CN105967705A - Clay-based refractory brick for coal gas producer - Google Patents
Clay-based refractory brick for coal gas producer Download PDFInfo
- Publication number
- CN105967705A CN105967705A CN201610307852.4A CN201610307852A CN105967705A CN 105967705 A CN105967705 A CN 105967705A CN 201610307852 A CN201610307852 A CN 201610307852A CN 105967705 A CN105967705 A CN 105967705A
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- CN
- China
- Prior art keywords
- clay
- refractory brick
- powder
- andalusite
- gas generator
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
Abstract
The invention relates to the field of coal gas producers, in particular to a clay-based refractory brick for a coal gas producer. A formula of the clay-based refractory brick comprises the following ingredients: 45-65% of clay, 15-25% of bauxite, 10-20% of wood dust, 5-10% of tabular corundum, 1-6% of silica micropowder, 1-6% of aluminum oxide micropowder, 1-5% of kyanite, 1-4% of andalusite, 0.5-2% of calcium aluminate, 1-5% of an additive and 0.5-2% of a coagulant. The preparation process comprises the following steps of: (1) porphyrizing; (2) mixing raw materials; (3) ageing the mixture; (4) sintering; (5) performing heat preservation; (6) molding; and (7) curing. The refractory brick is simple to manufacture, controllable in cost and excellent in high temperature resistance. Furthermore, by virtue of a large amount of adopted clay and the inherent characteristics of the clay, the refractory brick has better fire performance than those of traditional refractory bricks.
Description
Technical field
The present invention relates to gas generator field, a kind of gas generator refractory brick based on clay.
Background technology
Gas generator is the production that coal is converted into imflammable gas coal gas (being mainly composed of CO, H2, CH4 etc.)
Equipment, part gas generator uses refractory brick to pile up and forms.Its operation principle is: sieved by the coal meeting gasifying process index
After choosing, firing machine join in gas stove, blast self-produced steam with air gas mixture as gasifying agent from furnace bottom.Coal exists
Through physics, chemical reaction in stove, generating imflammable gas, gas in upper segment is through cyclone oil remover, electric trapper filtered tar. hypomere
Coal gas, through cyclone dust extractor dust out, is transported to user after mixing and uses.
Refractory brick is called for short firebrick.The refractory material being fired into refractory clay or other refractory raw materials.Faint yellow or band brown.Energy
The high temperature of resistance to 1580 DEG C 1770 DEG C.Also firebrick it is.There is the refractory material of definite shape and size.By process of preparing
Division can be divided into burnt brick, unburned brick, fused cast refractories (molten-cast brick), refratory insulating brick;Standard type can be divided into by shape and size
Brick, common brick, special shaped brick etc..Can be used as building kiln and the high temperature construction material of various Thermal Equipment and structural material, and
At high temperature it is amenable to various physicochemical change and mechanism.Such as chamotte brick, high-alumina brick, silica brick, magnesia brick etc..
Clay be containing the grains of sand seldom, have the soil of stickiness, moisture to be not easy to pass therethrough and just have preferable plasticity.General
Clay is all formed by after silicate mineral at the earth's surface air slaking.General in original place air slaking, it is the most original that granule forms more greatly tap
Stone, the most primary clay or a clay.Flint clay often in block or en plaque, does not typically soak scattered in water,
Refractoriness is higher, for the primary raw material of refractory product.
Summary of the invention
For the problems of the prior art, present invention is primarily targeted at, promote the fire resistant quality of existing refractory brick, improve resistance to
Firebrick service life, so that refractory brick has more the value in industry.
The object of the invention to solve the technical problems realizes by the following technical solutions.The one proposed according to the present invention
Gas generator refractory brick based on clay, its formula consists of: clay 45%-65%, bauxite 15%-25%, wood flour
10%-20%, plate diamond spar 5%-10%, silicon powder 1%-6%, alumina powder 1%-6%, kyanite 1%-5%, andalusite 1%-4%,
Calcium aluminate 0.5%-2%, additive 1%-5%, coagulant 0.5%-2%;
Preferably, its formula consists of: clay 50%, bauxite 20%, wood flour 15%, plate diamond spar 5%, silicon powder 2%,
Alumina powder 2%, kyanite 1%, andalusite 1%, calcium aluminate 0.5%, additive 2%, coagulant 1.5%.
Preferably, described additive is Cr2O3, and described coagulant is sodium aluminate.
