CN105957915A - High-temperature resistant solar spectrum selective absorption and radiation structure - Google Patents

High-temperature resistant solar spectrum selective absorption and radiation structure Download PDF

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Publication number
CN105957915A
CN105957915A CN201610326036.8A CN201610326036A CN105957915A CN 105957915 A CN105957915 A CN 105957915A CN 201610326036 A CN201610326036 A CN 201610326036A CN 105957915 A CN105957915 A CN 105957915A
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flat metal
metal substrate
resistant
elevated temperatures
absorbs
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CN201610326036.8A
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CN105957915B (en
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胡治朋
张渊
刘芬
薛亚莉
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South China Normal University
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South China Normal University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0232Optical elements or arrangements associated with the device
    • H01L31/02322Optical elements or arrangements associated with the device comprising luminescent members, e.g. fluorescent sheets upon the device
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S10/00PV power plants; Combinations of PV energy systems with other systems for the generation of electric power
    • H02S10/30Thermophotovoltaic systems
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators

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  • Photovoltaic Devices (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)

Abstract

A high-temperature resistant solar spectrum selective absorption and radiation structure disclosed by the present invention comprises an absorber and a radiator, and the materials of the absorber and the radiator are both high-temperature resistant materials. The absorber is used to absorb the incident sunlight selectively, and comprises a metal nanometer triangle granule array which is arranged according to a hexagonal close-packed structure and a first flat metal substrate, and the metal nanometer triangle granule array is constructed on the top surface of the first flat metal pedestal. The radiator is used to selectively radiate the photons matching the band gap of a solar cell and comprises a metal nanometer square array and a second flat metal pedestal, the metal nanometer square array is constructed on the bottom surface of the second flat metal substrate, and the bottom surface of the first flat metal pedestal is constructed on the top surface of the second flat metal pedestal. The high-temperature resistant solar spectrum selective absorption and radiation structure of the present invention realizes the effective modulation to the sunlight energy spectrums, and breaks through the utilization efficiency theory limit of the conventional solar cell to the sunlight.

