CN105948954A - Production method for sugar alcohol chelated synergist - Google Patents
Production method for sugar alcohol chelated synergist Download PDFInfo
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- CN105948954A CN105948954A CN201610549387.5A CN201610549387A CN105948954A CN 105948954 A CN105948954 A CN 105948954A CN 201610549387 A CN201610549387 A CN 201610549387A CN 105948954 A CN105948954 A CN 105948954A
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- Prior art keywords
- sugar alcohol
- production method
- mass ratio
- water
- solvent
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to a production method for a sugar alcohol chelated synergist. The production method comprises the following steps: adding trace elements, sugar alcohol and a solvent into a reaction kettle according to a certain mass ratio, the mass ratio of the trace elements, secondary elements, the sugar alcohol and the solvent being (1-30):(1-30):(20-80):(0-50), and performing chelating reaction at certain temperature, so as to obtain the sugar alcohol chelated synergist until the trace elements are completely dissolved. According to the product, the utilization rate of a fertilizer can be obviously increased.
Description
Technical field
The present invention relates to the production method of a kind of sugar alcohol chelating builders.
Background technology
Current domestic utilization rate of fertilizer is the highest, and for the inverse the highest problem of benefit utilization rate of fertilizer, domestic fertilizer content is more
Doing the highest, the Chemical Mixed Fertilizer of domestic 50% content does not has obvious gap in the Chemical Mixed Fertilizer effect of external 41% content, causes on the contrary
A kind of waste of resource, the most domestic lacks the potentiation product that can significantly improve utilization rate of fertilizer.
Summary of the invention
The technical problem to be solved is to provide the production method of a kind of sugar alcohol chelating builders, improves fertilizer
Utilization rate.
In order to solve above-mentioned technical problem, present invention employs techniques below scheme:
The production method of a kind of sugar alcohol chelating builders, it is characterised in that described sugar alcohol chelating builders is prepared according to following steps
Form:
Trace element, moderate-element, sugar alcohol and solvent are joined according to mass ratio 1～30:1～30:20～80:0～50
In reactor, at 50～85 DEG C, carry out chelatropic reaction, after dissolving completely to trace element, be cooled to room temperature, obtain sugar alcohol chela
Close synergist.
Described trace element is zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid and molybdenum
A kind of or arbitrary proportion in acid ammonium two or more；Described moderate-element is four water-calcium nitrate, calcium acetate, magnesium sulfate and nitric acid
A kind of or arbitrary proportion in magnesium two or more；Sugar alcohol is sorbitol, maltose alcohol, xylitol, erithritol, lactose and sweet
A kind of or arbitrary proportion in dew alcohol two or more；Solvent is the one in water, ethanol, methanol and glycerol or arbitrary proportion
Two or more.
Described trace element is zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid, molybdic acid
Ammonium, calcium acetate and magnesium nitrate are according to the compositions of mass ratio 5:3:3:2:2:1:8:8；Sugar alcohol is sorbitol, erithritol and manna
Alcohol is according to the compositions of mass ratio 30:15:20；Solvent is water and the glycerol compositions according to mass ratio 1:2.
Described chelatropic reaction temperature is 80 DEG C；Trace element, the mass ratio of sugar alcohol and solvent are 32:65:3.
The present invention has a following Advantageous Effects:
1), sugar alcohol be a kind of good chelating agent, can be combined with multiple nutrients material and form stable complex, be currently the only
Mineral nutrient can be carried in phloem, carry out the material of fast transportation；It is the natural extract in plant phloem juice, nothing
Poison, to plant and human body without any damage；Molecular weight is low, is easily absorbed by blade, release of easily degrading in entering into plant body
Go out nutrient, consume energy low；It is a kind of natural wetting agent, there is moisture-keeping functions, be avoided that medicinal liquid lost efficacy because being dried rapidly at blade,
Extend blade and absorb the time of nutrient；It is a kind of natural surfactant, nutrient can be made to expand on whole blade
Exhibition uniform fold, improve the absorption area of blade, it is to avoid the blade of burning owing to local concentration is too high.
2), sugar alcohol presented in liquid stable, especially in alkaline solution, dissolubility is higher.Owing in phloem being
Alkaline environment, major part metal class mineral nutrient dissolubility and mobility under alkaline environment is the most poor, and sugar alcohol chelate is more
Can be embodied it and carry the advantage that mineral nutrient moves at phloem.
3), sugar alcohol can improve the resistance of plant.On the one hand, sugar alcohol is the important thing participating in intracellular penetration regulation
Matter, plant is under the environment stresses such as salt damage, arid and waterflooding, and it is raw that sugar alcohol can make plant adapt to adverse circumstance by regulation cell permeability
Long；On the other hand, sugar alcohol can improve the resistance to active oxygen, it is to avoid owing to burning ultraviolet day, arid, disease and anoxia etc. former
Because of the plant-active oxygen injury caused.
