CN105969247A - Flame-retardant sealant for high-performance cable longitudinal sealing - Google Patents

Flame-retardant sealant for high-performance cable longitudinal sealing Download PDF

Info

Publication number
CN105969247A
CN105969247A CN201610339290.1A CN201610339290A CN105969247A CN 105969247 A CN105969247 A CN 105969247A CN 201610339290 A CN201610339290 A CN 201610339290A CN 105969247 A CN105969247 A CN 105969247A
Authority
CN
China
Prior art keywords
parts
longitudinal sealing
trichloroethane
cable longitudinal
flame retardant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610339290.1A
Other languages
Chinese (zh)
Inventor
王海岭
张红艳
胡光辉
范小树
王玲玲
周美彪
王飞
余宗明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Long'an Cable Group Co Ltd
Original Assignee
Anhui Long'an Cable Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Long'an Cable Group Co Ltd filed Critical Anhui Long'an Cable Group Co Ltd
Priority to CN201610339290.1A priority Critical patent/CN105969247A/en
Publication of CN105969247A publication Critical patent/CN105969247A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J111/00Adhesives based on homopolymers or copolymers of chloroprene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention discloses a flame-retardant sealant for high-performance cable longitudinal sealing. The sealant is prepared from the following raw materials in parts by weight: 100 parts of chloroprene rubber LDJ-240, 2-6 parts of magnesium oxide, 2-6 parts of zinc oxide, 2.05-2.7 parts of accelerator, 2-6 parts of anti-aging agent ODA, 20-50 parts of flame retardant HZR-2, 5-20 parts of antimony trioxide, 20-50 parts of coumarone, 10-40 parts of white carbon black, 0.5-2.5 parts of coupling agent KH-550 and 400-800 parts of 1,1,1-trichloroethane-isopropanol mixed solution. In the 1,1,1-trichloroethane-isopropanol mixed solution, the weight ratio of the 1,1,1-trichloroethane to the isopropanol is (7-13):1. The sealant has the advantages of no toxicity, environment friendliness and excellent flame retardancy.

