CN105949939A - Acid-and-alkali-resistant coating for exhaust equipment - Google Patents

Acid-and-alkali-resistant coating for exhaust equipment Download PDF

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Publication number
CN105949939A
CN105949939A CN201610181098.4A CN201610181098A CN105949939A CN 105949939 A CN105949939 A CN 105949939A CN 201610181098 A CN201610181098 A CN 201610181098A CN 105949939 A CN105949939 A CN 105949939A
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acid
resistance
coating
alkali
aluminium powder
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CN201610181098.4A
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苏和堂
赵玉霞
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Chuzhou Vocational and Technical College
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Chuzhou Vocational and Technical College
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an acid-and-alkali-resistant coating for exhaust equipment. The coating is made from the following raw materials: a siloxane acrylic resin, itaconic acid, polysiloxane, polyacrylamide, bisphenol A epoxy resin, dibutyl phthalate, glass flakes, nanometer silicon carbide, paraffin wax, butyl acetate, diethylenetriamine, coal ash, titanium dioxide, aluminium powder, styrene, azodiisobutyronitrile, sodium lignosulfonate, benzotriazol, duanbaifen, hydroxy propyl cellulose, ethylene bis stearamide, calcium molybdate, polyacrylamide, polyether triol and a proper amount of absolute ethanol. The coating has excellent acid and alkali resistance, water resistance, impact resistance, wear resistance and flame retardance. The coating is high in adhesive force, good in high-temperature resistance and aging resistance, simple in manufacturing method, and worthy of popularization.

