CN105962473B - Graphene electric heating clothes and production method and system - Google Patents
Graphene electric heating clothes and production method and system Download PDFInfo
- Publication number
- CN105962473B CN105962473B CN201610306130.7A CN201610306130A CN105962473B CN 105962473 B CN105962473 B CN 105962473B CN 201610306130 A CN201610306130 A CN 201610306130A CN 105962473 B CN105962473 B CN 105962473B
- Authority
- CN
- China
- Prior art keywords
- conductive
- graphene
- yarn
- layer
- strand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/002—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches with controlled internal environment
- A41D13/005—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches with controlled internal environment with controlled temperature
- A41D13/0051—Heated garments
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D27/00—Details of garments or of their making
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/02—Layered materials
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41H—APPLIANCES OR METHODS FOR MAKING CLOTHES, e.g. FOR DRESS-MAKING OR FOR TAILORING, NOT OTHERWISE PROVIDED FOR
- A41H42/00—Multi-step production lines for making clothes
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0088—Fabrics having an electronic function
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/593—Stiff materials, e.g. cane or slat
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
- D06B1/02—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
- D06B23/04—Carriers or supports for textile materials to be treated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2400/00—Functions or special features of garments
- A41D2400/10—Heat retention or warming
- A41D2400/12—Heat retention or warming using temperature-controlled means
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2500/00—Materials for garments
- A41D2500/20—Woven
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/12—Carbon; Pitch
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/18—Physical properties including electronic components
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2403/00—Details of fabric structure established in the fabric forming process
- D10B2403/02—Cross-sectional features
- D10B2403/024—Fabric incorporating additional compounds
- D10B2403/0243—Fabric incorporating additional compounds enhancing functional properties
- D10B2403/02431—Fabric incorporating additional compounds enhancing functional properties with electronic components, e.g. sensors or switches
Abstract
The present invention a kind of graphene electric heating clothes are disclosed, mainly for the electric heating clothes quantity of heat production under prior art it is low the problem of, it is proposed that a kind of graphene electric heating clothes, including clothes surface layer, thermal source, power supply and control device；Thermal source is made up of graphene heating fabric, and graphene heating fabric includes conductive layer, two insulating barriers, thermometric layer and coating；Conductive layer includes warp thread and weft yarn；Warp thread and weft yarn are conductive graphene fiber；Conductive graphene fiber includes linear matrix material and is wrapped in the conductive coating of linear matrix material outer surface, and conductive coating contains following composition in parts by mass：1~1.8 part of graphene, 7~25 parts of conductive black, 40~50 parts of acrylic resin；The opposite sides of conductive layer and the both positive and negative polarity of power supply are connected；Temperature sensor is electrically connected with control device, and control device is contacted with power supply, thermal source.Heat that the present invention is produced is more, soft pliable is folded, wearing comfort is high.
Description
Technical field
The present invention relates to a kind of graphene electric heating clothes and production method and production system.
Background technology
Cold of the winter anomaly of northern China, in cold winter, people generally require warming clothes to protect certainly
Oneself, traditional insulation garment is the convection current of the air and outside air that thicken clothes, reduce in clothes, so that, reduce heat
Scatter and disappear.But, the transfer mode of heat is not only a kind of, even if the thermal loss caused by reducing thermal convection current, human body
Heat still can be progressively scatter and disappear, it is this lost people to be caused to feel cold.Due to not being avoided that scattering and disappearing for heat, went out later
The electrothermal heating apparatus for people's additional heat is showed, has been disposed in clothes, scattering and disappearing for heat can be offset, made one to feel
It is that heat is produced using resistance wire to warm, traditional electrothermal heating apparatus, it is big that resistance wire takes volume, it is impossible to folds, simultaneously
The comfort level of people can be reduced again.With the appearance of conductive fiber, engender and conductive fiber is woven into conducting fabric, adopted
The mode of heat is produced with conducting fabric, still, existing conducting fabric conductive capability is poor, and the heat of generation is few, while in life
Chemical solvent is needed to use during production, environment can be polluted.
The content of the invention
In view of the above-mentioned problems, the present invention provides the graphene electric heating clothes more than a kind of generation heat.
To reach above-mentioned purpose, the present invention provides a kind of graphene electric heating clothes, including clothes surface layer, in clothes surface layer
Thermal source, power supply and the control device set according to array way；
The thermal source is made up of graphene heating fabric, and the graphene heating fabric includes conductive layer, is arranged on conduction
Two insulating barriers of layer both sides, the thermometric layer being disposed therein on the outside of an insulating barrier and the covering being covered on the outside of thermometric layer
Layer；
The conductive layer includes warp thread and weft yarn, and the warp thread and weft yarn, which mutually drift along, to be woven together；The warp thread and
Weft yarn is conductive graphene fiber；Or,
The warp thread is conductive graphene fiber, and the weft yarn is conductive graphene fiber and wire, the wire
Form electrode；
The conductive graphene fiber includes linear matrix material and is wrapped in leading for the linear matrix material outer surface
Electrocoat, the conductive coating contains following composition in parts by mass：1~1.8 part of graphene, 7~25 parts of conductive black, third
40~50 parts of olefin(e) acid resin；
If the side of the thermometric layer is provided with dry temperature sensor, the warp thread or latitude of the thermometric layer according to array way
Yarn includes the wire and non-conductive fibre of the temperature sensor, and the weft yarn or warp thread of the thermometric layer are non-conductive fibre；
The warp thread and weft yarn of the coating are non-conductive fibre, the conductive layer, two insulating barriers, thermometrics layer and covering
Layer is bonded together；
The both positive and negative polarity of the opposite sides of the conductive layer and power supply is connected, or, adjacent two electrode respectively with power supply just
Negative pole is connected；
The temperature sensor is electrically connected with control device, and the control device is contacted with power supply, thermal source.
The graphene electric heating clothes of the present invention, use graphene and conductive black for conductive agent, are viscous using acrylic resin
Agent is tied, the material used will not be polluted to natural environment.It is tablet additionally, due to graphene, and conductive black is particle
Shape.Therefore graphene conductive coating forms one kind using flake graphite alkene as conducting matrix grain, and conductive black is embedded in flake graphite alkene
Between form the state of conductive node so that, conductive capability of the invention is greatly enhanced than the fiber of existing outer plating metal, its
Comfortableness and folding processing characteristics are also greatly enhanced than wire.It is many, soft that graphene electric heating clothes of the present invention produce heat
Foldable, wearing comfort are high.
