CN105967608A - Moisture-proof cement hollow brick and preparation method thereof - Google Patents

Moisture-proof cement hollow brick and preparation method thereof Download PDF

Info

Publication number
CN105967608A
CN105967608A CN201610212605.6A CN201610212605A CN105967608A CN 105967608 A CN105967608 A CN 105967608A CN 201610212605 A CN201610212605 A CN 201610212605A CN 105967608 A CN105967608 A CN 105967608A
Authority
CN
China
Prior art keywords
parts
hollow brick
powder
raw material
cement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610212605.6A
Other languages
Chinese (zh)
Inventor
朱安会
马洪章
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Xin Run Type Material Co Ltd
Original Assignee
Anhui Xin Run Type Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Xin Run Type Material Co Ltd filed Critical Anhui Xin Run Type Material Co Ltd
Priority to CN201610212605.6A priority Critical patent/CN105967608A/en
Publication of CN105967608A publication Critical patent/CN105967608A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06—Aluminous cements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28C—PREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C5/00—Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions
    • B28C5/003—Methods for mixing
    • B28C5/006—Methods for mixing involving mechanical aspects
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00—Other methods of shaping glass
    • C03B19/10—Forming beads
    • C03B19/1005—Forming solid beads
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002—Use of waste materials, e.g. slags
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/138—Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The invention discloses a moisture-proof cement hollow brick and a preparation method thereof. The moisture-proof cement hollow brick is prepared from the following raw materials (by weight): 57-69 parts of fluoraluminate cement, 21-27 parts of anorthite, 4-9 parts of organosilicon microspheres, 17-24 parts of ferronickel slag, 13-21 parts of mineral wool leftover, 18-26 parts of the Yellow River silt, 10-15 parts of heavy calcium powder, 5-10 parts of waste polyethylene, 12-19 parts of gravel chippings, 15-20 parts of boiler ash, 4-6 parts of sodium stearate, 8-16 parts of phosphorus tailings, 3-5 parts of polyamide wax micro-powder, 14-22 parts of blast furnace water-quenched slag, 5-10 parts of waste tire rubber powder, 7-14 parts of polyacrylamide, 3-5 parts of lithium fluoride, 10-15 parts of tungsten tailings, 4-7 parts of sodium tripolyphosphate and a proper amount of water. By the addition of raw materials including organosilicon microspheres, waste polyethylene, sodium stearate, polyamide wax micro-powder, waste tire rubber powder, etc., water absorption of the cement hollow brick is significantly reduced, and humidity resistance of the cement hollow brick is then enhanced.

