CN105254325A - Aerated building blocks manufactured by utilizing desulfurized petroleum coke residues and manufacturing method thereof - Google Patents

Aerated building blocks manufactured by utilizing desulfurized petroleum coke residues and manufacturing method thereof Download PDF

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Publication number
CN105254325A
CN105254325A CN201510634358.4A CN201510634358A CN105254325A CN 105254325 A CN105254325 A CN 105254325A CN 201510634358 A CN201510634358 A CN 201510634358A CN 105254325 A CN105254325 A CN 105254325A
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China
Prior art keywords
parts
powder
mix
water
building blocks
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CN201510634358.4A
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Chinese (zh)
Inventor
吴传兴
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Maanshan Jiechuang Plastic Science & Technology Co Ltd
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Maanshan Jiechuang Plastic Science & Technology Co Ltd
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Priority to CN201510634358.4A priority Critical patent/CN105254325A/en
Publication of CN105254325A publication Critical patent/CN105254325A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses aerated building blocks manufactured by utilizing desulfurized petroleum coke residues and a manufacturing method thereof. The aerated building blocks are manufactured by, by weight, 27-39 parts of desulfurized petroleum coke residues, 14-22 parts of silica sand, 18-26 parts of sandy gravels, 22-23 parts of hematite tailings, 15-25 parts of light calcium powder, 11-19 parts of kaolin, 10-15 parts of porous ceramsite, 4-6 parts of hydroxyethyl cellulose, 7-14 parts of rice husk ash, 12-18 parts of furnace kiln slag, 16-24 parts of rubber waste, 20-30 parts of high alumina cement, 17-23 parts of hectorite, 1.6-2.2 parts of aluminum powder and an appropriate amount of water. The aerated building blocks manufactured through mutual matching of the desulfurized petroleum coke residues and the raw materials including the sandy gravels, the hematite tailings, the rice husk ash, the furnace kiln slag, the waste rubber, the hectorite and the like have the advantages of high strength, fire resistance and prevention, low thermal expansion coefficient, high thermal shock resistance, good heat preservation and insulation performance, permeation resistance, water resistance and the like and have important economic and social benefits.

