CN105949825A - Preparation method of coating for exterior walls of buildings on tropic island - Google Patents

Preparation method of coating for exterior walls of buildings on tropic island Download PDF

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Publication number
CN105949825A
CN105949825A CN201610310846.4A CN201610310846A CN105949825A CN 105949825 A CN105949825 A CN 105949825A CN 201610310846 A CN201610310846 A CN 201610310846A CN 105949825 A CN105949825 A CN 105949825A
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preparation
minutes
mass parts
add
mass
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CN105949825B (en
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代少俊
蒋伟丽
侯贵华
许宁
张峰
张勤芳
姜瑞雨
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Yangcheng Institute of Technology
Yancheng Institute of Technology
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Yangcheng Institute of Technology
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/28Glass
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

Abstract

The invention provides a preparation method of coating for exterior walls of buildings on a tropic island. The preparation method is characterized by comprising steps as follows: inorganic filler and filler with a thermal insulation function are mixed with a certain amount of water, stirred for 6-15 minutes, then mixed with a coalescing agent and a film forming material, supplemented with water and ground for 20-40 minutes, and the coating is obtained. The coating is prepared from the raw materials in percentage by mass as follows: 30%-40% of the film forming material, 5%-20% of the filler with the thermal insulation function, 1%-5% of the coalescing agent, 10%-20% of the inorganic filler and the balance of deionized water.