Description

A kind of hydrophobic cement hollow brick and preparation method thereof
Technical field
The present invention relates to a kind of hollow brick and preparation method thereof, be specifically related to a kind of hydrophobic cement hollow brick and system thereof Preparation Method.
Background technology
Hollow concrete block is the one of novel wall material, has excellent from heavy and light, intensity height, good heat insulating etc. Point.Produce and use this kind of novel wall material, it is possible to achieve energy-conservation, save land, economize on water, profit is useless, increase and build Build effective usable floor area, shorten the purposes such as construction period, there is the superiority that conventional clay is incomparable, be Substitute one of preferred material of solid clay brick, by the support energetically of national industrial policies.But current cement Hollow brick there is also the shortcoming of humidity resistance difference, and life-time service is easily damaged in wet condition, thus shortens In the service life of hollow concrete block, limit the range of hollow concrete block.
Summary of the invention
It is an object of the invention to provide a kind of hydrophobic cement hollow brick and preparation method thereof.This hollow concrete block is inhaled Water rate is low, and humidity resistance is excellent.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of hydrophobic cement hollow brick, is made up of the raw material of following weight portion: fluoroaluminate cement 57-69, Anorthite 21-27, organosilicon microsphere 4-9, ferronickel slag 17-24, mineral wool leftover bits and pieces 13-21, Yellow river silt 18-26, dicalcium powder 10-15, polyethylene waste material 5-10, stone fragment 12-19, Boiler Ash 15-20, stearic acid Sodium 4-6, phosphorus ore tailing 8-16, polyamide wax micropowder 3-5, blast furnace water quenching slag 14-22, waste-tyre rubber-powder 5-10, polyacrylamide 7-14, lithium fluoride 3-5, Tungsten tailing 10-15, sodium tripolyphosphate 4-7, water are appropriate.
The preparation method of a kind of hydrophobic cement hollow brick, comprises the following steps:
(1) by ferronickel slag, Yellow river silt, stone fragment, Tungsten tailing mix homogeneously, pulverize, cross 50-70 Mesh sieve, adds appropriate water, stirs, ball processed, and size controlling is at 3-6mm, then by prepared Raw material ball is dried at 90-100 DEG C to moisture content below 1%, then dried raw material ball is placed in Muffle Roasting in stove: be first warming up to 1190-1270 DEG C with 8-10 DEG C/min, is incubated 12-18min, then with 4-8 DEG C / min is cooled to 580-640 DEG C, is incubated 24-32min, is cooled to room temperature, obtains haydite；
(2) by anorthite, dicalcium powder, phosphorus ore tailing, lithium fluoride mix homogeneously, it is heated to material the most molten Chemical conversion fused solution, then puts into the fused solution obtained and carries out shrend in clear water, obtain the glass particle material crushed, Being dried 5-7h after dewatered and washed part at 60-80 DEG C, the glass particle material then drying obtained is placed in microwave calcining Roasting in stove: first control microwave power at 400-500W, roasting 20-40min, then control microwave power and exist 700-800W, calcines 15-25min, then controls microwave power at 900-1000W, calcines 10-15min, cold But to room temperature, glass microballoon is obtained；
(3) fluoroaluminate cement, mineral wool leftover bits and pieces, Boiler Ash, organosilicon microsphere, polyethylene are given up Material, sodium stearate, polyamide wax micropowder, blast furnace water quenching slag, waste-tyre rubber-powder mix homogeneously, then Adding appropriate water once to stir, mixing speed is 400-600r/min, and mixing time is 8-14min, still aging 12-24h after stirring, then add remaining former in the raw material after ageing Material and step (1) prepare haydite and step (2) prepare glass microballoon carry out secondary mixing, Mixing speed is 600-800r/min, and mixing time is 4-9min；
(4) compound that step (3) prepares is added in air brick brick press compressing, the demoulding It is placed on maintenance under natural environment, obtains required hollow brick.
Beneficial effects of the present invention:
(1) present invention by organosilicon microsphere, polyethylene waste material, sodium stearate, polyamide wax micropowder, The interpolation of the raw materials such as waste-tyre rubber-powder, significantly reduces the water absorption rate of hollow concrete block, thus improves The humidity resistance of hollow concrete block, by raw materials such as mineral wool leftover bits and pieces, Boiler Ash, blast furnace water quenching slags Interpolation, heat stability and the chemical stability of hollow concrete block can be improved.
(2) present invention uses the haydite that the raw materials such as ferronickel slag, Yellow river silt, stone fragment, Tungsten tailing prepare It is the most compound with the glass microballoon that the raw material such as anorthite, dicalcium powder, phosphorus ore tailing, lithium fluoride prepares, It is evenly distributed in hollow concrete block, the heat conductivity of hollow concrete block can be substantially reduced so that It has the heat preservation and insulation of excellence, can also improve mechanical property and the change of hollow concrete block simultaneously Learn the performances such as stability.
Detailed description of the invention
A kind of hydrophobic cement hollow brick, is made up of the raw material of following weight (kg): fluoroaluminate cement 66, Anorthite 24, organosilicon microsphere 6, ferronickel slag 21, mineral wool leftover bits and pieces 17, Yellow river silt 22, dicalcium powder 12, Polyethylene waste material 7, stone fragment 15, Boiler Ash 17, sodium stearate 5, phosphorus ore tailing 12, polyamide wax are micro- Powder 4, blast furnace water quenching slag 16, waste-tyre rubber-powder 8, polyacrylamide 11, lithium fluoride 4.5, Tungsten tailing 12, Sodium tripolyphosphate 6, water are appropriate.
The preparation method of a kind of hydrophobic cement hollow brick, comprises the following steps:
(1) by ferronickel slag, Yellow river silt, stone fragment, Tungsten tailing mix homogeneously, pulverize, cross 60 mesh sieves, Adding appropriate water, stir, ball processed, prepared raw material ball, at 4mm, is then existed by size controlling It is dried at 95 DEG C to moisture content below 1%, then dried raw material ball is placed in roasting in Muffle furnace: first It is warming up to 1260 DEG C with 9 DEG C/min, is incubated 12min, then is cooled to 620 DEG C with 6 DEG C/min, be incubated 28min, It is cooled to room temperature, obtains haydite；
(2) by anorthite, dicalcium powder, phosphorus ore tailing, lithium fluoride mix homogeneously, it is heated to material the most molten Chemical conversion fused solution, then puts into the fused solution obtained and carries out shrend in clear water, obtain the glass particle material crushed, Being dried 6h after dewatered and washed part at 70 DEG C, the glass particle material then drying obtained is placed in microwave baking furnace Roasting: first control microwave power at 450W, roasting 30min, then control microwave power at 750W, calcine 20min, Control microwave power again at 900W, calcine 12min, be cooled to room temperature, obtain glass microballoon；
(3) fluoroaluminate cement, mineral wool leftover bits and pieces, Boiler Ash, organosilicon microsphere, polyethylene are given up Material, sodium stearate, polyamide wax micropowder, blast furnace water quenching slag, waste-tyre rubber-powder mix homogeneously, then Adding appropriate water once to stir, mixing speed is 500r/min, and mixing time is 12min, Still aging 12h after stirring, then adds remaining raw material and step in the raw material after ageing (1) glass microballoon that the haydite prepared and step (2) prepare carries out secondary mixing, and mixing speed is 700r/min, mixing time is 6min；
(4) compound that step (3) prepares is added in air brick brick press compressing, the demoulding It is placed on maintenance under natural environment, obtains required hollow brick.
The main performance testing result of the hollow concrete block that above-described embodiment prepares is as shown in the table:

