CN105949837A - Phosphorus and zinc antirust coating for metal - Google Patents

Phosphorus and zinc antirust coating for metal Download PDF

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Publication number
CN105949837A
CN105949837A CN201610578807.2A CN201610578807A CN105949837A CN 105949837 A CN105949837 A CN 105949837A CN 201610578807 A CN201610578807 A CN 201610578807A CN 105949837 A CN105949837 A CN 105949837A
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parts
zinc
deionized water
styrene
barium sulfate
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CN201610578807.2A
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Chinese (zh)
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董芬芳
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a phosphorus and zinc antirust coating for metal. The coating is prepared from deionized water, zinc phosphate, chromic oxide, barium sulfate, talcum powder, styrene, methyl methacrylate, butyl acylate, dimethyl dichlorosilane and ammonium persulfate; the coating is free of precipitation, flash rusting and rerusting, long in storage period, flame retardant and resistant to acid and alkali, and the viscosity ranges from 70 s to 90 s; adhesive force is the first grade, salt-fog resistance is achieved within 15 d to 35 d without the anomaly, and water resistance is achieved within 20 d to 40 d without blistering and disengaging; salt water resistance is achieved within 10 d to 30 d without the anomaly, surface drying is achieved within 3 h to 7 h, and practical drying is achieved within 14 h to 18 h. The reparation method is simple, the raw materials are simple and easy to obtain, and the coating can be widely produced and continuously replace existing materials.

