmental Science And Technology Co Ltd
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Abstract

The invention relates to the field of sewage treatment, in particular to a coking sewage treatment agent and a preparing method of the coking sewage treatment agent. The coking sewage treatment agent and the preparing method are characterized in that 20 to 30 parts of ferric trichloride, 10 to 20 parts of aluminum polychlorid, 10 to 20 parts of polyferric sulfate, 5 to 10 parts of ferrous sulfate and 5 to 10 parts of zinc chloride are put into a reaction kettle; water is added; then, the temperature is controlled to be 20 to 28 DEG C; the stirring is carried out for 1h; then, 1 to 2 parts of anionic polyacrylamide are added for sufficient reaction; 5 to 10 parts of auxiliary ingredients of calcium oxide for precipitation purification, 2 to 4 parts of calcium aluminate powder and 3 to 5 parts of flocculating agents are added. The coking sewage treatment agent has higher removal rates on the chemical oxygen consumption, suspended materials and the chromacity. The method has the advantages that the operation cost is low, the decontamination effect is good, organic matters can be effectively degraded, odor is eliminated, and in addition, the effective decoloration is realized.

Description

A kind of coking sewage treating agent and preparation method thereof
Technical field
The present invention relates to sewage treatment area, particularly relate to a kind of coking sewage treating agent and preparation method thereof. background technology
Coking chemical waste water is the waste water that coke-oven plant produces in coke refining, gas purification process, containing a large amount of poisonous and harmful hard-degraded substances, as organism such as phenolic compound, fatty compounds, heterogeneous ring compound and polycyclic aromatic hydrocarbonss, these materials are very large to environmental hazard, according to reports, most of heterocycle and aromatic hydrocarbons have variable and carinogenicity, therefore, coking chemical waste water is processed, is very important.At present, China generally adopts the treating coking wastewater biologically that A/O etc. is traditional, but efficiency is lower, effectively cannot remove the aromatic hydrocarbons in coking chemical waste water and nitrogen-containing heterocycle compound, water outlet COD and ammonia nitrogen are difficult to qualified discharge simultaneously, therefore, be necessary to seek a kind of can the approach of COD and ammonia nitrogen in efficient removal coking chemical waste water simultaneously.
The random discharge of coked waste water causes environmental pollution important source of pollution, therefore from permanent consideration, need the more effective coking sewage treating agent of one, about coking sewage treating agent, generally adopt iron protochloride, bodied ferric sulfate, waste material flue dust by the laggard row relax of mixing at present, the treatment effect of above-mentioned treatment agent is poor, equipment used floor space is large, and construction cost is high, and facility investment is large, running cost is high, has certain limitation in applying.Degrade to objectionable impurities and process thorough not, problem is removed in the decomposition except poison, deodorizing problem and organic pollutant fully not solving sewage.Especially to some important indicators, the removal rate as chemical oxygen demand, suspended substance is very low, is difficult to the emission standard reaching national regulation, and easily produces residue, cause secondary pollution.
Summary of the invention
(1) technical problem solved
For the deficiencies in the prior art, the invention provides a kind of coking sewage treating agent and preparation method thereof, coking sewage treating agent of the present invention is a kind of coking sewage treating agent high to the removal rate of coking chemical oxygen consumption of sewage (COD), suspended substance (SS), colourity, make coking water rapidly and efficiently reach sewage drainage standard.
(2) technical scheme
Technical problem to be solved by this invention can be achieved through the following technical solutions:
A kind of coking sewage treating agent, its raw material is configured to by mass parts:
Iron trichloride 20-30 part polymerize aluminum chloride 10-20 part
The ferrous 5-10 part zinc chloride 5-10 part polyacrylamide 1-2 part of bodied ferric sulfate 10-20 part acid
Calcium oxide 5-10 part calcium aluminate powder 2-4 part
Flocculation agent 3-5 part.
A kind of coking sewage treating agent, its raw material is configured to by mass parts: iron trichloride 25-30 part polymerize aluminum chloride 15-20 part
Bodied ferric sulfate 15-20 part ferrous sulfate 8-10 part zinc chloride 8-10 part polyacrylamide 1-1.5 part
Calcium oxide 5-8 part calcium aluminate powder 2-4 part flocculation agent 3-5 part.
A kind of coking sewage treating agent, described flocculation agent comprise in chitosan class flocculation agent, modified starch flocculant, modified fibre flocculation agent, lignin flocculation agent, gummy flocculation agent, algin flocculation agent, gelatin flocculation agent one or several.
A kind of preparation method of coking sewage treating agent, its concrete preparation process is: iron trichloride 20-30 part, polymerize aluminum chloride 10-20 part, bodied ferric sulfate 10-20 part, ferrous sulfate 5-10 part, zinc chloride 5-10 part are put into reactor, then added water by (1); (2) controlled by temperature of reaction kettle to carry out more than stirring 1h at 20-28 DEG C, ancillary component calcium oxide 5-10 part, calcium aluminate powder 2-4 part of then adding anionic polyacrylamide 1-2 part and precipitation purification are fully reacted; (3) in reactor, add flocculation agent 3-5 part, temperature of reaction kettle is controlled carry out stirring 30-45 minute at 22-26 DEG C, make it fully react.
