CN108882411A - A kind of Demountable assemble type graphene electric heating cloth and preparation method thereof - Google Patents

A kind of Demountable assemble type graphene electric heating cloth and preparation method thereof Download PDF

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Publication number
CN108882411A
CN108882411A CN201810879333.4A CN201810879333A CN108882411A CN 108882411 A CN108882411 A CN 108882411A CN 201810879333 A CN201810879333 A CN 201810879333A CN 108882411 A CN108882411 A CN 108882411A
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China
Prior art keywords
electric heating
conductive
heating cloth
layer
carbon nanotube
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CN201810879333.4A
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Chinese (zh)
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姜宇
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Beijing Inmo Science And Technology Co Ltd
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Beijing Inmo Science And Technology Co Ltd
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Priority to CN201810879333.4A priority Critical patent/CN108882411A/en
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/20Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
    • H05B3/34Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs
    • H05B3/342Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs heaters used in textiles
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/20Metallic fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton

Abstract

The invention belongs to electric heating cloth technical field, a kind of Demountable assemble type graphene electric heating cloth and production method are specifically disclosed, wherein electric heating cloth includes:Conductive layer, conductive layer includes base fabric, conductor wire and conductive electrode, base fabric is woven by fiber line, more are also evenly distributed in the longitudinal of base fabric by watersoluble plumbago alkene-conductive fiber line of carbon nanotube dye system and the conductor wire of carbon fiber textile shuffling, the both ends of base fabric are also respectively provided with a conductive electrode, and the both ends of conductive electrode are respectively provided with a power connector end mouth;Insulating protective layer, two layers of insulating protective layer set up separately in conductive layer two sides and in being coated on, and only power connector end mouth stretches out insulating protective layer in conductive layer.The present invention contaminates the excellent electric conductivity and the uniform heating wire of fever of the blended preparation of fiber line processed by using superconduction carbon fiber and graphene, and the power connector end mouth that can be mutually detachably connected with, so that conductive fabric is generated heat, uniform, the thermal efficiency is high, and can realize and be freely disassembled and assemble.

Description

A kind of Demountable assemble type graphene electric heating cloth and preparation method thereof
Technical field
The invention belongs to electric heating cloth technical field more particularly to a kind of Demountable assemble type graphene electric heating cloth and its production Method.
Background technique
The electric heating cloth of the prior art mostly uses wire, carbon fiber etc. as heating material, that there are heat generations when use is poor, The disadvantages such as heating efficiency is low;Graphene, carbon nanotube have superior thermal coefficient and lower resistivity, make currently on the market The conductive fabric for using graphene, carbon nanotube to prepare as conductive material is that conductive material is sprayed on flexibility using spraying process On fabric, but because there is wellability difference between the two, therefore leads to the electric heating cloth of such technique preparation that there are the temperature difference is larger, It generates heat non-uniform problem.
Furthermore electric heating cloth in the market all uses monoblock type heating method, i.e., electric heating cloth is designed to an entirety, cannot Realization is freely disassembled assembling, can not realize the application of the special dimensions such as outdoor or extreme humidity, is difficult that people are flexibly met more Sample daily demand.
Therefore, against the above deficiency, present invention urgent need provides a kind of Demountable assemble type graphene electric heating cloth and its production Method.
Summary of the invention
The purpose of the present invention is to provide a kind of Demountable assemble type graphene electric heating cloths, conductive in the prior art to solve That there are the temperature difference is larger for cloth, the non-uniform problem of fever.
On the one hand, the present invention provides a kind of Demountable assemble type graphene electric heating cloths, including:Conductive layer, the conduction Layer includes base fabric, conductor wire and conductive electrode, and the base fabric is woven by warp, latitude fiber line, in the longitude side of the base fabric It is also evenly distributed with the conductive fiber line and and carbon fiber made by watersoluble plumbago alkene-carbon nanotube dye of more interval braidings upwards The conductor wire of weaving shuffling, is also respectively provided with one and conductor wire conductive electrode connected vertically at the both ends of the base fabric, The both ends of the every conductive electrode are respectively provided with a power connector end mouth;Insulating protective layer, two layers of insulating protective layer point In being located at the conductive layer two sides and being coated on, only power connector end mouth stretches out the protective layer in the conductive layer.
A kind of Demountable assemble type graphene electric heating cloth further preferably further includes as described above:Warming line and temperature Device is controlled, the more warming lines are uniformly distributed interval establishment, the temperature controller and more institutes on the latitude direction of the base fabric State the connection of warming line.