Description

A kind of preparation method of torrid zone islands and reefs building external paint
Technical field
Belong to building coating technical field, be specifically related to the preparation method of a kind of torrid zone islands and reefs building external paint.
Background technology
Torrid zone islands and reefs building is in the natural environment of high temperature, high humidity, high salinity and high-strength ultraviolet, for island, the torrid zone The coating of reef must is fulfilled for high humidity high temperature resistant, resistance to, salt spray resistance and ageing-resistant requirement;In addition for torrid zone islands and reefs Coating should also have certain heat-proof quality.
Building external paint with organic polymer as film forming matter in the islands and reefs environment of the torrid zone, easily occur after-tacking (due to High humility), xanthochromia (due to high uitraviolet intensity), the torrid zone high temperature of islands and reefs, intensive ultraviolet environment under life-time service The most aging.The hardness of the film of aqueous inorganic paint (referring mainly to silicate solutions and Ludox) is the highest, anti-wear performance Excellence, good weatherability, colour retention is preferable;But pliability is poor, shrinkage factor is relatively big, causes its resistance to impact bad; Meanwhile, aqueous silicate solution constantly has micelle to generate in storage process, and the bin stability of silicate paint is poor. And the inorganic aqueous coating with Ludox as main film forming substance, owing to Ludox is in dehydrating polycondensation mistake in its film forming procedure Cohesiveness in journey is excessive, easily causes the coating even large area that chaps and comes off.
Pottery or hollow glass bead boring, density is low, and heat conductivity is little, can effectively hinder slow heat energy to thing Internal portion conducts, and these performances make the first-selected filler of insulating moulding coating.But the high-quality ceramic hollow of all size Microballon, still based on import, its price is the highest.The hollow glass micropearl technique of domestic production is immature, intensity Relatively low, hollow-core construction is destroyed in coating production process, swollen after making coating because of water suction after destruction, knot lump, coating Bin stability extreme difference.The Rutile type titanium dioxide using refraction coefficient to be 2.76 is functional white color pigment, also has Reach certain cooling, heat-blocking action, but when titanium white powder pigment volumetric concentration > 10% time, the gathering meeting of titanium dioxide The scattering efficiency making scattered light is substantially reduced.Use titanium salt hydrolysis peplos method will to have high index of refraction, the dioxy of high whiteness Changing titanium and be coated on cenosphere surface in advance, the titanium dioxide crystal phase structure making cenosphere granule have high index of refraction covers Cap rock.Combine thermal resistance reflection dual property through the floating bead that upper method is modified, be used as to prepare the filler of reflective heat-insulation paint, Can effectively strengthen the reflective insulation performance of film.But this kind of Chemical coating method preparation technology is more tired, and quality stability is not Height, production process observable index is bigger.
Summary of the invention
Goal of the invention: it is contemplated that overcome prior art defect, it is therefore an objective to provide a kind of torrid zone islands and reefs external wall to be coated with The preparation method of material, the coating using this technique to prepare has good heat-proof quality, in high temperature, high humidity, high salinity Can life-time service with in the natural environment of high-strength ultraviolet.
Technical scheme: the preparation method of the torrid zone provided by the present invention islands and reefs building external paint, it is characterised in that by such as Lower step is carried out: inorganic filler and heat insulating function filler first add a certain amount of water, after stirring 6~15 minutes, adds into Film auxiliary agent and film forming matter, then fill into water, grind and obtain for 20~40 minutes.In described step, the proportioning of each raw material is:
In above-mentioned preparation process, described inorganic filler be the one in calcium carbonate, wollastonite or silicon dioxide or The combination of two kinds.
Described heat insulating function filler needs to meet that heat-proof quality is excellent, with low cost, the simple requirement of production technology, Therefore, the preparation method of this filler is we provided: be the rutile titanium dioxide of 50% by 1~10 mass parts concentration Colloidal sol, 10~40 mass parts hollow beads and 50~80 mass parts deionized water mixing, dropping 1~10ml mass dense Degree is the sodium hydroxide solution of 1%, stirs 5~10 minutes, adds the silane coupler of 0.1~1 part of quality, ultrasonic 4~10 Minute obtain.Described hollow beads is ceramic hollow microballon, glass hollow microballon or the one of fly ash float.
Described coalescents includes AMP-95 multifunctional assistant, defoamer, coalescents, levelling agent, thickening Agent, antifreezing agent and dispersant, be all commercially available prod, without special requirement.
