CN105960035A - Self-controlled temperature electrothermal film production method and electrothermal film thereof - Google Patents

Self-controlled temperature electrothermal film production method and electrothermal film thereof Download PDF

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Publication number
CN105960035A
CN105960035A CN201610329138.5A CN201610329138A CN105960035A CN 105960035 A CN105960035 A CN 105960035A CN 201610329138 A CN201610329138 A CN 201610329138A CN 105960035 A CN105960035 A CN 105960035A
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electrothermal film
self
carbon fibre
fibre paper
production method
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CN201610329138.5A
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CN105960035B (en
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陈亮
龚向民
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Rongjie Health Technology Co., Ltd.
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Shenzhen Josen Industrial Co Ltd
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/20Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
    • H05B3/34Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs
    • H05B3/36Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs heating conductor embedded in insulating material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/145Carbon only, e.g. carbon black, graphite
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/18Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor the conductor being embedded in an insulating material

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  • Paper (AREA)
  • Resistance Heating (AREA)
  • Surface Heating Bodies (AREA)

Abstract

The present invention relates to the electrothermal film product field, in particular to a self-controlled temperature electrothermal film production method and an electrothermal film thereof. The self-controlled temperature electrothermal film production method comprises the steps of orderly stirring and mixing the carbon fiber chopped silks, the graphite and the carbon fiber fillers according to a mass percent of 1:7:2, then carrying out the hot-pressing, low-temperature drying, curing, drying and carbonization operations orderly, and then adding electrodes, and finally press fitting to obtain the self-controlled temperature electrothermal film. According to the present invention, the carbon fiber fillers are added during the electrothermal film production process, so that the electrothermal film has a self-controlled temperature characteristic and does not burn due to an overhigh local temperature, and accordingly, the usage safety of a product is guaranteed.

