CN105951303A - Composite non-woven fabric based on eggshell inner membrane and black rice and preparing method thereof - Google Patents
Composite non-woven fabric based on eggshell inner membrane and black rice and preparing method thereof Download PDFInfo
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- CN105951303A CN105951303A CN201610427959.2A CN201610427959A CN105951303A CN 105951303 A CN105951303 A CN 105951303A CN 201610427959 A CN201610427959 A CN 201610427959A CN 105951303 A CN105951303 A CN 105951303A
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- China
- Prior art keywords
- gallus domesticus
- inner membrance
- crusta gallus
- ovum crusta
- zizaniae caduciflorae
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0092—Electro-spinning characterised by the electro-spinning apparatus characterised by the electrical field, e.g. combined with a magnetic fields, using biased or alternating fields
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Nonwoven Fabrics (AREA)
- Artificial Filaments (AREA)
- Peptides Or Proteins (AREA)
- Medicinal Preparation (AREA)
- Materials For Medical Uses (AREA)
Abstract
The invention provides a method for preparing a composite non-woven fabric based on an eggshell inner membrane and black rice. The method comprises the steps of taking the eggshell inner membrane in a fresh egg out to be dissolved in lithium bromide solution at a constant temperature for hydrolysis, obtaining eggshell inner membrane solution after dialysis concentration, adding fibroin solution to the eggshell inner membrane solution to form spinning solution, and conducting electrostatic spinning to obtain a fibrous membrane containing the eggshell inner membrane; adding black rice starch to ethyl alcohol solvent, conducting sufficient stirring till uniform mixing, then adding alkali liquor, conducting heating for alkalization, adding citric acid and fibroin solution to form spinning solution, conducting standing defoaming, and obtaining a fibrous membrane containing black rice starch after electrostatic spinning; laminating the fibrous membrane containing the eggshell inner membrane with the fibrous membrane containing black rice starch by means of a Yatai laminator to obtain the composite non-woven fabric based on the eggshell inner membrane and black rice.
Description
Technical field
The invention belongs to textile material technical field, be specifically related to a kind of based on Ovum crusta Gallus domesticus inner membrance with the composite non woven of fructus zizaniae caduciflorae
Cloth and preparation method thereof.
Background technology
Along with improving constantly of people's living standard, people are more and more higher for the requirement of food materials, the precision of food materials and
Quality is more and more higher.But, there is the auxiliary product of many food materials but to be ignored by people, become rubbish, not only more
Waste resource and pollute environment.In recent years, along with environmental protection, being rooted in the hearts of the people of sustainable concept, many food materials
It is developed and applies to other field, in the hope of improving its economic worth.
Egg is the wholefood of ideals of human being, good and cheap, wide material sources, the albumen of the how edible egg of people and egg
Clearly, the utilization rate for Ovum crusta Gallus domesticus and inner membrance thereof is the highest.Starch granules is the main of the nature green plants storage energy
Form, majority starch granule is to be formed by amylopectin and two kinds of macromolecule ordered sets of amylopectin, is a kind of natural
Polycrystalline structure, containing crystal region and unformed area.The structure of starch granules is sufficiently complex, can be with theory of evolution maneuver pair
The position of starch molecule carries out replacing formation deformation starch, improves the added value of starch.
Polypropylene slurry that a kind of Ovum crusta Gallus domesticus disclosed in Chinese patent CN 105544213A is modified and preparation method thereof, will
The Ovum crusta Gallus domesticus removing inner membrance grinds to form the powder of micro/nano level, through dodecylbenzene sodium sulfonate modified addition acrylic monomers
In, the polypropylene slurry of modification is formed through initiator and heat effect.The method utilizes Ovum crusta Gallus domesticus powder to improve polypropylene
The adhesion property of slurry and starch finishing effect, and do not affect the environmental protection performance of slurry, improve the exploitation value of Ovum crusta Gallus domesticus
Value.China's document (" corn starch graft modification thickener and printing performance thereof ", yellow little Hua etc., printing and dyeing, the 3rd phase,
7-8, page 15,2006) disclosed in a kind of corn starch graft modification thickener, by using modification of corn starch thickener
Replace sodium alginate, reduce the cost of printing with reactive dye, improve the economic worth of starch.Can by above-mentioned prior art
Knowing, food materials and auxiliary product thereof can be used for textile manufacturing through processing with modified.
Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae starch are applied to field of textiles by applicant of the present invention, with fibroin together as
Composite non woven cloth material prepared by raw material, and utilizes green maneuver to be bonded by two kinds of nonwoven cloth materials, prepares green ring
Protect, the compound nonwoven cloth of excellent performance, improve Ovum crusta Gallus domesticus inner membrance and the economic worth of fructus zizaniae caduciflorae starch, expand weaving face fabric
Kind.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of based on Ovum crusta Gallus domesticus inner membrance and the compound nonwoven cloth of fructus zizaniae caduciflorae and system
Preparation Method, uses Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae starch as raw material, is compounded to form spinning with fibroin solutions respectively
Liquid, forms fibrous membrane through electrostatic spinning technique, two kinds of fibrous membranes is compounded to form through plastic packaging machine the compound nothing of extra quality bilayer
Spin cloth.Non-woven cloth light weight prepared by the method is thin, and two sides has different premium properties, pro-skin, health care, U.S.
Appearance, moisturizing, can be used for preparing textile garment or skin care item.
For solving above-mentioned technical problem, the technical scheme is that
A kind of based on Ovum crusta Gallus domesticus inner membrance with the compound nonwoven cloth of fructus zizaniae caduciflorae, described based on Ovum crusta Gallus domesticus inner membrance with the compound nothing of fructus zizaniae caduciflorae
Spin cloth and include the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance and the fibrous membrane containing fructus zizaniae caduciflorae starch, the described fiber containing Ovum crusta Gallus domesticus inner membrance
Film includes that coating solution and fibroin solutions in Ovum crusta Gallus domesticus, the described fibrous membrane containing fructus zizaniae caduciflorae starch include fructus zizaniae caduciflorae starch and silkworm
Silk protein solution.
Preferred as technique scheme, the described fibrous membrane containing Ovum crusta Gallus domesticus inner membrance is prepared by electrostatic spinning, described contains
The fibrous membrane of fructus zizaniae caduciflorae starch is prepared by electrostatic spinning, and described compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae is by containing chicken
The fibrous membrane of eggshell inner membrance and the fibrous membrane containing fructus zizaniae caduciflorae starch are composited.
The present invention also provides for a kind of based on Ovum crusta Gallus domesticus inner membrance with the preparation method of the compound nonwoven cloth of fructus zizaniae caduciflorae, including following step
Rapid:
(1) Ovum crusta Gallus domesticus inner membrance in fresh egg is taken off, be dissolved in lithium-bromide solution, thermostatted water at 50-65 DEG C
Solving 15-30min, dialysis obtains coating solution in Ovum crusta Gallus domesticus after concentrating, molten by adding fibroin in coating solution in Ovum crusta Gallus domesticus
Liquid, is sufficiently stirred for forming spinning liquid, after standing froth breaking, obtains the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance through electrostatic spinning；
(2) fructus zizaniae caduciflorae is dried grind to form fructus zizaniae caduciflorae starch, fructus zizaniae caduciflorae starch is added in alcohol solvent, be stirred well to mixing
Uniformly, add alkali liquor, heating alkalization, add citric acid and fibroin solutions, be sufficiently stirred for forming spinning
Liquid, after standing froth breaking, obtains the fibrous membrane containing fructus zizaniae caduciflorae starch through electrostatic spinning；
(3) fibrous membrane containing Ovum crusta Gallus domesticus inner membrance prepared by step (1) and step (2) prepare containing fructus zizaniae caduciflorae starch
Fibrous membrane utilizes Asia-Pacific plastic packaging machine to carry out lamination, obtains the compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae.