4), after sugar alcohol and middle and trace element chelate by the present invention, join in fertilizer as a kind of additive, have bright
The aobvious effect improving utilization rate of fertilizer.
Detailed description of the invention
The present invention is further illustrated below in conjunction with instantiation.
Embodiment one
By zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid, ammonium molybdate, calcium acetate, nitric acid
Magnesium, sorbitol, erithritol, mannitol, water and glycerol add according to mass ratio 5:3:3:2:2:1:8:8:30:15:20:1:2
In reactor, at 80 DEG C, carry out chelatropic reaction, to zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, sulfuric acid monohydrate
After manganese, boric acid, ammonium molybdate, calcium acetate and magnesium nitrate dissolve completely, it is cooled to room temperature, obtains sugar alcohol chelating builders.
Embodiment two
By zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid, ammonium molybdate, calcium acetate, nitric acid
Magnesium, sorbitol, erithritol, mannitol, water and glycerol add according to mass ratio 5:3:3:2:2:1:8:8:20:15:30:1:2
In reactor, at 80 DEG C, carry out chelatropic reaction, to zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, sulfuric acid monohydrate
After manganese, boric acid, ammonium molybdate, calcium acetate and magnesium nitrate dissolve completely, it is cooled to room temperature, obtains sugar alcohol chelating builders.
Embodiment three
By zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid, ammonium molybdate, calcium acetate, nitric acid
Magnesium, sorbitol, erithritol, mannitol, water and glycerol add according to mass ratio 5:3:3:2:2:1:8:8:20:35:10:1:2
In reactor, at 80 DEG C, carry out chelatropic reaction, to zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, sulfuric acid monohydrate
After manganese, boric acid, ammonium molybdate, calcium acetate and magnesium nitrate dissolve completely, it is cooled to room temperature, obtains sugar alcohol chelating builders.
Embodiment four
By zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid, ammonium molybdate, calcium acetate, nitric acid
Magnesium, sorbitol, erithritol, mannitol, water and glycerol add according to mass ratio 5:3:3:2:2:1:8:8:10:25:30:1:2
In reactor, at 80 DEG C, carry out chelatropic reaction, to zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, sulfuric acid monohydrate
After manganese, boric acid, ammonium molybdate, calcium acetate and magnesium nitrate dissolve completely, it is cooled to room temperature, obtains sugar alcohol chelating builders.
Embodiment five
By zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid, ammonium molybdate, calcium acetate, nitric acid
Magnesium, sorbitol, erithritol and mannitol join in reactor according to mass ratio 5:3:3:2:2:1:8:8:10:25:33,80
Carry out chelatropic reaction at DEG C, to zinc sulphate heptahydrate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid, ammonium molybdate,
After calcium acetate and magnesium nitrate dissolve completely, it is cooled to room temperature, obtains sugar alcohol chelating builders.
Beneficial effects of the present invention is further illustrated below in conjunction with experimental data:
1, experiment material to be tested
1 materials and methods:
1.1 test sites: Qingzhou, Weifang, neutral brown earth.
1.2 tomato varieties: R-800 large fruit.
1.3 for examination fertilizer: for mill run (sugar alcohol replaces with water, and other production is consistent with embodiment 1)
, embodiment 1, embodiment 2, embodiment 3 and embodiment 4 do effectiveness comparison.
1.4 EXPERIMENTAL DESIGN: test sets 5 process, repeats for 2 times, Gong10Ge community, plot area 60m2.Every community is respectively
Foliage-spray dilutes mill run (sugar alcohol replaces with water, and other production is consistent with embodiment 1), the embodiment 1 of 2500 times, implements
Example 2, embodiment 3 and embodiment June 18 5,2015 June in 4,2015 and July 1 in 2015 have carried out place to each community respectively
Reason, July 16 in 2015, Fructus Lycopersici esculenti was plucked successively, and community list contracture does not calculate yield.
This experiment other management in addition to experiment processes difference are the most consistent.
2 results and analysis
(sugar alcohol replaces with water, and other produces and embodiment 1 for embodiment 1, embodiment 2, embodiment 3 and embodiment 4 and mill run
Unanimously) process is compared, and the Fructus Lycopersici esculenti growth potential that embodiment processes is strong, and stem is the most resistant to lodging, Ye Senong, and fruit mass color is good, has an attack of one's old illness
Rate is low.Table 1 is the tomato production of each process.
Table 1 respectively processes the impact on tomato production
Embodiment 1 yield processes apparently higher than other as can be seen from Table 1, adds the product of the present invention after sugar alcohol, and yield is obvious
It is better than not adding the mill run of sugar alcohol.
Discuss: China's utilization rate of fertilizer is the highest at present, serious waste of resources, govern the development of agricultural, improve fertilizer
Utilization rate, reduces the content of fertilizer, and saving the energy is the direction that we study.