To reach above-mentioned purpose, the present invention provides a kind of production method of graphene electric heating clothes, including heating face fabric life
Production process, clothes surface layer production process, heating face fabric installation process and garment lining are installed；
The heating face fabric production process comprises the following steps：Weave conductive layer, braiding insulating barrier, braiding thermometric layer, volume
Knit coating and connection；
The braiding conductive layer includes following process：Spinning, yarn spraying and silk, strand spraying, braiding；
The spinning process：Chopped fiber is spinned, a monofilament long fibre is formed；
The yarn spraying process：By the monofilament long fibre alternating spray graphene ink and conductive black ink, and
Control the composition of the conductive coating of yarn outer surface by mass as follows：1~1.8 part of graphene, 7~25 parts of conductive black, third
40~50 parts of olefin(e) acid resin；Form graphene conductive monofilament；
Described and wire process：The graphene conductive monofilament is compound as a strand；
The strand spraying process：By the strand alternating spray conductive black ink and graphene ink, and control stock
The composition of the conductive coating of line outer surface by mass is as follows：1~1.8 part of graphene, 7~25 parts of conductive black, acrylic acid tree
40~50 parts of fat；Form conductive graphene fiber；
The knitting process：Some warp thread parallel intervals are arranged；When weft yarn all using conductive graphene fiber when,
Some spaced conductive graphene fibers parallel to each other are sequentially passed through into warp thread, electrodeless conductive layer is formed；Work as weft yarn
During using conductive graphene fiber and wire, by some be parallel to each other spaced conductive graphene fibers and some
The spaced wire that is parallel to each other alternately passes through warp thread, is formed with electrode conducting layer；
The braiding insulating barrier step：Using insulating materials as master batch production insulation chopped fiber, insulation chopped fiber is spun
It is made into insulation long fibre, insulation long fibre is turned into insulation strand by simultaneously silk, strand is used as warp thread and weft yarns to insulate
Into insulating barrier；
The braiding thermometric layer step：Several temperature are set to pass in the way of array on the outside of an insulating barrier wherein
Sensor；Using the wire of the temperature sensor as part warp thread or weft yarn, using non-conductive fibre as weft yarn or warp thread, braiding
As thermometric layer；
The braiding coating step：The fiber made using insulating materials weaves coating as warp thread and weft yarn；
The Connection Step：Dielectric layers are separately positioned on to the both sides of conductive layer, wherein on the outside of an insulating barrier
Thermometric layer is provided with, coating is provided with the outside of thermometric layer, the temperature sensor of the thermometric layer is contacted with insulating barrier.
The clothes surface layer production process includes cutting, the sewing of garment surface shell fabric and the warming material of garment surface shell fabric
The filling of material；
The installation process of the heating face fabric includes the connection step for cutting step, installation steps and power supply and control device
Suddenly；Wherein,
The cutting step：The heating face fabric is cut to rectangular block, and ensures the length of clothes for rectangle block length
Integral multiple, the width of clothes is the integral multiple of rectangular block width；If being woven with metal electrode on heating face fabric, ensure every piece
There are two metal electrodes on rectangular block, and metal electrode is in the opposite sides of rectangular block；
The installation steps：Rectangular block after cutting out is arranged in the way of array and is fixed in clothes surface layer；
The Connection Step of the power supply and control device：Temperature sensor in each rectangular block and control device are electrically connected
Connect, control device is connected with power supply and each rectangular block.
The installation of the garment lining：Garment lining is connected with clothes surface layer, heating face fabric is covered.
Further, spraying adjustment process is also included in the yarn spraying process and the strand spraying process, it is described
Spraying adjustment process includes：Resistive thread rate measurement process, spray rate adjustment process；Wherein,
The resistive thread rate measuring process：The monofilament long fibre or the strand are often by a graphene ink spray
Apply or the spraying of conductive black ink, carry out a resistivity measurement；
The spray rate set-up procedure：If current resistivity deviates predetermined resistivity scope, adjust and spray next time
When graphene ink or conductive black ink spray rate, if to current resistivity in the range of predetermined resistivity,
The spray rate of graphene ink or conductive black ink when keeping spraying next time is constant.
Further, Homogenization Treatments process is also included in the yarn spraying process and the strand spraying process；
The Homogenization Treatments process：Monofilament long fibre or strand are caused using ultrasonic vibrating unit in spraying process
Vibrations, mix the graphene ink and conductive black ink on monofilament long fibre, and by graphene ink and conductive black
Ink is uniformly distributed on monofilament long fibre.
Further, baking operation is also included after the yarn spraying process and the strand spraying process；
The baking operation：The graphene conductive monofilament or the graphene fiber are subjected to drying process several times；
The graphene conductive monofilament or the graphene fiber often pass through primary drying process, a moisture measurement are carried out, if currently
Humidity deviate from predetermined humidity range, then drying process next time is adjusted, if current humidity is predetermined wet
In the range of degree, then keep drying process next time constant.
Heating face fabric production process in graphene electric heating clothes production method of the present invention, is woven into list by chopped fiber first
Silk, and tubing flow displacement graphitization alkene ink and conductive black ink then will be submitted in monofilament, conductive painting is initially formed on monofilament
Layer, so as to carry out again and the content of conductive agent in whole piece conductive fiber can be improved after silk, improves its conductive capability, due to simultaneously
Silk is to merge the monofilament of two or more than two, forms strand, therefore, may exist between monofilament and not exclusively connect
Tactile position, and the position of this incomplete contact between can cause conductive capability in this place to decline, therefore, after simultaneously silk is completed
The spraying of graphene ink and conductive black ink is carried out again, so that the gap between each monofilament is filled up, while improving conductive
The content of agent, strengthens conductive capability.The enhancing of conductive capability can improve the ability of the generation heat of heating face fabric, therefore, this hair
The heat that the graphene electric heating clothes of bright graphene electric heating clothes production method production are produced is more, can save the energy.In addition originally
The graphene electric heating clothes for inventing production are comfortable and easy to wear, can arbitrarily fold.
To reach above-mentioned purpose, the present invention proposes a kind of graphene electric heating clothes production system, including surface layer production unit,
Heating face fabric production system, lining production unit, heating face fabric cutting device and heating face fabric erecting device；Wherein,
The surface layer production unit is used to cut out and sewing clothing surface layer, including cutting device and sewing device；
The lining production unit is used to cutting out, sew and installing garment lining；
The heating face fabric production system includes conductive layer weaving unit, insulating barrier weaving unit, thermometric layer weaving unit
And connection machine；
Spinning machine that conductive layer weaving unit includes setting gradually, yarn flush coater, doubling winder, strand flush coater and
Conductive layer loom；Wherein
The used in spinning machine by raw material chopped fiber in being processed into monofilament long fibre；
The yarn flush coater includes some graphene ink spray equipments and some conductive black ink spray equipments；Institute
State and conductive black oil is provided with graphene ink spray equipment interval setting, the interval of adjacent two graphenes ink spray equipment
Black spray equipment；
The doubling winder is used to the monofilament long fibre by spraying being processed into strand；
The strand flush coater includes some conductive black ink spray equipments and some graphene ink spray equipments；Institute
State in conductive black ink spray equipment interval setting, the interval of adjacent two conductive blacks ink spray equipment and be provided with graphene
Ink spray equipment；
The conductive layer loom is used for warp thread and weft yarns into graphene heating face fabric conductive layer；
The insulating barrier weaving unit includes chopped fiber extruder, spinning machine, doubling winder and insulating barrier loom；Wherein,
The master batch that the chopped fiber extruder is used to make insulating materials is extruded into chopped fiber；
The thermometric layer weaving unit includes spinning machine, doubling winder and thermometric layer loom；Wherein,
Array way is provided with temperature sensor clamping device on the thermometric layer loom；
The connection machine includes raw material fixing device, stratiform press fit device and finished product collection device；Wherein,
The raw material fixing device include set gradually from top to bottom coating cloth beam, thermometric layer cloth beam, it is upper absolutely
Edge layer cloth beam, conductive layer cloth beam and lower insulating barrier cloth beam；Glue extrusion is provided between the adjacent cloth beam of each two
Device；
Layered press fit device is arranged in front of raw material fixing device, and layered press fit device includes upper and lower pressing
Roller, the plane that the axis of the upper and lower press bonding roller is determined is perpendicular；
The finished product collection device is finished product cloth beam；
The heating face fabric erecting device includes the sewing mechanism for fixing heating face fabric and the weldering for welding lead
Connection mechanism；
Heating face fabric cutting device is used to cut out heating face fabric as rectangular block.