Description

A kind of high performance cable longitudinal sealing flame retardant sealant
Technical field
The present invention relates to fluid sealant technical field, particularly relate to a kind of high performance cable longitudinal sealing flame retardant sealant.
Background technology
It is known that chloroprene rubber sealant is main molten with aromatic hydrocarbons such as benzene,toluene,xylene, gasoline, thiacyclohexane, acetone Agent, particularly containing benezene solvent, not only can cause human body chronic poisoning, makes people feel dizzy weak, and leukocyte declines, and may Thoroughly send out other pathological changes, and aromatic hydrocarbon solvent ignition point is the lowest, hold fire hazardous, it is impossible to meet and require flame retardant rating requirement Place.
Summary of the invention
The present invention proposes a kind of high performance cable longitudinal sealing flame retardant sealant, asepsis environment-protecting, and fire resistance is excellent Different.
A kind of high performance cable longitudinal sealing flame retardant sealant that the present invention proposes, its raw material includes by weight:
Wherein 1,1,1-trichloroethane is with isopropanol mixed liquor, and 1,1,1-trichloroethane is 7-with the weight ratio of isopropanol 13:1。
Preferably, accelerator include Vulcanization accelerator TMTD, altax, accelerant N A-22 one or more.
Preferably, accelerator includes Vulcanization accelerator TMTD, altax, accelerant N A-22 with 0.75-1:0.8-1:0.5- The weight ratio composition of 0.7.
Preferably, fire retardant HZR-2, the weight ratio of antimony oxide are 30-40:10-15.
Preferably, coupling agent KH-550, the weight ratio of age resistor ODA are 1-2:3-4.
Preferably, in 1,1,1-trichloroethane with isopropanol mixed liquor, 1,1,1-trichloroethane and the weight of isopropanol Ratio is 10:1.
Preferably, described high performance cable longitudinal sealing flame retardant sealant, its raw material includes by weight:
In the present invention, fire retardant HZR-2, antimony oxide mating reaction, anti-flammability is fabulous, with 1,1, the 1-trichlorine added Ethane and isopropanol mixed liquor synergism, further enhancing fire resistance, and oxygen index (OI) reaches more than 36%, due to use Being free from benzene equal solvent, toxicity is low, environmental protection, and common neoprene fluid sealant is all to use benzene,toluene,xylene etc. molten Agent, has toxicity, and easily meets fire burning, age resistor ODA and coupling agent KH-550 mating reaction, can be effectively improved fluid sealant Adhesive strength and thermostability, raw material comprehensive function of the present invention, not only low toxicity, fire-retardant, bonding force is high, and the bonding time is long, thermostability Good, peel strength is high, water-tolerant, and acid-proof alkaline is high, and the bonding time is fast, is especially applicable to cable longitudinal sealing fluid sealant.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of high performance cable longitudinal sealing flame retardant sealant, its raw material includes by weight:
Wherein 1,1,1-trichloroethane is with isopropanol mixed liquor, and 1,1,1-trichloroethane is 7 with the weight ratio of isopropanol: 1。
Embodiment 2
A kind of high performance cable longitudinal sealing flame retardant sealant, its raw material includes by weight:
Wherein 1,1,1-trichloroethane is with isopropanol mixed liquor, and 1,1,1-trichloroethane with the weight ratio of isopropanol is 13:1。
Embodiment 3
A kind of high performance cable longitudinal sealing flame retardant sealant, its raw material includes by weight:
Wherein 1,1,1-trichloroethane is with isopropanol mixed liquor, and 1,1,1-trichloroethane is 8 with the weight ratio of isopropanol: 1。
Embodiment 4
A kind of high performance cable longitudinal sealing flame retardant sealant, its raw material includes by weight:
Wherein 1,1,1-trichloroethane is with isopropanol mixed liquor, and 1,1,1-trichloroethane with the weight ratio of isopropanol is 11:1。
Embodiment 5
A kind of high performance cable longitudinal sealing flame retardant sealant, its raw material includes by weight:
Wherein 1,1,1-trichloroethane is with isopropanol mixed liquor, and 1,1,1-trichloroethane with the weight ratio of isopropanol is 10:1。
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (7)

1. a high performance cable longitudinal sealing flame retardant sealant, it is characterised in that its raw material includes by weight:
Wherein 1,1,1-trichloroethane is with isopropanol mixed liquor, and 1,1,1-trichloroethane is 7-13 with the weight ratio of isopropanol: 1。
High performance cable longitudinal sealing flame retardant sealant the most according to claim 1, it is characterised in that accelerator includes Vulcanization accelerator TMTD, altax, accelerant N A-22 one or more.
High performance cable longitudinal sealing flame retardant sealant the most according to claim 1 and 2, it is characterised in that accelerator Form including Vulcanization accelerator TMTD, altax, accelerant N A-22 the weight ratio with 0.75-1:0.8-1:0.5-0.7.
4. according to the high performance cable longitudinal sealing flame retardant sealant described in any one of claim 1-3, it is characterised in that resistance Combustion agent HZR-2, the weight ratio of antimony oxide are 30-40:10-15.
5. according to the high performance cable longitudinal sealing flame retardant sealant described in any one of claim 1-4, it is characterised in that Coupling agent KH-550, the weight ratio of age resistor ODA are 1-2:3-4.
6. according to the high performance cable longitudinal sealing flame retardant sealant described in any one of claim 1-5, it is characterised in that 1,1,1-trichloroethane is with isopropanol mixed liquor, and 1,1,1-trichloroethane is 10:1 with the weight ratio of isopropanol.
7. according to the high performance cable longitudinal sealing flame retardant sealant described in any one of claim 1-6, it is characterised in that its Raw material includes by weight:
CN201610339290.1A 2016-05-20 2016-05-20 Flame-retardant sealant for high-performance cable longitudinal sealing Pending CN105969247A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610339290.1A CN105969247A (en) 2016-05-20 2016-05-20 Flame-retardant sealant for high-performance cable longitudinal sealing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610339290.1A CN105969247A (en) 2016-05-20 2016-05-20 Flame-retardant sealant for high-performance cable longitudinal sealing