Preferred as technique scheme, in described step (1), the solid-liquid ratio of Ovum crusta Gallus domesticus inner membrance and lithium-bromide solution
For 1g:5-10ml.
Preferred as technique scheme, in described step (1), in Ovum crusta Gallus domesticus, the mass fraction of coating solution is
5-10%.
Preferred as technique scheme, in described step (2), the particle diameter of fructus zizaniae caduciflorae starch is 3-5 μm.
Preferred as technique scheme, in described step (2), the temperature of heating alkalization is 35-40 DEG C, the time
For 60-90min.
Preferred as technique scheme, in described step (1) or step (2), electrospinning conditions is for spinning
Filament voltage 15-20KV, spinning liquid fltting speed 0.5-1ml/h, accept distance for 20-25cm.
Preferred as technique scheme, in described step (3), the thickness of the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance is
0.3-0.5mm, the fibrous membrane thickness containing fructus zizaniae caduciflorae starch is 0.5-1mm.
Preferred, in described step (3), based on Ovum crusta Gallus domesticus inner membrance and the composite non woven of fructus zizaniae caduciflorae as technique scheme
The thickness of cloth be 0.3-0.5mm grammes per square metre be 59-84g/cm2。
Compared with prior art, the method have the advantages that
(1) compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae prepared by the present invention there is the fiber containing Ovum crusta Gallus domesticus inner membrance
Film, containing Ovum crusta Gallus domesticus inner membrance in this fibrous membrane, the main component of this inner membrance is fibrin, keratin, sugar, amino
Acid etc., containing various active composition, good biocompatibility, also have the effect such as skin Caring, granulation promoting.
(2) compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae prepared by the present invention there is the fiber containing fructus zizaniae caduciflorae starch
Film, containing fructus zizaniae caduciflorae starch in this fibrous membrane, fructus zizaniae caduciflorae starch is rich in thick protein, lysine, plant fat, fiber
Element, several mineral materials and vitamin, compared with common rice starch, the content of vitamin C and carotene is more
Height, the cellulose membrane will prepared as raw material after fructus zizaniae caduciflorae starch conversion, good water absorption, skin-friendly is good, also has and calms the nerves
Effect.
(3) in compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae prepared by the present invention except containing Ovum crusta Gallus domesticus inner membrance and
Fructus zizaniae caduciflorae starch, possibly together with fibroin, the high-quality protein that fibroin is well recognized as, there is pro-skin skin Caring moisturizing whitening etc.
Multi-efficiency.
(4) compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae prepared by the present invention is double raw material dilayer compounding non-spinning fabricses
Material, is combined the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance and the fibrous membrane containing fructus zizaniae caduciflorae starch, makes fabric one mask of non-woven fabrics
The performance of Ovum crusta Gallus domesticus inner membrance, one side is had to have the performance of fructus zizaniae caduciflorae starch, and overlap through plastic packaging machine, make both tight
Close stacking, papery is frivolous.
(5) two sides based on Ovum crusta Gallus domesticus inner membrance and the compound nonwoven cloth of fructus zizaniae caduciflorae prepared by the present invention has different Optimalities
Can, pro-skin, keep healthy, improve looks, moisturizing, can be used for preparing textile garment or skin care item.
Detailed description of the invention
The present invention is described in detail, in illustrative examples and the explanation of this present invention below in conjunction with specific embodiment
It is used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1:
(1) Ovum crusta Gallus domesticus inner membrance in fresh egg is taken off, 1g Ovum crusta Gallus domesticus inner membrance is dissolved in 5ml lithium-bromide solution,
Constant temperature hydrolysis 15min at 50 DEG C, dialysis obtains coating solution in the Ovum crusta Gallus domesticus that mass fraction is 5%, by volume after concentrating
Than being the fibroin solutions of 10% for coating solution in the Ovum crusta Gallus domesticus of 1:3 adds mass fraction, it is sufficiently stirred for, concentrates shape
Become spinning liquid, after standing froth breaking, under 15KV voltage, with the speed electrostatic spinning of 0.5ml/h, connect at 20cm
Receive the fibrous membrane obtained containing Ovum crusta Gallus domesticus inner membrance.