Description

A kind of aerated-block utilizing desulfurization oil cinder to prepare and preparation method thereof
Technical field
The present invention relates to a kind of aerated-block utilizing desulfurization oil cinder to prepare and preparation method thereof, belong to building material field.
Background technology
Aerated-block is a kind of energy-conservation, joint soil, sharp useless novel wall material, there is light weight, heat-insulation and heat-preservation, sound absorption sound insulation, antidetonation, fire prevention, can saw, can dig, can follow closely, easy construction and the advantages such as buildings usable floor area can be increased, and to be widely used in civilian and public various building.
Desulfurization oil cinder is the product after refinery desulfurization, is the industrial residue that high sulfur petroleum coke is obtained by Combustion technology of circulating fluidized, containing a large amount of CaO and CaSO 4, be a kind of novel calcareous material, there is good gelling material, it is good green building material, can replace gypsum and lime for the preparation of aerated-block, the recycling for desulfurization oil cinder provides a new approach, has important economic benefit and social benefit.
Summary of the invention
The object of the present invention is to provide a kind of aerated-block utilizing desulfurization oil cinder to prepare and preparation method thereof.
For achieving the above object, the present invention adopts following technical scheme:
The aerated-block utilizing desulfurization oil cinder to prepare, is made up of the raw material of following weight part: desulfurization oil cinder 27-39, silica sand 14-22, sandy gravel 18-26, rhombohedral iron ore mine tailing 22-33, light calcium carbonate powder 15-25, kaolin 11-19, porous ceramic grain 10-15, Natvosol 4-6, rice hull ash 7-14, stove dreg 12-18, rubber scrap 16-24, high-alumina cement 20-30, hectorite 17-23, aluminium powder 1.6-2.2, water are appropriate;
The preparation method of described porous ceramic grain is as follows: a, in mass ratio 5-10:4-8:3-6 take manganese ore gangue, Yellow Phosphorous Slag, glass cullet, mix, and pulverizes, and crosses 400-500 mesh sieve; B, in mass ratio 7-12:5-8:2-4 take flyash, cancrinite, wagnerite, mix, and pulverize, and cross 200-300 mesh sieve, add the water being equivalent to mixed powder weight 4-6 times amount, wet ball grinding 2-3h, dry; The sodium pyrosulfate being equivalent to the spent pulping liquor of the powder weight 30-40% that step a obtains, the bicarbonate of ammonia of 5-10% and 3-5% is added in c, the powder that obtains to step a, mix, wet granulation, size controlling is at 0.4-0.8mm, then microwave agglomerating furnace is put into, microwave heating is to 480-520 DEG C, and insulation 20-30min, is cooled to normal temperature; D, in mass ratio 2-3:1 take powder that step b obtains and the obtained particle of step c, mix, then add and be equivalent to the kibushi clay of mixture weight 20-30% and the titanium dioxide of 8-14% and appropriate water, mix, wet granulation, size controlling, at 1-2mm, then puts into retort furnace, with the ramp of 4-8 DEG C/min to 840-880 DEG C, insulation 0.5-1h, again with the ramp of 2-5 DEG C/min to 1160-1220 DEG C, insulation 1-2h, be cooled to normal temperature.
The homemade porous ceramics of the present invention is made with raw materials such as manganese ore gangue, Yellow Phosphorous Slag, glass cullet, flyash, cancrinites, and have pore and enrich, intensity is high; fire-resistant; withstand voltage, the advantages such as acid-alkali-corrosive-resisting, are applied to aerated-block; not only can improve mechanical property and the refractoriness of aerated-block; can also improve heat insulation property and the sound insulating and absorbing of aerated-block, and raw material sources are extensive, technique is simple; with low cost, mass-producing can be applied to aerated-block.
A preparation method for the aerated-block utilizing desulfurization oil cinder to prepare, is made up of the following step:
(1) get desulfurization oil cinder, sandy gravel, rhombohedral iron ore mine tailing, rubber scrap, stove dreg, hectorite mix, pulverize, cross 150-250 mesh sieve, stand-by;
(2) get light calcium carbonate powder and kaolin to add water to stir and make the slurries that concentration is 35-45%, then the powder that silica sand, rice hull ash, porous ceramic grain and step (1) are obtained is added, stir 4-7min, add high-alumina cement and Natvosol again, and the water content adjusting compound is to 55-65%, stir 3-5min;
(3) added by aluminium powder in the obtained slip of step (2), inject mould after stirring 30-50s and get angry, get angry 35-45min at 65-70 DEG C of temperature;
(4) mould is put into curing room 60-70 DEG C vapor cure, get product.
Beneficial effect of the present invention:
The present invention utilizes the raw material such as desulfurization oil cinder and sandy gravel, rhombohedral iron ore mine tailing, rice hull ash, stove dreg, rubber scrap, the hectorite obtained aerated-block that cooperatively interacts to have good, the impervious feature such as water-fast of high strength, fire-resistant fire prevention, low thermal coefficient of expansion, high-heat resistance shock resistant, heat insulation property, has important economic benefit and social benefit.
Embodiment
Utilize an aerated-block prepared by desulfurization oil cinder, be made up of the raw material of following weight (kg): desulfurization oil cinder 34, silica sand 16, sandy gravel 23, rhombohedral iron ore mine tailing 27, light calcium carbonate powder 20, kaolin 14, porous ceramic grain 12, Natvosol 5, rice hull ash 11, stove dreg 16, rubber scrap 22, high-alumina cement 25, hectorite 21, aluminium powder 1.9, water are appropriate;
The preparation method of described porous ceramic grain is as follows: a, in mass ratio 10:8:6 take manganese ore gangue, Yellow Phosphorous Slag, glass cullet, mix, and pulverizes, and crosses 500 mesh sieves; B, in mass ratio 12:8:4 take flyash, cancrinite, wagnerite, mix, and pulverize, and cross 300 mesh sieves, add the water being equivalent to mixed powder weight 4-6 times amount, wet ball grinding 3h, dry; Add in c, the powder that obtains to step a be equivalent to step a and obtain the spent pulping liquor of powder weight 40%, the bicarbonate of ammonia of 10% and 5% sodium pyrosulfate, mix, wet granulation, size controlling is at 0.8mm, then microwave agglomerating furnace is put into, microwave heating to 520 DEG C, insulation 30min, is cooled to normal temperature; D, in mass ratio 3:1 take powder that step b obtains and the obtained particle of step c, mix, then add and be equivalent to the kibushi clay of mixture weight 30% and the titanium dioxide of 14% and appropriate water, mix, wet granulation, size controlling, at 2mm, then puts into retort furnace, with the ramp to 880 DEG C of 8 DEG C/min, insulation 1h, again with the ramp to 1220 DEG C of 5 DEG C/min, insulation 2h, is cooled to normal temperature.
A preparation method for the aerated-block utilizing desulfurization oil cinder to prepare, is made up of the following step:
(1) get desulfurization oil cinder, sandy gravel, rhombohedral iron ore mine tailing, rubber scrap, stove dreg, hectorite mix, pulverize, cross 150-250 mesh sieve, stand-by;
(2) get light calcium carbonate powder and kaolin to add water to stir and make the slurries that concentration is 35-45%, then the powder that silica sand, rice hull ash, porous ceramic grain and step (1) are obtained is added, stir 4-7min, add high-alumina cement and Natvosol again, and the water content adjusting compound is to 55-65%, stir 3-5min;
(3) added by aluminium powder in the obtained slip of step (2), inject mould after stirring 30-50s and get angry, get angry 35-45min at 65-70 DEG C of temperature;
(4) mould is put into curing room 60-70 DEG C vapor cure, get product.
The aerated-block that above-described embodiment obtains salient features detect see the following form:
Project Unit Detected result
Cold crushing strength Mpa 6.2
Drying shrinkage value mm/m 0.4
Thermal conductivity W/m.K 0.08
Water-intake rate 0.11