(3) beneficial effect
The invention provides a kind of coking sewage treating agent and preparation method thereof, a kind of coking sewage treating agent higher to the removal rate of coking chemical oxygen consumption of sewage (COD), suspended substance, colourity is provided, make coking water reach sewage drainage standard quickly and efficiently, and can not secondary pollution be produced.The present invention prepares coking sewage treating agent and uses cheaper starting materials to be easy to get, and the industrial ecology Circular Economic Thought of resource-based comprehensive utilization and trashformation reuse, low cost is prepared high added value coking sewage treating agent and is successfully applied to the process of coked waste water.The treatment effect of coking sewage treating agent of the present invention to coked waste water is better, by the present invention is carried out Experimental comparison with similar sewage-treating agent, through test of many times, verify that its effect is more stable, comparatively half is shortened in conventional processing agent in time, cost-saving, higher to the removal rate of coking chemical oxygen consumption of sewage (COD), suspended substance, colourity, can sewage drainage standard be reached, and can not secondary pollution be produced.Apply this treatment agent carry out Treatment of Coking Effluent application test research show, COD clearance reaches 78.82%, and chroma removal rate reaches 75%, and turbidity removal rate can reach 85.72%.
Embodiment
For making the object of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
embodiment 1:
In the present embodiment coking sewage treating agent raw material and be constructed as follows: iron trichloride 20 parts, polymerize aluminum chloride 10 parts, bodied ferric sulfate 10 parts, ferrous 5 parts of acid, zinc chloride 5 parts, polyacrylamide 1.5 parts, 8 parts, calcium oxide, calcium aluminate powder 3 parts, flocculation agent 4 parts.
Preparation method:
(1) iron trichloride 20 parts, polymerize aluminum chloride 10 parts, bodied ferric sulfate 10 parts, 5 parts, ferrous sulfate, zinc chloride 5 parts are put into reactor, then added water; (2) controlled by temperature of reaction kettle to carry out more than stirring 1h at 20-28 DEG C, 8 parts, ancillary component calcium oxide, calcium aluminate powder 3 parts of parts of then adding anionic polyacrylamide 1.5 parts and precipitation purification are fully reacted; (3) in reactor, add flocculation agent 4 parts, temperature of reaction kettle is controlled carry out stirring 30-45 minute at 22-26 DEG C, make it fully react, obtained finished product.
embodiment 2:
In the present embodiment coking sewage treating agent raw material and be constructed as follows: iron trichloride 25 parts, polymerize aluminum chloride 16 parts, bodied ferric sulfate 15 parts, ferrous 8 parts of acid, zinc chloride 8 parts, polyacrylamide 1.2 parts, 8 parts, calcium oxide, calcium aluminate powder 3 parts, flocculation agent 5 parts.
By the present embodiment weight part, preparation method is with embodiment 1.
embodiment 3:
In the present embodiment coking sewage treating agent raw material and be constructed as follows: iron trichloride 30 parts, polymerize aluminum chloride 20 parts, bodied ferric sulfate 20 parts, ferrous 10 parts of acid, zinc chloride 10 parts, polyacrylamide 1.5 parts, 8 parts, calcium oxide, calcium aluminate powder 4 parts, flocculation agent 5 parts.
By the present embodiment weight part, preparation method is with embodiment 1.
embodiment 4:
By sewage-treating agent obtained for embodiment 1 to embodiment 3, effluent cycle process experiment is carried out to the coked waste water of Ma Gang coke-oven plant, 1000 liters, sewage, pump flow 5m3/h, the model of ozonizer is 200g/h, per minute passes into oxygen 38 liters, and the ozone content after ozonizer process in oxygen is about 90mg/L.Sewage temperature is room temperature, containing hydro carbons and sulfocompound in sewage, has a strand unpleasant kerosene taste.Continue experiment 2h, sewage smells is by having unpleasant kerosene taste to smell disappearance, and occur lather collapse after a large amount of foam in process, final treatment effect is as shown in table 1.
The agent of table 1 different treatment is to COD contrast before and after the coked waste water process of Ma Gang coke-oven plant
It should be noted that, in this article, such as term " comprises ", " comprising " or its any other variant are intended to contain comprising of nonexcludability, thus make to comprise the process of a series of key element, method, article or equipment and not only comprise those key elements, but also comprise other key elements clearly do not listed, or also comprise by the intrinsic key element of this process, method, article or equipment.When not more restrictions, the key element limited by statement " comprising ... ", and be not precluded within process, method, article or the equipment comprising described key element and also there is other identical element.
Above embodiment only in order to technical scheme of the present invention to be described, is not intended to limit; Although with reference to previous embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that: it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (4)