A kind of Demountable assemble type graphene electric heating cloth as described above further includes further preferably macromolecule waterproof Layer, two layers of macromolecule waterproof layer are laid on the outside of two layers of insulating protective layer.
A kind of Demountable assemble type graphene electric heating cloth as described above further includes further preferably anti-aging layer, and two The layer anti-aging layer is laid on the outside of two layers of macromolecule waterproof layer.
A kind of Demountable assemble type graphene electric heating cloth as described above, further preferably, the two of the anti-aging layer End is also correspondingly arranged on nylon adherent buckle, is additionally provided with multiple fixing buckle bands along the anti-aging layer surrounding.
A kind of Demountable assemble type graphene electric heating cloth as described above, further preferably, the insulating protective layer is One or more layers in PE, PP, PVC or PET material.
On the other hand, the invention also discloses the production sides for any of the above-described kind of Demountable assemble type graphene electric heating cloth Method includes the following steps:S1:Choose cotton thread or synthetic line, carbon fiber, conduction wire and there is infectivity high temperature resistant Fiber line;S2:Watersoluble plumbago alkene-carbon nanotube conducting slurry is configured, by dyeing and printing process by watersoluble plumbago alkene-carbon nanotube Electrocondution slurry, which is attached on fiber line, is made conductive fiber line, then by conductive fiber line with carbon fiber is blended obtains conductor wire;S3: Conductor wire, cotton thread or synthetic line and wire are weaved by predetermined dimension and power connector end mouth is installed, conductive layer is made; S4:In the two sides paving insulating protective layer of conductive layer, so that only power connector end mouth stretches out insulating protective layer in conductive layer.
Further, a kind of Demountable assemble type graphene electric heating cloth production method as described above, further preferably, Watersoluble plumbago alkene-carbon nanotube conducting the slurry includes single-component water-based resin, graphene slurry, carbon nanotube, water.
Further, a kind of Demountable assemble type graphene electric heating cloth production method as described above, further preferably, Watersoluble plumbago alkene-carbon nanotube conducting the slurry further includes aqueous defoamer, aqueous dispersion and conductive black.
Further, a kind of Demountable assemble type graphene electric heating cloth production method as described above, further preferably, In the watersoluble plumbago alkene-carbon nanotube conducting slurry, 100 parts of the single-component water-based resin, the aqueous defoamer 0.5 Part, described dispersing agent 1-2 parts, 30-120 parts of the graphene slurry of 8% concentration, the carbon nanotube 20-75 of 5% concentration Part, described conductive black 10-30 parts.
The present invention has the following advantages that compared with prior art:
The invention discloses a kind of Demountable assemble type graphene electric heating cloths, including:Conductive layer, the conductive layer include base Cloth, conductor wire and conductive electrode, the base fabric from resistant to high temperature through being woven to, weft fiber line, in the warp of the base fabric The conductive fiber line made by watersoluble plumbago alkene-carbon nanotube dye and carbon fiber of more interval braidings are also evenly distributed on degree direction The conductor wire of dimension weaving shuffling is also respectively provided with one and the conductor wire conductive electricity connected vertically at the both ends of the base fabric Pole, the both ends of the every conductive electrode are respectively provided with a power connector end mouth;Insulating protective layer, two layers of insulating protective layer Set up separately in the conductive layer two sides and in being coated on, only power connector end mouth stretches out the protective layer in the conductive layer. The present invention is by using superconduction carbon fiber and the excellent electric conductivity of the blended preparation of graphene and the uniform heating wire of fever, Yi Jike The power connector end mouth being mutually detachably connected with, so that conductive fabric is generated heat, uniform, the thermal efficiency is high, and realizes in use freely Disassembly and assembling.
Detailed description of the invention
Fig. 1 is a kind of schematic view of the front view of Demountable assemble type graphene electric heating cloth of the present invention;
Fig. 2 is the sectional view of Fig. 1;
Fig. 3 is the measuring device figure of heater electric-thermal emission conversion efficiency in the measurement of electric radiation transfer efficiency;
Fig. 4 is the temperature measuring point schematic diagram of plate, rectangular heater in the measurement of non-uniform temperature degree.
Description of symbols:
1- base fabric, 2- conductor wire, 3- conductive electrode, 4- power connector end mouth, 5- nylon adherent buckle, 6- fixing buckle band, 7- are exhausted Edge protective layer, 8- macromolecule waterproof layer, 9- anti-aging layer.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with attached drawing, it is clear that described implementation Example is a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill Personnel's every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that term " center ", "upper", "lower", "left", "right", "vertical", The orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" be based on the orientation or positional relationship shown in the drawings, merely to Convenient for description the present invention and simplify description, rather than the device or element of indication or suggestion meaning must have a particular orientation, It is constructed and operated in a specific orientation, therefore is not considered as limiting the invention.In addition, term " first ", " second ", " third " is used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance.