Further, two are provided between adjacent graphene ink spray equipment and conductive black ink spray equipment
Guide roller, two guide rollers are arranged at intervals, and electric resistance measuring apparatus is provided between described two guide rollers；The conductive charcoal
Black ink spray equipment and the graphene ink spray equipment include controller and flow regulator, the controller and institute
State flow regulator electrical connection；Electric resistance measuring apparatus after the graphene ink spray equipment sprays with next graphene ink
Electric resistance measuring apparatus and next conductive black after the controller electrical connection of coating device, the conductive black ink spray equipment
The controller electrical connection of ink spray equipment.
Further, some ultrasonic generators are provided with the yarn flush coater and the strand flush coater,
The sound wave that the ultrasonic generator is launched intersects with monofilament long fibre or strand.
Further, it is provided with dryer after the yarn flush coater and the strand flush coater；The drying
Machine includes some drying bakers set gradually and the humidity sensor being arranged between adjacent two drying baker；The drying baker includes
Thermal-insulating body, moisture absorption apparatus, some infrared lamps and drying controller；The thermal-insulating body is perpendicular to graphene conductive monofilament
Two side walls are provided with string holes, and the infrared lamp is electrically connected with the drying controller, the humidity sensor and rear phase
The drying controller electrical connection of adjacent drying baker.
Further, yarn pulling device is additionally provided with the yarn flush coater, the yarn pulling device includes yarn
Line drawing guide rail, yarn clamping device and yarn drive device, described yarn drawing guide rail one end are arranged on the spinning machine
Yarn outlet, the other end of the yarn drawing guide rail is arranged on the yarn entering opening of the doubling winder, the yarn drive device driving
The yarn clamping device is moved along yarn drawing guide rail；Strand pulling device, institute are provided with the strand flush coater
Stating strand pulling device includes strand drawing guide rail, strand clamping device and strand drive device；The strand drawing guide rail
One end is arranged on the line outlet of the doubling winder, and what the other end of the strand drawing guide rail was arranged on the loom enters line
Mouthful.
Conductive layer weaving unit in graphene electric heating clothes production system of the present invention, sets between spinning machine and doubling winder
Yarn flush coater is put, strand flush coater is set after doubling winder, the outer surface of monofilament is coated one layer using yarn flush coater
Graphene and conductive black are the conductive coating of conductive agent, using strand flush coater by and simultaneously after monofilament between space filling lead
Electric agent, thus, it is possible to the content of the conductive agent in fibrous finished product be greatly improved, so as to improve the conductive capability of finished fiber.Again
Conductive layer is woven into as warp thread and weft yarn using finished fiber, so that, the conductive capability of conductive layer is considerably beyond existing hair
Hot fabric.Therefore, the calorific capacity of graphene electric heating clothes of the present invention is also considerably beyond existing electric heating clothes, and the present invention
Using fiber as base material, its material is soft, easily fold, and greatly enhances the electric heating clothes comfort level that the present invention is produced.
Embodiment
The present invention will be further described below.
Embodiment 1
The present embodiment provides a kind of graphene electric heating clothes, including clothes surface layer, in clothes surface layer according to array way
Thermal source, power supply and the control device of setting；
The thermal source is made up of graphene heating fabric, and the graphene heating fabric includes conductive layer, is arranged on conduction
Two insulating barriers of layer both sides, the thermometric layer being disposed therein on the outside of an insulating barrier and the covering being covered on the outside of thermometric layer
Layer；
The conductive layer includes warp thread and weft yarn, and the warp thread and weft yarn, which mutually drift along, to be woven together；The warp thread and
Weft yarn is conductive graphene fiber；Or,
The warp thread is conductive graphene fiber, and the weft yarn is conductive graphene fiber and wire, the wire
Form electrode；
The conductive graphene fiber includes linear matrix material and is wrapped in leading for the linear matrix material outer surface
Electrocoat, the conductive coating contains following composition in parts by mass：1~1.8 part of graphene, 7~25 parts of conductive black, third
40~50 parts of olefin(e) acid resin；
If the side of the thermometric layer is provided with dry temperature sensor, the warp thread or latitude of the thermometric layer according to array way
Yarn includes the wire and non-conductive fibre of the temperature sensor, and the weft yarn or warp thread of the thermometric layer are non-conductive fibre；
The warp thread and weft yarn of the coating are non-conductive fibre, the conductive layer, two insulating barriers, thermometrics layer and covering
Layer is bonded together；
The both positive and negative polarity of the opposite sides of the conductive layer and power supply is connected, or, adjacent two electrode respectively with power supply just
Negative pole is connected；
The temperature sensor is electrically connected with control device, and the control device is contacted with power supply, thermal source.
The graphene electric heating clothes of the present invention, use graphene and conductive black for conductive agent, are viscous using acrylic resin
Agent is tied, the material used will not be polluted to natural environment.It is tablet additionally, due to graphene, and conductive black is particle
Shape.Therefore graphene conductive coating forms one kind using flake graphite alkene as conducting matrix grain, and conductive black is embedded in flake graphite alkene
Between form the state of conductive node so that, conductive capability of the invention is greatly enhanced than the fiber of existing outer plating metal, because
This, the conductive capability of the graphene heating face fabric made using this conductive graphene fiber is also than existing heating face fabric significantly
Enhancing.In addition, the present invention sets insulating barrier outside conductive layer and sets thermometric layer on an insulating barrier wherein, can be at any time
The current temperature of conductive layer is measured, is conducive to the regulation to the heating face fabric temperature of temperature.
It is demonstrated experimentally that under conditions of individually selecting graphene as conductive agent, with graphene content in conductive coating
Increase, the conductive capability of fiber strengthens rapidly, when graphene content reaches 1 part, and the enhanced speed of its conductive capability slows down, and works as stone
When black alkene content is more than 1.8 parts, its conductive capability does not rise anti-drop, can die down on the contrary.Therefore, mass parts are employed in the present embodiment
For 1~1.8 part of graphene.
It is demonstrated experimentally that when using graphene and conductive black for conductive agent, it is conductive fine with the increase of conductive black content
The conductive capability of dimension strengthens rapidly, when the mass parts content of conductive black is 7-14 times of graphene, the conduction of conductive fiber
Ability is most strong.
It is demonstrated experimentally that being used as binding agent, with the content increase of acrylic resin, conductive fiber using acrylic resin
Conductive capability can be reduced slowly, and when the mass fraction of acrylic resin is more than 50 parts, the conductive capability of conductive fiber is rapid
Decline.Therefore the present embodiment chooses conductive capability best quality fraction constant interval, and the mass fraction for taking acrylic resin is
40~50 parts.