Description

The production method of a kind of Self-controlling temperature electrothermal film and Electric radiant Heating Film thereof
Technical field
The present invention relates to Electric radiant Heating Film product scope, be specifically related to production method and the Electric radiant Heating Film thereof of a kind of Self-controlling temperature electrothermal film.
Background technology
Far-infrared physiotherapy room is a kind of physical therapy product using far infrared radiator to produce far infrared radiation effect, and current far infrared radiator mainly uses Electric radiant Heating Film, the far-infrared radiation material of electrothermal tube one class.Electric radiant Heating Film is big due to heating area, human feeling is comfortable, market uses the most extensive, but traditional far-infrared electrothermal film uses metal electric heating silk or carbon fiber as heater, control temperature to use the mode of external temperature controller to carry out, owing to heating film is planar heat producing body, there is test point and select difficulty and easily occur that the overheated combustion case caused of local temperature occurs.
Summary of the invention
For overcoming drawbacks described above, the purpose of the present invention is i.e. to provide the production method of a kind of Self-controlling temperature electrothermal film and a kind of Self-controlling temperature electrothermal film.
It is an object of the invention to be achieved through the following technical solutions:
The present invention is the production method of a kind of Self-controlling temperature electrothermal film, including:
Carbon fiber chopped silk, graphite, carbon fiber filler are stirred mixing so that it is become liquid slurry;The concentration of described carbon fiber filler is 18~22mol/L, and in described liquid slurry, the mass percent between carbon fiber chopped silk, graphite, carbon fiber filler is: 1:7:2;
After this liquid slurry is coated on substrate surface, it is sent in hot press and carries out hot pressing, obtain carbon fibre paper;The temperature of described hot pressing is: 140 DEG C~300 DEG C, and the pressure of hot pressing is: 0.1MPa~0.4MPa, time a length of 1.5min~4min of hot pressing;
Described carbon fibre paper be impregnated in the polyvinyl alcohol water solution that concentration is 10%, take out carbon fibre paper after impregnating and carry out cold drying;
After cold drying, carbon fibre paper feeding low-temperature heat stove is heated, make carbon fibre paper complete resin solidification;The temperature of described heating is 200 DEG C, time a length of more than 2h of heating;
After by heating, impregnated in impregnation liquid by carbon fibre paper, described impregnation liquid is made up of by the mass ratio of 1:4:16 crystalline flake graphite, phenolic resin, methanol solution, takes out carbon fibre paper after impregnating and dries;
After completing to dry, being sent in inflated with nitrogen vacuum drying oven by carbon fibre paper and carry out carbonization, obtain the carbon fibre paper after carbonization, the temperature of described carbonization is more than 2000 DEG C;
Increase tinsel on carbon fibre paper in the carbonized, and in tinsel, connect binding post;
After connecting binding post, functional layer in the surface pressing of carbon fibre paper, obtain Self-controlling temperature electrothermal film.
Further, described carbon fiber chopped filament length degree is between 5mm~14mm.
Further, described carbon fiber filler is polyoxyethylene, comprising: octadecane acetic acid.
Further, the particle diameter of described graphite is 1~6 μm.
Further, the temperature of described drying is 90 DEG C, time a length of 3min of drying.
Further, time a length of 30min of described stirring mixing, the temperature of stirring mixing is 10 DEG C~30 DEG C.
Further, below the temperature 70 C of described cold drying, the time a length of 35min being dried.
Further, described carbon fiber filler hydrophilic-hydrophobic balance value is between 10~20.
The present invention is a kind of with the Self-controlling temperature electrothermal film obtained by the production method of Self-controlling temperature electrothermal film, including: carbon fibre paper, it is equipped with tinsel on described carbon fibre paper, it is connected to binding post on described tinsel, it is equipped with insulating barrier in the upper and lower surface of described carbon fibre paper, and the outer surface of an insulating barrier is provided with reflecting layer, the outer surface in described reflecting layer is provided with wearing layer.
Further, described insulating barrier is polyvinyl chloride layer, and described reflecting layer is aluminum film reflecting layer.
The present invention with the addition of carbon fiber filler in the production process of Electric radiant Heating Film so that the Electric radiant Heating Film of the present invention has possessed the characteristic of temp auto-controlled, does not haves the generation of the combustion case caused because local temperature is overheated, ensures the safety in utilization of product.
