CN105960035B - A kind of production method and its Electric radiant Heating Film of Self-controlling temperature electrothermal film - Google Patents

A kind of production method and its Electric radiant Heating Film of Self-controlling temperature electrothermal film Download PDF

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Publication number
CN105960035B
CN105960035B CN201610329138.5A CN201610329138A CN105960035B CN 105960035 B CN105960035 B CN 105960035B CN 201610329138 A CN201610329138 A CN 201610329138A CN 105960035 B CN105960035 B CN 105960035B
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carbon fiber
self
electrothermal film
fiber paper
controlling temperature
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CN105960035A (en
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陈亮
龚向民
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Rongjie Health Technology Co., Ltd.
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Rongjie Health Technology Co Ltd
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/20Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
    • H05B3/34Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs
    • H05B3/36Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs heating conductor embedded in insulating material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/145Carbon only, e.g. carbon black, graphite
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/18Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor the conductor being embedded in an insulating material

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  • Resistance Heating (AREA)
  • Paper (AREA)
  • Surface Heating Bodies (AREA)

Abstract

The present invention relates to Electric radiant Heating Film product scopes, more particularly to the production method and its Electric radiant Heating Film of a kind of Self-controlling temperature electrothermal film, the present invention includes: that carbon fiber is chopped silk, graphite, the mass percent between carbon fiber filler are as follows: the material of 1:7:2 is successively by being stirred, hot pressing, low temperature drying, solidification, drying, carbonization increase electrode, after pressing, Self-controlling temperature electrothermal film is obtained.Since the present invention is added to carbon fiber filler in the production process of Electric radiant Heating Film, so that Electric radiant Heating Film of the invention has the characteristic of temp auto-controlled, is not in the generation of combustion case caused by being overheated because of local temperature, ensures the safety in utilization of product.