As shown in Figure 1, 2, present embodiment discloses a kind of Demountable assemble type graphene electric heating cloths, including:Conductive layer and Insulating protective layer 7, wherein conductive layer includes base fabric 1, conductor wire 2 and conductive electrode 3, and base fabric 1 is from resistant to high temperature through fine to, broadwise Dimension line weaves, and the conductor wire 2 of more interval braidings is also evenly distributed in the longitudinal of base fabric 1, conductor wire 2 is by water Property graphene-carbon nano tube dye system conductive fiber line and carbon fiber textile shuffling form, be also respectively provided with one at the both ends of base fabric 1 Root and the conductive electrode 3 connected vertically of conductor wire 2, the both ends of every conductive electrode 3 are respectively provided with a power connector end mouth 4;Absolutely Edge protective layer 7 has two layers, in two layers of insulating protective layer 7 sets up separately in conductive layer two sides and be coated on conductive layer, so that conductive layer In only power connector end mouth 4 stretch out protective layer.In the present embodiment, conductor wire 2 is contaminated by carbon fiber and watersoluble plumbago alkene-carbon nanotube The conductive fiber line weaving shuffling of system forms, and keeps its electric conductivity excellent and generates heat uniformly, so that uniformly being divided by conductor wire 2 The base fabric 1 of cloth interval establishment also has good conductive property and generates heat uniformly;Conductive electrode 3 and base positioned at 1 both ends of base fabric More conductor wires 2 are all connected in cloth 1, and the both ends of conductive electrode 3 are respectively provided with a power connector end mouth 4, on the one hand can be straight It connects and is connect with external power supply, on the other hand can also be detachably connected with the power connector end mouth 4 of other base fabrics 1, i.e., by only Special power interface design, electric heating cloth may be implemented is freely disassembled assembling, meets the daily demand of different scenes.
Preferably, in the present embodiment, high-temperature fibre line also have can textile property, be high temperature resistant type cotton fiber, fiber crops Fiber, leaf fibre, animal origin can contaminate any one in synthetic fibers processed etc..Preferably, conductor wire 2 by carbon fiber and by Watersoluble plumbago alkene-carbon nanotube dye system conductive fiber line weaving shuffling is constituted;Wherein carbon nano paint mainly by water-base resin, Graphene, carbon nanotube, electrically conductive graphite, aqueous dispersion auxiliary agent and water dyeing auxiliary agent etc. are constituted;Fiber line after dye system is dry After dry and carbon fiber carries out blended establishment, constitutes conductor wire 2.
As shown in Figure 1, 2, in a kind of Demountable assemble type graphene electric heating cloth disclosed in the present embodiment, further include: Warming line and temperature controller, more warming lines are uniformly distributed interval establishment, temperature controller and more warmings on the latitude direction of base fabric 1 Line connection.The setting of warming line and temperature controller mainly for detection of temperature in electric heating cloth height, and then pass through thermostat control The on-off of power supply in electric heating cloth, to realize temperature control.
It as shown in Figure 1, 2, further include height in a kind of Demountable assemble type graphene electric heating cloth disclosed in the present embodiment Molecule waterproof layer 8, two layers of macromolecule waterproof layer 8 are laid on the outside of two layers of insulating protective layer 7;It further, further include anti-old Change layer 9, two layers of anti-aging layer 9 is laid on the outside of two layers of macromolecule waterproof layer 8.Further, the both ends of anti-aging layer 9 are also right It should be provided with nylon adherent buckle 5, be additionally provided with multiple fixing buckle bands 6 along 9 surrounding of anti-aging layer.The setting master of macromolecule waterproof layer 8 It is used to expand the usage scenario of electric heating cloth in the present embodiment, makes it that can also work in the rainy day or under water;Anti-aging layer 9 The erosion that external environment is then mainly used for isolating to the conductive layer of electric heating cloth is set, and then extends the service life of electric heating cloth.Buddhist nun Imperial thread gluing 5 and the setting of multiple fixing buckle bands 6 then facilitate the fixation of electric heating cloth.
As shown in Figure 1, in a kind of Demountable assemble type graphene electric heating cloth disclosed in the present embodiment, insulating protective layer 7 be one or more layers in PE, PP, PVC or PET material, insulating protective layer 7 with a thickness of 0.05-0.3cm.
