CN105949997A - High-anti-fouling coating for exhaust equipment - Google Patents

High-anti-fouling coating for exhaust equipment Download PDF

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Publication number
CN105949997A
CN105949997A CN201610181100.8A CN201610181100A CN105949997A CN 105949997 A CN105949997 A CN 105949997A CN 201610181100 A CN201610181100 A CN 201610181100A CN 105949997 A CN105949997 A CN 105949997A
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Prior art keywords
styrene
coating
chitosan
powder
temperature
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CN201610181100.8A
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Chinese (zh)
Inventor
赵玉霞
苏和堂
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Chuzhou Vocational and Technical College
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Chuzhou Vocational and Technical College
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Priority to CN201610181100.8A priority Critical patent/CN105949997A/en
Publication of CN105949997A publication Critical patent/CN105949997A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1675—Polyorganosiloxane-containing compositions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a high-anti-fouling coating for exhaust equipment. The coating is made from the following raw materials, coal ash, aluminium powder, cuprous oxide, an acrylic resin, a styrene-acrylic emulsion, an organic silicon resin, maleated rosin, acetylene black powder, glycol ether, zinc pyrithione, butyl acetate, triethylamine, triethyl hexyl phosphoric acid, polydimethylsiloxane, styrene, azodiisobutyronitrile, glass powder, chitosan, tetraethoxysilane, pentaerythritol stearate, sodium silicate, zinc nitrate and a proper amount of absolute ethanol. The coating has good waterproof and anti-fouling performance, is easy to clean, and is good in fire retardance. The coating is simple to make, is simple in method, less in equipment input, convenient to apply, and worthy of popularization.