Embodiment 2
The present embodiment provides a kind of production method of graphene electric heating clothes, including heating face fabric production process, garment surface
Layer production process, heating face fabric installation process and garment lining are installed；
The heating face fabric production process comprises the following steps：Weave conductive layer, braiding insulating barrier, braiding thermometric layer, volume
Knit coating and connection；
The braiding conductive layer includes following process：Spinning, yarn spraying and silk, strand spraying, braiding；
The spinning process：Chopped fiber is spinned, a monofilament long fibre is formed；
The yarn spraying process：By the monofilament long fibre alternating spray graphene ink and conductive black ink, and
Control the composition of the conductive coating of yarn outer surface by mass as follows：1~1.8 part of graphene, 7~25 parts of conductive black, third
40~50 parts of olefin(e) acid resin；Form graphene conductive monofilament；
Described and wire process：The graphene conductive monofilament is compound as a strand；
The strand spraying process：By the strand alternating spray conductive black ink and graphene ink, and control stock
The composition of the conductive coating of line outer surface by mass is as follows：1~1.8 part of graphene, 7~25 parts of conductive black, acrylic acid tree
40~50 parts of fat；Form conductive graphene fiber；
The knitting process：Some warp thread parallel intervals are arranged；When weft yarn all using conductive graphene fiber when,
Some spaced conductive graphene fibers parallel to each other are sequentially passed through into warp thread, electrodeless conductive layer is formed；Work as weft yarn
During using conductive graphene fiber and wire, by some be parallel to each other spaced conductive graphene fibers and some
The spaced wire that is parallel to each other alternately passes through warp thread, is formed with electrode conducting layer；
The braiding insulating barrier step：Using insulating materials as master batch production insulation chopped fiber, insulation chopped fiber is spun
It is made into insulation long fibre, insulation long fibre is turned into insulation strand by simultaneously silk, strand is used as warp thread and weft yarns to insulate
Into insulating barrier；
The braiding thermometric layer step：Several temperature are set to pass in the way of array on the outside of an insulating barrier wherein
Sensor；Using the wire of the temperature sensor as part warp thread or weft yarn, using non-conductive fibre as weft yarn or warp thread, braiding
As thermometric layer；
The braiding coating step：The fiber made using insulating materials weaves coating as warp thread and weft yarn；
The Connection Step：Dielectric layers are separately positioned on to the both sides of conductive layer, wherein on the outside of an insulating barrier
Thermometric layer is provided with, coating is provided with the outside of thermometric layer, the temperature sensor of the thermometric layer is contacted with insulating barrier.
The clothes surface layer production process includes cutting, the sewing of garment surface shell fabric and the warming material of garment surface shell fabric
The filling of material；
The installation process of the heating face fabric includes the connection step for cutting step, installation steps and power supply and control device
Suddenly；Wherein,
The cutting step：The heating face fabric is cut to rectangular block, and ensures the length of clothes for rectangle block length
Integral multiple, the width of clothes is the integral multiple of rectangular block width；If being woven with metal electrode on heating face fabric, ensure every piece
There are two metal electrodes on rectangular block, and metal electrode is in the opposite sides of rectangular block；
The installation steps：Rectangular block after cutting out is arranged in the way of array and is fixed in clothes surface layer；
The Connection Step of the power supply and control device：Temperature sensor in each rectangular block and control device are electrically connected
Connect, control device is connected with power supply and each rectangular block.
The installation of the garment lining：Garment lining is connected with clothes surface layer, heating face fabric is covered.
The present embodiment graphene electric heating clothes production method first weaves chopped fiber during heating face fabric is produced
Into monofilament, and tubing flow displacement graphitization alkene ink and conductive black ink then will be submitted in monofilament, and be initially formed and lead on monofilament
Electrocoat, so as to carry out again and the content of conductive agent in whole piece conductive fiber can be improved after silk, improves its conductive capability, by
Yu Bingsi is to merge the monofilament of two or more than two, forms strand, therefore, between monofilament may exist endless
The position of Full connected, and the position of this incomplete contact between can cause conductive capability in this place to decline, and therefore, be completed in simultaneously silk
Carry out the spraying of graphene ink and conductive black ink again afterwards, so as to fill up the gap between each monofilament, improve simultaneously
The content of conductive agent, strengthens conductive capability.
If having produced fiber according to the conventional mode of production, then to conductive coating is sprayed on fiber, can cause monofilament it
Between position can not spray conductive coating, its conductive capability will necessarily decline, and the present embodiment provide conductive fiber system
Make method, first sprayed monofilament, then carry out and silk, integral spray is finally carried out again, so as to make monofilament contact surface
On also have in conductive coating, and the gap that can not completely attach to of monofilament and can be also filled up completely with by conductive coating, make conductive fibre
The conductive coating content of dimension is increased substantially, and because the conductive capability of graphene is high originally than electroplating the conductive capability of metal,
Therefore, the conductive fiber of the production method production of the present embodiment both soft easy processing, has good electric conductivity again.
The present embodiment is set temperature sensor by array way, and using the wire of temperature sensor as warp thread or weft yarn
Thermometric layer is woven, temperature sensor can be fixed on to a fixed position, also, regard the wire of temperature sensor as warp
Yarn or weft yarn can also reduce the occupancy in space, make the thickness of the graphene heating face fabric of finished product thinning.
Embodiment 3
Also include spraying on the basis of above-described embodiment, in the yarn spraying process and the strand spraying process to adjust
Journey is had suffered, the spraying adjustment process includes：Resistive thread rate measurement process, spray rate adjustment process；Wherein,
The resistive thread rate measuring process：The monofilament long fibre or the strand are often by a graphene ink spray
Apply or the spraying of conductive black ink, carry out a resistivity measurement；
The spray rate set-up procedure：If current resistivity deviates predetermined resistivity scope, adjust and spray next time
When graphene ink or conductive black ink spray rate, if to current resistivity in the range of predetermined resistivity,
The spray rate of graphene ink or conductive black ink when keeping spraying next time is constant.
In the spraying process of yarn, due to the shake of yarn or strand or due to graphene ink or conductive black
The uniformity coefficient of ink not wait the problem of, frequently can lead to it is uneven in spraying process, and conductive coating it is uneven just
The conductive capability of conductive fiber can be caused different at each position, and the conductive capability of conductive fiber can be worst by conductive capability
Position restriction, therefore, spray the decline of the uneven conductive capability that will directly result in conductive fiber, also will be further
Cause the conductive capability of conductive layer uneven.In order to ensure the uniformity coefficient for the conductive capability of conductive layer produced, this implementation
Example is tested the resistance of conductive fiber after sprayed every time, if the resistance value not predetermined resistance range it
It is interior, it will be adjusted in follow-up spraying process, that is to say, that：After the spraying of graphene ink of process, carry out
Resistance test, if test resistance value is more than predetermined resistance, graphene ink spraying next time will increase spraying
Speed, so as to increase the content of graphene at this, so that the resistance value at this is adjusted in the range of predetermined resistance；Similarly, it is right
Same control mode is also used in the spraying of conductive black ink.It so, it is possible the conductive graphene fiber for ensureing to produce
Conductive capability it is good, and the conductive capability of the graphene heating face fabric after the completion of weaving is uniform.Heating face fabric conductive capability
The caloric value that can uniformly make each position of graphene electric heating clothes it is identical, thus, it is possible to improve the present embodiment graphene electricity
The wearing comfort of hot clothes.
Embodiment 4
On the basis of above-described embodiment, stating in yarn spraying process and the strand spraying process also includes at homogenization
Science and engineering sequence；
The Homogenization Treatments process：Monofilament long fibre or strand are caused using ultrasonic vibrating unit in spraying process
Vibrations, mix the graphene ink and conductive black ink on monofilament long fibre, and by graphene ink and conductive black
Ink is uniformly distributed on monofilament long fibre.
