CN105968898A - Fishing net anti-fouling agent - Google Patents
Fishing net anti-fouling agent Download PDFInfo
- Publication number
- CN105968898A CN105968898A CN201610328159.5A CN201610328159A CN105968898A CN 105968898 A CN105968898 A CN 105968898A CN 201610328159 A CN201610328159 A CN 201610328159A CN 105968898 A CN105968898 A CN 105968898A
- Authority
- CN
- China
- Prior art keywords
- parts
- fouling agent
- fishing net
- epoxy resin
- net
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention discloses a fishing net anti-fouling agent. The anti-fouling agent is prepared from the following components in parts by weight: hydroxyl silicone oil, chlorothalonil, epoxy resin coating, gramine, sulfanilamide, nanometer aluminum oxide, gamma-aminopropyltriethoxysilane, an initiator and a film-forming agent. The treated epoxy resin coating is used as a carrier, so that the manufactured fishing net anti-fouling agent has strong adhesive force, can be well bonded with a net, has good water resistance and has certain flexibility and toughness. The fishing net treated by the anti-fouling agent has a remarkable capability for inhibiting and killing algae, moss, serpulidae, mussel and other adhesion organisms, manual regular net washing or new net changing is avoided, and thus massive cost and labor force can be saved; and the home-made film-forming agent is bonded with the epoxy resin coating, the anti-fouling agent has excellent water resistance and abrasion resistance, and the coated bio-resistant drugs cannot drained into water, so that the water body is prevented from being polluted, the drug efficacy of the treated fishing net can not be lost in a short time, and the service life of the anti-fouling agent is prolonged.
Description
Technical field
The present invention relates to the antifouling field of fishing gear, particularly relate to a kind of fishing net anti-fouling agent.
Background technology
The raw materials such as China's culture fishery quickly grows, and wherein uses substantial amounts of fishing net, fishing net typically use polyethylene, polrvinyl chloride, polypropylene goods nylon are made.According to the difference of cultivation object, netting twine has slightly to be had carefully, and mesh varies, thus is processed into the cylinder mould of all size, net cage.Owing to fishing net long period of soaking is in sea water or fresh water, it is highly prone to algae, liverwort, Long Jie, the erosion of the aufwuches such as mussel, thus shortens its service life.In order to solve this class problem, need often tissue manpower brush net scrubbing, even more renew net, cause manpower, material resources and waste of time.Therefore, fishing net pollutes the urgent problem having become as aquaculture.
Summary of the invention
It is an object of the invention to provide a kind of fishing net anti-fouling agent, be achieved through the following technical solutions:
A kind of fishing net anti-fouling agent, is made up of following component: hydroxy silicon oil 12 parts, Bravo 10 parts, 60 parts of epoxy resin glued membrane, donaxine 10 parts, 5 parts of aniline sulfanilamide, nano aluminium oxide 3 parts, gamma-aminopropyl-triethoxy-silane 6 parts, initiator 2 parts, film former 8 parts by weight.
Further, the granularity of described nano aluminium oxide is 8-10nm.
Further, described initiator is benzoyl peroxide.
Further, described film former is made up of following component in percentage terms: 21% butyl acrylate, 10% acrylic acid amides, 32% styrene, 37% linoleic acid；Preparation overall process temperature controls between 55-70 DEG C.
Further, described epoxy resin glued membrane is through pretreatment: be 0.25 part uniformly mix Ethoxysilane under alkaline environment by epoxy resin glued membrane and weight portion, it is heated to 250 DEG C, after continuing 15 minutes, start Slow cooling, when being cooled to 155 DEG C, it is incubated 15 minutes, continue cool to 123 DEG C, be incubated 30 minutes, till being finally cooled to room temperature.
The invention has the beneficial effects as follows: the present invention uses epoxy resin glued membrane after treatment as carrier so that the fishing net anti-fouling agent adhesive force of making is strong, well can be combined with etting, water-tolerant, and not swelling comes off, and has certain flexibility and toughness；The fishing net that anti-fouling agent of the present invention processed is to algae, liverwort, Long Jie, the aufwuches such as mussel have the ability of killing that significantly presses down, avoid human at periodic intervals's brush net or more renew net, great amount of cost and labour force are saved, by self-control film former, be combined with epoxy resin glued membrane, making anti-fouling agent water proof and wearable performance of the present invention excellent, the antibiont medicine of parcel will not be discharged in water, pollutes thus without to water body, the fishing net that will not process the short time loses drug effect, extends the service life of anti-fouling agent.
Detailed description of the invention
A kind of fishing net anti-fouling agent, is made up of following component: hydroxy silicon oil 12 parts, Bravo 10 parts, 60 parts of epoxy resin glued membrane, donaxine 10 parts, 5 parts of aniline sulfanilamide, nano aluminium oxide 3 parts, gamma-aminopropyl-triethoxy-silane 6 parts, initiator 2 parts, film former 8 parts by weight.
Further, the granularity of described nano aluminium oxide is 8-10nm.
Further, described initiator is benzoyl peroxide.
Further, described film former is made up of following component in percentage terms: 21% butyl acrylate, 10% acrylic acid amides, 32% styrene, 37% linoleic acid；Preparation overall process temperature controls between 55-70 DEG C.