(2) fructus zizaniae caduciflorae is dried grind to form the fructus zizaniae caduciflorae starch of 3 μm, 1g fructus zizaniae caduciflorae starch is added the alcohol solvent of 30ml
In, it is stirred well to mix homogeneously, adds the 15g/L sodium hydroxide solution of 5ml, 35 DEG C of heating alkalization
60min, adds 3ml citric acid and 30ml mass fraction is the fibroin solutions of 10%, is sufficiently stirred for, and concentrates shape
Become spinning liquid, after standing froth breaking, under 15KV voltage, with the speed electrostatic spinning of 0.5ml/h, connect at 20cm
Receive the fibrous membrane obtained containing fructus zizaniae caduciflorae starch.
(3) fibrous membrane containing fructus zizaniae caduciflorae starch thick with 0.5mm for the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance thick for 0.3mm is utilized
Asia-Pacific plastic packaging machine carries out lamination, obtains the compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae.
Embodiment 2:
(1) Ovum crusta Gallus domesticus inner membrance in fresh egg is taken off, 1g Ovum crusta Gallus domesticus inner membrance is dissolved in 10ml lithium-bromide solution
In, constant temperature hydrolysis 30min at 65 DEG C, dialysis obtains coating solution in the Ovum crusta Gallus domesticus that mass fraction is 10% after concentrating, will
Volume ratio be 1:5 Ovum crusta Gallus domesticus in add mass fraction in coating solution be the fibroin solutions of 15%, be sufficiently stirred for, dense
Contracting forms spinning liquid, after standing froth breaking, under 20KV voltage, with the speed electrostatic spinning of 1ml/h, at 25cm
Receive the fibrous membrane obtained containing Ovum crusta Gallus domesticus inner membrance.
(2) fructus zizaniae caduciflorae is dried grind to form the fructus zizaniae caduciflorae starch of 5 μm, 1g fructus zizaniae caduciflorae starch is added the alcohol solvent of 30ml
In, it is stirred well to mix homogeneously, adds the 20g/L sodium hydroxide solution of 10ml, 40 DEG C of heating alkalization
90min, adds 3ml citric acid and 40ml mass fraction is the fibroin solutions of 15%, is sufficiently stirred for, and concentrates shape
Become spinning liquid, after standing froth breaking, under 20KV voltage, with the speed electrostatic spinning of 1ml/h, receive at 25cm
Obtain the fibrous membrane containing fructus zizaniae caduciflorae starch.
(3) fibrous membrane containing fructus zizaniae caduciflorae starch thick with 1mm for the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance thick for 0.5mm is utilized Asia
Too plastic packaging machine carries out lamination, obtains the compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae.
Embodiment 3:
(1) Ovum crusta Gallus domesticus inner membrance in fresh egg is taken off, 1g Ovum crusta Gallus domesticus inner membrance is dissolved in 6ml lithium-bromide solution,
Constant temperature hydrolysis 20min at 55 DEG C, dialysis obtains coating solution in the Ovum crusta Gallus domesticus that mass fraction is 7%, by volume after concentrating
Than being the fibroin solutions of 12% for coating solution in the Ovum crusta Gallus domesticus of 1:4 adds mass fraction, it is sufficiently stirred for, concentrates shape
Become spinning liquid, after standing froth breaking, under 18KV voltage, with the speed electrostatic spinning of 0.7ml/h, connect at 22cm
Receive the fibrous membrane obtained containing Ovum crusta Gallus domesticus inner membrance.