The present embodiment is homogenized graphene ink and conductive black ink using ultrasonic wave in spraying process, by
It is that a face or several faces are sprayed that can only be selected in the spraying of graphene ink and conductive black ink, therefore, in spraying
During the problem of necessarily cause skewness on linear matrix material, because ultrasonic wave has superpower stirring capacity, because
This, is stirred in spraying process using ultrasonic wave to graphene ink and conductive black ink, can be by graphene ink
It is evenly distributed on linear matrix material, can also makes between graphene ink and conductive black ink with conductive black ink
It is well mixed, so that, make each position conductive capability of conductive fiber identical, it is to avoid the conductive capability of restriction conductive fiber occur
Position.Therefore, it can make the conductive capability of each position of conductive layer uniform using the process of homogenization, that is, make each position
The even heat of generation is put, is conducive to improving the comfort level of the present embodiment graphene electric heating clothes.
Embodiment 5
On the basis of above-described embodiment, also include drying after the yarn spraying process and the strand spraying process
Dry process；
The baking operation：The graphene conductive monofilament or the graphene fiber are subjected to drying process several times；
The graphene conductive monofilament or the graphene fiber often pass through primary drying process, a moisture measurement are carried out, if currently
Humidity deviate from predetermined humidity range, then drying process next time is adjusted, if current humidity is predetermined wet
In the range of degree, then keep drying process next time constant.
The present embodiment has carried out drying and processing after yarn spraying and strand spraying, due to needing to carry out after yarn spraying
And silk, and when silk application pressure can be carried out to each monofilament, if now monofilament is not oven-dried, be easily caused binding agent quilt
Extrusion, and cause graphene ink or conductive black ink to be extruded, it is impossible to and the good combination of monofilament long fibre, therefore,
Carrying out and dried before silk.If disposably dried to monofilament, the binding agent for being easily caused outer layer is dry
And internal layer is unseasoned, so as to cause moisture of internal layer etc. to be sealed by binding agent, internal layer is caused to dry, influence is conductive fine
The quality of dimension, accordingly, it would be desirable to be gradually dried, and will strictly control the degree dried each time, accordingly, it would be desirable to each
Humidity Detection is carried out after secondary drying process, and adjusts drying process next time in time.Similarly, strand needs after the spray application
Braiding step is carried out, during braiding, strand also can be by certain pressure, it is therefore desirable to strand is dried processing.
Embodiment 6
The present embodiment provides a kind of graphene electric heating clothes production system, including surface layer production unit, heating face fabric production
System, lining production unit, heating face fabric cutting device and heating face fabric erecting device；Wherein,
The surface layer production unit is used to cut out and sewing clothing surface layer, including cutting device and sewing device；
The lining production unit is used to cutting out, sew and installing garment lining；
The heating face fabric production system includes conductive layer weaving unit, insulating barrier weaving unit, thermometric layer weaving unit
And connection machine；
Spinning machine that conductive layer weaving unit includes setting gradually, yarn flush coater, doubling winder, strand flush coater and
Conductive layer loom；Wherein
The used in spinning machine by raw material chopped fiber in being processed into monofilament long fibre；
The yarn flush coater includes some graphene ink spray equipments and some conductive black ink spray equipments；Institute
State and conductive black oil is provided with graphene ink spray equipment interval setting, the interval of adjacent two graphenes ink spray equipment
Black spray equipment；
The doubling winder is used to the monofilament long fibre by spraying being processed into strand；
The strand flush coater includes some conductive black ink spray equipments and some graphene ink spray equipments；Institute
State in conductive black ink spray equipment interval setting, the interval of adjacent two conductive blacks ink spray equipment and be provided with graphene
Ink spray equipment；
The conductive layer loom is used for warp thread and weft yarns into graphene heating face fabric conductive layer；
The insulating barrier weaving unit includes chopped fiber extruder, spinning machine, doubling winder and insulating barrier loom；Wherein,
The master batch that the chopped fiber extruder is used to make insulating materials is extruded into chopped fiber；
The thermometric layer weaving unit includes spinning machine, doubling winder and thermometric layer loom；Wherein,
Array way is provided with temperature sensor clamping device on the thermometric layer loom；
The connection machine includes raw material fixing device, stratiform press fit device and finished product collection device；Wherein,
The raw material fixing device include set gradually from top to bottom coating cloth beam, thermometric layer cloth beam, it is upper absolutely
Edge layer cloth beam, conductive layer cloth beam and lower insulating barrier cloth beam；Glue extrusion is provided between the adjacent cloth beam of each two
Device；
Layered press fit device is arranged in front of raw material fixing device, and layered press fit device includes upper and lower pressing
Roller, the plane that the axis of the upper and lower press bonding roller is determined is perpendicular；
The finished product collection device is finished product cloth beam；
The heating face fabric erecting device includes the sewing mechanism for fixing heating face fabric and the weldering for welding lead
Connection mechanism；
Heating face fabric cutting device is used to cut out heating face fabric as rectangular block.
Yarn flush coater in the present embodiment carries out the spraying of graphene ink, and graphene ink and conductive charcoal first
Interlock progress during the spraying of black ink, thereby it is ensured that conductive black can be filled into the laminar structured of graphene
In space, formed using the graphene of sheet as skeleton, using granular conductive black as the three-dimensional conductive structure of node, it is led
Electricity is very capable.And when carrying out the spraying of strand, it is necessary first to the space between monofilament is filled, and in filling space
Ability on, the graphene of sheet is necessarily weaker than granular conductive black more, therefore, in the spraying process of strand
In, first spraying conductive black ink, and the process sprayed that conductive black ink and graphene ink are interlocked is taken, from
And, without can be formed outside strand using sheet graphene as skeleton, using granular conductive carbon black as the three-dimensional conductive of node
Structure, additionally it is possible to connect the conductive structure of outer layer and the conductive structure of monofilament outer surface, forms overall conductive structure,
Strengthen the conductive capability of conductive fiber.The enhancing of conductive fiber conductive capability also implies that the face being woven into using conductive fiber
The conductive capability enhancing of material, therefore, the conductive capability of the conductive layer for the graphene heating face fabric that the system of the present embodiment is produced
Conductive capability than existing conducting fabric is much better than, the graphene electric heating clothes that the system of the present embodiment is produced also just than
Big many of existing electric heating clothes quantity of heat production, so as to save the energy.In addition, by heating face fabric be cut into rectangular block and
Set, when a certain piece of heating face fabric is damaged, can very easily change in the way of array.
Embodiment 7
On the basis of a upper embodiment, adjacent graphene ink spray equipment and conductive black ink spray equipment it
Between be provided with two guide rollers, two guide rollers are arranged at intervals, and resistance measurement dress is provided between described two guide rollers
Put；The conductive black ink spray equipment and the graphene ink spray equipment include controller and flow regulator,
The controller is electrically connected with the flow regulator；Electric resistance measuring apparatus after the graphene ink spray equipment is with
Electric resistance measuring apparatus after the controller electrical connection of one graphene ink spray equipment, the conductive black ink spray equipment
Electrically connected with the controller of next conductive black ink spray equipment.