Claims (2)

1. the aerated-block utilizing desulfurization oil cinder to prepare, it is characterized in that, be made up of the raw material of following weight part: desulfurization oil cinder 27-39, silica sand 14-22, sandy gravel 18-26, rhombohedral iron ore mine tailing 22-33, light calcium carbonate powder 15-25, kaolin 11-19, porous ceramic grain 10-15, Natvosol 4-6, rice hull ash 7-14, stove dreg 12-18, rubber scrap 16-24, high-alumina cement 20-30, hectorite 17-23, aluminium powder 1.6-2.2, water are appropriate;
The preparation method of described porous ceramic grain is as follows: a, in mass ratio 5-10:4-8:3-6 take manganese ore gangue, Yellow Phosphorous Slag, glass cullet, mix, and pulverizes, and crosses 400-500 mesh sieve; B, in mass ratio 7-12:5-8:2-4 take flyash, cancrinite, wagnerite, mix, and pulverize, and cross 200-300 mesh sieve, add the water being equivalent to mixed powder weight 4-6 times amount, wet ball grinding 2-3h, dry; The sodium pyrosulfate being equivalent to the spent pulping liquor of the powder weight 30-40% that step a obtains, the bicarbonate of ammonia of 5-10% and 3-5% is added in c, the powder that obtains to step a, mix, wet granulation, size controlling is at 0.4-0.8mm, then microwave agglomerating furnace is put into, microwave heating is to 480-520 DEG C, and insulation 20-30min, is cooled to normal temperature; D, in mass ratio 2-3:1 take powder that step b obtains and the obtained particle of step c, mix, then add and be equivalent to the kibushi clay of mixture weight 20-30% and the titanium dioxide of 8-14% and appropriate water, mix, wet granulation, size controlling, at 1-2mm, then puts into retort furnace, with the ramp of 4-8 DEG C/min to 840-880 DEG C, insulation 0.5-1h, again with the ramp of 2-5 DEG C/min to 1160-1220 DEG C, insulation 1-2h, be cooled to normal temperature.
2. the preparation method of the aerated-block utilizing desulfurization oil cinder to prepare according to claim 1, is characterized in that, be made up of the following step:
(1) get desulfurization oil cinder, sandy gravel, rhombohedral iron ore mine tailing, rubber scrap, stove dreg, hectorite mix, pulverize, cross 150-250 mesh sieve, stand-by;
(2) get light calcium carbonate powder and kaolin to add water to stir and make the slurries that concentration is 35-45%, then the powder that silica sand, rice hull ash, porous ceramic grain and step (1) are obtained is added, stir 4-7min, add high-alumina cement and Natvosol again, and the water content adjusting compound is to 55-65%, stir 3-5min;
(3) added by aluminium powder in the obtained slip of step (2), inject mould after stirring 30-50s and get angry, get angry 35-45min at 65-70 DEG C of temperature;
(4) mould is put into curing room 60-70 DEG C vapor cure, get product.
CN201510634358.4A 2015-09-29 2015-09-29 Aerated building blocks manufactured by utilizing desulfurized petroleum coke residues and manufacturing method thereof Pending CN105254325A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106082967A (en) * 2016-06-12 2016-11-09 安徽省亚欧陶瓷有限责任公司 A kind of ceramic tile utilizing blast furnace gas mud and desulfurization oil cinder to prepare and preparation method thereof
CN106082936A (en) * 2016-06-13 2016-11-09 马鞍山市金韩防水保温工程有限责任公司 A kind of exterior wall desulfurization oil cinder thermal insulation mortar and preparation method thereof
CN106699203A (en) * 2016-12-19 2017-05-24 马鞍山豹龙新型建材有限公司 Refractory bricks prepared from pebbles in Changjiang River, and preparation method of refractory bricks
CN112341064A (en) * 2020-12-01 2021-02-09 济南黄河路桥建设集团有限公司 Water-permeable cement concrete block and preparation method thereof
CN112411297A (en) * 2020-12-01 2021-02-26 济南黄河路桥建设集团有限公司 Construction method of permeable cement pavement