(2) fructus zizaniae caduciflorae is dried grind to form the fructus zizaniae caduciflorae starch of 4 μm, 1g fructus zizaniae caduciflorae starch is added the alcohol solvent of 30ml
In, it is stirred well to mix homogeneously, adds the 17g/L sodium hydroxide solution of 8ml, 36 DEG C of heating alkalization
70min, adds 3ml citric acid and 35ml mass fraction is the fibroin solutions of 12%, is sufficiently stirred for, and concentrates shape
Become spinning liquid, after standing froth breaking, under 17KV voltage, with the speed electrostatic spinning of 0.8ml/h, connect at 23cm
Receive the fibrous membrane obtained containing fructus zizaniae caduciflorae starch.
(3) fibrous membrane containing fructus zizaniae caduciflorae starch thick with 0.6mm for the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance thick for 0.4mm is utilized
Asia-Pacific plastic packaging machine carries out lamination, obtains the compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae.
Embodiment 4:
(1) Ovum crusta Gallus domesticus inner membrance in fresh egg is taken off, 1g Ovum crusta Gallus domesticus inner membrance is dissolved in 410ml lithium-bromide solution
In, constant temperature hydrolysis 430min at 504 DEG C, dialysis obtains coating solution in the Ovum crusta Gallus domesticus that mass fraction is 54% after concentrating,
It is the fibroin solutions of 13% by coating solution in Ovum crusta Gallus domesticus that volume ratio is 1:34 adds mass fraction, fully stirs
Mix, concentrate and form spinning liquid, stand after froth breaking, under 20KV voltage, with the speed electrostatic spinning of 0.54l/h,
The fibrous membrane obtained containing Ovum crusta Gallus domesticus inner membrance is received at 23cm.
(2) fructus zizaniae caduciflorae is dried grind to form the fructus zizaniae caduciflorae starch of 3 μm, 1g fructus zizaniae caduciflorae starch is added the alcohol solvent of 30ml
In, it is stirred well to mix homogeneously, adds the 15g/L sodium hydroxide solution of 10ml, 37 DEG C of heating alkalization
70min, adds 3ml citric acid and 35ml mass fraction is the fibroin solutions of 12%, is sufficiently stirred for, and concentrates shape
Become spinning liquid, after standing froth breaking, under 18KV voltage, with the speed electrostatic spinning of 0.8ml/h, connect at 20cm
Receive the fibrous membrane obtained containing fructus zizaniae caduciflorae starch.
(3) fibrous membrane containing fructus zizaniae caduciflorae starch thick with 0.7mm for the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance thick for 0.3mm is utilized
Asia-Pacific plastic packaging machine carries out lamination, obtains the compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae.
Embodiment 5:
(1) Ovum crusta Gallus domesticus inner membrance in fresh egg is taken off, 1g Ovum crusta Gallus domesticus inner membrance is dissolved in 10ml lithium-bromide solution
In, constant temperature hydrolysis 15min at 50-65 DEG C, dialysis obtains coating solution in the Ovum crusta Gallus domesticus that mass fraction is 6% after concentrating,
It is the fibroin solutions of 10% by coating solution in Ovum crusta Gallus domesticus that volume ratio is 1:5 adds mass fraction, fully stirs
Mix, concentrate and form spinning liquid, stand after froth breaking, under 20KV voltage, with the speed electrostatic spinning of 0.7ml/h,
The fibrous membrane obtained containing Ovum crusta Gallus domesticus inner membrance is received at 25cm.
(2) fructus zizaniae caduciflorae is dried grind to form the fructus zizaniae caduciflorae starch of 5 μm, 1g fructus zizaniae caduciflorae starch is added the alcohol solvent of 30ml
In, it is stirred well to mix homogeneously, adds the 15g/L sodium hydroxide solution of 5ml, 40 DEG C of heating alkalization
90min, adds 3ml citric acid and 40ml mass fraction is the fibroin solutions of 10%, is sufficiently stirred for, and concentrates shape
Become spinning liquid, after standing froth breaking, under 18KV voltage, with the speed electrostatic spinning of 0.7ml/h, connect at 25cm
Receive the fibrous membrane obtained containing fructus zizaniae caduciflorae starch.