As shown in Figure 1, in a kind of Demountable assemble type graphene electric heating cloth disclosed in the present embodiment, phase in base fabric 1 Be divided into 5-15cm between adjacent two conductor wires 2, between adjacent two warmings line between be divided into 15-25cm.Conductive electrode 3 is a branch of Wire, wire are copper wire and/or filamentary silver.
As shown in Figure 1, in a kind of Demountable assemble type graphene electric heating cloth disclosed in the present embodiment, power connector end Mouth 4 is waterproof partition-type leakproof electrically connected port, can be used in moist or underwater environment, the design of port plug-in type, side Just the assembling and disassembly of electric heating cloth.
Preferably, AC power source or DC power supply can be selected in the present embodiment.
Further, the present invention also provides a kind of production methods of Demountable assemble type graphene electric heating cloth comprising Following steps:S1:Choose cotton thread or synthetic line, carbon fiber, the wire of conduction and with infectivity high-temperature fibre Line;S2:Watersoluble plumbago alkene-carbon nanotube conducting slurry is configured, is starched watersoluble plumbago alkene-carbon nanotube conducting by dyeing and printing process Material is attached on fiber line, then by the conductive fiber line printed and dyed with carbon fiber is blended obtains conductor wire;S3:By conductor wire, cotton Line or synthetic line and wire weave by predetermined dimension and install power connector end mouth, and conductive layer is made;S4:In conductive layer Two sides paving insulating protective layer so that in conductive layer only power connector end mouth stretch out insulating protective layer.
In step S1, cotton thread or synthetic line are the main materials of textile substrate, can only choose one kind in actual use, And it is preferential choose the cotton thread or synthetic line with certain high temperature resistance, to avoid base fabric in use because by Damage;Carbon fiber and with infectivity high-temperature fibre line then mainly for the preparation of conductor wire;Conductive wire is then used to make Standby conductive electrode.
In step S2, watersoluble plumbago alkene-carbon nanotube conducting slurry includes single-component water-based resin, graphene slurry, carbon Nanotube and water, further, further including further includes aqueous defoamer, aqueous dispersion and conductive black;And wherein one-component 100 parts of water-base resin, 0.5 part of aqueous defoamer, 1-2 parts of dispersing agent, 30-120 parts of the graphene slurry of 8% concentration, 5% concentration 20-75 parts of carbon nanotube, 10-30 parts of conductive black.
Further, it chooses infectivity good, good conductivity and the fiber line of long-term heatproof 60-80 degree prepares conductor wire.
It, can be according to setting in advance when carrying out the selection and the configuration of watersoluble plumbago alkene-carbon nanotube conducting slurry of material Specification, average heat generation temperature and the power density of fixed conductive fabric are adjusted.
In watersoluble plumbago alkene-carbon nanotube conducting slurry principal ingredients, single-component water-based resin conduct is mainly used The base-material of slurry, admixed graphite alkene slurry, carbon nanotube component form mixed slurry coating, for disseminating cotton thread for conduction The preparation of line.
In watersoluble plumbago alkene-carbon nanotube conducting slurry, aqueous defoamer is by dimethicone, white carbon black, emulsifier etc. It prepares, using the defoaming agent for the water emulsion dispersibility that emulsifying technology is made to.All raw materials and link are nontoxic, have dispersion speed Degree is fast, and defoaming is fast, and the foam inhibition time is long, stablizes not stratified feature.The effect of aqueous dispersion is to reduce wetting dispersing agent to divide Time required for during dissipating and energy, stablize dispersed pigment dispersion, and modified pigment particle surface properties adjust face The motility for expecting particle, mainly there is fatty acid, aliphatic amide type and lipid.Conductive black has low resistance or higher resistive The carbon black of energy can assign product conduction or anti-static electrification.
Specifically, the invention also discloses the embodiments of several electric heating cloths preparation, and in embodiments, used single group Part water-base resin mainly includes aqueous one-component polyurethane resin, aqueous one-component epoxy ester resin, aqueous one-component acrylic acid Resin and aqueous one-component alkyd resin, it is main purchased from big magnificent Thailand AH-1502E13, AH-1702 product of peace, certainly as closed alliance Work XWS-100;Yantai Wanhua 4221,4220;Three liters of trade AC-32403, DSM XK-102, bodyguard Quanxing PA-1015, Zhu Haiji Sharp JL-11;It also meets the needs of embodiment with similar products such as TH-8386, general section SK-1076;Graphene using Sharp object contains LN-2P, LN-4NA;Black alkene science and technology G-Paste, G-powder;Letter receives scientific and technological SCpas1005, SCpas2001c;6th One or more of element S E1231, SE3521.Carbon nanotube mainly uses the rich science and technology CNTS-006-2 of carbon;Great Zhan nanometers GC40;First Elements C NTs;One or more of middle section's epoch TNEPO-TNM2.