Claims (4)
1. the production method of a sugar alcohol chelating builders, it is characterised in that described sugar alcohol chelating builders is according to following steps system
For forming: trace element, moderate-element, sugar alcohol and solvent are added according to mass ratio 1～30:1～30:20～80:0～50
In reactor, at 50～85 DEG C, carry out chelatropic reaction, after dissolving completely to trace element, be cooled to room temperature, obtain sugar alcohol
Chelating builders.
2. the production method of sugar alcohol chelating builders as claimed in claim 1, it is characterised in that: described trace element is seven water
Two of a kind of or arbitrary proportion in zinc sulfate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid and ammonium molybdate
More than Zhong；Described moderate-element is two kinds of a kind of or arbitrary proportion in four water-calcium nitrate, calcium acetate, magnesium sulfate and magnesium nitrate
Above；Sugar alcohol is two of a kind of or arbitrary proportion in sorbitol, maltose alcohol, xylitol, erithritol, lactose and mannitol
More than Zhong；Solvent is the two or more of a kind of or arbitrary proportion in water, ethanol, methanol and glycerol.
3. the production method of sugar alcohol chelating builders as claimed in claim 2, it is characterised in that: described trace element is seven water
Zinc sulfate, copper sulphate pentahydrate, ferrous sulfate heptahydrate, manganese sulfate monohydrate, boric acid, ammonium molybdate, calcium acetate and magnesium nitrate are according to quality
Compositions than 5:3:3:2:2:1:8:8；Sugar alcohol is the combination according to mass ratio 30:15:20 of sorbitol, erithritol and mannitol
Thing；Solvent is water and the glycerol compositions according to mass ratio 1:2.
4. the production method of sugar alcohol chelating builders as claimed in claim 1, it is characterised in that chelatropic reaction temperature described in:
It it is 80 DEG C；Trace element, the mass ratio of sugar alcohol and solvent are 32:65:3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610549387.5A CN105948954A (en) | 2016-07-13 | 2016-07-13 | Production method for sugar alcohol chelated synergist |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610549387.5A CN105948954A (en) | 2016-07-13 | 2016-07-13 | Production method for sugar alcohol chelated synergist |
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| CN105948954A true CN105948954A (en) | 2016-09-21 |
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| CN201610549387.5A Pending CN105948954A (en) | 2016-07-13 | 2016-07-13 | Production method for sugar alcohol chelated synergist |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106866288A (en) * | 2017-04-17 | 2017-06-20 | 福建绿滢生态农林发展有限公司 | Enzyme foliar fertilizer for vegetables with green leaves class and preparation method thereof |
| CN106892747A (en) * | 2017-02-20 | 2017-06-27 | 深圳市芭田生态工程股份有限公司 | Organic chelated fertilizer synergist and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102887779A (en) * | 2012-11-08 | 2013-01-23 | 广西新方向化学工业有限公司 | Liquid fertilizer containing many kinds of phytols and medium-trace elements and preparation method thereof |
| CN103159531A (en) * | 2013-04-17 | 2013-06-19 | 广西新方向化学工业有限公司 | Chelated liquid fertilizer containing multiple types of plant alcohols and medium trace elements and preparation method of liquid fertilizer |
| CN104892208A (en) * | 2015-06-11 | 2015-09-09 | 中化化肥有限公司烟台作物营养与植物保护研究中心 | Liquid compound trace element fertilizer and preparation method thereof |
| CN105330442A (en) * | 2015-12-07 | 2016-02-17 | 长沙金雨实业有限公司 | Preparing method for compound sugar alcohol leaf fertilizer |
-
2016
- 2016-07-13 CN CN201610549387.5A patent/CN105948954A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102887779A (en) * | 2012-11-08 | 2013-01-23 | 广西新方向化学工业有限公司 | Liquid fertilizer containing many kinds of phytols and medium-trace elements and preparation method thereof |
| CN103159531A (en) * | 2013-04-17 | 2013-06-19 | 广西新方向化学工业有限公司 | Chelated liquid fertilizer containing multiple types of plant alcohols and medium trace elements and preparation method of liquid fertilizer |
| CN104892208A (en) * | 2015-06-11 | 2015-09-09 | 中化化肥有限公司烟台作物营养与植物保护研究中心 | Liquid compound trace element fertilizer and preparation method thereof |
| CN105330442A (en) * | 2015-12-07 | 2016-02-17 | 长沙金雨实业有限公司 | Preparing method for compound sugar alcohol leaf fertilizer |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106892747A (en) * | 2017-02-20 | 2017-06-27 | 深圳市芭田生态工程股份有限公司 | Organic chelated fertilizer synergist and preparation method thereof |
| CN106866288A (en) * | 2017-04-17 | 2017-06-20 | 福建绿滢生态农林发展有限公司 | Enzyme foliar fertilizer for vegetables with green leaves class and preparation method thereof |
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Application publication date: 20160921 |
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