CN105963158A - Daily disposable nail polish and preparation method thereof - Google Patents
Daily disposable nail polish and preparation method thereof Download PDFInfo
- Publication number
- CN105963158A CN105963158A CN201610323407.7A CN201610323407A CN105963158A CN 105963158 A CN105963158 A CN 105963158A CN 201610323407 A CN201610323407 A CN 201610323407A CN 105963158 A CN105963158 A CN 105963158A
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- China
- Prior art keywords
- nial polish
- daily disposable
- emulsion
- organosilicon
- preparation
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a preparation method of a daily disposable nail polish. The preparation method specifically comprises the following steps: mixing 85-94 parts of polyurethane emulsion with 40-45% of solid content, 6-15 parts of organic silicon modified acrylate emulsion with 40-45% of solid content, 0.3-0.6 part of leveling agent, 0.1-0.3 part of antifoaming agent, 3-10 parts of mill base and 3-6 parts of thickening agent all by weight; and stirring and dispersing uniformly to obtain the daily disposable nail polish.
Description
Technical field
The present invention relates to nail polish material field, particularly to a kind of can the daily disposable nial polish that tears of whole membrane disposable and system thereof
Preparation Method.
Background technology
Tradition self-drying type nial polish is using oleoresin as film forming matter, and containing a large amount of volatile organic solvents, organic solvent
The main base of type nial polish is nitrocellulose, contains poisonous easy such as phthalate compound, benzene, formaldehyde simultaneously
Volatile solvent, life-time service is not only big to fingernail injury, and in nial polish dry run, the volatilization of toxic solvent also can
Cause the injury of respiratory system and human body skin.The most emerging a kind of daily disposable nial polish has removability, is a kind of water
Property high glaze organic membrane, has peelable, nontoxic advantage.But problem maximum in application process is to be difficult to resist daily immersion
Impact on film layer, all can make coating stripping, the most not use one day and just have a small amount of stripping, do not reach the when of washing one's hands
Maintain the purpose of the most several days complete film layers of a whole day, affect attractive in appearance.
As number of patent application CN201510672867.6 utilized aqueous pu dispersions be prepared for a kind of water-based nail polish, bulletin
Number CN104546550A, CN104352360A are prepared for water-based nail polish also with polyaminoester emulsion, and patent
CN104473820A utilize acrylic acid ester emulsion be prepared for a kind of water-based nail polish, it has been found that to utilize current technology to prepare
Nial polish although there is good hardness, glossiness and flow leveling, but the water resistance of nail film is bad, has a bath
During immersion easily cause and come off.Although also having some water-based nail polish products of some patent reports now, although attachment
Power increases, but can not reach the effect of oiliness nial polish, nor good removal, and present consumer can not be met
The frequently demand of colour changing.
Summary of the invention
It is an object of the invention to provide a kind of daily disposable nial polish and preparation method thereof, its technical problem to be solved is:
Existing peelable nial polish is difficult to resist the impact of daily immersion when specifically used, is easily peeled off and comes off, and can reach to improve firmly
The nail polish products of degree does not possess the effect of oiliness nial polish, and bad removal, it is difficult to meet the demand of the frequent colour changing of user.
For solving above-mentioned technical problem, the present invention provides a kind of daily disposable nial polish, and it is by the following components structure counted by weight
Become:
It is preferable over: the solid content of described polyaminoester emulsion is 40%-45%.
It is preferable over: the solid content of described organosilicon-modified acrylate emulsion is 40%-45%.
It is preferable over: what described polyaminoester emulsion was counted by weight content is 90 parts.
Be preferable over: described mill base can be the colour of loess, reddle, Haematitum, Huang orange, middle, yellowish, olive green, powder are green, ultramarine,
Cobalt blue, acid blue, dark red, pake purpke, violet, lemon yellow, rose-red, titanium dioxide, basic rhodamine, iron oxide yellow, phthalein be dark green,
Any one or the mill base of several combination during rubber is bright red.
It is preferable over: described thickening agent can be polyurethane associative thickener or hydroxylated cellulose.
The present invention provides the preparation method of a kind of daily disposable nial polish, by the 85-94 part solid content counted by weight is specially
Polyaminoester emulsion, 6-15 part solid content are the organosilicon-modified acrylate emulsion of 40%-45%, 0.3-0.6 part by 40%-45%
Levelling agent, 0.1-0.3 part defoamer, 3-10 part mill base and the mixing of 3-6 part thickening agent, and dispersed with stirring is uniform, i.e. obtains day
Throwing type nial polish.