(3) fibrous membrane containing fructus zizaniae caduciflorae starch thick with 0.5mm for the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance thick for 0.5mm is utilized
Asia-Pacific plastic packaging machine carries out lamination, obtains the compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae.
Embodiment 6:
(1) Ovum crusta Gallus domesticus inner membrance in fresh egg is taken off, 1g Ovum crusta Gallus domesticus inner membrance is dissolved in 8ml lithium-bromide solution,
Constant temperature hydrolysis 25min at 60 DEG C, dialysis obtains coating solution in the Ovum crusta Gallus domesticus that mass fraction is 10%, by volume after concentrating
Than being the fibroin solutions of 10% for coating solution in the Ovum crusta Gallus domesticus of 1:3 adds mass fraction, it is sufficiently stirred for, concentrates shape
Become spinning liquid, after standing froth breaking, under 20KV voltage, with the speed electrostatic spinning of 0.8ml/h, connect at 20cm
Receive the fibrous membrane obtained containing Ovum crusta Gallus domesticus inner membrance.
(2) fructus zizaniae caduciflorae is dried grind to form the fructus zizaniae caduciflorae starch of 5 μm, 1g fructus zizaniae caduciflorae starch is added the alcohol solvent of 30ml
In, it is stirred well to mix homogeneously, adds the 15g/L sodium hydroxide solution of 8ml, 40 DEG C of heating alkalization
75min, adds 3ml citric acid and 30ml mass fraction is the fibroin solutions of 12%, is sufficiently stirred for, and concentrates shape
Become spinning liquid, after standing froth breaking, under 15KV voltage, with the speed electrostatic spinning of 0.8ml/h, connect at 25cm
Receive the fibrous membrane obtained containing fructus zizaniae caduciflorae starch.
(3) fibrous membrane containing fructus zizaniae caduciflorae starch thick with 0.8mm for the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance thick for 0.5mm is utilized
Asia-Pacific plastic packaging machine carries out lamination, obtains the compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae.
After testing, embodiment 1-6 prepare based on Ovum crusta Gallus domesticus inner membrance and the thickness of the compound nonwoven cloth of fructus zizaniae caduciflorae, grammes per square metre,
The result of mechanical strength is as follows:
As seen from the above table, compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae prepared by the present invention is frivolous, mechanical strength
Preferably, have and take and usability.
The principle of above-described embodiment only illustrative present invention and effect thereof, not for limiting the present invention.Any ripe
Above-described embodiment all can be modified under the spirit and the scope of the present invention or change by the personage knowing this technology.
Therefore, art has usually intellectual such as without departing from disclosed spirit and technological thought
Lower all completed equivalences are modified or change, and must be contained by the claim of the present invention.
Claims (10)
1. one kind based on Ovum crusta Gallus domesticus inner membrance and the compound nonwoven cloth of fructus zizaniae caduciflorae, it is characterised in that: described base
Compound nonwoven cloth in Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae includes the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance and containing fructus zizaniae caduciflorae
The fibrous membrane of starch, the described fibrous membrane containing Ovum crusta Gallus domesticus inner membrance includes coating solution and silkworm silk egg in Ovum crusta Gallus domesticus
White solution, the described fibrous membrane containing fructus zizaniae caduciflorae starch includes fructus zizaniae caduciflorae starch and fibroin solutions.
It is the most according to claim 1 a kind of based on Ovum crusta Gallus domesticus inner membrance with the compound nonwoven cloth of fructus zizaniae caduciflorae,
It is characterized in that: the described fibrous membrane containing Ovum crusta Gallus domesticus inner membrance is prepared by electrostatic spinning, described containing fructus zizaniae caduciflorae shallow lake
The fibrous membrane of powder is prepared by electrostatic spinning, described compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae by
Fibrous membrane containing Ovum crusta Gallus domesticus inner membrance and the fibrous membrane containing fructus zizaniae caduciflorae starch are composited.