Description

A kind of high antifouling paint of exhaust equipment
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of high antifouling paint of exhaust equipment.
Background technology
The surface of shell of exhaust equipment can be brushed different pigment and guarantee that housing is without damage, the use longevity of extension device Life.Aluminum pigment is widely used in traditional solvent based coating and oil due to its special metallic luster and " changeable colors along with angle " effect Mo Zhong.It is big that it has excellent metallic effect demand, and flake aluminum has good reflection light and the energy of reflective thermal radiation Power, forms continuous print metal film in coating, can reflect visible ray, ultraviolet and infrared ray.Reflection to visible light full spectrum It is silvery white in color so that it is there is good decoration performance, ultrared reflection is made it have the heat-insulating property of reflective thermal radiation, and To the reflection of ultraviolet then can protective coating not by ultraviolet damage, extend the life-span of coating.Due to the performance of pure aluminum own Vivaciously, aluminium powder specific surface area is big, and the most surface treated aluminium powder is easy to reunite, and aluminium powder occurs chemistry anti-with other media Should easily lose original performance.Common aluminium powder pigment easily reacts with water, therefore can not directly use, with acid in water paint again Property or alkaline medium contact time be easily corroded, corrosion can make the glossiness of aluminium powder pigment decline, and color is gloomy, the hydrogen of release The biggest pressure is formed, consequently, it is possible to there is the danger of blast in container.Therefore to adapt to different application demands, improve aluminum The weatherability of powder, widens application, needs aluminium powder is carried out surface modification, makes powder body in preparation process and last handling process In be in high degree of dispersion state, be current aluminium powder pigment research important topic.
Having carried out the research of styrene polymerization cladding aluminium powder in " research of styrene polymerization cladding flake aluminum ", author adopts Being coated with aluminium powder under the system of dehydrated alcohol with refined styrene, result shows along with the increase of monomer consumption, slow Releasing efficiency to be gradually increased, conversion ratio, clad ratio, coating efficiency are had the biggest by the quality of the quality of monomer, consumption and aluminium powder Impact, the quality stability of product is the highest, and the corrosion resistant effect played in coating also needs to improve.The thing that flyash is good Reason, chemical characteristic make it have and well apply potential quality, add flyash and be not only able to strengthen the mobility of coating in coating, The pore structure of system can also be improved, improve the function of coating.The present invention utilizes aluminium powder and flyash to be mixed with high-alumina fly Coal ash microsphere, corrosion-resistant, impact strength, the erosion-wear-resisting performance that play in coating can play the biggest raising, but It is that to be directly added into the compatibility the highest, the combination property of material can be substantially reduced.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of high antifouling paint of exhaust equipment.
The present invention is achieved by the following technical solutions:
A kind of high antifouling paint of exhaust equipment, is made up of the raw material of following weight portion: flyash 20-22, aluminium powder 6-8, Red copper oxide 1-2, acrylic resin 20-25, styrene-acrylic emulsion 10-14, organic siliconresin 65-70, maleic rosin 5-6, acetylene carbon Powder 1.5-2, glycol ether 2-2.5, Zinc Pyrithione 1.5-2, butyl acetate 12-15, triethylamine 2-2.4, triethyl group hexyl phosphorus Acid 0.5-0.7, polydimethylsiloxane 0.5-0.7, styrene 12-14, azodiisobutyronitrile 1.2-1.4, glass dust 0.5- 0.7, chitosan 1.2-1.4, tetraethoxysilane 1.8-2.2, pentaerythritol stearate 0.6-0.8, waterglass 0.3-0.5, Zinc nitrate 2.2-2.6, dehydrated alcohol are appropriate.
Described a kind of high antifouling paint of exhaust equipment, is made up of step in detail below:
(1) flyash is ground to 200-400 mesh, and adds deionized water according to solid-to-liquid ratio 1:3-5 after citric acid mixing, Stirring reaction 1-2h at 50-60 DEG C, dropping ammonia regulation pH value is calcining 2-3h at filtration drying after neutrality, 600-680 DEG C, Natural cooling obtains modified coal ash, is added to chitosan in acetic acid dissolve and makes the chitosan solution that mass concentration is 20-25%, It is added to heat the most while stirring by modified coal ash and glass dust again, until drying；
(2) tetraethoxysilane anhydrous alcohol solution is made the solution that percent mass concentration is 12-15% and put into reactor In, add aluminium powder, zinc nitrate and pentaerythritol stearate mix and blend, liter high-temperature to isothermal reaction 45-when 60-85 DEG C 60min, adds product prepared by step (1) while hot, is stirring evenly and then adding into water glass solution, and then spray drying is ground into micro- Powder；