It is preferable over: use blender with the rotating speed dispersed with stirring said mixture material 10min of 1000r/min.
Compared with prior art, the invention has the beneficial effects as follows:
1, present invention introduces hydrophobic organosilicon material (organosilicon-modified acrylate emulsion), be coated on fingernail in guarantee
Fingernail oil lamella there is good adhesive force, glossiness and intensity on the basis of, improve the water resistance of fingernail oil lamella,
Extend its application time, be adapted to the market demand widely;
2, the present invention is using polyaminoester emulsion and organosilicon-modified acrylate emulsion as the film base material that becomes of nial polish, and polyurethane provides
The intensity of film layer and peelable performance, the water resistance of organosilicon reinforcing membrane layer, make to prepare fingernail oil lamella have high gloss,
High-leveling and good water resistance, daily laundry, have a bath during do not come off, and can whole film can be by
The feature disposably torn, has wide market prospect, compares current market product and has more preferable ruggedness.
Detailed description of the invention
A kind of daily disposable present invention proposed below with reference to preferred embodiment and the performance test results that each embodiment is carried out
Nial polish and preparation method thereof is described in greater detail below.
Embodiment 1:
The present invention provides the preparation method of a kind of daily disposable nial polish, by the polyaminoester emulsion 90 parts counted by weight, organosilicon
Modified acrylate emulsion 6 parts, levelling agent 0.3 part, defoamer 0.1 part, orange mill base 3 parts and polyurethane association type thickening
Agent 3 parts mixes, and uses homogenizer, with the rotating speed of 1000r/min, mixed material is stirred 10min and is stirred dispersion,
And be applied in preparing on fingernail.
Embodiment 2:
The present invention provides the preparation method of a kind of daily disposable nial polish, by the polyaminoester emulsion 90 parts counted by weight, organosilicon
Modified acrylate emulsion 10 parts, levelling agent 0.5 part, defoamer 0.2 part, bright red mill base 5 parts and polyurethane association type increase
Thick dose 4 parts mix, and use homogenizer, with the rotating speed of 1000r/min, mixed material stirs 10min and are stirred point
Dissipate, and be applied in preparing on fingernail.
Embodiment 3:
The present invention provides the preparation method of a kind of daily disposable nial polish, by the polyaminoester emulsion 90 parts counted by weight, organosilicon
Modified acrylate emulsion 13 parts, levelling agent 0.6 part, defoamer 0.2 part, violet mill base 6 parts and hydroxylated cellulose increase
Thick dose 4 parts mix, and use homogenizer, with the rotating speed of 1000r/min, mixed material stirs 10min and are stirred point
Dissipate, and be applied in preparing on fingernail.
Embodiment 4:
The present invention provides the preparation method of a kind of daily disposable nial polish, by the polyaminoester emulsion 90 parts counted by weight, organosilicon
Modified acrylate emulsion 15 parts, levelling agent 0.6 part, defoamer 0.3 part, acid blue mill base 10 parts and hydroxylated cellulose thickening
Agent 6 parts mixes, and uses homogenizer, with the rotating speed of 1000r/min, mixed material is stirred 10min and is stirred dispersion,
And be applied in preparing on fingernail.
Table 1: the performance test of embodiment 1-4 (note: that the measurement numeral 1,2,3,4,5 of index represents respectively is poor, poor,
Medium, preferable, good)
On the basis of the above, the polyaminoester emulsion of commercial separate sources, pure-acrylic emulsion and organosilicon-modified acrylate breast are used
Liquid carries out sampling test, tests its performance impact to fingernail oil lamella.
Polyaminoester emulsion A, purchased from Taizhou plain Huangyan He Cheng polyurethane product factory;Polyaminoester emulsion B, beautifies work purchased from Guangdong, Guangdong
Company limited;Pure-acrylic emulsion, purchased from Guangzhou Yang Mei Chemical Co., Ltd.;Organosilicon-modified acrylate emulsion A, purchased from south
Chang Hua spy Chemical Co., Ltd.;Organosilicon-modified acrylate emulsion B, purchased from Fu Yaotong Create New Technology S. R. L.;Levelling agent, disappear
The auxiliary agents such as infusion, pigment mill base, thickening agent are commercially available usual auxiliaries.By the emulsion of above-mentioned different proportion, thickening agent with
Levelling agent, defoamer, mill base stir under the stirring of high speed dispersor, are applied on fingernail with hairbrush, dry.Specifically
Sample formulations is as shown in table 2 below.