The present embodiment sets resistance to survey after each graphene ink spray equipment and conductive black ink spray equipment
Device is measured, a resistance measurement is all carried out after spraying is finished each time, and to measure obtained resistance value as foundation, under adjustment
The spray rate of graphene ink spray equipment or conductive black ink spray equipment, that is to say, that when stone of completion
After the spray equipment of black alkene ink, a resistance measurement is carried out, if now resistance is less than predetermined range, in stone next time
Slow down spray rate during black alkene ink spraying, to avoid the waste of material, if resistance now is more than the scope of predetermined value,
Need to accelerate spray rate in graphene ink spraying next time, to obtain the conductive fiber with good conductive ability.
Similarly, the spraying adjustment of conductive black ink is also such.
Embodiment 8
On the basis of above-described embodiment, some ultrasounds are provided with the yarn flush coater and the strand flush coater
Wave generating device, the sound wave that the ultrasonic generator is launched intersects with monofilament long fibre or strand.
The present embodiment is in spraying process using ultrasonic transmission device to the graphene oil on monofilament long fibre or strand
Ink or conductive black ink are stirred, and the graphene of sheet is uniformly mixed with granular conductive black, form uniform
Conductive structure, simultaneously, additionally it is possible to graphene is uniformly distributed with conductive black on linear matrix material, be conducive to linear
Uniform conductive structure is formed on matrix material, makes the conductive capability at each position of conductive fiber same or like, in the absence of bottleneck
Position.
Embodiment 9
On the basis of above-described embodiment, drying is provided with after the yarn flush coater and the strand flush coater
Machine；The dryer includes some drying bakers set gradually and the humidity sensor being arranged between adjacent two drying baker；Institute
Stating drying baker includes thermal-insulating body, moisture absorption apparatus, some infrared lamps and drying controller；The thermal-insulating body is perpendicular to graphite
Two side walls of alkene conductive monofilament are provided with string holes, and the infrared lamp is electrically connected with the drying controller, and the humidity is passed
The drying controller electrical connection of sensor drying baker adjacent with rear.
The present embodiment all sets dryer after yarn flush coater and strand flush coater, is avoided by incubator outside heat
Dissipate, save the energy, while absorbing the steam that evaporates using moisture absorption apparatus, it is to avoid in incubator humidity it is too high and influence yarn or
The drying of strand.If disposably dried to monofilament, be easily caused the binding agent of outer layer dried and internal layer not
Dry, so as to cause moisture of internal layer etc. to be sealed by binding agent, cause internal layer to dry, influence the quality of conductive fiber, because
This will strictly control the degree dried each time, it is necessary to be gradually dried, and therefore, be carried out using multiple drying units
Gradually dry, and all the humidity of yarn or strand is measured with humidity sensor after drying each time, if yarn
Or the humidity of strand deviate from predetermined humidity range, it is necessary to be adjusted in baking operation next time, if yarn
Or the humidity range of strand keeps baking operation next time constant within predetermined humidity range, then.Similarly, strand is in spray
Need to carry out braiding step after painting, during braiding, strand also can be by certain pressure, it is therefore desirable to carry out strand
Drying process.
Embodiment 10
On the basis of above-described embodiment, yarn pulling device is additionally provided with the yarn flush coater, the yarn is led
Drawing device includes yarn drawing guide rail, yarn clamping device and yarn drive device, and described yarn drawing guide rail one end is arranged on
The yarn outlet of the spinning machine, the other end of the yarn drawing guide rail is arranged on the yarn entering opening of the doubling winder, the yarn
Drive device drives the yarn clamping device to be moved along yarn drawing guide rail；Strand is provided with the strand flush coater
Pulling device, the strand pulling device includes strand drawing guide rail, strand clamping device and strand drive device；The strand
One end of drawing guide rail is arranged on the line outlet of the doubling winder, and the other end of the strand drawing guide rail is arranged on described weave cotton cloth
The line inlet port of machine.
Because the process such as spinning, yarn spraying and silk, strand spraying is continuous production process, therefore, in production process
In can continuously produce, as long as yarn and strand are continuous, it is possible to continuous production, so can just there is higher production efficiency,
But, because follow-up process in production is started can not apply the power of drawing, therefore, the present embodiment to yarn and strand
Yarn pulling device and strand pulling device are set on yarn flush coater and strand flush coater, when spinning machine just starts spinning,
Yarn clamping device clamps the end of a thread of yarn, and then yarn drive device drives yarn clamping device along yarn drawing guide rail fortune
It is dynamic, meanwhile, each spray equipment starts spraying, when yarn clamping device moves to the yarn entering opening of doubling winder, by yarn feeding simultaneously
The yarn entering opening of silk machine, yarn pulling device is stopped.Similarly, when doubling winder is just started working, strand pulling device is also so
The end of a thread of strand is pulled to the line inlet port of loom, and passes through woven fabric of weaving cotton cloth.So, without manually doing in whole process
In advance, whole conductive layer production process can be automatically performed.
More than, only presently preferred embodiments of the present invention, but protection scope of the present invention is not limited thereto, and it is any to be familiar with sheet
Those skilled in the art the invention discloses technical scope in, the change or replacement that can be readily occurred in should all be covered
Within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should be defined by claim is defined.
Claims (9)
1. a kind of graphene electric heating clothes, it is characterised in that：Set including clothes surface layer, in clothes surface layer according to array way
Thermal source, power supply and control device；
The thermal source is made up of graphene heating fabric, and the graphene heating fabric includes conductive layer, is arranged on conductive layer two
Two insulating barriers of side, the thermometric being disposed therein on the outside of insulating barrier layer and the coating being covered on the outside of thermometric layer；
The conductive layer includes warp thread and weft yarn, and the warp thread and weft yarn, which mutually drift along, to be woven together；The warp thread and weft yarn
It is conductive graphene fiber；Or,
The warp thread is conductive graphene fiber, and the weft yarn is conductive graphene fiber and wire, and the wire is formed
Electrode；
The conductive graphene fiber includes linear matrix material and is wrapped in the conductive painting of the linear matrix material outer surface
Layer, the conductive coating contains following composition in parts by mass：1~1.8 part of graphene, 7~25 parts of conductive black, acrylic acid
40~50 parts of resin；
If the side of the thermometric layer is provided with dry temperature sensor, the warp thread or weft yarn bag of the thermometric layer according to array way
The wire and non-conductive fibre of the temperature sensor are included, the weft yarn or warp thread of the thermometric layer are non-conductive fibre；
The warp thread and weft yarn of the coating are non-conductive fibre, and the conductive layer, two insulating barriers, thermometric layer and coating are viscous
Knot is together；
The opposite sides of the conductive layer and the both positive and negative polarity of power supply are connected, or, the both positive and negative polarity of adjacent two electrode respectively with power supply
Connection；
The temperature sensor is electrically connected with control device, and the control device is contacted with power supply, thermal source；
The production method of described graphene electric heating clothes includes heating face fabric production process, clothes surface layer production process, hair
Hot fabric installation process and garment lining are installed；
The heating face fabric production process comprises the following steps：Braiding conductive layer, braiding insulating barrier, braiding thermometric layer, braiding are covered
Cap rock and connection；
The braiding conductive layer includes following process：Spinning, yarn spraying and silk, strand spraying, braiding；
The spinning process：Chopped fiber is spinned, a monofilament long fibre is formed；
The yarn spraying process：By the monofilament long fibre alternating spray graphene ink and conductive black ink, and control
The composition of the conductive coating of yarn outer surface by mass is as follows：1~1.8 part of graphene, 7~25 parts of conductive black, acrylic acid