Description

A kind of metal phosphorus zinc antirusting paint
Technical field
The present invention relates to metal field of material technology, particularly relate to a kind of metal phosphorus zinc antirust Coating.
Background technology
Air, the chemistry of sea deionized water etc. or electrochemical corrosion can be protected metal surfaces from Coating.Coat antirusting paint in metal surface and can effectively avoid various corrosive goodses in air The directly invasion of matter so that maximized prolongation metal useful life.Physical property and change can be divided into The property the learned big class of antirust paint two.The former, by pigment and the suitable cooperation of paint vehicle, forms fine and close paint film To stop the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint etc.;The latter is by anti- The chemistry of rust pigment presses down rust effect, such as Plumbum preparatium, zinc chromate anti-rust paint etc..For bridge, boats and ships, The metals such as pipeline antirust.It is applicable to kitchen, toilet, balcony, basement, deionized water Pond, balcony swimming pool, warehouse, tunnel, timber floor be moistureproof and ground warms up anti-deionized water with With the Imitation Rock Porcelain Tiles of various suction amount of deionized water and the stickup floor wall of deionization cement basic layer and The floor anti-deionized water of specialty processes.
The antirust paint substantially oily antirust varniss used and deionization aqueous antirust paint two kinds.Oiliness Antirust paint makes material surface greasy removal difficulty, is rarely employed.Oily antirust varniss is easy to use, Cheap, but because containing the noxious substance such as nitrite, chromate, operator being endangered Relatively big, country has limited use, and these type of properties of product are single, it is impossible to meet magnetic alloy material The antirust requirement of material.It is applicable to the antirust of ferrous and nonferrous metals.
Physics rust resisting pigment is the pigment that an own chemical property of class is relatively stable, and they are by this The physical property of body, stable chemical performance, quality is hard, and granule is trickle, excellent fillibility, carries The consistency of high paint film, reduces the permeable of paint film thus plays antirust effect. dimethyl two Chlorosilane just belongs to this kind of material. and the rust-preventing characteristic of metallic aluminium powder is owing to aluminium powder has flakey knot Structure, forms paint film tight, also has the ability of stronger uv reflectance light, can improve paint film anti-ageing The ability changed.Deionized water dissolubility, non-combustible, environmentally safe, use safety.
Due to unique formula design, this product has the strongest penetrating power, can the most effective watt Solve greasy dirt common on metal surface, and convert it into one layer of tool while corrosion being decomposed There is the metal protective film of anti-corrosion performance, thus reach excellent phosphorus zinc and rust-proof effect.Extensively use In various indoor and outdoor steel surface Coating Pretreatment, bridge pipe-line maintenance, architectural engineering, boats and ships Build, the field such as machining manufacture, steel and iron parts are deposited.Industry, family all can use.
Coating, at the entitled paint of Chinese tradition.So-called coating is to be coated in be protected or filled The body surface of decorations, and can be with the continuous film of coated article formation firm attachment, it is common that with tree Fat or oil or emulsion are main, add or without pigment, filler, add corresponding additive, With the formulated thick liquid of organic solvent or water." the coating that China's coating circle is more authoritative Technique " book is defined such that " coating is a kind of material, and this material can be by difference Construction technology be coated in object surface, formed and adhere to firmly, there is some strength, continuous print Solid film.The film common name film so formed, also known as paint film or coating.”
Summary of the invention
The present invention provides the metal phosphorus zinc antirusting paint of a kind of fast drying, good salt tolerance, solves Existing metal material is dried the slow and not technical problem such as salt spray resistance.
The present invention is by the following technical solutions: a kind of metal phosphorus zinc antirusting paint, its raw material is pressed Mass fraction proportioning is as follows: deionized water 100 parts, zinc phosphate 2-6 part, chromic oxide 1-5 part, barium sulfate 3-7 part, Pulvis Talci 4-8 part, styrene 30-50 part, metering system Acid methyl ester 5-25 part, butyl acrylate 5-9 part, dimethyldichlorosilane 20-40 part, mistake Ammonium sulfate 4-8 part.