Further, described epoxy resin glued membrane is through pretreatment: be 0.25 part uniformly mix Ethoxysilane under alkaline environment by epoxy resin glued membrane and weight portion, it is heated to 250 DEG C, after continuing 15 minutes, start Slow cooling, when being cooled to 155 DEG C, it is incubated 15 minutes, continue cool to 123 DEG C, be incubated 30 minutes, till being finally cooled to room temperature.
The manufacture method of a kind of fishing net anti-fouling agent is:
1) following component is weighed by weight: hydroxy silicon oil 12 parts, Bravo 10 parts, 60 parts of epoxy resin glued membrane, donaxine 10 parts, 5 parts of aniline sulfanilamide, nano aluminium oxide 3 parts, gamma-aminopropyl-triethoxy-silane 6 parts, initiator 2 parts, film former 8 parts；
2) in rapid dispersion machine, required water is added, water is 6:3 with the ratio of anti-fouling agent main component, gradually add hydroxy silicon oil, Bravo, epoxy resin glued membrane, donaxine, aniline sulfanilamide, nano aluminium oxide, gamma-aminopropyl-triethoxy-silane again, stir 30 minutes with 300r/min rotating speed；
3) to 2) in raw material add initiator, film former to, stir after 1 hour with 150r/min speed, stand.
Claims (5)
1. a fishing net anti-fouling agent, it is characterized in that, be made up of following component by weight: hydroxy silicon oil 12 parts, Bravo 10 parts, 60 parts of epoxy resin glued membrane, donaxine 10 parts, 5 parts of aniline sulfanilamide, nano aluminium oxide 3 parts, gamma-aminopropyl-triethoxy-silane 6 parts, initiator 2 parts, film former 8 parts.
A kind of fishing net anti-fouling agent the most according to claim 1, it is characterised in that the granularity of described nano aluminium oxide is 8-10nm.
A kind of fishing net anti-fouling agent the most according to claim 1, it is characterised in that described initiator is benzoyl peroxide.
A kind of fishing net anti-fouling agent the most according to claim 1, it is characterised in that described film former is made up of following component in percentage terms: 21% butyl acrylate, 10% acrylic acid amides, 32% styrene, 37% linoleic acid；Preparation overall process temperature controls between 55-70 DEG C.
A kind of fishing net anti-fouling agent the most according to claim 1, it is characterized in that, described epoxy resin glued membrane is through pretreatment: be 0.25 part uniformly mix Ethoxysilane under alkaline environment by epoxy resin glued membrane and weight portion, is heated to 250 DEG C, after continuing 15 minutes, start Slow cooling, when being cooled to 155 DEG C, it is incubated 15 minutes, continues cool to 123 DEG C, it is incubated 30 minutes, till being finally cooled to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610328159.5A CN105968898A (en) | 2016-05-18 | 2016-05-18 | Fishing net anti-fouling agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610328159.5A CN105968898A (en) | 2016-05-18 | 2016-05-18 | Fishing net anti-fouling agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105968898A true CN105968898A (en) | 2016-09-28 |
Family
ID=56956982
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610328159.5A Pending CN105968898A (en) | 2016-05-18 | 2016-05-18 | Fishing net anti-fouling agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105968898A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1296044A (en) * | 1999-11-12 | 2001-05-23 | 陈光宇 | Low surface energy repelling type dirt-proof paint and use method thereof |
| CN101280148A (en) * | 2008-05-06 | 2008-10-08 | 常州市天安特种涂料有限公司 | Long-acting antifouling paint |
| CN102079890A (en) * | 2009-12-01 | 2011-06-01 | 周林 | Tetrachloroisophthalonitrile antirust paint |
| CN102558989A (en) * | 2010-12-09 | 2012-07-11 | 海洋化工研究院 | Anti-fouling coating material with excellent compatibility and use thereof |
| CN103113529A (en) * | 2013-01-05 | 2013-05-22 | 青岛大学 | Acrylic ester grafted epoxy resin containing donaxine structure and preparation method thereof |
| CN105442085A (en) * | 2015-12-18 | 2016-03-30 | 巢湖市天宇渔具有限公司 | Anti-algae fishing net |
-
2016
- 2016-05-18 CN CN201610328159.5A patent/CN105968898A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1296044A (en) * | 1999-11-12 | 2001-05-23 | 陈光宇 | Low surface energy repelling type dirt-proof paint and use method thereof |
| CN101280148A (en) * | 2008-05-06 | 2008-10-08 | 常州市天安特种涂料有限公司 | Long-acting antifouling paint |
| CN102079890A (en) * | 2009-12-01 | 2011-06-01 | 周林 | Tetrachloroisophthalonitrile antirust paint |
| CN102558989A (en) * | 2010-12-09 | 2012-07-11 | 海洋化工研究院 | Anti-fouling coating material with excellent compatibility and use thereof |
| CN103113529A (en) * | 2013-01-05 | 2013-05-22 | 青岛大学 | Acrylic ester grafted epoxy resin containing donaxine structure and preparation method thereof |
| CN105442085A (en) * | 2015-12-18 | 2016-03-30 | 巢湖市天宇渔具有限公司 | Anti-algae fishing net |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160928 |
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| WD01 | Invention patent application deemed withdrawn after publication |