Embodiment 1:
The preparation method of the present embodiment includes the following steps:
1) choose infectivity good, long-term 80 degree of heatproof of fiber line, choose the carbon fiber line to conduct electricity very well, model 1K and Resistivity is lower than 1*10-3Ω·cm;
2) 100 parts of single-component water-based resin, 0.5 part of aqueous defoamer, 1.3 parts of aqueous dispersion, 8% concentration graphene slurry 100 parts of material, 5% 50 parts of concentration carbon nanotube, 10 parts of conductive black, deionized water is several, and 2 parts of other function auxiliary agent, according to spy Determine technique dispersion, prepares watersoluble plumbago alkene-carbon nanotube conducting slurry, electrocondution slurry is attached to by fiber line by dyeing and printing process Upper obtained conductive fiber line;
3) the conductive fiber line and carbon fiber that will be printed and dyed, it is blended by the progress of special textile technology, conduction is prepared Line;
4) conductor wire, high temperature resistant type cotton thread or synthetic line, warming line, copper wire are woven into electric heating cloth according to specification, Wherein between conductor wire between be divided into 10cm, between warming line between be divided into 20cm;
5) to electric heating cloth carry out insulation protection processing, select pvc base material film, 80 DEG C, thickness 0.1cm of ageing-resistant temperature, and Water-proof type power port is installed at port can be prepared into Demountable assemble type electric heating cloth.
Prepared electric heating cloth partial parameters are as follows:
Embodiment 2:
The preparation method of the present embodiment includes the following steps:
1) infectivity good, the fiber line of 60 degree of long-term heatproof is chosen;Choose the carbon fiber line model 1.5k of good conductivity, electricity Resistance rate is lower than 1.2*10-3Ω·cm;
2) 100 parts of single-component water-based resin, 0.5 part of aqueous defoamer, 1.5 parts of aqueous dispersion, 8% concentration graphene slurry 80 parts of material, 5% 40 parts of concentration carbon nanotube, 20 parts of conductive black, deionized water is several, and 1.5 parts of other function auxiliary agent, according to spy Determine technique dispersion, prepares watersoluble plumbago alkene-carbon nanotube conducting slurry, electrocondution slurry is attached to by fiber line by dyeing and printing process On;
3) the conductive fiber line and carbon fiber that will be printed and dyed, it is blended by the progress of special textile technology, conduction is prepared Line;
4) conductor wire, high temperature resistant cotton thread or synthetic line, warming line, copper wire are woven into electric heating cloth according to specification, Be divided into 10cm between middle conductor wire, between warming line between be divided into 20cm;
5) to electric heating cloth carry out insulation protection processing, select pet base material film, 80 DEG C, thickness 0.08cm of ageing-resistant temperature, and Water-proof type power port is installed at port can be prepared into Demountable assemble type electric heating cloth.
Prepared electric heating cloth partial parameters are as follows:
Case study on implementation 3:
The preparation method of the present embodiment includes the following steps:
1) infectivity good, the fiber line of 60 degree of long-term heatproof is chosen;Choose the carbon fiber line model 2k of good conductivity, resistance Rate is lower than 0.8*10-3Ω·cm;
2) 100 parts of single-component water-based resin, 0.5 part of aqueous defoamer, 2 parts of aqueous dispersion, 8% concentration graphene slurry 120 parts, 5% 75 parts of concentration carbon nanotube, 10 parts of conductive black, deionized water is several, and 1.5 parts of other function auxiliary agent, according to spy Determine technique dispersion, prepares watersoluble plumbago alkene-carbon nanotube conducting slurry, electrocondution slurry is attached to by fiber line by dyeing and printing process On;
3) the conductive fiber line and carbon fiber that will be printed and dyed, it is blended by the progress of special textile technology, conduction is prepared Line;
4) conductor wire, high temperature resistant cotton thread or synthetic line, warming line, copper wire are woven into electric heating cloth according to specification, Be divided into 5cm between middle conductor wire, between warming line between be divided into 20cm;
5) to electric heating cloth carry out insulation protection processing, select pet base material film, ageing-resistant temperature 60 C, thickness 0.05cm, and Water-proof type power port is installed at port can be prepared into Demountable assemble type electric heating cloth.