As a preferred technical solution of the present invention: described metal phosphorus zinc antirusting paint former It is as follows that mass fraction proportioning pressed by material: deionized water 100 parts, zinc phosphate 3-5 part, three oxidations two Chromium 2-4 part, barium sulfate 4-6 part, Pulvis Talci 5-7 part, styrene 35-45 part, methyl-prop E pioic acid methyl ester 10-20 part, butyl acrylate 6-8 part, dimethyldichlorosilane 25-35 part, Ammonium persulfate. 5-7 part.
As a preferred technical solution of the present invention: described metal phosphorus zinc antirusting paint former It is as follows that mass fraction proportioning pressed by material: deionized water 100 parts, zinc phosphate 3 parts, chromic oxide 2 parts, 4 parts of barium sulfate, Pulvis Talci 5 parts, styrene 35 parts, methyl methacrylate 10 Part, butyl acrylate 6 parts, dimethyldichlorosilane 25 parts, Ammonium persulfate. 5 parts.
As a preferred technical solution of the present invention: described metal phosphorus zinc antirusting paint former It is as follows that mass fraction proportioning pressed by material: deionized water 100 parts, zinc phosphate 5 parts, chromic oxide 4 parts, 6 parts of barium sulfate, Pulvis Talci 7 parts, styrene 45 parts, methyl methacrylate 20 Part, butyl acrylate 8 parts, dimethyldichlorosilane 35 parts, Ammonium persulfate. 7 parts.
As a preferred technical solution of the present invention: described metal phosphorus zinc antirusting paint former It is as follows that mass fraction proportioning pressed by material: deionized water 100 parts, zinc phosphate 4 parts, chromic oxide 3 parts, 5 parts of barium sulfate, Pulvis Talci 6 parts, styrene 40 parts, methyl methacrylate 15 Part, butyl acrylate 7 parts, dimethyldichlorosilane 30 parts, Ammonium persulfate. 6 parts.
Beneficial effect
A kind of metal phosphorus zinc antirusting paint of the present invention uses above technical scheme with existing Technology is compared, and has following technical effect that 1, does not precipitates, does not dodge rust, does not return rust, protects storage Phase length, fire-retardant and acid-alkali-corrosive-resisting, viscosity 70-90s;2, adhesive force one-level, salt spray resistance 15-35d Without exception, resistance to water 20-40d is non-foaming, do not fall off;3, resistance to salt water 10-30d is as good as Often, surface drying 3-7h, do solid work 14-18h, preparation method is simple, and raw material is simple and easy to get, permissible Current material is replaced in the widespread production not division of history into periods.
Detailed description of the invention
Below in conjunction with example, the invention will be further described, and embodiment is only used for the present invention Illustrating, be not intended that the restriction to right, those skilled in the art can think Other alternative means arrived, the most within the scope of the invention as claimed.
Embodiment 1:
The first step: weigh deionized water 100 parts according to mass fraction proportioning, zinc phosphate 2 parts, Chromic oxide 1 part, 3 parts of barium sulfate, Pulvis Talci 4 parts, styrene 30 parts, methyl-prop E pioic acid methyl ester 5 parts, butyl acrylate 5 parts, dimethyldichlorosilane 20 parts, Ammonium persulfate. 4 parts.
Second step: deionized water, zinc phosphate, chromic oxide, barium sulfate and styrene are thrown Enter in reactor, be heated to 45 DEG C, stir 60min with 200r/min speed.
3rd step: the liquid after stirring stands 15min, adds Pulvis Talci, methyl-prop E pioic acid methyl ester, butyl acrylate, dimethyldichlorosilane and Ammonium persulfate., 65 DEG C of mixing Put into grinder after uniformly and grind 4h, pack after filtration.
Do not precipitate, do not dodge rust, do not return rust, guarantor storage period length, fire-retardant and acid-alkali-corrosive-resisting, viscosity 70s;Adhesive force one-level, salt spray resistance 15d is without exception, and resistance to water 20d is non-foaming, do not fall off; Resistance to salt water 10d is without exception, surface drying 7h, does solid work 18h, and preparation method is simple, and raw material is simple It is easy to get, can be with the widespread production not division of history into periods for current material.
Embodiment 2:
The first step: weigh deionized water 100 parts according to mass fraction proportioning, zinc phosphate 6 parts, Chromic oxide 5 parts, 7 parts of barium sulfate, Pulvis Talci 8 parts, styrene 50 parts, methyl-prop E pioic acid methyl ester 25 parts, butyl acrylate 9 parts, dimethyldichlorosilane 40 parts, Ammonium persulfate. 8 parts.
Second step: deionized water, zinc phosphate, chromic oxide, barium sulfate and styrene are thrown Enter in reactor, be heated to 65 DEG C, stir 80min with 400r/min speed.