3., based on Ovum crusta Gallus domesticus inner membrance and a preparation method for the compound nonwoven cloth of fructus zizaniae caduciflorae, its feature exists
In: comprise the following steps:
(1) Ovum crusta Gallus domesticus inner membrance in fresh egg is taken off, be dissolved in lithium-bromide solution, at 50-65
Constant temperature hydrolysis 15-30min at DEG C, dialysis obtains coating solution in Ovum crusta Gallus domesticus, by Ovum crusta Gallus domesticus inner membrance after concentrating
Solution adds fibroin solutions, is sufficiently stirred for forming spinning liquid, after standing froth breaking, through Static Spinning
Silk obtains the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance；
(2) fructus zizaniae caduciflorae is dried grind to form fructus zizaniae caduciflorae starch, fructus zizaniae caduciflorae starch is added in alcohol solvent, fills
Divide stirring to mix homogeneously, add alkali liquor, heating alkalization, add citric acid and fibroin is molten
Liquid, is sufficiently stirred for forming spinning liquid, after standing froth breaking, obtains the fibre containing fructus zizaniae caduciflorae starch through electrostatic spinning
Dimension film；
(3) prepared by the fibrous membrane containing Ovum crusta Gallus domesticus inner membrance step (1) prepared and step (2)
Fibrous membrane containing fructus zizaniae caduciflorae starch utilizes Asia-Pacific plastic packaging machine to carry out lamination, obtains based on Ovum crusta Gallus domesticus inner membrance and black
The compound nonwoven cloth of rice.
A kind of compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae the most according to claim 3
Preparation method, it is characterised in that: in described step (1), Ovum crusta Gallus domesticus inner membrance and lithium-bromide solution
Solid-liquid ratio is 1g:5-10ml.
A kind of compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae the most according to claim 3
Preparation method, it is characterised in that: in described step (1), the mass fraction of coating solution in Ovum crusta Gallus domesticus
For 5-10%.
A kind of compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae the most according to claim 3
Preparation method, it is characterised in that: in described step (2), the particle diameter of fructus zizaniae caduciflorae starch is 3-5 μm.
A kind of compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae the most according to claim 3
Preparation method, it is characterised in that: in described step (2), the temperature of heating alkalization is 35-40 DEG C,
Time is 60-90min.
A kind of compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae the most according to claim 3
Preparation method, it is characterised in that: in described step (1) or step (2), electrospinning conditions
For spinning voltage 15-20KV, spinning liquid fltting speed 0.5-1ml/h, accept distance for 20-25cm.
A kind of compound nonwoven cloth based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae the most according to claim 3
Preparation method, it is characterised in that: in described step (3), containing the thickness of the fibrous membrane of Ovum crusta Gallus domesticus inner membrance
Degree is 0.3-0.5mm, and the fibrous membrane thickness containing fructus zizaniae caduciflorae starch is 0.5-1mm.