Prepared electric heating cloth partial parameters are as follows:
Case study on implementation 4:
The preparation method of the present embodiment includes the following steps:
1) infectivity good, the fiber line of 80 degree of long-term heatproof is chosen;Choose the carbon fiber line model 2k of good conductivity, resistance Rate is lower than 5*10-3Ω·cm;
2) 100 parts of single-component water-based resin, 0.5 part of aqueous defoamer, 1 part of aqueous dispersion, 8% concentration graphene slurry 30 parts, 5% 20 parts of concentration carbon nanotube, 30 parts of conductive black, deionized water is several, and 1.5 parts of other function auxiliary agent, according to specific Technique dispersion, prepares watersoluble plumbago alkene-carbon nanotube conducting slurry, electrocondution slurry is attached on fiber line by dyeing and printing process;
3) the conductive fiber line and carbon fiber that will be printed and dyed, it is blended by the progress of special textile technology, conduction is prepared Line;
4) conductor wire, high temperature resistant type cotton thread or synthetic line, warming line, copper wire are woven into electric heating cloth according to specification, Wherein between conductor wire between be divided into 10cm, between warming line between be divided into 15cm;
5) to electric heating cloth carry out insulation protection processing, and at port install water-proof type power port i.e. can be prepared into it is removable Unload assembly type electric heating cloth.
Prepared electric heating cloth partial parameters are as follows:
Comparative example 1:
Heater wire used in sample belongs to carbon fiber heating line, is to coat a layer insulating on the surface layer of carbon fiber, leads to By carbon fiber heating when electric, other structures are same as the present application.For the heater wire in comparative example 1, the few carbon fiber of beam number Heating efficiency is low, and comfort is poor after carbon fiber more than beam number cladding, and electric blanket be usually be coated with by individual carbon fibers line and At using effect can be seriously affected when encountering breakage.
Comparative example 2:
Heater wire used in sample belongs to PVC line with heating function, is the winding electric resistance alloy silk conduct on glass fibre core wire Heater, and in the electric heating wire of the soft insulation PVC material of its external sheath, is generated heat by heater strip when energization, other structures and The application is identical.Due to the PVC material on surface, the permanent heatproof of comparative example 2, heating efficiency are low, ageing-resistant performance is poor.
Comparative example 3:
Heater wire used in sample belongs to silicone rubber heating line, is the winding electric resistance alloy silk conduct on glass fibre core wire Heater, and in the electric heating wire of the soft insulation silica gel material of its external sheath, is generated heat by heater strip when energization, other structures and The application is identical.The line with heating function of opposite PVC material, the temperature tolerance and resistance to ag(e)ing of comparative example 3 are preferable, but comfortable in use process Property it is poor, can not achieve with base fabric material entirety splice, can only be fixed in base fabric in a manner of plug-in sewing.
Effete test embodiment:
To further illustrate a kind of performance of Demountable assemble type graphene electric heating cloth disclosed in this invention, the examination of this effect It tests example and chooses 50cm*80cm specification electric heating cloth sample in embodiment 1,50cm*80cm specification electric heating cloth specimen in embodiment 2 respectively 50cm*50cm specification electric heating cloth sample in product, embodiment 3,50cm*80cm specification electric heating cloth sample and comparative example 1 in embodiment 4 50cm*80cm specification electric heating cloth sample in middle 50cm*80cm specification electric heating cloth sample, comparative example 2,50cm*50cm in comparative example 3 Specification electric heating cloth sample is tested:
1) voltage rating measures:
According to GB/T 5095.2-1997 electronic equipment electromechanical compo fundamental test regulation and measurement method, by sample Each exit successively be connected between shell or remaining exit of mounting plate bear detail specification defined test voltage; In addition direct current or ac test voltage are subjected to 60s ± 5s, add the rate of test voltage that should be not more than 500V/s.
2) far infrared transmissivity parametric measurement:
Show that emissivity measures the remote red of above-mentioned sample respectively using emissivity test equipment according to ASTM C1371 program Outer emissivity parameter.
3) Far-infrared spoke is according to temperature rise (DEG C) measurement:
According to GB/T 30127-2013《The detection and evaluation of textile far infrared performance》, take sample at 20 DEG C of temperature, phase In the thermostatic chamber for being 60% to humidity, using infrared lamp as light source, same specification is irradiated respectively under certain distance with 45° angle, same group The fabric of the general fibre and far IR fibre knitted records the temperature of two kinds of fabrics under different time intervals with infrared tester T0And T1, then seek difference.