A kind of gas generator refractory brick based on clay of the present invention, its preparation process comprises the following steps:
(1) pulverize: the components in certain proportion in above-mentioned formula is configured, use double-roll crusher above-mentioned formula will to remove andalusite and wood
Material outside bits mixes and pulverizes, and then wears into mixed-powder with ball mill and sieves, and mixed-powder fineness is 205 mesh,
Wood flour Raymond machine is levigate and sieves, and wood flour fineness is less than 1mm, and andalusite double-roll crusher is individually pulverized and enters ball mill
Pulverizing powder also sieves, and andalusite fineness of powder is 86 mesh;
(2) batch mixing: use Secondary mixing, above-mentioned mixed-powder, wood flour and andalusite powder are together placed in blender,
Mixing time is 2-3min for the first time, and rotating speed is 80-120r/min, is subsequently adding the water of 10%-12% and is allowed to be mixed into plastic
Shape, mixing time is 4-5min for the second time, and rotating speed is 150-210r/min;
(3) ageing mixture: ageing mixture is carried out in ageing mixture storehouse, the ageing mixture time is 10h, and ageing mixture equipment uses reversible moving formula distributing device;
(4) sintering: firing temperature uses 1400-1600 DEG C;
(5) insulation: temperature retention time is 4-6h;
(6) molding: molding uses semi-hard plastic double-stage vacuum extruding machine, and briquetting pressure is 10MPa, a size of 240mm × 115mm
× 90mm or 390mm × 190mm × 190mm;
(7) maintenance: at room temperature maintenance 48h.
Preferably, firing temperature uses 1450-1500 DEG C, and optimum temperature is 1500 DEG C.
By technique scheme, the refractory brick of the present invention at least has the advantage that
The refractory brick of the present invention is simple to manufacture, and cost is controlled, and resistance to elevated temperatures is excellent, and due to a large amount of uses of clay of the present invention,
And the inherent character of clay itself so that the more traditional refractory brick of fire resistance of refractory brick of the present invention is higher.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with tool
Body embodiment, is expanded on further the present invention.
Embodiment 1
A kind of gas generator refractory brick based on clay of the present invention, its formula consists of: clay 50%, bauxite
20%, wood flour 15%, plate diamond spar 5%, silicon powder 2%, alumina powder 2%, kyanite 1%, andalusite 1%, calcium aluminate
0.5%, additive 2%, coagulant 1.5%.
Preferably, described additive is Cr2O3, and described coagulant is sodium aluminate.
A kind of gas generator refractory brick based on clay of the present invention, its preparation process comprises the following steps:
(1) pulverize: the components in certain proportion in above-mentioned formula is configured, use double-roll crusher above-mentioned formula will to remove andalusite and wood
Material outside bits mixes and pulverizes, and then wears into mixed-powder with ball mill and sieves, and mixed-powder fineness is 205 mesh,
Wood flour Raymond machine is levigate and sieves, and wood flour fineness is less than 1mm, and andalusite double-roll crusher is individually pulverized and enters ball mill
Pulverizing powder also sieves, and andalusite fineness of powder is 86 mesh;
(2) batch mixing: use Secondary mixing, above-mentioned mixed-powder, wood flour and andalusite powder are together placed in blender,
Mixing time is 2-3min for the first time, and rotating speed is 80-120r/min, is subsequently adding the water of 10%-12% and is allowed to be mixed into plastic
Shape, mixing time is 4-5min for the second time, and rotating speed is 150-210r/min;
(3) ageing mixture: ageing mixture is carried out in ageing mixture storehouse, the ageing mixture time is 10h, and ageing mixture equipment uses reversible moving formula distributing device;
(4) sintering: firing temperature uses 1400-1600 DEG C;
(5) insulation: temperature retention time is 4-6h;
(6) molding: molding uses semi-hard plastic double-stage vacuum extruding machine, and briquetting pressure is 10MPa, a size of 240mm × 115mm
× 90mm or 390mm × 190mm × 190mm;
(7) maintenance: at room temperature maintenance 48h.
Preferably, firing temperature uses 1450-1500 DEG C, and optimum temperature is 1500 DEG C.
The ultimate principle of the present invention, principal character and advantage have more than been shown and described.Skilled person will appreciate that of the industry,
The present invention is not restricted to the described embodiments, the principle that the present invention is simply described of the description in above-mentioned embodiment and description,
Without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these changes and improvements all fall
Enter in the scope of protection of present invention.Claimed scope is defined by appending claims and equivalent thereof.