Description

A kind of resistant to elevated temperatures solar spectral selective absorbs and irradiation structure
Technical field
The present invention relates to heliotechnics and application, be specifically related to one and can be applicable in solar thermal photovoltaic system Resistant to elevated temperatures solar spectral selective absorb and irradiation structure.
Background technology
In today that Fossil fuel reduces increasingly, solar energy as a kind of new forms of energy because of its environmental protection, rich reserves, Reproducible feature, by everybody common concern, in numerous Solar use modes, especially with solaode This mode that primary energy can transfer to senior secondary energy sources, everybody is paid close attention to the most.In conventional solar cell Field, energy can not be absorbed and used less than the incident photon of battery energy gap, and higher than the incident illumination of energy gap Son, its energetic portions can be converted into thermal losses, here it is limit the bottleneck of solar-photovoltaic technology Schockley-Queisser (SQ) limit.Under the constraint of the SQ limit, energy gap is the single node of 1.0eV Semi-conductor cell in the case of total focus, its photoelectric transformation efficiency can only to 41%, non-focusing in the case of, just only Remaining 30%.In order to break through this limit, there has been proposed solar thermal photovoltaic system, i.e. at incident illumination and battery Between add selective absorbing-irradiation structure, this absorption-irradiation structure is by absorber and back-to-back group of irradiator two parts Conjunction forms.Absorber is responsible for absorbing sunlight and being translated into heat energy, and with this heating radiator, irradiator then passes through Thermal-radiating form gives off the photon matched with solaode energy gap.Through absorbing irradiation structure so One inhales a process put, it is achieved that the modulation to solar energy Spectral structure, limits the generation of the SQ limit from source, Greatly increasing the battery utilization rate to luminous energy, its theoretical limit efficiency, up to 85%, is the two of the SQ limit originally Have a surplus again.Therefore, spectral selection absorbs irradiation structure is a part particularly important in solar thermal photovoltaic system.
In spectral selection absorption-irradiation structure, absorber is responsible for absorbing incident illumination, and determine system always inputs energy, Therefore selective absorbing device must be the most powerful for the absorbability of sunlight, and absorption region can cover sunlight All wave bands (0.3 μm is to 2.5 μm), absorb energy as much as possible, improve absorption-irradiation structure at thermal balance shape Temperature under state, in order to irradiator can export higher-quality photon stream.The heat radiation of absorber self should be prevented simultaneously Loss, to ensure sufficiently high thermal equilibrium temperature, additionally, exotic material also should be selected to manufacture, because work temperature Degree is generally at about 2000K.At present, existing much about the research work of spectral selection absorber, such as based on Tungsten and the microcellular structure of tantalum, pyramid structure etc., but its absorption efficiency is the most prominent, its structure is past simultaneously Toward requiring higher depth-to-width ratio, such as paper " Nam, Youngsuk, et al.Solar Energy Materials and Solar Cells 122 (2014): 287-296. " in require aperture 1.45 μm, hole depth 8 μm, this be highly detrimental to reality production Manufacture.
In spectral selection absorption-irradiation structure, irradiator can be described as the parts of very core, it achieves the sun The modulating action of spectrum, is the direct supplier of solaode photon energy, is also the pass overcoming SQ limit generation mechanism Key place.According to the generation mechanism of the SQ limit, it is conceivable that preferably spectral selection irradiator should be: can suppress Less than the photon radiation of battery energy gap, the photon radiation that energy is too high can be reduced again.So irradiator should be arrowband Radiation, ties according to the calculating of paper " Rephaeli E, Fan S.Optics express, 2009,17 (17): 15145-15159. " Really, the radiation bandwidth of irradiator is 0.07eV when, and solar battery efficiency reaches peak.Such as Andrej Lenert Et al. work, use optical filter structure realize narrow wave radiation (Lenert, Andrej, et al.Nature Nanotechnology 9.2 (2014): 126-130.), but this device need to operate under vacuum conditions, and used The optical filter that is made up of silicon and silicon dioxide of radiating element, its fusing point too low (about 1000K), be not suitable for height Temperature environment, finally tests the efficiency obtained and is only 3.2%, still have the biggest room for promotion.In addition, major part is reported The research in road the most only devises the light within the irradiator in broadband, i.e. cutoff wavelength and can radiate, and the most deliberately goes to press down High-energy radiation processed.
Therefore, solar spectral selective absorption-irradiation structure still has the space of the highest transformation and lifting, designs Simple in construction, excellent performance and resistant to elevated temperatures solar spectral selective absorb irradiation structure for solving existing research The bottleneck that report system is faced will have very important realistic meaning and using value.
Summary of the invention