Description

A kind of exhaust equipment acid and alkali-resistance coating
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of exhaust equipment acid and alkali-resistance coating.
Background technology
The surface of shell of exhaust equipment can be brushed different pigment and guarantee that housing is without damage, the use longevity of extension device Life.Aluminum pigment is widely used in traditional solvent based coating and oil due to its special metallic luster and " changeable colors along with angle " effect Mo Zhong.It is big that it has excellent metallic effect demand, and flake aluminum has good reflection light and the energy of reflective thermal radiation Power, forms continuous print metal film in coating, can reflect visible ray, ultraviolet and infrared ray.Reflection to visible light full spectrum It is silvery white in color so that it is there is good decoration performance, ultrared reflection is made it have the heat-insulating property of reflective thermal radiation, and To the reflection of ultraviolet then can protective coating not by ultraviolet damage, extend the life-span of coating.Due to the performance of pure aluminum own Vivaciously, aluminium powder specific surface area is big, and the most surface treated aluminium powder is easy to reunite, and aluminium powder occurs chemistry anti-with other media Should easily lose original performance.Common aluminium powder pigment easily reacts with water, therefore can not directly use, with acid in water paint again Property or alkaline medium contact time be easily corroded, corrosion can make the glossiness of aluminium powder pigment decline, and color is gloomy, the hydrogen of release The biggest pressure is formed, consequently, it is possible to there is the danger of blast in container.Therefore to adapt to different application demands, improve aluminum The weatherability of powder, widens application, needs aluminium powder is carried out surface modification, makes powder body in preparation process and last handling process In be in high degree of dispersion state, be current aluminium powder pigment research important topic.
Having carried out the research of styrene polymerization cladding aluminium powder in " research of styrene polymerization cladding flake aluminum ", author adopts Being coated with aluminium powder under the system of dehydrated alcohol with refined styrene, result shows along with the increase of monomer consumption, slow Releasing efficiency to be gradually increased, conversion ratio, clad ratio, coating efficiency are had the biggest by the quality of the quality of monomer, consumption and aluminium powder Impact, the quality stability of product is the highest, and the corrosion resistant effect played in coating also needs to improve.The thing that flyash is good Reason, chemical characteristic make it have and well apply potential quality, add flyash and be not only able to strengthen the mobility of coating in coating, The pore structure of system can also be improved, improve the function of coating.The present invention utilizes aluminium powder and flyash to be mixed with high-alumina fly Coal ash microsphere, corrosion-resistant, impact strength, the erosion-wear-resisting performance that play in coating can play the biggest raising, but It is that to be directly added into the compatibility the highest, the combination property of material can be substantially reduced.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of exhaust equipment acid and alkali-resistance coating.
The present invention is achieved by the following technical solutions:
A kind of exhaust equipment acid and alkali-resistance coating, is made up of the raw material of following weight portion: silicone acrylic resin 25- 30, itaconic acid 2-3, polysiloxanes 0.6-1, poly-propionic acid amide. 1-2, bisphenol A epoxide resin 70-75, dibutyl phthalate 4- 5, glass flake 5-6, nanometer silicon carbide 2.5-3, paraffin 2-3, butyl acetate 10-12, diethylenetriamine 2.4-3, flyash 22- 25, titanium dioxide 6-8, aluminium powder 7-9, styrene 12-14, azodiisobutyronitrile 1.2-1.4, sodium lignin sulfonate 0.2-0.3, benzo Triazole 0.6-0.8, forging white lead 3.5-4, hydroxypropyl cellulose 0.2-0.3, vinyl double stearic amide 0.3-0.4, molybdic acid Calcium 1.5-2, polyacrylamide 0.4-0.6, trihydroxy polyethers 0.5-0.7, dehydrated alcohol are appropriate.
Described a kind of exhaust equipment acid and alkali-resistance coating, is made up of step in detail below:
(1) by coal-ash immersion 15-18h in the sodium hydroxide solution of 20-25%, after dropping dilute hydrochloric acid regulation pH value is neutrality Filter, at 580-620 DEG C, calcine 2-3h after cleaning several times with deionized water, pulverize standby after cooling;By hydroxypropyl cellulose Stearic amide mixing double with vinyl are added in deionized water, are heated to 80-85 DEG C while stirring, are stirring evenly and then adding into molybdenum Acid calcium, polyacrylamide and trihydroxy polyethers high speed shear, then add standby flyash and continue stirring;
(2) by sodium lignin sulfonate, aluminium powder, BTA and forging white lead grinding distribution in mortar, spray into after being uniformly dispersed Mass concentration is 0.5% sodium stearate solution, is then added in the product of step (1) common mix and blend, is spray-dried;