Polyaminoester emulsion provides good film strength for fingernail oil film, it is ensured that strippable property;And pure-acrylic emulsion can improve nail film
Adhesive force and pliability, although the nail film of strippable property does not requires have the highest adhesive force of General nail oil lamella and reservation
Time, but preferably strippable property fingernail oil lamella the most at least can bear firmly have a bath, the daily requirement meeting water contact such as wash one's hands.
The introducing of this hydrophobic group of organosilicon can improve the resistance to water of nail film, and protection nail film will not take off contacting water when
Fall.
Table 2: the peelable nial polish test recipe that sample 1-23 provides
Select the polyaminoester emulsion of different manufacturers, pure-acrylic emulsion and the organosilicon-modified acrylate emulsion bought on market according to one
Fixed ratio is tested.As can be seen from Table 2, polyaminoester emulsion plays leading position in nial polish, pure-acrylic emulsion and having
The effect of machine its modification of silicon emulsion, the solid content of every kind of emulsion is all between 40%~45%, and secures always containing of all emulsions
Amount is 94g, and the content of regulation different component prepares sample.
Sample 1-8 mainly investigates the difference of polyaminoester emulsion A and B, and its test result is as shown in table 2 below.
Table 3: for the different polyaminoester emulsion impact (notes: the measurement numeral of index 1,2,3,4,5 points on nial polish performance
It is poor, poor, medium, preferable, good not represent)
From experimental result it can be seen that polyaminoester emulsion A and B is similar on the impact of nial polish performance, can become faster
Film, the strippable property all having had and adhesive force, along with the increase glossiness of pure-acrylic emulsion amount has declined, hardness increases.
The resistance to water of nail film, all in medium situation, is soaked in water, is easily come off the when of wiping.
Sample 9-16 is main has investigated the organosilicon-modified acrylate emulsion impact on nial polish film performance, and table 4 is surveyed for it
Test result.
Table 4: organosilicon-modified acrylate emulsion on the impact of nial polish performance (note: the measurement numeral 1 of index, 2,3,4,
5 represent respectively poor, poor, medium, preferable, good)
Sample | Film formation time (min) | Glossiness | Strippable property | Hardness | Adhesive force | Resistance to water |
9 | 4 | 5 | 5 | 3 | 5 | 3 |
10 | 4 | 5 | 5 | 3 | 5 | 5 |
11 | 4 | 4 | 5 | 3 | 5 | 5 |
12 | 4 | 4 | 5 | 2 | 4 | 4 |
13 | 4 | 5 | 5 | 3 | 5 | 3 |
14 | 4 | 5 | 5 | 3 | 5 | 5 |
15 | 4 | 4 | 5 | 3 | 5 | 5 |
16 | 4 | 4 | 5 | 2 | 4 | 4 |
From experimental result it can be seen that organosilicon-modified acrylate emulsion A and B is also similar on the impact of nial polish performance,
And in terms of film formation time, glossiness and strippable property, similar trend and result is maintained to pure-acrylic emulsion.Along with organosilicon changes
Property acrylic acid ester emulsion amount increase, there is downward trend in hardness and adhesive force, and this point is different from pure-acrylic emulsion, and this may
Cause owing to organosilicon itself has high flexibility.In terms of resistance to water, nail film has obtained obvious improvement, particularly sample
Product 10 and sample 14 show optimal performance, show similar test result.
Hereafter, we select formula based on No. 10 sample formulations, have studied the pure-acrylic emulsion and organic-silicon-modified third of different ratio
The impact on nail film performance of the olefin(e) acid ester emulsion, its sample is 17-23 sample.The result of its performance test is as shown in table 5.
Table 5: the most commensurability pure-acrylic emulsion and the organosilicon-modified acrylate emulsion impact (note: the weighing apparatus of index on nail film performance
It is poor, poor, medium, preferable, good that amount numeral 1,2,3,4,5 represents respectively)
From experimental result it can be seen that maintaining polyaminoester emulsion and pure third or organosilicon-modified acrylate emulsion certain proportion
Under conditions of, change pure third and with the ratio regular meeting of organosilicon-modified acrylate emulsion, hardness and the resistance to water of nail film layer are produced bright
Aobvious impact, hardness raises along with the increase of pure-acrylic emulsion amount, and resistance to water but can decline, and the optimal sample of comprehensive consideration is 17-19
Number, consistent with the property retention not having pure-acrylic emulsion.