It is an object of the invention to, for above-mentioned the deficiencies in the prior art, provide a kind of high temperature resistant for solar thermal photovoltaic system Solar spectral selective absorb and irradiation structure.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of resistant to elevated temperatures solar spectral selective absorbs and irradiation structure, including absorber and irradiator, described suction The material receiving device and irradiator employing is resistant to elevated temperatures metal material;
Described absorber, for the sunlight of selective absorbing incidence, is received including the metal arranged by HCP structure Rice triangular shape particle array and the first flat metal substrate, described metal nano triangular shape particle Array Construction is flat in first The end face of whole metallic substrates;
Described irradiator goes out, for selective radiation, the photon matched with solaode energy gap, receives including metal Rice square array and the second flat metal substrate, described metal nano square Array Construction is in the second flat metal substrate Bottom surface;
The bottom surface of described first flat metal substrate is implemented in the end face of the second flat metal substrate.
Preferably, the spectral absorption selectivity of described absorber is by the size of metal nano triangular shape particle array and material Regulated and controled.
Preferably, the spectral radiance selectivity of described irradiator is regulated and controled by size and the material of metal nano square array.
Preferably, the size of described metal nano triangular shape particle array is by using environment to determine.
Preferably, the size of described metal nano square array is determined by selected solaode band gap width.
Preferably, the thickness of described first flat metal substrate is deep in the transmission of the first flat metal substrate more than incident illumination Degree.
Preferably, the thickness of described second flat metal substrate is deep in the transmission of the second flat metal substrate more than incident illumination Degree.
Preferably, the material that described metal nano triangular shape particle array and the first flat metal substrate use is identical.
Preferably, the material that described metal nano square array and the second flat metal substrate use is identical.
The present invention compared with prior art, has the advantage that and beneficial effect:
1, the absorber of the present invention and the material of irradiator employing are resistant to elevated temperatures metal material, can arrive at 2000K Normally working under the high temperature of 3000K, the size optimized according to actual operation requirements and material, solar energy is turned by it Changing efficiency and exceeded the SQ limit (41%) of conventional solar cell, performance is the most excellent.
2, the metal nano triangular shape particle array of the present invention, the first flat metal substrate, the second flat metal substrate, Metal nano square array is from top to bottom arranged in order, simple in construction, and its depth-to-width ratio will be little relative to existing structure.
3, the bottom surface of the first flat metal substrate is implemented in the end face of the second flat metal substrate by the present invention, to ensure to inhale Receive and have good heat conductivity between device and irradiator.
4, the serious forgiveness of the present invention is high, easily fabricated, integral structure, stability high, can be in solar thermal photovoltaic system System is used widely.
Accompanying drawing explanation
Fig. 1 is that the solar spectral selective of the present invention absorbs the perspective view with irradiation structure.
Fig. 2 is that the solar spectral selective of the present invention absorbs and the absorber top view in irradiation structure.
Fig. 3 is the sectional view of the dotted line intercepting along Fig. 5.
Fig. 4 is simulation result and the energy of solar spectrum of absorber absorption spectra under plane wave vertical incidence of the present invention Intensity;
Fig. 5 is that the solar spectral selective of the present invention absorbs and the irradiator top view in irradiation structure.
Fig. 6 is the sectional view of the dotted line intercepting along Fig. 2.
Fig. 7 is the irradiator of the present invention radiation spectrum simulation result when temperature T=2000K and preferable blackbody spectrum of radiation Curve chart.
Fig. 8 is that the solar spectral selective of the present invention absorbs the solar battery efficiency with irradiation structure along with temperature change Situation about changing, and SQ limit position.
Wherein, 1-metal nano triangular shape particle array, 2-the first flat metal substrate, 3-metal nano square array, 4-the second flat metal substrate.
Detailed description of the invention
Below in conjunction with embodiment and accompanying drawing, the present invention is described in further detail, but embodiments of the present invention do not limit In this.
Embodiment 1:
As it is shown in figure 1, the solar spectral selective of the present embodiment absorbs and irradiation structure, including absorber and radiation Device;Described absorber, for the sunlight of selective absorbing incidence, is received including the metal arranged by HCP structure Rice triangular shape particle array 1 and the first flat metal substrate 2, described metal nano triangular shape particle array 1 is implemented in the The end face of one flat metal substrate 2;Described irradiator goes out and solaode energy gap phase for selective radiation The photon joined, including metal nano square array 3 and the second flat metal substrate 4, described metal nano square array 3 It is implemented in the bottom surface of the second flat metal substrate 4;It is smooth that the bottom surface of described first flat metal substrate 2 is implemented in second The end face of metallic substrates 4, to ensure to have good heat conductivity between absorber and irradiator.