Claims (5)
1. a gas generator refractory brick based on clay, it is characterised in that: its formula consists of: clay 45%-65%,
Bauxite 15%-25%, wood flour 10%-20%, plate diamond spar 5%-10%, silicon powder 1%-6%, alumina powder 1%-6%, aquamaine
Stone 1%-5%, andalusite 1%-4%, calcium aluminate 0.5%-2%, additive 1%-5%, coagulant 0.5%-2%.
A kind of gas generator refractory brick based on clay the most according to claim 1, it is characterised in that: its formula group
Become: clay 50%, bauxite 20%, wood flour 15%, plate diamond spar 5%, silicon powder 2%, alumina powder 2%, kyanite
1%, andalusite 1%, calcium aluminate 0.5%, additive 2%, coagulant 1.5%.
A kind of gas generator refractory brick based on clay the most according to claim 1, it is characterised in that: described adds
Adding agent is Cr2O3, and described coagulant is sodium aluminate.
A kind of gas generator refractory brick based on clay the most according to claim 1 and 2, it is characterised in that: preparation
Process comprises the following steps:
(1) pulverize: the components in certain proportion in above-mentioned formula is configured, use double-roll crusher above-mentioned formula will to remove andalusite and wood
Material outside bits mixes and pulverizes, and then wears into mixed-powder with ball mill and sieves, and mixed-powder fineness is 205 mesh,
Wood flour Raymond machine is levigate and sieves, and wood flour fineness is less than 1mm, and andalusite double-roll crusher is individually pulverized and enters ball mill
Pulverizing powder also sieves, and andalusite fineness of powder is 86 mesh;
(2) batch mixing: use Secondary mixing, above-mentioned mixed-powder, wood flour and andalusite powder are together placed in blender,
Mixing time is 2-3min for the first time, and rotating speed is 80-120r/min, is subsequently adding the water of 10%-12% and is allowed to be mixed into plastic
Shape, mixing time is 4-5min for the second time, and rotating speed is 150-210r/min;
(3) ageing mixture: ageing mixture is carried out in ageing mixture storehouse, the ageing mixture time is 10h, and ageing mixture equipment uses reversible moving formula distributing device;
(4) sintering: firing temperature uses 1400-1600 DEG C;
(5) insulation: temperature retention time is 4-6h;
(6) molding: molding uses semi-hard plastic double-stage vacuum extruding machine, and briquetting pressure is 10MPa, a size of 240mm × 115mm
× 90mm or 390mm × 190mm × 190mm;
(7) maintenance: at room temperature maintenance 48h.
A kind of gas generator refractory brick based on clay the most according to claim 4, it is characterised in that: firing temperature
Using 1450-1500 DEG C, optimum temperature is 1500 DEG C.
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CN201610307852.4A CN105967705A (en) | 2016-05-11 | 2016-05-11 | Clay-based refractory brick for coal gas producer |
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CN201610307852.4A CN105967705A (en) | 2016-05-11 | 2016-05-11 | Clay-based refractory brick for coal gas producer |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112573908A (en) * | 2020-10-23 | 2021-03-30 | 济源市涟源炉业有限公司 | Novel refractory brick material and preparation process thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1334257A (en) * | 2000-07-15 | 2002-02-06 | 淄博科鲁能源动力有限责任公司 | High-strength antiwear refractory brick |
CN104446568A (en) * | 2014-12-15 | 2015-03-25 | 山东鲁阳股份有限公司 | Fireproof insulating brick and preparation method thereof |
CN105367096A (en) * | 2015-11-25 | 2016-03-02 | 南京联合荣大工程材料有限责任公司 | Refractory raw material and blast furnace press-in material containing same |
-
2016
- 2016-05-11 CN CN201610307852.4A patent/CN105967705A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1334257A (en) * | 2000-07-15 | 2002-02-06 | 淄博科鲁能源动力有限责任公司 | High-strength antiwear refractory brick |
CN104446568A (en) * | 2014-12-15 | 2015-03-25 | 山东鲁阳股份有限公司 | Fireproof insulating brick and preparation method thereof |
CN105367096A (en) * | 2015-11-25 | 2016-03-02 | 南京联合荣大工程材料有限责任公司 | Refractory raw material and blast furnace press-in material containing same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112573908A (en) * | 2020-10-23 | 2021-03-30 | 济源市涟源炉业有限公司 | Novel refractory brick material and preparation process thereof |
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Application publication date: 20160928 |