1. a coking sewage treating agent, is characterized in that raw material is configured to by mass parts:
Iron trichloride 20-30 part
Polymerize aluminum chloride 10-20 part
Bodied ferric sulfate 10-20 part
Ferrous sulfate 5-10 part
Zinc chloride 5-10 part
Polyacrylamide 1-2 part
Calcium oxide 5-10 part
Calcium aluminate powder 2-4 part flocculation agent 3-5 part.
2. a kind of coking sewage treating agent according to claim 1, is characterized in that raw material is configured to by mass parts:
Iron trichloride 25-30 part
Polymerize aluminum chloride 15-20 part
Bodied ferric sulfate 15-20 part
Ferrous sulfate 8-10 part
Zinc chloride 8-10 part
Polyacrylamide 1-1.5 part
Calcium oxide 5-8 part
Calcium aluminate powder 2-4 part flocculation agent 3-5 part.
3. as claim 1-2 coking sewage treating agent as described in one of them, it is characterized in that, described flocculation agent comprise in chitosan class flocculation agent, modified starch flocculant, modified fibre flocculation agent, lignin flocculation agent, gummy flocculation agent, algin flocculation agent, gelatin flocculation agent one or several.
4. as the preparation method of claim 1-2 coking sewage treating agent as described in one of them, it is characterized in that, its concrete preparation process is: iron trichloride 20-30 part, polymerize aluminum chloride 10-20 part, bodied ferric sulfate 10-20 part, ferrous sulfate 5-10 part, zinc chloride 5-10 part are put into reactor, then added water by (1); (2) controlled by temperature of reaction kettle to carry out more than stirring 1h at 20-28 DEG C, ancillary component calcium oxide 5-10, calcium aluminate powder 2-4 part of then adding anionic polyacrylamide 1-2 part and precipitation purification are fully reacted; (3) in reactor, add flocculation agent 3-5 part, temperature of reaction kettle is controlled carry out stirring 30-45 minute at 22-26 DEG C, make it fully react.
CN201510258563.5A 2015-05-20 2015-05-20 Coking sewage treatment agent and preparing method thereof Active CN104843809B (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105253925A (en) * 2015-09-24 2016-01-20 安庆丰源化工有限公司 Decolouring deodorizing sewage treatment agent
CN105293598A (en) * 2015-09-24 2016-02-03 安庆丰源化工有限公司 Fine chemical wastewater treatment agent
CN105540805A (en) * 2015-12-08 2016-05-04 甘肃省建材科研设计院 Potato starch waste water macro-molecule organic matter separation treatment special-purpose flocculating agent
CN106396144A (en) * 2016-08-10 2017-02-15 仙桃市中楚化工有限责任公司 A water stabilizing agent for middle- and low-pressure steam boilers
CN106587212A (en) * 2016-12-30 2017-04-26 余姚市哈特馒餐饮有限公司 Sewage treatment agent for treating oily wastewater and preparation method of sewage treatment agent
CN106746192A (en) * 2016-12-08 2017-05-31 安徽睿知信信息科技有限公司 A kind of city domestic sewage processing method
CN107098406A (en) * 2017-05-14 2017-08-29 安徽泛亚环保科技有限公司 A kind of domestic sewage treating compound and its production method
CN107162207A (en) * 2017-05-14 2017-09-15 安徽泛亚环保科技有限公司 It is a kind of to reduce the medicament and its production method of sanitary sewage COD value
CN107265583A (en) * 2017-06-22 2017-10-20 四川省金晨科技有限公司 It is a kind of for composite flocculation agent of sewage disposal and preparation method thereof
CN107879396A (en) * 2017-12-08 2018-04-06 郑州源冉生物技术有限公司 A kind of efficiently coking sewage treating agent and preparation method thereof
CN108715507A (en) * 2018-05-25 2018-10-30 苏州佑君环境科技有限公司 A kind of method for sludge treatment based on cloud computing
CN114212912A (en) * 2021-12-09 2022-03-22 安徽汇源镀锌有限公司 Hot galvanizing wastewater treatment method for metal product