As shown in Figures 2 and 3, in the present embodiment, the material that absorber uses is tungsten to the structure of described absorber, In absorber, the thickness of the first flat metal substrate 2 is sufficiently thick, it is ensured that light tight, say, that the first flat metal The thickness of substrate 2 is more than the incident illumination transmission depth in the first flat metal substrate 2, metal nano triangular shape particle battle array Row 1 are obtained by Nanosphere lithography technique, a diameter of 1 μm of nanosphere, and the triangular shape particle formed is curl triangle Shape granule, the gap between granule is 100nm, and the thickness of metal nano triangular shape particle array 1 is 1 μm.
As shown in Figure 4, light gray line is the energy intensity of solar spectrum, and pitch black line is the spectral absorptive capacity of absorber, It can be seen that sunlight almost can be absorbed by absorber totally, simultaneously after the wavelength of 2 μm absorbance rapidly under Fall, effectively reduces the thermal losses that long-wave radiation brings.
As it can be seen in figures 5 and 6, in the present embodiment, the material that irradiator uses is tantalum to the structure of described irradiator, spoke In emitter, the thickness of metal nano square array 3 is 140nm, and the cycle is 500nm, and the length of side of each square is 470 Nm, the second flat metal substrate 4 thickness is sufficiently thick, it is ensured that light tight, say, that the second flat metal substrate 4 Thickness is more than the incident illumination transmission depth in the second flat metal substrate 4.
The material that the present embodiment relates to is exotic material, can bear the high temperature of about 2500K, as it is shown in fig. 7, Light gray line is preferable blackbody spectrum of radiation, and pitch black line is the irradiator radiation spectrum simulation result when temperature T=2000K, It can be seen that cutoff wavelength λ of irradiatorc=1.53 μm, are the narrow-band radiateds of bandwidth about 0.25 μm, had both inhibited length Wave radiation, again limit shortwave radiation, can use in conjunction with the solaode that energy gap is 0.81eV.
The change that can calculate the present embodiment solar battery efficiency at different temperatures according to detailed balancing principle is bent Line, as shown in Figure 8, it can be seen that after temperature reaches 1700K, the solar battery efficiency of this enforcement exceedes The SQ limit, conversion ratio up to 51% time the highest.
Embodiment 2
The parameter of the present embodiment arranges and keeps consistent with embodiment 1;The material of described irradiator is tantalum, metal nano side The thickness of block array 3 is 165nm, and the cycle is 500nm, and the length of side of each square is 475nm, the second flat metal Substrate 4 thickness is sufficiently thick, it is ensured that light tight.Now cutoff wavelength λ of irradiatorc=1.77 μm, can be in conjunction with energy gap Solaode for 0.7eV uses, and solar battery efficiency is up to 48%, and operating temperature is about 2000K.
Embodiment 3
The parameter of the present embodiment arranges and keeps consistent with embodiment 1;The material of described irradiator is tantalum, and described metal is received The thickness of rice square array 3 is 200nm, and the cycle is 500nm, and the length of side of each square is 478nm, described radiation Flat metal substrate 4 thickness of device is sufficiently thick, it is ensured that light tight.Now cutoff wavelength λ of irradiatorc=2.06 μm, can Using in conjunction with the solaode that energy gap is 0.6eV, solar battery efficiency is up to 45%, and operating temperature is 2000 About K.
By selecting the irradiator of different physical dimensions, described solar spectral selective absorbs can quilt with irradiation structure It is adjusted in different radiation cutoff wavelengths, to adapt to the solaode of different energy gap, and sun light absorption department Point determine that, so its parameter is also relatively fixed, to ensure that described resistant to elevated temperatures solar spectral selects because of solar spectrum The conversion that selecting property absorbs with irradiation structure is in optimum state.And the material selection for irradiator also can be by demand and suction Receive device and keep consistent, be such as all tungsten material.
In sum, the material that the absorber of the present invention and irradiator use is resistant to elevated temperatures metal material, can be Normally work under the high temperature of 2000K to 3000K, the metal nano triangular shape particle optimized according to actual operation requirements Array and the size of metal nano square array and material, it has exceeded traditional solar-electricity to the transformation efficiency of solar energy The SQ limit (41%) in pond, performance is the most excellent.
The above, patent preferred embodiment the most of the present invention, but the protection domain of patent of the present invention is not limited to This, any those familiar with the art is in the scope disclosed in patent of the present invention, according to patent of the present invention Technical scheme and patent of invention conceive equivalent or change in addition, broadly fall into the protection domain of patent of the present invention.