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101597158A (en) * 2008-06-03 2009-12-09 周慧堂 A kind of lagging material and preparation method thereof
CN101713234A (en) * 2009-10-30 2010-05-26 武汉理工大学 Non-autoclaved and unburned brick and preparation method thereof
CN102557533A (en) * 2010-12-29 2012-07-11 赵肖 Baking-free and steaming-free tailing brick and preparation method thereof
CN102964103A (en) * 2012-12-04 2013-03-13 青岛理工大学 Foam cement containing desulfurized petroleum coke ash-residue admixture
CN103449768A (en) * 2013-07-31 2013-12-18 潘逸东 Aerated brick containing waste residues

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101597158A (en) * 2008-06-03 2009-12-09 周慧堂 A kind of lagging material and preparation method thereof
CN101713234A (en) * 2009-10-30 2010-05-26 武汉理工大学 Non-autoclaved and unburned brick and preparation method thereof
CN102557533A (en) * 2010-12-29 2012-07-11 赵肖 Baking-free and steaming-free tailing brick and preparation method thereof
CN102964103A (en) * 2012-12-04 2013-03-13 青岛理工大学 Foam cement containing desulfurized petroleum coke ash-residue admixture
CN103449768A (en) * 2013-07-31 2013-12-18 潘逸东 Aerated brick containing waste residues

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106082967A (en) * 2016-06-12 2016-11-09 安徽省亚欧陶瓷有限责任公司 A kind of ceramic tile utilizing blast furnace gas mud and desulfurization oil cinder to prepare and preparation method thereof
CN106082936A (en) * 2016-06-13 2016-11-09 马鞍山市金韩防水保温工程有限责任公司 A kind of exterior wall desulfurization oil cinder thermal insulation mortar and preparation method thereof
CN106699203A (en) * 2016-12-19 2017-05-24 马鞍山豹龙新型建材有限公司 Refractory bricks prepared from pebbles in Changjiang River, and preparation method of refractory bricks
CN112341064A (en) * 2020-12-01 2021-02-09 济南黄河路桥建设集团有限公司 Water-permeable cement concrete block and preparation method thereof
CN112411297A (en) * 2020-12-01 2021-02-26 济南黄河路桥建设集团有限公司 Construction method of permeable cement pavement
CN112341064B (en) * 2020-12-01 2021-06-29 济南黄河路桥建设集团有限公司 Water-permeable cement concrete block and preparation method thereof
CN112411297B (en) * 2020-12-01 2021-07-20 济南黄河路桥建设集团有限公司 Construction method of permeable cement pavement

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