3rd step: the liquid after stirring stands 35min, adds Pulvis Talci, methyl-prop E pioic acid methyl ester, butyl acrylate, dimethyldichlorosilane and Ammonium persulfate., 85 DEG C of mixing Put into grinder after uniformly and grind 6h, pack after filtration.
Do not precipitate, do not dodge rust, do not return rust, guarantor storage period length, fire-retardant and acid-alkali-corrosive-resisting, viscosity 75s;Adhesive force one-level, salt spray resistance 20d is without exception, and resistance to water 25d is non-foaming, do not fall off; Resistance to salt water 15d is without exception, surface drying 6h, does solid work 17h, and preparation method is simple, and raw material is simple It is easy to get, can be with the widespread production not division of history into periods for current material.
Embodiment 3:
The first step: weigh deionized water 100 parts according to mass fraction proportioning, zinc phosphate 3 parts, Chromic oxide 2 parts, 4 parts of barium sulfate, Pulvis Talci 5 parts, styrene 35 parts, methyl-prop E pioic acid methyl ester 10 parts, butyl acrylate 6 parts, dimethyldichlorosilane 25 parts, Ammonium persulfate. 5 parts.
Second step: deionized water, zinc phosphate, chromic oxide, barium sulfate and styrene are thrown Enter in reactor, be heated to 45 DEG C, stir 60min with 200r/min speed.
3rd step: the liquid after stirring stands 15min, adds Pulvis Talci, methyl-prop E pioic acid methyl ester, butyl acrylate, dimethyldichlorosilane and Ammonium persulfate., 65 DEG C of mixing Put into grinder after uniformly and grind 4h, pack after filtration.
Do not precipitate, do not dodge rust, do not return rust, guarantor storage period length, fire-retardant and acid-alkali-corrosive-resisting, viscosity 80s;Adhesive force one-level, salt spray resistance 25d is without exception, and resistance to water 30d is non-foaming, do not fall off; Resistance to salt water 20d is without exception, surface drying 5h, does solid work 16h, and preparation method is simple, and raw material is simple It is easy to get, can be with the widespread production not division of history into periods for current material.
Embodiment 4:
The first step: weigh deionized water 100 parts according to mass fraction proportioning, zinc phosphate 5 parts, Chromic oxide 4 parts, 6 parts of barium sulfate, Pulvis Talci 7 parts, styrene 45 parts, methyl-prop E pioic acid methyl ester 20 parts, butyl acrylate 8 parts, dimethyldichlorosilane 35 parts, Ammonium persulfate. 7 parts.
Second step: deionized water, zinc phosphate, chromic oxide, barium sulfate and styrene are thrown Enter in reactor, be heated to 65 DEG C, stir 80min with 400r/min speed.
3rd step: the liquid after stirring stands 35min, adds Pulvis Talci, methyl-prop E pioic acid methyl ester, butyl acrylate, dimethyldichlorosilane and Ammonium persulfate., 85 DEG C of mixing Put into grinder after uniformly and grind 6h, pack after filtration.
Do not precipitate, do not dodge rust, do not return rust, guarantor storage period length, fire-retardant and acid-alkali-corrosive-resisting, viscosity 85s;Adhesive force one-level, salt spray resistance 30d is without exception, and resistance to water 35d is non-foaming, do not fall off; Resistance to salt water 25d is without exception, surface drying 4h, does solid work 15h, and preparation method is simple, and raw material is simple It is easy to get, can be with the widespread production not division of history into periods for current material.
Embodiment 5:
The first step: weigh deionized water 100 parts according to mass fraction proportioning, zinc phosphate 4 parts, Chromic oxide 3 parts, 5 parts of barium sulfate, Pulvis Talci 6 parts, styrene 40 parts, methyl-prop E pioic acid methyl ester 15 parts, butyl acrylate 7 parts, dimethyldichlorosilane 30 parts, Ammonium persulfate. 6 parts.
Second step: deionized water, zinc phosphate, chromic oxide, barium sulfate and styrene are thrown Enter in reactor, be heated to 55 DEG C, stir 70min with 300r/min speed.
3rd step: the liquid after stirring stands 25min, adds Pulvis Talci, methyl-prop E pioic acid methyl ester, butyl acrylate, dimethyldichlorosilane and Ammonium persulfate., 75 DEG C of mixing Put into grinder after uniformly and grind 5h, pack after filtration.
Do not precipitate, do not dodge rust, do not return rust, guarantor storage period length, fire-retardant and acid-alkali-corrosive-resisting, viscosity 90s;Adhesive force one-level, salt spray resistance 35d is without exception, and resistance to water 40d is non-foaming, do not fall off; Resistance to salt water 30d is without exception, surface drying 3h, does solid work 14h, and preparation method is simple, and raw material is simple It is easy to get, can be with the widespread production not division of history into periods for current material.