Description

A kind of production method and its Electric radiant Heating Film of Self-controlling temperature electrothermal film
Technical field
The present invention relates to Electric radiant Heating Film product scopes, and in particular to a kind of production method and its electric heating of Self-controlling temperature electrothermal film Film.
Background technique
Far-infrared physiotherapy room is a kind of physiotherapy products that far infrared radiation effect is generated using far infrared radiator, remote at present Infrared radiator is mainly the far-infrared radiation material for using Electric radiant Heating Film, electrothermal tube one kind.Electric radiant Heating Film is since heating area is big, people For body-sensing by comfortable, market use is more extensive, but traditional far-infrared electrothermal film use metal electric heating silk or carbon fiber as Heater carries out temperature control by the way of external temperature controller, and since heating film is planar heat producing body, there are detections to click It selects difficulty and is easy to appear combustion case caused by local temperature overheats and occur.
Summary of the invention
To overcome drawbacks described above, the purpose of the present invention is to provide a kind of production method and one of Self-controlling temperature electrothermal film Kind Self-controlling temperature electrothermal film.
The purpose of the present invention is achieved through the following technical solutions:
The present invention is a kind of production method of Self-controlling temperature electrothermal film, comprising:
Be chopped silk, graphite, carbon fiber filler of carbon fiber is stirred mixing, becomes liquid slurry;The carbon The concentration of fiber filling agent is 18~22mol/L, in the liquid slurry, carbon fiber be chopped silk, graphite, carbon fiber filler it Between mass percent are as follows: 1:7:2;
After the liquid slurry is coated on substrate surface, it is sent into hot press and carries out hot pressing, obtain carbon fiber paper;The hot pressing Temperature are as follows: 140 DEG C~300 DEG C, the pressure of hot pressing are as follows: 0.1MPa~0.4MPa, when a length of 1.5min~4min of hot pressing;
The carbon fiber paper is impregnated in the polyvinyl alcohol water solution that concentration is 10%, takes out carbon fiber paper after impregnating and carry out Low temperature drying;
After low temperature drying, carbon fiber paper feeding low-temperature heat furnace is heated, carbon fiber paper is made to complete resin solidification;It is described The temperature of heating is 200 DEG C, the when a length of 2h or more of heating;
After through heating, carbon fiber paper is impregnated in maceration extract, the maceration extract is by crystalline flake graphite, phenolic resin, first Alcoholic solution is formed by the mass ratio of 1:4:16, is taken out carbon fiber paper after impregnating and is dried;
After completing drying, carbon fiber paper is sent into inflated with nitrogen vacuum drying oven and is carbonized, the carbon fiber paper after being carbonized, institute The temperature for stating carbonization is 2000 DEG C or more;
Increase metal foil on carbon fiber paper in the carbonized, and connects connecting terminal in metal foil;
After connecting connecting terminal, upper functional layer is pressed on the surface of carbon fiber paper, obtains Self-controlling temperature electrothermal film.
Further, the carbon fiber is chopped filament length degree between 5mm~14mm.
Further, the carbon fiber filler is polyoxyethylene comprising: octadecane acetic acid.
Further, the partial size of the graphite is 1~6 μm.
Further, the temperature of the drying is 90 DEG C, the when a length of 3min of drying.
Further, the when a length of 30min being stirred, the temperature being stirred are 10 DEG C~30 DEG C.
Further, the temperature 70 C of the low temperature drying is hereinafter, a length of 35min when dry.
Further, the carbon fiber filler hydrophilic-hydrophobic balance value is between 10~20.
The obtained Self-controlling temperature electrothermal film of a kind of production method with Self-controlling temperature electrothermal film of the invention, comprising: carbon fiber paper, institute It states and is equipped with metal foil on carbon fiber paper, be connected to connecting terminal on the metal foil, in the upper and lower surface of the carbon fiber paper Equipped with insulating layer, and the outer surface of an insulating layer is equipped with reflecting layer, and the outer surface in the reflecting layer is equipped with wearing layer.
Further, the insulating layer is polyvinyl chloride layer, and the reflecting layer is aluminium film reflecting layer.
The present invention is added to carbon fiber filler in the production process of Electric radiant Heating Film, so that Electric radiant Heating Film of the invention has The characteristic of temp auto-controlled is not in the generation of combustion case caused by overheating because of local temperature, ensures the safety in utilization of product.
Detailed description of the invention
The present invention is described in detail by following preferred embodiments and attached drawing for ease of explanation,.
Fig. 1 is the production procedure schematic diagram of production method of the invention;
Fig. 2 is Self-controlling temperature electrothermal film decomposition texture schematic diagram of the invention.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further described.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and do not have to It is of the invention in limiting.
Referring to Fig. 1, the present invention is the production method of Self-controlling temperature electrothermal film, comprising:
101. being stirred
Be chopped silk, graphite, carbon fiber filler of carbon fiber is stirred mixing, becomes liquid slurry;The carbon The concentration of fiber filling agent is 18~22mol/L, in the liquid slurry, carbon fiber be chopped silk, graphite, carbon fiber filler it Between mass percent are as follows: 1:7:2;
102. hot pressing
After the liquid slurry is coated on substrate surface, it is sent into hot press and carries out hot pressing, obtain carbon fiber paper;The hot pressing Temperature are as follows: 140 DEG C~300 DEG C, the pressure of hot pressing are as follows: 0.1MPa~0.4MPa, when a length of 1.5min~4min of hot pressing;
103. low temperature drying
The carbon fiber paper is impregnated in the polyvinyl alcohol water solution that concentration is 10%, takes out carbon fiber paper after impregnating and carry out Low temperature drying;
104. solidification
After low temperature drying, carbon fiber paper feeding low-temperature heat furnace is heated, carbon fiber paper is made to complete resin solidification;It is described The temperature of heating is 200 DEG C, the when a length of 2h or more of heating;
105. drying
After through heating, carbon fiber paper is impregnated in maceration extract, the maceration extract is by crystalline flake graphite, phenolic resin, first Alcoholic solution is formed by the mass ratio of 1:4:16, is taken out carbon fiber paper after impregnating and is dried;
106. carbonization
After completing drying, carbon fiber paper is sent into inflated with nitrogen vacuum drying oven and is carbonized, the carbon fiber paper after being carbonized, institute The temperature for stating carbonization is 2000 DEG C or more;
107. increasing electrode
Increase metal foil on carbon fiber paper in the carbonized, which will be used as carbon fiber paper top electrode, and in metal Connecting terminal is connected in paillon;
108. pressing
After connecting connecting terminal, upper functional layer is pressed on the surface of carbon fiber paper, obtains Self-controlling temperature electrothermal film.It is specially By heat pressing process by the first insulating layer, carbon fiber paper, second insulating layer, aluminium film reflecting layer, wearing layer it is hot-forming complete from Control-temperature electric heating film.
Further, the carbon fiber is chopped filament length degree between 5mm~14mm.
Further, the carbon fiber filler is polyoxyethylene comprising: hydrophobic part alkane carbon atom is 8~10 Above octadecane acetic acid (C18H37O-(CH2CH2O)8- H).
Further, the partial size of the graphite is 1~6 μm.
Further, the temperature of the drying is 90 DEG C, the when a length of 3min of drying.
Further, the when a length of 30min being stirred, the temperature being stirred are 10 DEG C~30 DEG C.
Further, the temperature 70 C of the low temperature drying is hereinafter, a length of 35min when dry.
Further, the carbon fiber filler hydrophilic-hydrophobic balance value is between 10~20.
Referring to Fig. 2, a kind of obtained Self-controlling temperature electrothermal film of production method with Self-controlling temperature electrothermal film of the invention, packet Include: carbon fiber paper 4 is equipped with metal foil 2 on the carbon fiber paper 4, connecting terminal 3, the wiring is connected on the metal foil 2 Terminal 3 is used to be connected with external power supply, and the first insulating layer 1, second is respectively equipped in the upper and lower surface of the carbon fiber paper 4 absolutely Edge layer 5, and the outer surface of second insulating layer 5 is equipped with reflecting layer 6, the outer surface in the reflecting layer 6 is equipped with wearing layer 7.This hair Its structure of bright Self-controlling temperature electrothermal film issues heat mainly from the first insulating layer 1, and thermal energy is fully utilized.
Further, the insulating layer is polyvinyl chloride layer, and the reflecting layer 6 is aluminium film reflecting layer.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (10)