4) electric radiation transfer efficiency measures:
According to GB/T7828-2008, the 17th chapter heater electric-thermal radiates the measurement method of transformation efficiency, the survey needed Measuring device includes:Regulated power supply, voltage fluctuation are not more than ± 1%;Power meter, precision are not less than 0.5 grade;Pyroelectricity radiates function Rate meter, uncertainty are not less than 2%.Shown in measuring device Fig. 3 of heater electric-thermal emission conversion efficiency:
Specific measurement method is as follows:
The geometric dimension for measuring heater swept area uniformly chooses n (n is not less than 9) a face on tested radiating surface Member, and using the center of face element as the tested point of heater;Make surveyed radiating surface that can make point source approximation relative to detector, radiates function The tested surface three of the photosurface of rate meter detector, light bar plane and heater wants parallel and coaxial, adjustment limit beam light bar, make by Survey the visual field that surface radiation face is full of detector;Power on, after it reaches the heating-up time, the record electric power value P that measuresc, It successively measures and records a measured value P for measurement point radiant poweri, finally it is calculated from the formula electric radiation transfer efficiency.
5) Leakage Current mA is measured:
According to GB/T7828-2008, the 12nd chapter regulation, measuring instrument【Voltmeter of the precision not less than 0.5 grade, precision are not Milliammeter and insulation pressure test platform lower than 0.5 grade etc.】, test in the case where heater is powered and reaches stable state into Row, heater is powered in normal operation, adjusts supply voltage, makes input power equal to 1.15 times of rated power. It is tested when heater operating temperature reaches stable state.It should be by the conversion of selection switch, respectively in heater when measurement Two eduction rods or two Leakage Current is measured between electrode and heater housing, measurement result takes the larger value.
6) non-uniform temperature degree DEG C measures:
According to GB/T7828-2008, the 8th chapter regulation selects measuring instrument【Radiation Temperature Measurement Instrument or other temperature measurers and match Covering device, accuracy meet 5.7 regulation in GB/T10066.1-2004, and thermometric range should be with the work temperature of tested heater Range is spent to be adapted】, measurement method【Plate, rectangular heater temperature measuring point should meet shown in Fig. 4】
According to the normal direction total emissivity value ε of heater radiating surfacen, adjust temperature measurer and carry out normal direction total emissivity εnAmendment.So Sample is placed on sample frame afterwards and temperature measuring distance is determined according to Radiation Temperature Measurement Instrument visual field, makes each temperature measuring point shown in upper figure Diameter is equal, and is full of temperature measurer visual field.Electrified regulation is carried out to sample, after so that sample heating is reached steady-working state, is used Radiation Temperature Measurement Instrument or other temperature measurers successively measure the temperature value of each temperature measuring point, and record each point temperature value, according to test result Calculate temperature distribution is non-uniform degree.
7) heating-up time min is measured:
According to GB/T7828-2008, the 10th chapter regulation, measuring instrument【Radiation Temperature Measurement Instrument or other temperature measurers and mating Device, accuracy meet 5.7 regulation in GB/T10066.1-2004, and thermometric range should be with the operating temperature of tested heater Range is adapted;Time recording device (such as function recording instrument, stopwatch)】;Measurement method【According in heater radiating surface geometry Normal direction total emissivity value ε at the heartn, adjust Radiation Temperature Measurement Instrument and carry out normal direction total emissivity εnAmendment.Tested sample is placed in sample On frame, temperature measuring distance is determined, sample radiating surface geometric center is made to be full of the visual field of Radiation Temperature Measurement Instrument;Apply nominal operation to sample Voltage measures temperature with Radiation Temperature Measurement Instrument, and record from room temperature and rise to temperature stable state while sample electrified regulation Heating curve, according to recording curve, when temperature being taken to rise to the 90% of temperature stable state from room temperature, the required time is as liter The warm time】
8) power deviation measures:
According to GB/T7828-2008, Chapter 11 regulation, test equipment【0.5 grade of electric power meter, 0.2 grade of voltmeter】, Apply rated operational voltage to sample, heat up, after reaching stable state, the numerical value shown on electric power meter is to survey Power must monitor the rated operational voltage that sample is applied with voltmeter, as the following formula according to power deviation rate in temperature-rise period It calculates:
J={ (P-Ph)/Ph* 100%
J power deviation rate, dimensionless
P surveys electrical power, and unit is watt (W)
PhElectric rating, unit are watt (W)
Table 1
Graphene-carbon nanometer and carbon fiber can be integrated using electric heating cloth of the invention it can be seen from above-mentioned case study on implementation The advantages of dimension, under the premise of improving electric conductivity, by blended weave realize electric heating cloth generate heat uniformity the problem of, Er Qieyou There is controllability in graphene-carbon nanotube dyeing and weaving line, therefore electric heating cloth can be made in low-voltage DC and the item of alternating current It works under part, heating rate is fast, and comfortable safety, furthermore electric heating cloth described in invention has Demountable assemble type, can satisfy Application under different condition, especially under outdoor environment.