By contrasting commercial polyaminoester emulsion, pure-acrylic emulsion and the organosilicon-modified acrylate emulsion performance to fingernail oil lamella
Impact, finds that the emulsion of different manufacturers is little on the impact of performance, and the introducing of organosilicon can significantly improve the water resistance of film layer,
In conjunction with polyaminoester emulsion high film build and intensity, the water resistance that the nial polish of preparation has strippable property, high gloss is become reconciled.
Comprehensive described, technical scheme sufficiently effective can complete foregoing invention purpose, and the structure of the present invention is former
Reason and principle of work and power are the most sufficiently verified, and can reach intended effect and purpose, and the present invention
Embodiment can also convert according to these principles, and therefore, the present invention includes that all are previously mentioned scope in claim
Interior all replacement contents.Any equivalence change made in scope of the present invention patent, all belongs to the patent model of this case application
Within enclosing.
Claims (8)
1. a daily disposable nial polish, it is characterised in that be made up of the following components counted by weight:
2. daily disposable nial polish as claimed in claim 1, it is characterised in that: the solid content of described polyaminoester emulsion is
40%-45%.
3. daily disposable nial polish as claimed in claim 2, it is characterised in that: described organosilicon-modified acrylate emulsion
Solid content is 40%-45%.
4. daily disposable nial polish as claimed in claim 3, it is characterised in that: what described polyaminoester emulsion was counted by weight
Content is 90 parts.
5. daily disposable nial polish as claimed in claim 4, it is characterised in that: described mill base can be the colour of loess, reddle, Haematitum,
Huang orange, middle, yellowish, olive green, powder are green, ultramarine, cobalt blue, acid blue, dark red, pake purpke, violet, lemon yellow, rose
Rare red, titanium dioxide, basic rhodamine, iron oxide yellow, phthalein are dark green, rubber bright red in any one or the mill base of several combination.
6. daily disposable nial polish as claimed in claim 4, it is characterised in that: described thickening agent can be that polyurethane association type increases
Thick dose or hydroxylated cellulose.
7. the preparation method of a daily disposable nial polish, it is characterised in that: it is specially and the 85-94 part counted by weight is contained admittedly
Polyaminoester emulsion, 6-15 part solid content are the organosilicon-modified acrylate emulsion of 40%-45%, 0.3-0.6 for 40%-45%'s by amount
Part levelling agent, 0.1-0.3 part defoamer, 3-10 part mill base and the mixing of 3-6 part thickening agent, and dispersed with stirring is uniform, i.e. obtains
Daily disposable nial polish.
8. the preparation method of daily disposable nial polish as claimed in claim 7, it is characterised in that: use blender with 1000r/min
Rotating speed dispersed with stirring said mixture material 10min.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107951755A (en) * | 2017-12-30 | 2018-04-24 | 张静 | A kind of water-fast anti-strip nail polish |
CN114306136A (en) * | 2021-12-31 | 2022-04-12 | 瑞昌市瑞美化妆品有限公司 | Water-resistant water-based nail polish and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101836940A (en) * | 2009-03-19 | 2010-09-22 | 蒋和平 | Water-soluble high-hardness antibacterial nail polish and preparation method thereof |
CN104352360A (en) * | 2014-10-20 | 2015-02-18 | 上海展辰涂料有限公司 | Solid-color quick-drying water-based nail polish |
CN105147536A (en) * | 2015-10-16 | 2015-12-16 | 湖北东盛特种涂料科技有限公司 | Aqueous strippable nail enamel and preparation method thereof |
-
2016
- 2016-05-16 CN CN201610323407.7A patent/CN105963158A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101836940A (en) * | 2009-03-19 | 2010-09-22 | 蒋和平 | Water-soluble high-hardness antibacterial nail polish and preparation method thereof |
CN104352360A (en) * | 2014-10-20 | 2015-02-18 | 上海展辰涂料有限公司 | Solid-color quick-drying water-based nail polish |
CN105147536A (en) * | 2015-10-16 | 2015-12-16 | 湖北东盛特种涂料科技有限公司 | Aqueous strippable nail enamel and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107951755A (en) * | 2017-12-30 | 2018-04-24 | 张静 | A kind of water-fast anti-strip nail polish |
CN114306136A (en) * | 2021-12-31 | 2022-04-12 | 瑞昌市瑞美化妆品有限公司 | Water-resistant water-based nail polish and preparation method thereof |
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