The most according to claim 3 a kind of based on Ovum crusta Gallus domesticus inner membrance with the compound nonwoven cloth of fructus zizaniae caduciflorae
Preparation method, it is characterised in that: in described step (3), based on Ovum crusta Gallus domesticus inner membrance and fructus zizaniae caduciflorae answer
Close non-woven fabrics thickness be 0.3-0.5mm grammes per square metre be 59-84g/cm2。
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| CN201711217616.4A CN107964735A (en) | 2016-06-16 | 2016-06-16 | A kind of application of compound nonwoven cloth |
| CN201610427959.2A CN105951303B (en) | 2016-06-16 | 2016-06-16 | A kind of preparation method of the compound nonwoven cloth based on egg shell inner membrance and black rice |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018100469A (en) * | 2016-12-21 | 2018-06-28 | 国立大学法人信州大学 | Nanofiber, production method of nanofiber, and face mask |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090031691A1 (en) * | 2007-07-30 | 2009-02-05 | Takeharu Tajima | Fiber, fiber assembly, and fiber producing method |
| WO2009031620A1 (en) * | 2007-09-05 | 2009-03-12 | Taiyokagaku Co., Ltd. | Water-soluble electrospun sheet |
| CN101575771A (en) * | 2009-06-08 | 2009-11-11 | 清华大学 | Method for preparing blending electrospun fiber membrane by adopting membrane protein contained in avian egg shells |
| CN101804218A (en) * | 2010-04-13 | 2010-08-18 | 王艳 | Human-body absorbable trauma dressing containing Yunnan white drug powder or Yunnan white drug powder extractive |
| CN102936794A (en) * | 2012-11-20 | 2013-02-20 | 东华大学 | Method for preparing composite nanofiber membrane based on natural material silk fibroin and chitosan |
| CN103120803A (en) * | 2012-12-29 | 2013-05-29 | 钟春燕 | Preparation method of bacterial cellulose composite chitosan moist antimicrobial dressing |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1202162C (en) * | 2003-02-28 | 2005-05-18 | 清华大学 | Dissolving and filming method of egg shell membrane |
| CN1244727C (en) * | 2004-09-07 | 2006-03-08 | 东华大学 | Process for producing regenerated silk protein super fine fiber |
| US7459492B2 (en) * | 2004-09-30 | 2008-12-02 | Universidad De Chile | Polypropylene composites with reinforcement based on eggshells: procedure to obtain the said composite, reinforcement based on eggshells, and procedure for obtaining it |
| CN101736430B (en) * | 2010-02-05 | 2012-07-04 | 东华大学 | Method for preparing silk fibroin nano-fibre with skin-care effect |
| CN103536505A (en) * | 2013-09-26 | 2014-01-29 | 江阴康奈尔生物科技有限公司 | Extraction method of active egg white essence and egg white essence skincare product |
-
2016
- 2016-06-16 CN CN201610427959.2A patent/CN105951303B/en active Active
- 2016-06-16 CN CN201711217616.4A patent/CN107964735A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090031691A1 (en) * | 2007-07-30 | 2009-02-05 | Takeharu Tajima | Fiber, fiber assembly, and fiber producing method |
| WO2009031620A1 (en) * | 2007-09-05 | 2009-03-12 | Taiyokagaku Co., Ltd. | Water-soluble electrospun sheet |
| CN101575771A (en) * | 2009-06-08 | 2009-11-11 | 清华大学 | Method for preparing blending electrospun fiber membrane by adopting membrane protein contained in avian egg shells |
| CN101804218A (en) * | 2010-04-13 | 2010-08-18 | 王艳 | Human-body absorbable trauma dressing containing Yunnan white drug powder or Yunnan white drug powder extractive |
| CN102936794A (en) * | 2012-11-20 | 2013-02-20 | 东华大学 | Method for preparing composite nanofiber membrane based on natural material silk fibroin and chitosan |
| CN103120803A (en) * | 2012-12-29 | 2013-05-29 | 钟春燕 | Preparation method of bacterial cellulose composite chitosan moist antimicrobial dressing |
Non-Patent Citations (2)
| Title |
|---|
| JUN JIA: "Preparation and Characterization of Soluble Eggshell Membrane Protein/PLGA Electrospun Nanofibers for Guided Tissue Regeneration Membrane", 《JOURNAL OF NANOMATERIALS》 * |
| 刘更等: "电纺制备PLGA/可溶性蛋壳膜蛋白纤维膜及其性能研究", 《口腔医学》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018100469A (en) * | 2016-12-21 | 2018-06-28 | 国立大学法人信州大学 | Nanofiber, production method of nanofiber, and face mask |
| CN108221082A (en) * | 2016-12-21 | 2018-06-29 | 国立大学法人信州大学 | Nanofiber, the preparation method of nanofiber and facial mask |
Also Published As
| Publication number | Publication date |
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| CN105951303B (en) | 2018-03-02 |
| CN107964735A (en) | 2018-04-27 |
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