Claims (2)

1. a hydrophobic cement hollow brick, it is characterized in that, be made up of the raw material of following weight portion: fluoroaluminate cement 57-69, anorthite 21-27, organosilicon microsphere 4-9, ferronickel slag 17-24, mineral wool leftover bits and pieces 13-21, Yellow river silt 18-26, dicalcium powder 10-15, polyethylene waste material 5-10, stone fragment 12-19, Boiler Ash 15-20, sodium stearate 4-6, phosphorus ore tailing 8-16, polyamide wax micropowder 3-5, blast furnace water quenching slag 14-22, waste-tyre rubber-powder 5-10, polyacrylamide 7-14, lithium fluoride 3-5, Tungsten tailing 10-15, sodium tripolyphosphate 4-7, water are appropriate.
2. the preparation method of a hydrophobic cement hollow brick as claimed in claim 1, it is characterised in that comprise the following steps:
(1) by ferronickel slag, Yellow river silt, stone fragment, Tungsten tailing mix homogeneously, pulverize, cross 50-70 mesh sieve, add appropriate water, stir, ball processed, size controlling is at 3-6mm, then prepared raw material ball is dried at 90-100 DEG C to moisture content below 1%, then dried raw material ball is placed in roasting in Muffle furnace: be first warming up to 1190-1270 DEG C with 8-10 DEG C/min, is incubated 12-18min, it is cooled to 580-640 DEG C again with 4-8 DEG C/min, insulation 24-32min, is cooled to room temperature, obtains haydite；
(2) by anorthite, dicalcium powder, phosphorus ore tailing, lithium fluoride mix homogeneously, it is heated to material and is completely melt into fused solution, then the fused solution obtained is put into and clear water carries out shrend, obtain the glass particle material crushed, at 60-80 DEG C, 5-7h it is dried after dewatered and washed part, then glass particle material drying obtained is placed in roasting in microwave baking furnace: first control microwave power at 400-500W, roasting 20-40min, control microwave power again at 700-800W, calcining 15-25min, control microwave power again at 900-1000W, calcining 10-15min, it is cooled to room temperature, obtain glass microballoon；
(3) by fluoroaluminate cement, mineral wool leftover bits and pieces, Boiler Ash, organosilicon microsphere, polyethylene waste material, sodium stearate, polyamide wax micropowder, blast furnace water quenching slag, waste-tyre rubber-powder mix homogeneously, add appropriate water once to stir, mixing speed is 400-600r/min, mixing time is 8-14min, still aging 12-24h after stirring, then raw material after ageing add remaining raw material and haydite that step (1) prepares and the glass microballoon that step (2) prepares carry out secondary mixing, mixing speed is 600-800r/min, mixing time is 4-9min；
(4) adding in air brick brick press compressing by the compound that step (3) prepares, the demoulding is placed on maintenance under natural environment, obtains required hollow brick.
CN201610212605.6A 2016-04-06 2016-04-06 Moisture-proof cement hollow brick and preparation method thereof Pending CN105967608A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610212605.6A CN105967608A (en) 2016-04-06 2016-04-06 Moisture-proof cement hollow brick and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610212605.6A CN105967608A (en) 2016-04-06 2016-04-06 Moisture-proof cement hollow brick and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105967608A true CN105967608A (en) 2016-09-28