(3) in equipped with the flask of agitator add step (2) prepare product, dehydrated alcohol, styrene, in the protection of nitrogen Under, start agitator heat make bottle in temperature control, at 70 DEG C, to be slowly added dropwise initiator azo two at this temperature Isopropyl cyanide, then constant temperature keeps this temperature to continue reaction 3-3.5h, and reaction cools down after terminating, reactant mixture methanol extraction, Filtering, filter cake is placed in that to dry, pulverize 300-400 mesh sieve in 50 DEG C of vacuum drying ovens standby;
(4) be sequentially added into bisphenol A epoxide resin in high-speed stirred dispersion machine, prepared by silicone acrylic resin, step (3) Product and butyl acetate first stir 8-12min with 500r/min, add poly-propionic acid amide. and stir 15-18min with 1300r/min, It is eventually adding polysiloxanes and surplus materials stirs 10-15min with 500-800r/min, stand 4-6min after having stirred i.e. Can.
The invention have the advantage that the present invention utilizes caustic corrosion flyash to improve its adsorption capacity, made by modifier modification Flyash surface introduces organic group and improves its cohesive, compatibility etc., and aluminium powder is by improve with unclassified stores is mixed and modified Corrosion-resistant, uvioresistant and glossiness, and reduce aluminum surface and easily occur chemical reaction to obtain problem, by both mixing with it as core Carry out styrene monomer emulsion cladding so that clad ratio is high, effective, improves dispersibility, permeability in resin matrix, has Effect solving aluminium powder is easily generated the problem of cross-linkable adhesive between trace, unordered polymerization aluminium powder in matrix resin so that be coated with Material plays excellent anticorrosion protective action;The coating that the present invention provides have well acid and alkali-resistance, water-fast, impact resistance, wear-resisting, Fire-retardant character, adhesive force of the present invention is high and high temperature resistant, ageing resistance is good, and preparation method is simple, is worthy to be popularized.
Detailed description of the invention
A kind of exhaust equipment acid and alkali-resistance coating, is made up of the raw material of following weight portion (kilogram): siloxanes propylene Acid resin 25, itaconic acid 2, polysiloxanes 0.6, poly-propionic acid amide. 1, bisphenol A epoxide resin 70, dibutyl phthalate 4, glass Scale 5, nanometer silicon carbide 2.5, paraffin 2, butyl acetate 10, diethylenetriamine 2.4, flyash 22, titanium dioxide 6, aluminium powder 7, benzene Ethylene 12, azodiisobutyronitrile 1.2, sodium lignin sulfonate 0.2, BTA 0.6, forging white lead 3.5, hydroxypropyl cellulose 0.2, the double stearic amide 0.3 of vinyl, calcium molybdate 1.5, polyacrylamide 0.4, trihydroxy polyethers 0.5, dehydrated alcohol are appropriate.
Described a kind of exhaust equipment acid and alkali-resistance coating, is made up of step in detail below:
(1) by coal-ash immersion 15h in the sodium hydroxide solution of 20%, dropping dilute hydrochloric acid regulation pH value is filtration after neutrality, uses Deionized water calcines 2h after cleaning several times at 580 DEG C, pulverizes standby after cooling;By double to hydroxypropyl cellulose and vinyl stearic Acid amide mixing be added in deionized water, be heated to 80 DEG C while stirring, be stirring evenly and then adding into calcium molybdate, polyacrylamide and Trihydroxy polyethers high speed shear, then adds standby flyash and continues stirring;
(2) by sodium lignin sulfonate, aluminium powder, BTA and forging white lead grinding distribution in mortar, spray into after being uniformly dispersed Mass concentration is 0.5% sodium stearate solution, is then added in the product of step (1) common mix and blend, is spray-dried;
(3) in equipped with the flask of agitator add step (2) prepare product, dehydrated alcohol, styrene, in the protection of nitrogen Under, start agitator heat make bottle in temperature control, at 70 DEG C, to be slowly added dropwise initiator azo two at this temperature Isopropyl cyanide, then constant temperature keeps this temperature to continue reaction 3h, and reaction cools down after terminating, and reactant mixture methanol extraction filters, Filter cake is placed in that to dry, pulverize 300 mesh sieves in 50 DEG C of vacuum drying ovens standby;
(4) be sequentially added into bisphenol A epoxide resin in high-speed stirred dispersion machine, prepared by silicone acrylic resin, step (3) Product and butyl acetate first stir 8min with 500r/min, add poly-propionic acid amide. and stir 15min with 1300r/min, finally add Enter polysiloxanes and surplus materials stirs 10min with 500r/min, after having stirred, stand 4min.
This coating artificial ageing resistance 4800 hours, pliability > 1mm, resistance to impact > 60cm, resistance to 30% sulfuric acid solution > 180d, resistance to 30% sodium hydroxide solution > 180d, resistance to 3% sodium chloride solution > 180d, thermostability (heating 80h at 500 DEG C) is without becoming Change, fire resistance >=4 grade.