Finally it should be noted that:The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent Present invention has been described in detail with reference to the aforementioned embodiments for pipe, those skilled in the art should understand that:Its according to So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into Row equivalent replacement;And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution The range of scheme.

Claims (10)

1. a kind of Demountable assemble type graphene electric heating cloth, which is characterized in that including:
Conductive layer, the conductive layer include base fabric, conductor wire and conductive electrode, and the base fabric is woven by warp, latitude fiber line, Being led by watersoluble plumbago alkene-carbon nanotube dye system for more interval braidings is also evenly distributed in the longitudinal of the base fabric The conductor wire of electric fiber line and carbon fiber textile shuffling is also respectively provided with one and the more conductor wires at the both ends of the base fabric Conductive electrode connected vertically, the both ends of the every conductive electrode are respectively provided with a power connector end mouth;
Insulating protective layer, two layers of insulating protective layer set up separately in the conductive layer two sides and are coated on interior, the conduction Only power connector end mouth stretches out the insulating protective layer in layer.
2. a kind of Demountable assemble type graphene electric heating cloth according to claim 1, which is characterized in that further include:
Warming line and temperature controller, more warming lines uniform intervals on the latitude direction of the base fabric are worked out, the temperature control Device is connect with the more warming lines.
3. a kind of Demountable assemble type graphene electric heating cloth according to claim 2, which is characterized in that further include macromolecule Waterproof layer, two layers of macromolecule waterproof layer are laid on the outside of two layers of insulating protective layer.
4. a kind of Demountable assemble type graphene electric heating cloth according to claim 3, which is characterized in that further include anti-aging Layer, two layers of anti-aging layer are laid on the outside of two layers of macromolecule waterproof layer.
5. a kind of Demountable assemble type graphene electric heating cloth according to claim 4, which is characterized in that the anti-aging layer Both ends be provided with nylon adherent buckle, be additionally provided with multiple fixing buckle bands along the anti-aging layer surrounding.
6. a kind of Demountable assemble type graphene electric heating cloth according to claim 1, which is characterized in that the insulation protection Layer is one or more layers in PE, PP, PVC or PET material.
7. a kind of production method for Demountable assemble type graphene electric heating cloth described in any one of claim 1-6, special Sign is, includes the following steps:
S1:Choose cotton thread or synthetic line, carbon fiber, conduction wire and there is infectivity fiber line resistant to high temperature;
S2:Watersoluble plumbago alkene-carbon nanotube conducting slurry is configured, by dyeing and printing process by watersoluble plumbago alkene-carbon nanotube conducting Slurry, which is attached on fiber line, is made conductive fiber line, then by conductive fiber line and the blended obtained conductor wire of carbon fiber;
S3:Conductor wire, cotton thread or synthetic line and wire are weaved by predetermined dimension and power connector end mouth is installed, is made Conductive layer;
S4:In the two sides paving insulating protective layer of conductive layer, and make only power connector end mouth stretching insulation protection in conductive layer Layer.
8. a kind of Demountable assemble type graphene electric heating cloth production method according to claim 7, which is characterized in that described Watersoluble plumbago alkene-carbon nanotube conducting slurry includes single-component water-based resin, graphene slurry, carbon nanotube, water.
9. a kind of Demountable assemble type graphene electric heating cloth production method according to claim 8, which is characterized in that described Watersoluble plumbago alkene-carbon nanotube conducting slurry further includes aqueous defoamer, aqueous dispersion and conductive black.
10. a kind of Demountable assemble type graphene electric heating cloth production method according to claim 9, which is characterized in that institute It states in watersoluble plumbago alkene-carbon nanotube conducting slurry, 100 parts of the single-component water-based resin, 0.5 part of the aqueous defoamer, Described dispersing agent 1-2 parts, 30-120 parts of the graphene slurry of 8% concentration, described carbon nanotube 20-75 parts of 5% concentration, Described conductive black 10-30 parts.
CN201810879333.4A 2018-08-03 2018-08-03 A kind of Demountable assemble type graphene electric heating cloth and preparation method thereof Pending CN108882411A (en)

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