Family

ID=56989209

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610212605.6A Pending CN105967608A (en) 2016-04-06 2016-04-06 Moisture-proof cement hollow brick and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105967608A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106518105A (en) * 2016-10-10 2017-03-22 马鞍山豹龙新型建材有限公司 Water-resistant moisture-proof refractory brick and preparation method thereof
CN106518104A (en) * 2016-10-10 2017-03-22 马鞍山豹龙新型建材有限公司 Chromium-free refractory brick for rotary cement kiln burning zone and preparation method of chromium-free refractory brick
CN106518100A (en) * 2016-10-10 2017-03-22 马鞍山豹龙新型建材有限公司 Refractory brick containing waste foam concrete and preparation method thereof
CN107032803A (en) * 2016-10-10 2017-08-11 马鞍山豹龙新型建材有限公司 A kind of antiwear refractory brick and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101857400A (en) * 2010-04-22 2010-10-13 连来才 Lightweight insulating brick and production process thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101857400A (en) * 2010-04-22 2010-10-13 连来才 Lightweight insulating brick and production process thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
夏寿荣等: "《最新混凝土外加剂生产配方精选400例》", 31 January 2014, 中国建材工业出版社 *
高燕等: ""利用陶粒和玻璃微珠制备轻质高强混凝土的研究"", 《砖瓦》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106518105A (en) * 2016-10-10 2017-03-22 马鞍山豹龙新型建材有限公司 Water-resistant moisture-proof refractory brick and preparation method thereof
CN106518104A (en) * 2016-10-10 2017-03-22 马鞍山豹龙新型建材有限公司 Chromium-free refractory brick for rotary cement kiln burning zone and preparation method of chromium-free refractory brick
CN106518100A (en) * 2016-10-10 2017-03-22 马鞍山豹龙新型建材有限公司 Refractory brick containing waste foam concrete and preparation method thereof
CN107032803A (en) * 2016-10-10 2017-08-11 马鞍山豹龙新型建材有限公司 A kind of antiwear refractory brick and preparation method thereof

Similar Documents

Publication Publication Date Title
CN105967608A (en) Moisture-proof cement hollow brick and preparation method thereof
CN105967629A (en) Cement hollow brick with high seismic resistance and preparation method thereof
CN105967606A (en) Anti-crack cement hollow brick and preparation method thereof
CN106892617A (en) A kind of environmentally friendly seepage brick and its manufacture method
CN105967585A (en) Freeze-thaw resistant cement hollow brick and preparation method thereof
CN106365679B (en) A kind of light cellular partition board and preparation method thereof
CN106145996A (en) A kind of method utilizing underground railway track dregs to prepare light ceramic
CN108503371A (en) A method of preparing foamed ceramic material using blast furnace slag and aluminous fly-ash
KR101314384B1 (en) Metal oxide composition heated by microwave irradiation, organic/inorganic composition and product comprising the same
CN105967607A (en) Anti-mould cement hollow brick and preparation method thereof
CN104609817A (en) High temperature-resistant and high-toughness aerated brick and preparation method thereof
CN103755309A (en) Municipal sludge sintered shale perforated brick and production method thereof
CN105254325A (en) Aerated building blocks manufactured by utilizing desulfurized petroleum coke residues and manufacturing method thereof
CN105417958B (en) A kind of method that high-intensity foam glass material is prepared using copper tailing
CN104609837B (en) Method of producing haydite for thermal insulation block by utilizing steel slag quenched with wind
CN105967625A (en) Cement hollow brick capable of generating far-infrared rays and preparation method thereof
CN105967640A (en) High-strength fired clay hollow brick and preparation method thereof
CN108484127A (en) A kind of highiy refractory brick and preparation method
CN105967584A (en) Cement hollow brick with good sound insulation and noise reduction performance and preparation method thereof
CN105272078A (en) Water and freeze resistant aerated building block and making method thereof
CN105967612A (en) Cement hollow brick with high compression resistance and preparation method thereof
CN101921099A (en) Floatation algal residue paving brick
CN105948698A (en) Sintered hollow clay brick for severe cold region and manufacturing method of sintered hollow clay brick
CN109836128A (en) Utilize the haydite and preparation method thereof of aggregate sandstone tailing production
CN101831980A (en) Manganese slag lightweight aggregate wall block

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160928