Accompanying drawing explanation
For ease of explanation, the present invention is described in detail by following preferred embodiment and accompanying drawing.
Fig. 1 is the production procedure schematic diagram of the production method of the present invention;
Fig. 2 is the Self-controlling temperature electrothermal film decomposition texture schematic diagram of the present invention.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the present invention is described in more detail.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
Referring to Fig. 1, the present invention is the production method of Self-controlling temperature electrothermal film, including:
101. stirring mixing
Carbon fiber chopped silk, graphite, carbon fiber filler are stirred mixing so that it is become liquid slurry;The concentration of described carbon fiber filler is 18~22mol/L, and in described liquid slurry, the mass percent between carbon fiber chopped silk, graphite, carbon fiber filler is: 1:7:2;
102. hot pressing
After this liquid slurry is coated on substrate surface, it is sent in hot press and carries out hot pressing, obtain carbon fibre paper;The temperature of described hot pressing is: 140 DEG C~300 DEG C, and the pressure of hot pressing is: 0.1MPa~0.4MPa, time a length of 1.5min~4min of hot pressing;
103. cold drying
Described carbon fibre paper be impregnated in the polyvinyl alcohol water solution that concentration is 10%, take out carbon fibre paper after impregnating and carry out cold drying;
104. solidification
After cold drying, carbon fibre paper feeding low-temperature heat stove is heated, make carbon fibre paper complete resin solidification;The temperature of described heating is 200 DEG C, time a length of more than 2h of heating;
105. dry
After by heating, impregnated in impregnation liquid by carbon fibre paper, described impregnation liquid is made up of by the mass ratio of 1:4:16 crystalline flake graphite, phenolic resin, methanol solution, takes out carbon fibre paper after impregnating and dries;
106. carbonization
After completing to dry, being sent in inflated with nitrogen vacuum drying oven by carbon fibre paper and carry out carbonization, obtain the carbon fibre paper after carbonization, the temperature of described carbonization is more than 2000 DEG C;
107. increase electrode
Increasing tinsel on carbon fibre paper in the carbonized, this tinsel as electrode on carbon fibre paper, and will connect binding post in tinsel;
108. pressing
After connecting binding post, functional layer in the surface pressing of carbon fibre paper, obtain Self-controlling temperature electrothermal film.Its specifically by heat pressing process by the first insulating barrier, carbon fibre paper, the second insulating barrier, aluminum film reflecting layer, wearing layer is hot-forming i.e. completes Self-controlling temperature electrothermal film.
Further, described carbon fiber chopped filament length degree is between 5mm~14mm.
Further, described carbon fiber filler is polyoxyethylene, comprising: hydrophobic part alkane carbon atom is at the octadecane acetic acid (C of 8~more than 1018H37O-(CH2CH2O)8-H).
Further, the particle diameter of described graphite is 1~6 μm.
Further, the temperature of described drying is 90 DEG C, time a length of 3min of drying.
Further, time a length of 30min of described stirring mixing, the temperature of stirring mixing is 10 DEG C~30 DEG C.
Further, below the temperature 70 C of described cold drying, the time a length of 35min being dried.
Further, described carbon fiber filler hydrophilic-hydrophobic balance value is between 10~20.
Refer to Fig. 2, the present invention is a kind of with the Self-controlling temperature electrothermal film obtained by the production method of Self-controlling temperature electrothermal film, including: carbon fibre paper 4, it is equipped with tinsel 2 on described carbon fibre paper 4, being connected to binding post 3 on described tinsel 2, described binding post 3, for being connected with outside power supply, the upper and lower surface of described carbon fibre paper 4 is respectively equipped with first insulating barrier the 1, second insulating barrier 5, and second the outer surface of insulating barrier 5 be provided with reflecting layer 6, the outer surface in described reflecting layer 6 is provided with wearing layer 7.Its structure of the Self-controlling temperature electrothermal film of the present invention makes heat mainly send from the first insulating barrier 1 so that heat energy can be fully utilized.
Further, described insulating barrier is polyvinyl chloride layer, and described reflecting layer 6 is aluminum film reflecting layer.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all any amendment, equivalent and improvement etc. made within the spirit and principles in the present invention, should be included within the scope of the present invention.