Publications (1)

Publication Number Publication Date
CN105969247A true CN105969247A (en) 2016-09-28

Family

ID=56956128

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610339290.1A Pending CN105969247A (en) 2016-05-20 2016-05-20 Flame-retardant sealant for high-performance cable longitudinal sealing

Country Status (1)

Country Link
CN (1) CN105969247A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110698778A (en) * 2019-10-15 2020-01-17 南通大学 Halogen-free flame-retardant type environment-friendly sealing adhesive material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1063120A (en) * 1991-05-16 1992-07-29 湖北省国营后湖农场化工厂 Burning-resistant type adhesive
CN1182110A (en) * 1996-11-07 1998-05-20 李景德 Fireproof all-purpose adhesive
CN1206732A (en) * 1997-07-30 1999-02-03 孙明 Chlorobutyl benzene-free fire-retarded universal glue
JP2011026423A (en) * 2009-07-24 2011-02-10 Denki Kagaku Kogyo Kk Adhesive and process for producing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1063120A (en) * 1991-05-16 1992-07-29 湖北省国营后湖农场化工厂 Burning-resistant type adhesive
CN1182110A (en) * 1996-11-07 1998-05-20 李景德 Fireproof all-purpose adhesive
CN1206732A (en) * 1997-07-30 1999-02-03 孙明 Chlorobutyl benzene-free fire-retarded universal glue
JP2011026423A (en) * 2009-07-24 2011-02-10 Denki Kagaku Kogyo Kk Adhesive and process for producing the same

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
熊腊森: "《粘接手册》", 31 August 2008, 机械工业出版社 *
马榴强: "《精细化工工艺学》", 29 February 2008, 化学工艺出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110698778A (en) * 2019-10-15 2020-01-17 南通大学 Halogen-free flame-retardant type environment-friendly sealing adhesive material and preparation method thereof
CN110698778B (en) * 2019-10-15 2021-12-28 南通大学 Halogen-free flame-retardant type environment-friendly sealing adhesive material and preparation method thereof

Similar Documents

Publication Publication Date Title
CN101463166B (en) Formula of environment protection type flame-retardant rubber pipe
CN103436005A (en) High-temperature-resistant halogen-free flame retardant thermoplastic polyurethane elastomer for cable and preparation method thereof
CN105968432A (en) Oil-resistant rubber
CN103980601B (en) A kind of flame-proof anti-aging cable jacket material
CN104046030A (en) High temperature-resistant oil-resistant rubber
CN105111519A (en) Fire fighting truck tire tread rubber composition
CN102911409A (en) Environment-friendly tensile high-temperature-resistant control cable material and preparation method thereof
CN104311909A (en) Fire-resistant and flame-retardant tire rubber composite
CN102408620A (en) Environment-friendly sheath material for cable and preparation method thereof
CN105968433A (en) Oil-resistant rubber
CN106700277A (en) Low-smoke and low-toxicity halogen-free flame retardant ethylene propylene diene methylene (EPDM) vibration isolating rubber material
CN103113639A (en) Flame-retardant chloroprene rubber formula
CN103772769A (en) Flame-retardant butadiene-styrene rubber formula
CN102730364B (en) Cold-resistant heat-resistant wire rope core flame-retardant conveyor belt
CN105969247A (en) Flame-retardant sealant for high-performance cable longitudinal sealing
CN105111599B (en) A kind of flame retardant automotive rubber weather strip
CN106751297A (en) A kind of ageing-resistant cable material of high temperature resistant
CN107686659A (en) Mildewproof rubber
CN105504411A (en) Flame-retardant shock-absorbing rubber composite formulation
CN106009103A (en) Oil-resistant and flame-retardant rubber
CN106750641A (en) A kind of fire-retardant nitrile rubber formula
CN107501642A (en) Mildewproof rubber
CN105968434A (en) Tire airtight layer rubber
CN102190817A (en) Flame-retardant high-strength rubber composition
CN107141676A (en) A kind of environmental protection flame retardant rubber composite and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160928