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101955251A (en) * 2010-09-07 2011-01-26 朱文强 Coking sewage treating agent and preparation method thereof
CN104445562A (en) * 2014-11-05 2015-03-25 南华大学 Preparation method of coking wastewater treating agent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101955251A (en) * 2010-09-07 2011-01-26 朱文强 Coking sewage treating agent and preparation method thereof
CN104445562A (en) * 2014-11-05 2015-03-25 南华大学 Preparation method of coking wastewater treating agent

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105253925A (en) * 2015-09-24 2016-01-20 安庆丰源化工有限公司 Decolouring deodorizing sewage treatment agent
CN105293598A (en) * 2015-09-24 2016-02-03 安庆丰源化工有限公司 Fine chemical wastewater treatment agent
CN105540805A (en) * 2015-12-08 2016-05-04 甘肃省建材科研设计院 Potato starch waste water macro-molecule organic matter separation treatment special-purpose flocculating agent
CN106396144A (en) * 2016-08-10 2017-02-15 仙桃市中楚化工有限责任公司 A water stabilizing agent for middle- and low-pressure steam boilers
CN106746192A (en) * 2016-12-08 2017-05-31 安徽睿知信信息科技有限公司 A kind of city domestic sewage processing method
CN106587212A (en) * 2016-12-30 2017-04-26 余姚市哈特馒餐饮有限公司 Sewage treatment agent for treating oily wastewater and preparation method of sewage treatment agent
CN107098406A (en) * 2017-05-14 2017-08-29 安徽泛亚环保科技有限公司 A kind of domestic sewage treating compound and its production method
CN107162207A (en) * 2017-05-14 2017-09-15 安徽泛亚环保科技有限公司 It is a kind of to reduce the medicament and its production method of sanitary sewage COD value
CN107265583A (en) * 2017-06-22 2017-10-20 四川省金晨科技有限公司 It is a kind of for composite flocculation agent of sewage disposal and preparation method thereof
CN107879396A (en) * 2017-12-08 2018-04-06 郑州源冉生物技术有限公司 A kind of efficiently coking sewage treating agent and preparation method thereof
CN108715507A (en) * 2018-05-25 2018-10-30 苏州佑君环境科技有限公司 A kind of method for sludge treatment based on cloud computing
CN114212912A (en) * 2021-12-09 2022-03-22 安徽汇源镀锌有限公司 Hot galvanizing wastewater treatment method for metal product
CN114212912B (en) * 2021-12-09 2024-02-13 安徽汇源镀锌有限公司 Hot galvanizing wastewater treatment method for metal products

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Inventor after: Cao Huaying

Inventor after: Guo Peijie

Inventor after: Lin Ruijun

Inventor after: Li Jun

Inventor after: Li Wenjing

Inventor after: Yan Lijie

Inventor after: Sheng Zhenwen

Inventor after: Luo Zhongbin

Inventor after: Peng Jingbo

Inventor after: Zhang Chuang

Inventor before: Du Xiaowei

COR Change of bibliographic data
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Effective date of registration: 20161118

Address after: 518000 Guangdong, Futian District Lotus Street news Road, East Building, information information, No. 2619, block

Applicant after: Shenzhen environmental science and Technology Co., Ltd.

Address before: 713300, Yang Zhongzu, new town, Linping Town, Xianyang, Shaanxi, Qianxian County

Applicant before: Du Xiaowei

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Denomination of invention: A coking wastewater treatment agent and its preparation method

Effective date of registration: 20201028

Granted publication date: 20170125

Pledgee: Bank of Jiangsu Limited by Share Ltd. Shenzhen branch

Pledgor: Shenzhen Toyusun Environmental Technology Co.,Ltd.

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