(3) in equipped with the flask of agitator add step (2) prepare product, dehydrated alcohol, styrene, in the protection of nitrogen Under, start agitator heat make bottle in temperature control, at 70 DEG C, to be slowly added dropwise initiator azo two at this temperature Isopropyl cyanide, then constant temperature keeps this temperature to continue reaction 3-3.5h, and reaction cools down after terminating, reactant mixture methanol extraction, Filtering, filter cake is placed in that to dry, pulverize 300-400 mesh sieve in 50 DEG C of vacuum drying ovens standby；
(4) be sequentially added into acrylic resin in high-speed stirred dispersion machine, prepared by styrene-acrylic emulsion, organic siliconresin, step (3) Product and butyl acetate first stir 6-9min with 400r/min, add triethyl group hexyl phosphoric acid and stir 5-with 1300r/min 8min, is eventually adding polydimethylsiloxane and surplus materials stirs 9-13min with 800r/min, stands 2-after having stirred 5min.
The invention have the advantage that the present invention by its specific surface area of flyash modified raising with contact site, and use modifying agent It is modified improving the performance of the aspects such as its antibacterial, absorption, and utilizes silicon source, zinc source modified to aluminium powder, improve its activity, glue Knot property, and stopped aluminum and be susceptible to the problem of chemical reaction, then use modified aluminium and modified coal ash mixing, with it as core Carry out styrene monomer emulsion cladding so that in coating, play the property of the aspects such as powerful anticorrosive, antipollution, impact resistance Can, and after mixing, clad ratio is high, and effective, improve quality stability, and also efficiently solve single aluminium powder at base Body resin is easily generated the problem of cross-linkable adhesive between trace, unordered polymerization aluminium powder；The coating water-proof that the present invention prepares is antifouling Performance is good, easy to clean, fire retardant performance is strong, easy to make, method is simple, equipment investment is few, easy construction, be easy to coating, It is worthy to be popularized.
Detailed description of the invention
A kind of high antifouling paint of exhaust equipment, is made up of the raw material of following weight portion (kilogram): flyash 20, aluminum Powder 6, Red copper oxide 1, acrylic resin 20, styrene-acrylic emulsion 10, organic siliconresin 65, maleic rosin 5, acetylene carbon dust 1.5, second two Alcohol ether 2, Zinc Pyrithione 1.5, butyl acetate 12, triethylamine 2, triethyl group hexyl phosphoric acid 0.5, polydimethylsiloxane 0.5, benzene Ethylene 12, azodiisobutyronitrile 1.2, glass dust 0.5, chitosan 1.2, tetraethoxysilane 1.8, pentaerythritol stearate 0.6, waterglass 0.3, zinc nitrate 2.2, dehydrated alcohol are appropriate.
Described a kind of high antifouling paint of exhaust equipment, is made up of step in detail below:
(1) flyash is ground to 200 mesh, and add deionized water according to solid-to-liquid ratio 1:3, at 50 DEG C after citric acid mixing Lower stirring reaction 1h, dropping ammonia regulation pH value is filtration drying after neutrality, calcines 2h at 600 DEG C, and natural cooling obtains modified powder Coal ash, is added to chitosan in acetic acid dissolve and makes the chitosan solution that mass concentration is 20%, then by modified coal ash and glass Powder is added to heat the most while stirring, until drying；
(2) tetraethoxysilane anhydrous alcohol solution is made the solution that percent mass concentration is 12% and puts in reactor, Adding aluminium powder, zinc nitrate and pentaerythritol stearate mix and blend, liter high-temperature, to isothermal reaction 45min when 60 DEG C, is taken advantage of Heat adds product prepared by step (1), is stirring evenly and then adding into water glass solution, is then spray-dried and is ground into micropowder；
(3) in equipped with the flask of agitator add step (2) prepare product, dehydrated alcohol, styrene, in the protection of nitrogen Under, start agitator heat make bottle in temperature control, at 70 DEG C, to be slowly added dropwise initiator azo two at this temperature Isopropyl cyanide, then constant temperature keeps this temperature to continue reaction 3h, and reaction cools down after terminating, and reactant mixture methanol extraction filters, Filter cake is placed in that to dry, pulverize 300 mesh sieves in 50 DEG C of vacuum drying ovens standby；
(4) be sequentially added into acrylic resin in high-speed stirred dispersion machine, prepared by styrene-acrylic emulsion, organic siliconresin, step (3) Product and butyl acetate first stir 6min with 400r/min, add triethyl group hexyl phosphoric acid and stir 5min with 1300r/min, Rear addition polydimethylsiloxane and surplus materials thereof stir 9min with 800r/min, stand 2min after having stirred.
This coating artificial ageing resistance 4800 hours, pliability ＞ 1mm, resistance to impact ＞ 50cm, resistance to 30% sulfuric acid solution ＞ 180d, resistance to 30% sodium hydroxide solution ＞ 180d, resistance to 3% sodium chloride solution ＞ 180d, thermostability (heating 80h at 500 DEG C) is without becoming Change, fire resistance >=5 grade.