Claims (2)

1. an exhaust equipment acid and alkali-resistance coating, it is characterised in that be made up of the raw material of following weight portion: siloxanes third Olefin(e) acid resin 25-30, itaconic acid 2-3, polysiloxanes 0.6-1, poly-propionic acid amide. 1-2, bisphenol A epoxide resin 70-75, O-phthalic Dibutyl phthalate 4-5, glass flake 5-6, nanometer silicon carbide 2.5-3, paraffin 2-3, butyl acetate 10-12, diethylenetriamine 2.4- 3, flyash 22-25, titanium dioxide 6-8, aluminium powder 7-9, styrene 12-14, azodiisobutyronitrile 1.2-1.4, sodium lignin sulfonate 0.2-0.3, BTA 0.6-0.8, forging white lead 3.5-4, hydroxypropyl cellulose 0.2-0.3, the double stearic amide of vinyl 0.3-0.4, calcium molybdate 1.5-2, polyacrylamide 0.4-0.6, trihydroxy polyethers 0.5-0.7, dehydrated alcohol are appropriate.
A kind of exhaust equipment acid and alkali-resistance coating, it is characterised in that prepared by step in detail below Make:
(1) by coal-ash immersion 15-18h in the sodium hydroxide solution of 20-25%, after dropping dilute hydrochloric acid regulation pH value is neutrality Filter, at 580-620 DEG C, calcine 2-3h after cleaning several times with deionized water, pulverize standby after cooling;By hydroxypropyl cellulose Stearic amide mixing double with vinyl are added in deionized water, are heated to 80-85 DEG C while stirring, are stirring evenly and then adding into molybdenum Acid calcium, polyacrylamide and trihydroxy polyethers high speed shear, then add standby flyash and continue stirring;
(2) by sodium lignin sulfonate, aluminium powder, BTA and forging white lead grinding distribution in mortar, spray into after being uniformly dispersed Mass concentration is 0.5% sodium stearate solution, is then added in the product of step (1) common mix and blend, is spray-dried;
(3) in equipped with the flask of agitator add step (2) prepare product, dehydrated alcohol, styrene, in the protection of nitrogen Under, start agitator heat make bottle in temperature control, at 70 DEG C, to be slowly added dropwise initiator azo two at this temperature Isopropyl cyanide, then constant temperature keeps this temperature to continue reaction 3-3.5h, and reaction cools down after terminating, reactant mixture methanol extraction, Filtering, filter cake is placed in that to dry, pulverize 300-400 mesh sieve in 50 DEG C of vacuum drying ovens standby;
(4) be sequentially added into bisphenol A epoxide resin in high-speed stirred dispersion machine, prepared by silicone acrylic resin, step (3) Product and butyl acetate first stir 8-12min with 500r/min, add poly-propionic acid amide. and stir 15-18min with 1300r/min, It is eventually adding polysiloxanes and surplus materials stirs 10-15min with 500-800r/min, stand 4-6min after having stirred i.e. Can.
CN201610181098.4A 2016-03-28 2016-03-28 Acid-and-alkali-resistant coating for exhaust equipment Withdrawn CN105949939A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964325A (en) * 2017-10-09 2018-04-27 江苏海晟涂料有限公司 A kind of wear-resisting ship coating of impact resistance and preparation method thereof
CN117946579A (en) * 2024-02-04 2024-04-30 深圳市朗迈新材料科技有限公司 Waterborne polyurethane anti-slip floor coating and preparation method thereof

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1152012A (en) * 1995-12-15 1997-06-18 中国人民解放军海军后勤技术装备研究所 Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint
CN104910587A (en) * 2015-06-16 2015-09-16 陕西理工学院 Preparation method for epoxy resin composite material added with modified fly ash

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1152012A (en) * 1995-12-15 1997-06-18 中国人民解放军海军后勤技术装备研究所 Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint
CN104910587A (en) * 2015-06-16 2015-09-16 陕西理工学院 Preparation method for epoxy resin composite material added with modified fly ash

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张学敏等: "《涂料与涂装技术》", 31 January 2006, 化学工业出版社 *
陈子路: "苯乙烯聚合包覆片状铝粉的研究", 《中国优秀硕士学位论文全文数据库(电子期刊),工程科技第Ⅰ辑》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964325A (en) * 2017-10-09 2018-04-27 江苏海晟涂料有限公司 A kind of wear-resisting ship coating of impact resistance and preparation method thereof
CN117946579A (en) * 2024-02-04 2024-04-30 深圳市朗迈新材料科技有限公司 Waterborne polyurethane anti-slip floor coating and preparation method thereof

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