Described film forming matter need to meet deposit high humidity high temperature resistant, resistance to, salt spray resistance, ageing-resistant and storge quality is excellent Requirement, therefore, we provides the preparation method of this material: for by molten for 20~40 mass parts silicon that mass concentration is 30% Glue mixes 10~20 minutes with the 10~20 mass parts potassium silicate solutions that mass concentration is 40% at a temperature of 10 DEG C~40 DEG C After, add Ludox consumption 1~4% coupling agent stir 5~10 minutes, be eventually adding the organic emulsion of 50~80 mass parts Mix and form for 8~16 minutes.Described coupling agent be VTES, vinyltrimethoxy silane, γ- One in r-chloropropyl trimethoxyl silane, γ-(methacryloxy) propyl trimethoxy silicane.Described has Machine emulsion is silicone acrylic emulsion and the one of carbon fluorine emulsion.
Further, a preferred plan of the present invention is:
It substantially forms and includes following components by weight percent:
The preparation method of torrid zone islands and reefs building external paint, is first to add a certain amount of by inorganic filler and heat insulating function filler Water, after stirring 10 minutes, adds coalescents and film forming matter, and water is supplemented to 100 parts, grind 30 minutes Arrive.
Described coalescents include AMP-95 multifunctional assistant, defoamer, levelling agent, thickening agent, antifreezing agent and Dispersant, is all commercially available prod, without special requirement.
Described film forming matter is prepared as follows: for by 40 mass parts Ludox and quality that mass concentration is 30% Concentration be 40% 20 mass parts potassium silicate solutions mix 10 minutes at a temperature of 30 DEG C after, add Ludox consumption 3% γ-r-chloropropyl trimethoxyl silane coupling agent stir 10 minutes, be eventually adding the carbon fluorine emulsion mixing 10 of 40 mass parts Minute form.
Described function thermal insulating filling is prepared as follows: be the rutile titanium dioxide of 50% by 5 mass parts concentration The deionized water mixing of colloidal sol, the glass hollow microballon of 40 mass parts and 60 mass parts, dropping 4ml mass concentration is 1% Sodium hydroxide solution, stir 10 minutes, add 0.4 part of quality silane coupler, within ultrasonic 10 minutes, obtain.
Beneficial effect: the present invention using Ludox, potassium silicate, carbon fluorine emulsion as film forming matter, have concurrently inorganic coating and The advantage of organic coating, have good shelf-stability and film property, weather-proof well, in hot and humid environment not After-tacking, salt spray resistance is excellent.
A kind of method that simultaneously the invention provides coated by titanium dioxide hollow beads, the method technique is simply, easily grasp Make, cost relatively low, the coated prod that obtains is held concurrently heat reflection and thermal resistance heat insulating function, is a kind of compound heat-insulation filler, every Thermal effect is good.
The test of temperature difference effect it is thermally shielded by method described in JG/T235-2008 " architectural reflective heat-insulation paint " standard, To strengthen, without asbestos fibre cement, the blank test plate (panel) that flat board is the experiment of the heat insulation temperature difference, use 80 μm bar spreader twice Preparing test and use heat insulation test plate (panel), carry out heat insulating temperature difference testing after being dried 7d, light source uses the heating lamp of 1 250 watts to enter Row irradiates, and irradiation time is 1h, records a secondary data every 5min, under same light source irradiates, by heat insulation test plate (panel) Being thermally shielded the temperature difference to contrast with blank model, heat insulation test plate (panel) is at most low 13.8 DEG C than blank model.
Detailed description of the invention:
Below embodiments of the invention are elaborated.
Embodiment 1
It substantially forms and includes following components by weight percent:
The preparation method of torrid zone islands and reefs building external paint, is first to add a certain amount of by inorganic filler and heat insulating function filler Water, after stirring 10 minutes, adds coalescents and film forming matter, and water is supplemented to 100 parts, grind 30 minutes Arrive.
Described coalescents include AMP-95 multifunctional assistant, defoamer, levelling agent, thickening agent, antifreezing agent and Dispersant, is all commercially available prod, without special requirement.
Described film forming matter is prepared as follows: for by 40 mass parts Ludox and quality that mass concentration is 30% Concentration be 40% 20 mass parts potassium silicate solutions mix 10 minutes at a temperature of 30 DEG C after, add Ludox consumption 3% γ-r-chloropropyl trimethoxyl silane coupling agent stir 10 minutes, be eventually adding the carbon fluorine emulsion mixing 10 of 40 mass parts Minute form.
Described function thermal insulating filling is prepared as follows: be the rutile titanium dioxide of 50% by 5 mass parts concentration The deionized water mixing of colloidal sol, the glass hollow microballon of 40 mass parts and 60 mass parts, dropping 4ml mass concentration is 1% Sodium hydroxide solution, stir 10 minutes, add 0.4 part of quality silane coupler, within ultrasonic 10 minutes, obtain.
Embodiment 2