1. a kind of production method of Self-controlling temperature electrothermal film characterized by comprising
Be chopped silk, graphite, carbon fiber filler of carbon fiber is stirred mixing, becomes liquid slurry;The carbon fiber The concentration of filler is 18~22mol/L, in the liquid slurry, carbon fiber be chopped silk, graphite, between carbon fiber filler Mass percent are as follows: 1:7:2;
After the liquid slurry is coated on substrate surface, it is sent into hot press and carries out hot pressing, obtain carbon fiber paper;The temperature of the hot pressing Degree are as follows: 140 DEG C~300 DEG C, the pressure of hot pressing are as follows: 0.1MPa~0.4MPa, when a length of 1.5min~4min of hot pressing;
The carbon fiber paper is impregnated in the polyvinyl alcohol water solution that concentration is 10%, takes out carbon fiber paper after impregnating and carry out low temperature It is dry;
After low temperature drying, carbon fiber paper feeding low-temperature heat furnace is heated, carbon fiber paper is made to complete resin solidification;The heating Temperature be 200 DEG C, the when a length of 2h or more of heating;
After through heating, carbon fiber paper is impregnated in maceration extract, the maceration extract is molten by crystalline flake graphite, phenolic resin, methanol Liquid is formed by the mass ratio of 1:4:16, is taken out carbon fiber paper after impregnating and is dried;
After completing drying, carbon fiber paper is sent into inflated with nitrogen vacuum drying oven and is carbonized, the carbon fiber paper after being carbonized, the carbon The temperature of change is 2000 DEG C or more;
Increase metal foil on carbon fiber paper in the carbonized, and connects connecting terminal in metal foil;
After connecting connecting terminal, upper functional layer is pressed on the surface of carbon fiber paper, obtains Self-controlling temperature electrothermal film.
2. the production method of Self-controlling temperature electrothermal film according to claim 1, which is characterized in that the carbon fiber is chopped filament length Degree is between 5mm~14mm.
3. the production method of Self-controlling temperature electrothermal film according to claim 2, which is characterized in that the carbon fiber filler is Octadecane acetic acid.
4. the production method of Self-controlling temperature electrothermal film according to claim 3, which is characterized in that the partial size of the graphite is 1 ~6 μm.
5. the production method of Self-controlling temperature electrothermal film according to claim 4, which is characterized in that the temperature of the drying is 90 DEG C, the when a length of 3min of drying.
6. the production method of Self-controlling temperature electrothermal film according to claim 5, which is characterized in that the duration being stirred For 30min, the temperature being stirred is 10 DEG C~30 DEG C.
7. the production method of Self-controlling temperature electrothermal film according to claim 6, which is characterized in that the temperature of the low temperature drying 70 DEG C hereinafter, a length of 35min when dry.
8. the production method of Self-controlling temperature electrothermal film according to claim 7, which is characterized in that the carbon fiber filler parent Water hydrophobic balance value is between 10~20.
9. a kind of obtained Self-controlling temperature electrothermal film of production method with Self-controlling temperature electrothermal film described in claim 1, feature It is, comprising: carbon fiber paper is equipped with metal foil on the carbon fiber paper, connecting terminal, the carbon are connected on the metal foil Be equipped with insulating layer in the upper and lower surface of fine paper, and the outer surface of an insulating layer is equipped with reflecting layer, the reflecting layer it is outer Surface is equipped with wearing layer.
10. Self-controlling temperature electrothermal film according to claim 9, which is characterized in that the insulating layer is polyvinyl chloride layer, described Reflecting layer is aluminium film reflecting layer.
CN201610329138.5A 2016-05-18 2016-05-18 A kind of production method and its Electric radiant Heating Film of Self-controlling temperature electrothermal film Active CN105960035B (en)