Claims (5)

1. a metal phosphorus zinc antirusting paint, it is characterised in that described metal phosphorus zinc is prevented It is as follows that mass fraction proportioning pressed by the raw material of rust coating: deionized water 100 parts, zinc phosphate 2-6 part, Chromic oxide 1-5 part, barium sulfate 3-7 part, Pulvis Talci 4-8 part, styrene 30-50 part, Methyl methacrylate 5-25 part, butyl acrylate 5-9 part, dimethyldichlorosilane 20-40 Part, Ammonium persulfate. 4-8 part.
A kind of metal phosphorus zinc antirusting paint the most according to claim 1, its feature exists In, it is as follows that mass fraction proportioning pressed by the raw material of described metal phosphorus zinc antirusting paint: deionized water 100 parts, zinc phosphate 3-5 part, chromic oxide 2-4 part, barium sulfate 4-6 part, Pulvis Talci 5-7 part, styrene 35-45 part, methyl methacrylate 10-20 part, butyl acrylate 6-8 Part, dimethyldichlorosilane 25-35 part, Ammonium persulfate. 5-7 part.
A kind of metal phosphorus zinc antirusting paint the most according to claim 1, its feature exists In, it is as follows that mass fraction proportioning pressed by the raw material of described metal phosphorus zinc antirusting paint: deionized water 100 parts, zinc phosphate 3 parts, chromic oxide 2 parts, 4 parts of barium sulfate, Pulvis Talci 5 parts, Styrene 35 parts, methyl methacrylate 10 parts, butyl acrylate 6 parts, dimethyl dichloro 25 parts of silane, Ammonium persulfate. 5 parts.
A kind of metal phosphorus zinc antirusting paint the most according to claim 2, its feature exists In, it is as follows that mass fraction proportioning pressed by the raw material of described metal phosphorus zinc antirusting paint: deionized water 100 parts, zinc phosphate 5 parts, chromic oxide 4 parts, 6 parts of barium sulfate, Pulvis Talci 7 parts, Styrene 45 parts, methyl methacrylate 20 parts, butyl acrylate 8 parts, dimethyl dichloro 35 parts of silane, Ammonium persulfate. 7 parts.
A kind of metal phosphorus zinc antirusting paint the most according to claim 1, its feature exists In: it is as follows that mass fraction proportioning pressed by the raw material of described metal phosphorus zinc antirusting paint: deionized water 100 parts, zinc phosphate 4 parts, chromic oxide 3 parts, 5 parts of barium sulfate, Pulvis Talci 6 parts, Styrene 40 parts, methyl methacrylate 15 parts, butyl acrylate 7 parts, dimethyl dichloro 30 parts of silane, Ammonium persulfate. 6 parts.
CN201610578807.2A 2016-07-19 2016-07-19 Phosphorus and zinc antirust coating for metal Pending CN105949837A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752630A (en) * 2016-12-16 2017-05-31 盐城工学院 A kind of steel rust prevention coating and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1472263A (en) * 2003-05-08 2004-02-04 同济大学 Steel-structure anti-corrosion coating and preparing mehtod thereof
CN102245807A (en) * 2008-12-16 2011-11-16 日本帕卡濑精株式会社 Surface treating agent for galvanized steel sheet
CN102559010A (en) * 2011-12-26 2012-07-11 海洋化工研究院 Chromium-free waterborne epoxy anticorrosion primer with excellent solvent oil resistant performance
CN104877487A (en) * 2015-05-20 2015-09-02 苏州市贝克生物科技有限公司 Medical waterproof corrosion-resistant anti-rusting coating and preparation method thereof
CN104927425A (en) * 2015-06-30 2015-09-23 苏州乔纳森新材料科技有限公司 Medical rust-removal and antirust paint and preparation method therefor

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Publication number Priority date Publication date Assignee Title
CN1472263A (en) * 2003-05-08 2004-02-04 同济大学 Steel-structure anti-corrosion coating and preparing mehtod thereof
CN102245807A (en) * 2008-12-16 2011-11-16 日本帕卡濑精株式会社 Surface treating agent for galvanized steel sheet
CN102559010A (en) * 2011-12-26 2012-07-11 海洋化工研究院 Chromium-free waterborne epoxy anticorrosion primer with excellent solvent oil resistant performance
CN104877487A (en) * 2015-05-20 2015-09-02 苏州市贝克生物科技有限公司 Medical waterproof corrosion-resistant anti-rusting coating and preparation method thereof
CN104927425A (en) * 2015-06-30 2015-09-23 苏州乔纳森新材料科技有限公司 Medical rust-removal and antirust paint and preparation method therefor

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752630A (en) * 2016-12-16 2017-05-31 盐城工学院 A kind of steel rust prevention coating and preparation method thereof

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Application publication date: 20160921