It substantially forms and includes following components by weight percent:
The preparation method of torrid zone islands and reefs building external paint, is first to add a certain amount of by inorganic filler and heat insulating function filler Water, after stirring 10 minutes, adds coalescents and film forming matter, and water is supplemented to 100 parts, grind 30 minutes Arrive.
Described coalescents include AMP-95 multifunctional assistant, defoamer, levelling agent, thickening agent, antifreezing agent and Dispersant, is all commercially available prod, without special requirement.
Described film forming matter is prepared as follows: by dense with quality for 40 mass parts Ludox that mass concentration is 30% Degree be 40% 20 mass parts potassium silicate solutions mix 10 minutes at a temperature of 30 DEG C after, add Ludox consumption 3% γ-r-chloropropyl trimethoxyl silane coupling agent stirs 10 minutes, and the carbon fluorine emulsion being eventually adding 40 mass parts mixes 10 points Clock forms.
Described function thermal insulating filling is prepared as follows: be the rutile titanium dioxide of 50% by 5 mass parts concentration The deionized water mixing of colloidal sol, the glass hollow microballon of 40 mass parts and 60 mass parts, dropping 4ml mass concentration is 1% Sodium hydroxide solution, stir 10 minutes, add 0.4 part of quality silane coupler, within ultrasonic 10 minutes, obtain.
Embodiment 3
It substantially forms and includes following components by weight percent:
The preparation method of torrid zone islands and reefs building external paint, is first to add a certain amount of by inorganic filler and heat insulating function filler Water, after stirring 10 minutes, adds coalescents and film forming matter, and water is supplemented to 100 parts, grind 30 minutes Arrive.
Described coalescents include AMP-95 multifunctional assistant, defoamer, levelling agent, thickening agent, antifreezing agent and Dispersant, is all commercially available prod, without special requirement.
Described film forming matter is prepared as follows: for by 40 mass parts Ludox and quality that mass concentration is 30% Concentration be 40% 20 mass parts potassium silicate solutions mix 10 minutes at a temperature of 30 DEG C after, add Ludox consumption 3% γ-r-chloropropyl trimethoxyl silane coupling agent stir 10 minutes, be eventually adding the carbon fluorine emulsion mixing 10 of 40 mass parts Minute form.
Described function thermal insulating filling is prepared as follows: be the rutile titanium dioxide of 50% by 5 mass parts concentration The deionized water mixing of colloidal sol, the glass hollow microballon of 40 mass parts and 60 mass parts, dropping 4ml mass concentration is 1% Sodium hydroxide solution, stir 10 minutes, add 0.4 part of quality silane coupler, within ultrasonic 10 minutes, obtain.
Embodiment 4
It substantially forms and includes following components by weight percent:
The preparation method of torrid zone islands and reefs building external paint, is first to add a certain amount of by inorganic filler and heat insulating function filler Water, after stirring 10 minutes, adds coalescents and film forming matter, and water is supplemented to 100 parts, grind 30 minutes Arrive.
Described coalescents include AMP-95 multifunctional assistant, defoamer, levelling agent, thickening agent, antifreezing agent and Dispersant, is all commercially available prod, without special requirement.
Described film forming matter is prepared as follows: for by 40 mass parts Ludox and quality that mass concentration is 30% Concentration be 40% 20 mass parts potassium silicate solutions mix 10 minutes at a temperature of 30 DEG C after, add Ludox consumption 3% γ-r-chloropropyl trimethoxyl silane coupling agent stir 10 minutes, be eventually adding the carbon fluorine emulsion mixing 10 of 40 mass parts Minute form.
Described function thermal insulating filling is prepared as follows: be the rutile titanium dioxide of 50% by 5 mass parts concentration The deionized water mixing of colloidal sol, the glass hollow microballon of 40 mass parts and 60 mass parts, dropping 4ml mass concentration is 1% Sodium hydroxide solution, stir 10 minutes, add 0.4 part of quality silane coupler, within ultrasonic 10 minutes, obtain.
To embodiment 1~example 4 about the performance test results such as table 1.
Table 1: coating traditional performance is tested
The test of temperature difference effect it is thermally shielded by method described in JG/T235-2008 " architectural reflective heat-insulation paint " standard, To strengthen, without asbestos fibre cement, the blank test plate (panel) that flat board is the experiment of the heat insulation temperature difference, use 80 μm bar spreader twice Preparing test and use heat insulation test plate (panel), carry out heat insulating temperature difference testing after being dried 7d, light source uses the heating lamp of 1 250 watts to enter Row irradiates, and irradiation time is 1h, records a secondary data every 5min, under same light source irradiates, by heat insulation test plate (panel) It is thermally shielded the temperature difference to contrast with blank model.Recording the maximum heat insulation temperature difference, testing result is as shown in table 2.
Table 2: the maximum heat insulation temperature difference
Sequence number Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
The maximum heat insulation temperature difference/DEG C 5.2 9.4 11.9 13.8