Claims (10)

1. the production method of a Self-controlling temperature electrothermal film, it is characterised in that including:
Carbon fiber chopped silk, graphite, carbon fiber filler are stirred mixing so that it is become liquid slurry;The concentration of described carbon fiber filler is 18~22mol/L, and in described liquid slurry, the mass percent between carbon fiber chopped silk, graphite, carbon fiber filler is: 1:7:2;
After this liquid slurry is coated on substrate surface, it is sent in hot press and carries out hot pressing, obtain carbon fibre paper;The temperature of described hot pressing is: 140 DEG C~300 DEG C, and the pressure of hot pressing is: 0.1MPa~0.4MPa, time a length of 1.5min~4min of hot pressing;
Described carbon fibre paper be impregnated in the polyvinyl alcohol water solution that concentration is 10%, take out carbon fibre paper after impregnating and carry out cold drying;
After cold drying, carbon fibre paper feeding low-temperature heat stove is heated, make carbon fibre paper complete resin solidification;The temperature of described heating is 200 DEG C, time a length of more than 2h of heating;
After by heating, impregnated in impregnation liquid by carbon fibre paper, described impregnation liquid is made up of by the mass ratio of 1:4:16 crystalline flake graphite, phenolic resin, methanol solution, takes out carbon fibre paper after impregnating and dries;
After completing to dry, being sent in inflated with nitrogen vacuum drying oven by carbon fibre paper and carry out carbonization, obtain the carbon fibre paper after carbonization, the temperature of described carbonization is more than 2000 DEG C;
Increase tinsel on carbon fibre paper in the carbonized, and in tinsel, connect binding post;
After connecting binding post, functional layer in the surface pressing of carbon fibre paper, obtain Self-controlling temperature electrothermal film.
The production method of Self-controlling temperature electrothermal film the most according to claim 1, it is characterised in that described carbon fiber chopped filament length degree is between 5mm~14mm.
The production method of Self-controlling temperature electrothermal film the most according to claim 2, it is characterised in that described carbon fiber filler is polyoxyethylene, comprising: octadecane acetic acid.
The production method of Self-controlling temperature electrothermal film the most according to claim 3, it is characterised in that the particle diameter of described graphite is 1~6 μm.
The production method of Self-controlling temperature electrothermal film the most according to claim 4, it is characterised in that the temperature of described drying is 90 DEG C, time a length of 3min of drying.
The production method of Self-controlling temperature electrothermal film the most according to claim 5, it is characterised in that time a length of 30min of described stirring mixing, the temperature of stirring mixing is 10 DEG C~30 DEG C.
The production method of Self-controlling temperature electrothermal film the most according to claim 6, it is characterised in that below the temperature 70 C of described cold drying, the time a length of 35min being dried.
The production method of Self-controlling temperature electrothermal film the most according to claim 7, it is characterised in that described carbon fiber filler hydrophilic-hydrophobic balance value is between 10~20.
9. one kind with the Self-controlling temperature electrothermal film obtained by the production method of the Self-controlling temperature electrothermal film described in claim 1, it is characterized in that, including: carbon fibre paper, it is equipped with tinsel on described carbon fibre paper, it is connected to binding post on described tinsel, being equipped with insulating barrier in the upper and lower surface of described carbon fibre paper, and the outer surface of an insulating barrier is provided with reflecting layer, the outer surface in described reflecting layer is provided with wearing layer.
Self-controlling temperature electrothermal film the most according to claim 9, it is characterised in that described insulating barrier is polyvinyl chloride layer, described reflecting layer is aluminum film reflecting layer.
CN201610329138.5A 2016-05-18 2016-05-18 A kind of production method and its Electric radiant Heating Film of Self-controlling temperature electrothermal film Active CN105960035B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106455154A (en) * 2016-09-28 2017-02-22 常州中科特炭新能源科技有限公司 Preparation technology of low-voltage olefince-carbon flexible electrothermal film
CN110218352A (en) * 2019-05-09 2019-09-10 乐福之家纳米材料有限责任公司 A kind of production technology of graphene Electric radiant Heating Film
CN111149423A (en) * 2017-09-27 2020-05-12 艾沃卫科技股份有限公司 Carbon felt heating device and manufacturing method thereof
EP3641490A4 (en) * 2017-06-13 2021-03-17 Mozu Co., Ltd. Far-infrared radiation sheet, method for manufacturing far-infrared radiation sheet, and far-infrared radiation method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1124907A (en) * 1994-12-06 1996-06-19 浦子荣 Carbon fibre composite paper for conduction heating and preparing process thereof
CN1274783A (en) * 2000-04-18 2000-11-29 太原东立信息产业有限公司 Electrothermal high-temperature carbon fiber paper and its making process
EP2175688A1 (en) * 2008-10-07 2010-04-14 Ching-Ling Pan Activated carbon fiber soft electric heating product and manufacturing method thereof
CN202043305U (en) * 2011-02-01 2011-11-16 吉林大学 High-temperature-resisting carbon fiber paper soft composite electric heating slice
CN104661339A (en) * 2013-11-25 2015-05-27 大连康赛谱科技发展有限公司 Electrostatically-manufactured conductive heating carbon fiber composite material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1124907A (en) * 1994-12-06 1996-06-19 浦子荣 Carbon fibre composite paper for conduction heating and preparing process thereof
CN1274783A (en) * 2000-04-18 2000-11-29 太原东立信息产业有限公司 Electrothermal high-temperature carbon fiber paper and its making process
EP2175688A1 (en) * 2008-10-07 2010-04-14 Ching-Ling Pan Activated carbon fiber soft electric heating product and manufacturing method thereof
CN202043305U (en) * 2011-02-01 2011-11-16 吉林大学 High-temperature-resisting carbon fiber paper soft composite electric heating slice
CN104661339A (en) * 2013-11-25 2015-05-27 大连康赛谱科技发展有限公司 Electrostatically-manufactured conductive heating carbon fiber composite material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106455154A (en) * 2016-09-28 2017-02-22 常州中科特炭新能源科技有限公司 Preparation technology of low-voltage olefince-carbon flexible electrothermal film
EP3641490A4 (en) * 2017-06-13 2021-03-17 Mozu Co., Ltd. Far-infrared radiation sheet, method for manufacturing far-infrared radiation sheet, and far-infrared radiation method
US11343880B2 (en) 2017-06-13 2022-05-24 Mozu Co., Ltd Far-infrared ray radiation sheet, method of manufacturing far-infrared ray radiation sheet, and method of radiating far-infrared rays
CN111149423A (en) * 2017-09-27 2020-05-12 艾沃卫科技股份有限公司 Carbon felt heating device and manufacturing method thereof
CN110218352A (en) * 2019-05-09 2019-09-10 乐福之家纳米材料有限责任公司 A kind of production technology of graphene Electric radiant Heating Film

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