Claims (2)

1. the high antifouling paint of exhaust equipment, it is characterised in that be made up of the raw material of following weight portion: flyash 20-22, aluminium powder 6-8, Red copper oxide 1-2, acrylic resin 20-25, styrene-acrylic emulsion 10-14, organic siliconresin 65-70, Malaysia Colophonium 5-6, acetylene carbon dust 1.5-2, glycol ether 2-2.5, Zinc Pyrithione 1.5-2, butyl acetate 12-15, triethylamine 2- 2.4, triethyl group hexyl phosphoric acid 0.5-0.7, polydimethylsiloxane 0.5-0.7, styrene 12-14, azodiisobutyronitrile 1.2- 1.4, glass dust 0.5-0.7, chitosan 1.2-1.4, tetraethoxysilane 1.8-2.2, pentaerythritol stearate 0.6-0.8, Waterglass 0.3-0.5, zinc nitrate 2.2-2.6, dehydrated alcohol are appropriate.
A kind of high antifouling paint of exhaust equipment, it is characterised in that prepared by step in detail below Make:
(1) flyash is ground to 200-400 mesh, and adds deionized water according to solid-to-liquid ratio 1:3-5 after citric acid mixing, Stirring reaction 1-2h at 50-60 DEG C, dropping ammonia regulation pH value is calcining 2-3h at filtration drying after neutrality, 600-680 DEG C, Natural cooling obtains modified coal ash, is added to chitosan in acetic acid dissolve and makes the chitosan solution that mass concentration is 20-25%, It is added to heat the most while stirring by modified coal ash and glass dust again, until drying；
(2) tetraethoxysilane anhydrous alcohol solution is made the solution that percent mass concentration is 12-15% and put into reactor In, add aluminium powder, zinc nitrate and pentaerythritol stearate mix and blend, liter high-temperature to isothermal reaction 45-when 60-85 DEG C 60min, adds product prepared by step (1) while hot, is stirring evenly and then adding into water glass solution, and then spray drying is ground into micro- Powder；
(3) in equipped with the flask of agitator add step (2) prepare product, dehydrated alcohol, styrene, in the protection of nitrogen Under, start agitator heat make bottle in temperature control, at 70 DEG C, to be slowly added dropwise initiator azo two at this temperature Isopropyl cyanide, then constant temperature keeps this temperature to continue reaction 3-3.5h, and reaction cools down after terminating, reactant mixture methanol extraction, Filtering, filter cake is placed in that to dry, pulverize 300-400 mesh sieve in 50 DEG C of vacuum drying ovens standby；
(4) be sequentially added into acrylic resin in high-speed stirred dispersion machine, prepared by styrene-acrylic emulsion, organic siliconresin, step (3) Product and butyl acetate first stir 6-9min with 400r/min, add triethyl group hexyl phosphoric acid and stir 5-with 1300r/min 8min, is eventually adding polydimethylsiloxane and surplus materials stirs 9-13min with 800r/min, stands 2-after having stirred 5min.
CN201610181100.8A 2016-03-28 2016-03-28 High-anti-fouling coating for exhaust equipment Withdrawn CN105949997A (en)

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CN201610181100.8A CN105949997A (en) 2016-03-28 2016-03-28 High-anti-fouling coating for exhaust equipment

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108456474A (en) * 2018-03-13 2018-08-28 佛山市飞时达新材料科技有限公司 A kind of preparation method and applications of exterior wall antifouling paint
CN118240434A (en) * 2024-03-01 2024-06-25 中铁建工集团有限公司 Fly ash-chitosan composite modified intumescent fireproof coating and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103773318A (en) * 2012-10-24 2014-05-07 中国石油化工股份有限公司 Preparation method of phase-change energy-storage material
CN105238158A (en) * 2015-09-22 2016-01-13 安徽皖东化工有限公司 Compound super-hydrophobic marine coating and manufacturing method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103773318A (en) * 2012-10-24 2014-05-07 中国石油化工股份有限公司 Preparation method of phase-change energy-storage material
CN105238158A (en) * 2015-09-22 2016-01-13 安徽皖东化工有限公司 Compound super-hydrophobic marine coating and manufacturing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈子路: "苯乙烯聚合包覆片状铝粉的研究", 《中国优秀硕士学位论文全文数据库（电子期刊），工程科技第Ⅰ辑》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108456474A (en) * 2018-03-13 2018-08-28 佛山市飞时达新材料科技有限公司 A kind of preparation method and applications of exterior wall antifouling paint
CN118240434A (en) * 2024-03-01 2024-06-25 中铁建工集团有限公司 Fly ash-chitosan composite modified intumescent fireproof coating and preparation method thereof

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