Claims (9)

1. the preparation method of a tropical islands and reefs building external paint, it is characterized in that carrying out as follows: inorganic filler and heat insulating function filler first add a certain amount of water, after stirring 6~15 minutes, add coalescents and film forming matter, fill into water again, grind and obtain for 20~40 minutes.
2. preparation method as claimed in claim 1, it is characterised in that by mass percentage, in described step, the proportioning of each raw material is:
3. preparation method as claimed in claim 1, it is characterised in that described inorganic filler is the combination of the one or two kinds of in calcium carbonate, wollastonite or silicon dioxide.
4. preparation method as claimed in claim 1, it is characterized in that described function thermal insulating filling is prepared as follows: by rutile titanium dioxide colloidal sol that 1~10 mass parts concentration are 50%, 10~40 mass parts hollow beads and the deionized water mixing of 50~80 mass parts, dropping 1~10ml mass concentration is the sodium hydroxide solution of 1%, stir 5~15 minutes, add the silane coupler of 0.1~1 part of quality, within ultrasonic 4~16 minutes, obtain.
5. preparation method as claimed in claim 4, it is characterised in that described hollow beads is ceramic hollow microballon, glass hollow microballon or the one of fly ash float.
6. preparation method as claimed in claim 1, it is characterised in that described coalescents includes AMP-95 multifunctional assistant, defoamer, levelling agent, thickening agent, antifreezing agent and dispersant, is all commercially available prod, without special requirement.
7. preparation method as claimed in claim 1, it is characterized in that described film forming matter is prepared as follows: after the 20~40 mass parts Ludox that mass concentration is 30% are mixed 10~20 minutes with the 10~20 mass parts potassium silicate solutions that mass concentration is 40% at a temperature of 10 DEG C~40 DEG C, add Ludox consumption 1~4% coupling agent stir 5~10 minutes, the organic emulsion mixing being eventually adding 50~80 mass parts forms for 8~16 minutes.
8. preparation method as claimed in claim 7, it is characterised in that described coupling agent is the one in VTES, vinyltrimethoxy silane, γ-r-chloropropyl trimethoxyl silane, γ-(methacryloxy) propyl trimethoxy silicane.
9. preparation method as claimed in claim 7, it is characterised in that described organic emulsion is silicone acrylic emulsion and the one of carbon fluorine emulsion.
CN201610310846.4A 2016-05-12 2016-05-12 A kind of preparation method of torrid zone islands and reefs building external paint Active CN105949825B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752561A (en) * 2016-11-14 2017-05-31 北京卫星制造厂 A kind of aeroge compound heat-insulation coating and preparation method thereof
CN109021637A (en) * 2018-05-25 2018-12-18 繁昌县若木营造装饰工程有限公司 A kind of environment-friendly building coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007046024A (en) * 2005-08-09 2007-02-22 Chitoshi Jinno Heat insulating water-based coating having incombustibility, method for coating photocatalyst and coated film thereof
KR100919968B1 (en) * 2009-02-23 2009-10-05 김충엽 Expandable fireproof coating composition
CN101591483A (en) * 2009-06-23 2009-12-02 中华制漆(深圳)有限公司 A kind of coating composition
CN105086709A (en) * 2015-08-30 2015-11-25 陈基平 Novel modified coating with addition of gamma-amino propyl trimethoxy silane
CN105368233A (en) * 2015-12-18 2016-03-02 盐城工学院 Composite thermal insulation coating and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007046024A (en) * 2005-08-09 2007-02-22 Chitoshi Jinno Heat insulating water-based coating having incombustibility, method for coating photocatalyst and coated film thereof
KR100919968B1 (en) * 2009-02-23 2009-10-05 김충엽 Expandable fireproof coating composition
CN101591483A (en) * 2009-06-23 2009-12-02 中华制漆(深圳)有限公司 A kind of coating composition
CN105086709A (en) * 2015-08-30 2015-11-25 陈基平 Novel modified coating with addition of gamma-amino propyl trimethoxy silane
CN105368233A (en) * 2015-12-18 2016-03-02 盐城工学院 Composite thermal insulation coating and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752561A (en) * 2016-11-14 2017-05-31 北京卫星制造厂 A kind of aeroge compound heat-insulation coating and preparation method thereof
CN109021637A (en) * 2018-05-25 2018-12-18 繁昌县若木营造装饰工程有限公司 A kind of environment-friendly building coating and preparation method thereof

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