40~50 parts of resin；Form graphene conductive monofilament；
Described and wire process：The graphene conductive monofilament is compound as a strand；
The strand spraying process：By the strand alternating spray conductive black ink and graphene ink, and control outside strand
The composition of the conductive coating on surface by mass is as follows：1~1.8 part of graphene, 7~25 parts of conductive black, acrylic resin 40
~50 parts；Form conductive graphene fiber；
The knitting process：Some warp thread parallel intervals are arranged；When weft yarn all using conductive graphene fiber when, if will
Dry root spaced conductive graphene fiber parallel to each other sequentially passes through warp thread, forms electrodeless conductive layer；When weft yarn is used
When conductive graphene fiber and wire, spaced conductive graphene fiber and some are parallel to each other mutually by some
The wire that parallel interval is set alternately passes through warp thread, is formed with electrode conducting layer；
The braiding insulating barrier step：Using insulating materials as master batch production insulation chopped fiber, insulation chopped fiber is woven into
Insulation long fibre, the long fibre that will insulate pass through and silk is as insulation strand, into exhausted with weft yarns using the strand that insulate as warp thread
Edge layer；
The braiding thermometric layer step：Several TEMPs are set in the way of array on the outside of an insulating barrier wherein
Device；Using the wire of the temperature sensor as part warp thread or weft yarn, using non-conductive fibre as weft yarn or warp thread, it is woven into
For thermometric layer；
The braiding coating step：The fiber made using insulating materials weaves coating as warp thread and weft yarn；
The Connection Step：Dielectric layers are separately positioned on to the both sides of conductive layer, set wherein on the outside of an insulating barrier
There is thermometric layer, coating is provided with the outside of thermometric layer, the temperature sensor of the thermometric layer is contacted with insulating barrier；
The clothes surface layer production process includes the cutting, the sewing of garment surface shell fabric and heat insulating material of garment surface shell fabric
Filling；
The installation process of the heating face fabric includes cutting the Connection Step of step, installation steps and power supply and control device；
Wherein,
The cutting step：The heating face fabric is cut to rectangular block, and ensures that the length of clothes is the whole of rectangle block length
Several times, the width of clothes is the integral multiple of rectangular block width；If being woven with metal electrode on heating face fabric, ensure every piece of rectangle
There are two metal electrodes on block, and metal electrode is in the opposite sides of rectangular block；
The installation steps：Rectangular block after cutting out is arranged in the way of array and is fixed in clothes surface layer；
The Connection Step of the power supply and control device：Temperature sensor in each rectangular block is electrically connected with control device,
Control device is connected with power supply and each rectangular block；
The installation of the garment lining：Garment lining is connected with clothes surface layer, heating face fabric is covered.
2. graphene electric heating clothes as claimed in claim 1, it is characterised in that：Yarn spraying process and the strand spraying
Also include spraying adjustment process in process, the spraying adjustment process includes：Resistive thread rate measurement process, spray rate adjustment
Process；Wherein,
The resistive thread rate measuring process：The monofilament long fibre or the strand often by the spraying of graphene ink or
Person's conductive black ink is sprayed, and carries out a resistivity measurement；
The spray rate set-up procedure：If current resistivity deviates predetermined resistivity scope, adjust when spraying next time
The spray rate of graphene ink or conductive black ink, if being kept to current resistivity in the range of predetermined resistivity
The spray rate of graphene ink or conductive black ink when spraying next time is constant.
3. graphene electric heating clothes as claimed in claim 1, it is characterised in that：Yarn spraying process and the strand spraying
Also include Homogenization Treatments process in process；
The Homogenization Treatments process：Cause the shake of monofilament long fibre or strand using ultrasonic vibrating unit in spraying process
It is dynamic, mix the graphene ink and conductive black ink on monofilament long fibre, and by graphene ink and conductive black ink
It is uniformly distributed on monofilament long fibre.
4. graphene electric heating clothes as claimed in claim 1, it is characterised in that：Sprayed in the yarn spraying process and the strand
Also include baking operation after painting process；
The baking operation：The graphene conductive monofilament or the graphene fiber are subjected to drying process several times；It is described
Graphene conductive monofilament or the graphene fiber often pass through primary drying process, a moisture measurement are carried out, if current humidity
Predetermined humidity range is deviate from, then drying process next time is adjusted, if current humidity is in predetermined humidity model
In enclosing, then keep drying process next time constant.
5. a kind of graphene electric heating clothes production system, it is characterised in that：Including surface layer production unit, heating face fabric production system
System, lining production unit, heating face fabric cutting device and heating face fabric erecting device；Wherein,
The surface layer production unit is used to cut out and sewing clothing surface layer, including cutting device and sewing device；
The lining production unit is used to cutting out, sew and installing garment lining；
The heating face fabric production system include conductive layer weaving unit, insulating barrier weaving unit, thermometric layer weaving unit and
Connection machine；
The conductive layer weaving unit includes spinning machine, yarn flush coater, doubling winder, strand flush coater and the conduction set gradually
Layer loom；Wherein
The used in spinning machine by raw material chopped fiber in being processed into monofilament long fibre；
The yarn flush coater includes some graphene ink spray equipments and some conductive black ink spray equipments；The stone
Black alkene ink spray equipment is arranged at intervals, and the spray of conductive black ink is provided with the interval of adjacent two graphenes ink spray equipment
Coating device；
The doubling winder is used to the monofilament long fibre by spraying being processed into strand；
The strand flush coater includes some conductive black ink spray equipments and some graphene ink spray equipments；It is described to lead
Electric carbon-loaded inks spray equipment is arranged at intervals, and graphene ink is provided with the interval of adjacent two conductive blacks ink spray equipment
Spray equipment；
The conductive layer loom is used for warp thread and weft yarns into graphene heating face fabric conductive layer；
The insulating barrier weaving unit includes chopped fiber extruder, spinning machine, doubling winder and insulating barrier loom；Wherein,
The master batch that the chopped fiber extruder is used to make insulating materials is extruded into chopped fiber；
The thermometric layer weaving unit includes spinning machine, doubling winder and thermometric layer loom；Wherein,
Array way is provided with temperature sensor clamping device on the thermometric layer loom；
The connection machine includes raw material fixing device, stratiform press fit device and finished product collection device；Wherein,
The raw material fixing device includes the coating cloth beam, thermometric layer cloth beam, upper insulating barrier set gradually from top to bottom
Cloth beam, conductive layer cloth beam and lower insulating barrier cloth beam；Glue extrusion device is provided between the adjacent cloth beam of each two；
Layered press fit device is arranged in front of raw material fixing device, and layered press fit device includes upper and lower press bonding roller, institute
The plane for stating the axis determination of upper and lower press bonding roller is perpendicular；
The finished product collection device is finished product cloth beam；
The heating face fabric erecting device includes the sewing mechanism for fixing heating face fabric and the bonding machine for welding lead
Structure；
Heating face fabric cutting device is used to cut out heating face fabric as rectangular block.
6. graphene electric heating clothes production system as claimed in claim 5, it is characterised in that：Adjacent graphene ink spraying dress
Put and two guide rollers are provided between conductive black ink spray equipment, two guide rollers are arranged at intervals, described two
Electric resistance measuring apparatus is provided between guide roller；The conductive black ink spray equipment and the graphene ink spray equipment
Include controller and flow regulator, the controller is electrically connected with the flow regulator；The graphene ink spraying
Electric resistance measuring apparatus after device is electrically connected with the controller of next graphene ink spray equipment, the conductive black ink
Electric resistance measuring apparatus after spray equipment is electrically connected with the controller of next conductive black ink spray equipment.