Claims (9)

1. a resistant to elevated temperatures solar spectral selective absorbs and irradiation structure, it is characterised in that: include absorber and The material that irradiator, described absorber and irradiator use is resistant to elevated temperatures metal material;
Described absorber, for the sunlight of selective absorbing incidence, is received including the metal arranged by HCP structure Rice triangular shape particle array and the first flat metal substrate, described metal nano triangular shape particle Array Construction is flat in first The end face of whole metallic substrates;
Described irradiator goes out, for selective radiation, the photon matched with solaode energy gap, receives including metal Rice square array and the second flat metal substrate, described metal nano square Array Construction is in the second flat metal substrate Bottom surface;
The bottom surface of described first flat metal substrate is implemented in the end face of the second flat metal substrate.
The resistant to elevated temperatures solar spectral selective of one the most according to claim 1 absorbs and irradiation structure, and it is special Levy and be: the spectral absorption selectivity of described absorber is adjusted by size and the material of metal nano triangular shape particle array Control.
The resistant to elevated temperatures solar spectral selective of one the most according to claim 1 absorbs and irradiation structure, and it is special Levy and be: the spectral radiance selectivity of described irradiator is regulated and controled by size and the material of metal nano square array.
The resistant to elevated temperatures solar spectral selective of one the most according to claim 1 absorbs and irradiation structure, and it is special Levy and be: the size of described metal nano triangular shape particle array is by using environment to determine.
The resistant to elevated temperatures solar spectral selective of one the most according to claim 1 absorbs and irradiation structure, and it is special Levy and be: the size of described metal nano square array is determined by selected solaode band gap width.
The resistant to elevated temperatures solar spectral selective of one the most according to claim 1 absorbs and irradiation structure, and it is special Levy and be: the thickness of described first flat metal substrate is more than the incident illumination transmission depth in the first flat metal substrate.
The resistant to elevated temperatures solar spectral selective of one the most according to claim 1 absorbs and irradiation structure, and it is special Levy and be: the thickness of described second flat metal substrate is more than the incident illumination transmission depth in the second flat metal substrate.
The resistant to elevated temperatures solar spectral selective of one the most according to claim 1 absorbs and irradiation structure, and it is special Levy and be: the material that described metal nano triangular shape particle array and the first flat metal substrate use is identical.
The resistant to elevated temperatures solar spectral selective of one the most according to claim 1 absorbs and irradiation structure, and it is special Levy and be: the material that described metal nano square array and the second flat metal substrate use is identical.
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CN106601830A (en) * 2016-12-27 2017-04-26 张四清 High-efficiency solar energy utilization system
CN107482994A (en) * 2017-08-22 2017-12-15 郑义 A kind of selective thermal transmitter for thermal photovoltaic system
CN108667394A (en) * 2018-05-09 2018-10-16 万成龙 A kind of Meta Materials of nanostructure
CN111123531A (en) * 2019-12-29 2020-05-08 中国科学院西安光学精密机械研究所 Antireflection micro-nano structure array based on space shaping
CN113035979A (en) * 2021-03-09 2021-06-25 南京大学 Absorption-radiator structure for solar thermal photovoltaic cell and preparation method thereof
CN114189198A (en) * 2021-12-01 2022-03-15 上海交通大学 Super-surface-selective radiator applied to thermophotovoltaic system and preparation method thereof
CN114497262A (en) * 2022-03-02 2022-05-13 爱思菲尔光学科技(苏州)有限公司 Narrow-band selective super-surface radiator and manufacturing method thereof

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CN106601830A (en) * 2016-12-27 2017-04-26 张四清 High-efficiency solar energy utilization system
CN107482994A (en) * 2017-08-22 2017-12-15 郑义 A kind of selective thermal transmitter for thermal photovoltaic system
CN108667394A (en) * 2018-05-09 2018-10-16 万成龙 A kind of Meta Materials of nanostructure
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CN113035979A (en) * 2021-03-09 2021-06-25 南京大学 Absorption-radiator structure for solar thermal photovoltaic cell and preparation method thereof
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CN114189198A (en) * 2021-12-01 2022-03-15 上海交通大学 Super-surface-selective radiator applied to thermophotovoltaic system and preparation method thereof
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CN114497262A (en) * 2022-03-02 2022-05-13 爱思菲尔光学科技(苏州)有限公司 Narrow-band selective super-surface radiator and manufacturing method thereof
CN114497262B (en) * 2022-03-02 2024-04-02 爱思菲尔光学科技(苏州)有限公司 Narrow band selective subsurface radiator and method of making same

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