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CN106455154B (en) * 2016-09-28 2019-10-01 常州中科特炭新能源科技有限公司 The preparation process of low-voltage olefinic carbon flexible electrothermal membrane
JP6611016B2 (en) 2017-06-13 2019-11-27 株式会社Mozu Far-infrared radiation sheet, manufacturing method of far-infrared radiation sheet, and far-infrared radiation method
KR101865825B1 (en) * 2017-09-27 2018-06-08 에버웰테크놀로지 주식회사 Heater including carbon felt and method for manufacturing the same
CN110218352A (en) * 2019-05-09 2019-09-10 乐福之家纳米材料有限责任公司 A kind of production technology of graphene Electric radiant Heating Film

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CN1062408C (en) * 1994-12-06 2001-02-21 北京寰海智业科技发展有限公司 Carbon fibre composite paper for conduction heating and preparing process thereof
CN1274783A (en) * 2000-04-18 2000-11-29 太原东立信息产业有限公司 Electrothermal high-temperature carbon fiber paper and its making process
EP2175688A1 (en) * 2008-10-07 2010-04-14 Ching-Ling Pan Activated carbon fiber soft electric heating product and manufacturing method thereof
CN202043305U (en) * 2011-02-01 2011-11-16 吉林大学 High-temperature-resisting carbon fiber paper soft composite electric heating slice
CN104661339A (en) * 2013-11-25 2015-05-27 大连康赛谱科技发展有限公司 Electrostatically-manufactured conductive heating carbon fiber composite material

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