7. graphene electric heating clothes production system as claimed in claim 5, it is characterised in that：The yarn flush coater and the stock
Be provided with some ultrasonic generators on wire spraying machine, the sound wave that the ultrasonic generator is launched it is long with monofilament
Fiber or strand are intersecting.
8. graphene electric heating clothes production system as claimed in claim 5, it is characterised in that：In the yarn flush coater and described
Dryer is provided with after strand flush coater；The dryer includes some drying bakers set gradually and is arranged on adjacent two
Humidity sensor between drying baker；The drying baker includes thermal-insulating body, moisture absorption apparatus, some infrared lamps and drying control
Device；The thermal-insulating body is provided with string holes perpendicular to two side walls of graphene conductive monofilament, and the infrared lamp dries with described
Dry controller electrical connection, the drying controller electrical connection of humidity sensor drying baker adjacent with rear.
9. graphene electric heating clothes production system as claimed in claim 5, it is characterised in that：Also set up on the yarn flush coater
There is yarn pulling device, the yarn pulling device includes yarn drawing guide rail, yarn clamping device and yarn drive device, institute
State yarn and pull the yarn outlet that guide rail one end is arranged on the spinning machine, the other end that the yarn pulls guide rail is arranged on described
The yarn entering opening of doubling winder, the yarn drive device drives the yarn clamping device to be moved along yarn drawing guide rail；Institute
State and strand pulling device is provided with strand flush coater, the strand pulling device includes strand drawing guide rail, strand and clamps dress
Put and strand drive device；One end of the strand drawing guide rail is arranged on the line outlet of the doubling winder, the strand drawing
The other end of guide rail is arranged on the line inlet port of the loom.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610306130.7A CN105962473B (en) | 2016-05-10 | 2016-05-10 | Graphene electric heating clothes and production method and system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610306130.7A CN105962473B (en) | 2016-05-10 | 2016-05-10 | Graphene electric heating clothes and production method and system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105962473A CN105962473A (en) | 2016-09-28 |
| CN105962473B true CN105962473B (en) | 2017-09-01 |
Family
ID=56991480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610306130.7A Active CN105962473B (en) | 2016-05-10 | 2016-05-10 | Graphene electric heating clothes and production method and system |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105962473B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107028248A (en) * | 2017-04-20 | 2017-08-11 | 泉州信和石墨烯研究院有限公司 | A kind of graphene clothes |
| CN107676851A (en) * | 2017-10-19 | 2018-02-09 | 周子惠 | A kind of graphene of storage that is easy to carry folds electric heater |
| CN108708184A (en) * | 2018-06-19 | 2018-10-26 | 陈敬学 | A kind of electric heating textile cloth and preparation method thereof and its manufactured underwear |
| CN108882411A (en) * | 2018-08-03 | 2018-11-23 | 北京安墨烯科技有限责任公司 | A kind of Demountable assemble type graphene electric heating cloth and preparation method thereof |
| CN117026621B (en) * | 2023-08-11 | 2024-03-29 | 波司登羽绒服装有限公司 | Composite slurry of fabric with heat preservation and antistatic functions, and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103556452A (en) * | 2013-10-30 | 2014-02-05 | 苏州龙杰特种纤维股份有限公司 | Elastic conductive composite fiber and preparation method thereof |
| CN104845361A (en) * | 2015-05-13 | 2015-08-19 | 扬州利贞复合材料有限公司 | Highly conductive thermoplastic plastic reinforced cooperatively by short carbon fiber and nano conductive carbon black/graphene and manufacturing method thereof |
| CN105002735A (en) * | 2015-07-21 | 2015-10-28 | 苏州明动新材料科技有限公司 | Electric conduction textile fibers preparation method |
| CN105063796A (en) * | 2015-07-21 | 2015-11-18 | 中国科学院宁波材料技术与工程研究所 | High-molecular composite conductive fiber and preparation method thereof |
| CN105484033A (en) * | 2015-12-30 | 2016-04-13 | 无锡腾华电缆材料科技有限公司 | Preparation method of conductive coated fabric |
-
2016
- 2016-05-10 CN CN201610306130.7A patent/CN105962473B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103556452A (en) * | 2013-10-30 | 2014-02-05 | 苏州龙杰特种纤维股份有限公司 | Elastic conductive composite fiber and preparation method thereof |
| CN104845361A (en) * | 2015-05-13 | 2015-08-19 | 扬州利贞复合材料有限公司 | Highly conductive thermoplastic plastic reinforced cooperatively by short carbon fiber and nano conductive carbon black/graphene and manufacturing method thereof |
| CN105002735A (en) * | 2015-07-21 | 2015-10-28 | 苏州明动新材料科技有限公司 | Electric conduction textile fibers preparation method |
| CN105063796A (en) * | 2015-07-21 | 2015-11-18 | 中国科学院宁波材料技术与工程研究所 | High-molecular composite conductive fiber and preparation method thereof |
| CN105484033A (en) * | 2015-12-30 | 2016-04-13 | 无锡腾华电缆材料科技有限公司 | Preparation method of conductive coated fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105962473A (en) | 2016-09-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105922669B (en) | Graphene heating face fabric and production method and system | |
| CN105962473B (en) | Graphene electric heating clothes and production method and system | |
| CN105821663B (en) | Conductive graphene fiber and production method and system | |
| KR101681819B1 (en) | Fabric heater | |
| CN105706525B (en) | With the multi-layered textile product of internal heating layer made of electrified fabric and corresponding manufacture processing | |
| CN101662852B (en) | Stretch broken carbon fibre thread for a heating device | |
| CN207711678U (en) | A kind of far infrared heating tapestry | |
| CN113235202A (en) | Multifunctional fabric and preparation method and application thereof | |
| WO2016003031A1 (en) | Planar heating cloth and method for manufacturing same | |
| KR101754924B1 (en) | A methode for flexible carbon heating-pad | |
| CN110241494A (en) | A kind of continuous identical tension heat setting device of fibrecord and method | |
| CN1775128A (en) | Nano intelligent temperature-controlled garment and its preparing method | |
| CN206879120U (en) | A kind of flexible sheet carbon fiber exothermic part | |
| KR100754322B1 (en) | Manufacturing apparatus for carbon thread using carbon coating solution, and manufacturing method for carbon thread using the apparatus | |
| KR101497015B1 (en) | Mesh heating element using conductive graphite or carbon and manufacturing method there of | |
| CN105376877A (en) | Electric blanket heating material and electric blanket | |
| CN206695559U (en) | A kind of window screening special glass fiber cloth dryer | |
| CN109849462A (en) | A kind of superfine graphite alkene Anti-static down jacket fabric | |
| CN108882408A (en) | A kind of three-dimensional interstitital texture composite electrothermal material | |
| CN206079919U (en) | Infrared intelligent light and heat blanket that generates heat of low -voltage | |
| CN214125549U (en) | Flexible thermoelectric device | |
| CN207933699U (en) | The woven carbon fiber unidirectional cloth fine shaping equipment of heating exhibition | |
| CN108642893A (en) | A kind of three dimensional fabric structure composite electrothermal material | |
| CN108638247A (en) | A kind of summer sleeping bamboo mat braider | |
| CN212026918U (en) | Composite heating wall cloth and heating wall surface |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |