CN105948049A - System and method for producing calcium carbide by utilizing carbide slag - Google Patents
System and method for producing calcium carbide by utilizing carbide slag Download PDFInfo
- Publication number
- CN105948049A CN105948049A CN201610282477.2A CN201610282477A CN105948049A CN 105948049 A CN105948049 A CN 105948049A CN 201610282477 A CN201610282477 A CN 201610282477A CN 105948049 A CN105948049 A CN 105948049A
- Authority
- CN
- China
- Prior art keywords
- unit
- carbide
- carbide slag
- outlet
- entrance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Processing Of Solid Wastes (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention relates to a system and a method for producing calcium carbide by utilizing carbide slag. The system includes a purification unit, a drying and conveying unit, a centrifugation unit, a calcining unit and a calcium carbide unit, wherein the above units are arranged in sequence. The purification unit comprises a carbonization unit and a press filtration unit. The carbonized solid slurry inlet of the press filtration unit is connected with the carbonized solid slurry outlet of the carbonization unit. The carbonized solid outlet of the press filtration unit is connected with the inlet of the drying and conveying unit. The centrifugal carbonized solid inlet of the centrifugation unit is connected with the outlet of the drying and conveying unit. The calcining carbonization solid inlet of the calcining unit is connected with a centrifugation and carbonization solid outlet. The calcium oxide powder inlet of the calcium carbide unit is connected with the calcium oxide powder outlet of the calcining unit. According to the technical scheme of the method for producing calcium carbide, the CO2-containing gas is introduced into the carbide slag slurry, so that the carbide slag slurry is purified. In this way, the problem that the carbide slag is difficult in treatment can be solved. Meanwhile, the low-cost and low-pollution production pathway of the calcium carbide is fundamentally realized.
Description
Technical field
The invention mainly relates to a kind of system and method producing carbide, particularly relate to a kind of carbide slag and produce
The system and method for carbide.
Background technology
Carbide slag is that carbide hydrolysis produces residue produced by acetylene, and moisture therein exists
60-80%, effective ingredient is mainly calcium hydroxide, possibly together with solids such as magnesium oxide, aluminium oxide, ferrosilicon
The gases such as impurity and dissolving a small amount of acetylene, hydrogen sulfide and hydrogen phosphide in aqueous.According to statistics,
The factory's discharge carbide slag slurries producing 200,000 tons of PVC year reaches 3,600,000 tons/year, enormous amount, and
Waste residue slurry distributes foul odour, and surrounding is created ill effect.At present, carbide slag should
With in the industries such as the production being concentrated mainly on manufacture of cement, desulfurization technology, construction material.But because electricity
There is more impurity in rock ballast, and water content is high, therefore the utilization rate of carbide slag is relatively low, not enough electricity
The 50% of rock ballast total amount, thus still with the presence of substantial amounts of carbide slag as garbage.
Meanwhile, calcium carbide production process needs substantial amounts of quality block limestone, need to exploit tens of every year
Hundred million tons of limestone, cause a certain degree of destruction to ecological environment.Meanwhile, carbide produces required carbon source
Still based on high-quality bulk coke, it is expensive, and exist same demand coke carbon source iron and steel,
The industries such as thermoelectricity, so that coke carbon source cost is higher.
Therefore, if carbide slag can be reclaimed, by certain technical finesse, it is allowed to meet carbide and produces work
The skill requirement to raw material, and it is mixed with as the coke powder of carbon source produce carbide, then can realize electricity
Recycling of stone-carbide slag-carbide, not only reduces the calcium carbide industry demand to limestone, also solves
The problem that the process of carbide slag of having determined is more difficult, and coke powder to compare coke more cheap and easy to get, thus can realize
Carbide industry low cost, oligosaprobic production ways.
In some prior aries, still suffer from problems with:
The modifying agent of carbide ground-slag uses strong acid and acid salt, and such modifying agent mixes new in carbide slag
Impurity so that carbide slag is relatively difficult with the mixing of acid and acid salt；
The addition of organic binder bond is relatively big, and relatively costly, the mixing with material is relatively difficult, actual behaviour
Make difficulty the biggest, it is virtually impossible to realize industrialization；
Calcination stage is with noble gas as carrier, and tar and pyrolysis gas that pyrolysis produces mix with noble gas
Closing, inferior quality, directly there is serious problem of environmental pollution in discharge.
In the prior art, also have the recovery method of some other carbide slags, carbide slag is raw as carbide
The raw material produced, but simply carbide slag is simply dried calcining, not to the impurity in carbide slag
Process, the carbide inferior quality therefore obtained.
Therefore, for the problems referred to above, it is necessary to provide a kind of technology utilizing production of calcium carbide from its residue, both
Energy purifying electric rock ballast so that the composition of carbide slag fully meets the requirement that carbide produces, and can directly have again
Effect utilizes coke powder, shortened process, reduces process costs, reduces carbide energy consumption.
Summary of the invention
For the problems referred to above, it is desirable to provide the system and method for a kind of production of calcium carbide from its residue, should
The purpose of system and method is to solve carbide slag as producing more the asking of impurity existing for carbide raw material
Topic, makes technological process shorten simultaneously, and process costs reduces, and carbide energy consumption reduces.
The system of production of calcium carbide from its residue that the present invention provides includes: the clean unit that sequentially arranges, dry
Dry supply unit, centrifugal unit, calcining unit and carbide unit, wherein, described clean unit includes
Carbonation unit and filter pressing unit, described carbonation unit includes carbide slag entrance, recirculated water entrance, CO2
Entrance and carbonized solid slurry outlet；Described filter pressing unit includes carbonized solid slurry entrance and carbonized solid
Outlet, the carbonized solid slurry entrance of described filter pressing unit and the carbonized solid slurry outlet of described carbonation unit
Being connected, the carbonized solid outlet of described filter pressing unit is connected with the entrance of described dry supply unit；Institute
Stating centrifugal unit and include centrifugal carbonized solid entrance and the outlet of centrifugal carbonized solid, described centrifugal carbonization is solid
Body entrance is connected with the outlet of described dry supply unit；Described calcining unit includes calcining carbonized solid
Entrance and calcium oxide powder outlet, described calcining carbonized solid entrance exports phase with described centrifugal carbonized solid
Even；Described carbide unit includes calcium oxide powder entrance, coke powder entrance, oxygen-containing gas entrance, furnace of calcium carbide
Gas outlet and carbide outlet；Described calcium oxide powder entrance exports with the calcium oxide powder of described calcining unit
It is connected.
Further, described system may also include pretreatment unit, and described pretreatment unit includes successively
Carbide slag breaker, the middle warehouse of carbide slag and the carbide slag helix transporting device being connected；Described electricity
The outlet of rock ballast helix transporting device is connected with the carbide slag entrance of described carbonation unit.
Further, described system may also include acetylene unit, described acetylene unit include carbide entrance,
The outlet of water inlet, acetylene and carbide slag outlet, described carbide entrance and the carbide of described carbide unit
Outlet is connected；The outlet of described carbide slag is connected with the carbide slag entrance of described carbonation unit.
Further, described system may also include carbide slag bath, and the entrance of described carbide slag bath is with described
The carbide slag outlet of acetylene unit is connected, the outlet of described carbide slag bath and the electricity of described pretreatment unit
Rock ballast breaker is connected.
Further, in said system, described calcining unit also includes off-gas recovery mouth, described flue gas
Recovery port is connected with the dry medium inlet of described dry supply unit.
The present invention also provides for a kind of method utilizing said system to produce carbide, comprises the following steps:
By < carbide slag of 1mm is placed in described carbonation unit the stirring that adds water, and forms carbide slag slurries；
Described carbide slag slurries in described carbonation unit is passed through containing CO2Gas, in order to reduce described
S, P content and separation magnesium oxide in carbide slag slurries, obtains carbonized solid slurry；
Described carbonized solid slurry purification obtained is delivered in described filter pressing unit, and extruding is tentatively to remove
Water, obtains carbonized solid；
By described dry supply unit, described carbonized solid is transported to described centrifugal unit；Conveying
Described carbonized solid is dried simultaneously, obtains being dried carbonized solid；
Described dry carbonized solid is removed iron oxides impurities at described centrifugal unit by centrifugation,
Obtain centrifugal carbonized solid；
Calcine in the described centrifugal carbonized solid being centrifugally separating to obtain is sent into described calcining unit,
Obtain calcium lime powder；
The described calcium lime powder of calcining gained is put into described carbide unit, adds in described carbide unit
Enter coke powder, and make described calcium lime powder mix with coke powder, generate carbide by oxygen full-boiled process.
Further, described method may further comprise the step of:
By described carbide slag breaker, bulk carbide slag is crushed to < 1mm, and broken carbide
Slag is placed in warehouse in the middle of described carbide slag, by described carbide slag helix transporting device by described broken electricity
Rock ballast is transported to described clean unit.
In said method, the solid content of described carbide slag slurries is 8.0-25wt%.
In said method, it is passed through described containing CO in described carbide slag slurries2After gas, described carbide slag slurries
PH regulator be 8-11；Described containing CO2CO in gas2Volumetric concentration be 15-27%.
Further, described method may further comprise the step of:
The carbide of described generation use dry method carbide acetylene production method generate acetylene and carbide slag, and
Described carbide slag is transported to described carbonation unit or described carbide slag bath.
According to the technique scheme of the present invention, both purified carbide slag so that the composition of carbide slag fills
Divide and meet the requirement that carbide produces, the most directly efficiently utilize coke powder, shorten technological process, fall
Low process costs, reduces carbide energy consumption simultaneously.
Accompanying drawing explanation
Fig. 1 is structure diagram and the process chart of production of calcium carbide from its residue of the present invention；
Fig. 2 is the schematic diagram of system one embodiment of production of calcium carbide from its residue of the present invention；And
Fig. 3 is the schematic diagram of another embodiment of system of production of calcium carbide from its residue of the present invention.
Detailed description of the invention
Below in conjunction with drawings and Examples, the detailed description of the invention of the present invention is carried out more detailed theory
Bright, so as to the advantage being more fully understood that the solution of the present invention and various aspects.But, below
The detailed description of the invention and the embodiment that describe are only descriptive purpose rather than limitation of the present invention.
It is illustrated in figure 1 structure diagram and the process chart of the production of calcium carbide from its residue of the present invention, this
The technical scheme of invention is: by carbide slag, by after pretreatment, (this pretreatment is according to the character of carbide slag
Depending on, it is not necessary to arrange), prepare certain density carbide slag slurries, then drum bottom carbide slag slurries
Bubble is passed through CO2, make the calcium phosphide in carbide slag, calcium sulfide etc. be decomposed into the gas such as hydrogen phosphide, hydrogen sulfide
Body escapes from carbide slag, thus reduces the S in carbide slag, P content；Meanwhile, the oxygen in carbide slag
Change magnesium can react under the effect of carbonic acid and produce the sodium bicarbonate being dissolved in water, enters aqueous solution, and dissolves
Spend less calcium carbonate to exist the most in solid form, thus reach to separate the effect of magnesium oxide, complete to this
Become the decontamination procedure of carbide slag；After carbide slag drying after purification removes portion of water, carry out from
The heart separates, and utilizes the difference of each oxide density, removes the aluminium oxide in carbide slag and oxidation further
Ferrum, obtains effective ingredient calcium carbonate；The calcium carbonate being performing centrifugal separation on obtaining is calcined in limekiln, produces
Raw calcium oxide powder；Calcium oxide powder mixes at carbide processing unit with coke powder, prepares carbide by oxygen full-boiled process；
Carbide can obtain acetylene and carbide slag further, and carbide slag can be used for producing carbide by recirculation, whole
Process forms closed cycle, can be greatly enhanced the utilization rate of raw material, reduces solid waste discharge, in protection
Production cost can be reduced while environment.
Wherein, oxygen full-boiled process of the present invention, refer to utilize oxygen-enriched or pure oxygen and part pulverized coal friring to put
The heat gone out, makes residue fine coal and powdery calcium oxide react generation carbide.
Specifically, as in figure 2 it is shown, disclose the embodiment of the system of production of calcium carbide from its residue of the present invention,
In the present embodiment, the system of production of calcium carbide from its residue includes pretreatment unit 1, carbonation unit 2, pressure
Filter unit 3, dry supply unit 4, centrifugal unit 5, calcining unit 6, carbide unit 7, acetylene list
Unit 8 composition, wherein pretreatment unit 1 not necessarily device, carbonation unit 2 and filter pressing unit 3 can
Generally being under the jurisdiction of clean unit, acetylene unit 8 is not necessary device, all visual field requirement and determine
Determine whether to increase in systems.
The pretreatment unit 1 of production of calcium carbide from its residue includes in the middle of carbide slag breaker 11, carbide slag
Warehouse 12, carbide slag helix transporting device 13；Storage in the middle of described carbide slag breaker 11, carbide slag
Storehouse 12 and carbide slag helix transporting device 13 are sequentially connected.When carbide slag is relatively large shape, can use
To this pretreatment unit 1.Carbide slag breaker 11 is used for crushing warehouse in the middle of carbide slag, carbide slag
12 for storing the carbide slag after crushing, and carbide slag helix transporting device 13 is for broken carbide
Slag transports carbonation unit 2 to.
In conjunction with Fig. 1, carbonation unit 2 generally tower reactor, including the electricity arranged on the reaction vessel
Rock ballast entrance 21, recirculated water entrance 22, CO2Entrance 23, CO2Outlet 24, overflow box outlet 25
And carbonized solid slurry outlet 26.Herein, the main component of the slurry of the described carbonized solid in container is carbon
Acid calcium, and mix the oxide of water miscible magnesium bicarbonate and other impurity；Described carbide slag entrance 21
It is connected with carbide slag helix transporting device 13.In this unit, first prepare certain density carbide slag slurries,
Then bottom carbide slag slurries, it is bubbled into CO2, carbide slag is purified.
Filter pressing unit 3 generally leaf filter, including the carbonized solid slurry entrance 31 being disposed thereon,
Filtrate (liquid 32 and carbonized solid outlet 33；Described carbonized solid slurry entrance 31 is starched with carbonized solid
Outlet 26 is connected；Described carbonized solid outlet 33 is connected with the entrance of dry supply unit 4.At this
The preliminary portion of water removed in carbide slag slurries in unit.
Being dried supply unit 4 is conveyer belt, and the effect being dried supply unit 4 is by filter pressing unit 3 institute
The carbonized solid obtained is transported to centrifugal unit 5, and is dried carbonized solid in course of conveying, institute
Flue gas produced by calcining unit 6 is come from dry medium, and in opposite direction with the transmission of conveyer belt.
I.e. carbonized solid transmits on a moving belt, faces transmission from the defeated next flue gas ejiction opening of calcining unit 6
Carbonized solid on band, gas flows from top to bottom, and carbonized solid moves toward upper from lower so that carbon
Change transmission limit, solid limit to be dried.
Centrifugal unit 5 is centrifuge, including the dried centrifugal carbonized solid entrance being arranged on device
51 and centrifugal after centrifugal carbonized solid outlet 52 and impurities outlet 53；Described centrifugal carbonized solid
Entrance 51 is connected with the outlet of dry supply unit 4.This unit is removed in carbide slag further
Aluminium oxide and ferrum oxide, obtain effective ingredient calcium carbonate.
Calcining unit 6 is limekiln, including the calcining carbonized solid entrance 61 being arranged on device, adds
Thermal medium entrance 62, off-gas recovery mouth 63 and calcining rear oxidation calcium powder outlet 64；Described calcining carbon
Change solid inlet 61 to be connected with centrifugal carbonized solid outlet 52.This element is performing centrifugal separation on obtain
Calcium carbonate calcine in limekiln, produce calcium oxide powder.
Carbide unit 7 is closed type calcium carbide furnace, including calcining rear oxidation calcium powder entrance 71, coke powder entrance
72, oxygen-containing gas entrance 73, calcium carbide furnace gas outlet 74 and carbide outlet 75；Described calcium oxide powder
Entrance 71 is connected with calcining unit calcium oxide powder outlet 64；Calcium carbide furnace gas outlet 74 adds with calcining unit
Thermal medium entrance 62 is connected.Carbide is prepared by oxygen full-boiled process in this unit.
As in figure 2 it is shown, said system may also include carbide slag bath 9.Acetylene unit 8 fills for acetylene
Put, go out including carbide entrance 81, water inlet 82, acetylene outlet 83, overfall 84 and carbide slag
Mouth 85；Described carbide entrance 81 exports 75 with the carbide of carbide unit and is connected；When carbide slag is described
Depositing for a long time in carbide slag bath 9, carbide slag can form bulk, needs preprocessed unit 1 to carry out it
Break process, thus described carbide slag outlet 85 can successively with carbide slag bath 9 and pretreatment unit 1
Carbide slag breaker 11 is connected, or, it is routed directly to carbonization through acetylene unit 8 carbide slag out
Unit 2 carries out purified treatment, as it is shown on figure 3, now carbide slag outlet 85 and the electricity of carbonation unit 2
Rock ballast entrance 21 is connected.
The method of the production of calcium carbide from its residue of the present invention comprises the following steps:
The first step: carbide slag pretreatment, this step determines according to the character of carbide slag used: work as carbide
The slag resting period is longer, in caking shape, then must first pass through carbide slag breaker 11 and is crushed to < 1
Mm, is placed in the middle of carbide slag in warehouse 12, and is transported to carbonation unit 2 by helix transporting device,
Add water stirring；When carbide slag is the carbide slag slurries that water content is bigger, then directly by it at carbonation unit 2
In add water stirring, form the carbide slag slurries of certain solid content；The solid content of the described carbide slag slurries obtained
For 8.0-25wt%；
Second step: purify, be passed through containing CO in the carbide slag slurries described in step one in carbonation unit 22
Gas, the pH of regulation solution is 8-11；Described containing CO2Gas is boiler exhaust gas or other flue gas,
CO2Volumetric concentration be 15-27%；
3rd step: be dried, carbide slag slurries purification obtained first passes through in filter pressing unit 3 and squeezes into
Row is preliminary except water, and after extruding, the water content in carbide slag is 40-60%；Afterwards, at dry supply unit
Carbide slag is dried by 4 flue gases using limekiln to be discharged, and baking temperature is 150-200 DEG C；
4th step: centrifugation is different from other impurity densities according to calcium carbonate, by dried
Carbide slag is separated by centrifugal separating device at centrifugal unit 5, removes oxidation therein further
The impurity such as ferrum；
5th step: calcining: the calcium carbonate finally given is carried out calcining at calcining unit 6 and obtains calculogenesis
Ashes, calcining heat is 850-1000 DEG C；Adding thermal medium needed for calcining is the electricity that carbide unit 7 produces
Stone furnace gas；
6th step: generate carbide, puts into carbide list by the calcium lime powder of calcining gained by hot feed technique
The furnace of calcium carbide of unit 7, and mix with the coke powder being simultaneously fed into, oxygen full-boiled process generates carbide；Furnace of calcium carbide used
For air flow bed；Oxygen-containing atmosphere used is air, high pure oxygen；Carbide generates temperature and is 1750-2000 DEG C；
7th step: generate acetylene and carbide slag, uses the most ripe dry method at acetylene unit 8
Carbide acetylene technology generates acetylene and carbide slag, the carbide slag of generation after foregoing purification separation,
Again as carbide raw materials for production, whole production circuit defines the mode of production of circulation.Certainly this
Step is not the steps necessary of technical solution of the present invention, and the carbide slag in technical solution of the present invention can be by
The most directly transport.
It should be noted that " wt% " refers both to percentage by weight herein.
From such scheme, carbide slag and coke powder that the present invention provides prepare carbide by oxidizing process
Method, raw materials used for carbide slag with coke powder, it is industry residue, cost of material is low；The present invention
Technical scheme both solved the environmental problem that the stacking low, random of carbide slag utilization rate causes, utilize again
Suitably purification method, greatly reduces magnesium oxide, ferrum oxide, aluminium oxide present in carbide slag
And the impurity such as calcium sulfide, calcium phosphide so that the composition of carbide slag meets the requirement that carbide produces, and
And the direct high temperature coke powder obtained with fast pyrogenation of calcium lime powder that carbide slag purified treatment obtains mixes,
Prepare carbide by oxygen full-boiled process, not only eliminate ball making process, shorten technological process, reduce work
Skill cost, and heat entrained by high temperature coke powder can be directly utilized, improve heat utilization efficiency, reduce electricity
Stone energy consumption.
Below in conjunction with specific embodiment, technical scheme is described.
In following embodiment, institute's taking technique condition value is exemplary, and its desirable numerical range is the most front
State shown in description.
Embodiment 1
By carbide slag breaker 11 the carbide clinker lumpd is crushed to < 1mm is stored in carbide slag
Middle warehouse 12, and be transported in carbonation unit 2 by carbide slag helix transporting device 13, add
Water stirs, and forms the carbide slag slurries of solid content about 20wt%；CO it is passed through in carbide slag slurries2Volumetric concentration
Being the boiler exhaust gas of 25%, the pH of regulation carbide slag slurries is 8-11, by the main component hydrogen in carbide slag
Calcium oxide carbonization is calcium carbonate, and oxidation of impurities reactive magnesium becomes water miscible magnesium bicarbonate, after carbonization
Filter pressing unit 3 sent into after preliminary sedimentation by solid so that it is water content is down to less than 40%, then drying
Supply unit 4 by Solid Conveying and Melting after carbonization to centrifugal unit 5, and in course of conveying use limekiln produce
Raw flue gas is dried, baking temperature about 150 DEG C；Dried calcium carbonate mixtures of impurities from
Centrifugal separator separates, can be by according to the difference between calcium carbonate and aluminium oxide, ferrum oxide, magnesium oxide etc.
Oxide impurity in calcium carbonate removes, and obtains calcium carbonate solid after purification, is incorporated to calcine the stone of unit 6
Ash furnace is calcined, and calcining heat is 950 DEG C, obtains carbide raw materials for production calcium lime powder；Send into carbide unit
The calcium lime powder of the air flow bed of 7 reacts with the coke powder being simultaneously introduced and oxygen-containing gas, produces at 1850 DEG C
Raw carbide；Generate carbide react with water in the acetylene generator of acetylene unit 8, obtain acetylene and
Carbide slag, the carbide slag of generation, after foregoing purification separation, produces former as carbide again
Material, forms closed cycle.
Embodiment 2
The carbide slag produced in acetylene unit 8 is directly transported in carbonation unit 2, and add water stirring,
Form the carbide slag slurries of solid content about 15wt%；CO it is passed through in carbide slag slurries2Volumetric concentration is 20%
Boiler exhaust gas, regulation carbide slag slurries pH be 8-11, by the main component calcium hydroxide in carbide slag
Carbonization is calcium carbonate, and oxidation of impurities reactive magnesium becomes water miscible magnesium bicarbonate, solid warp after carbonization
Sending into filter pressing unit 3 after preliminary sedimentation so that it is water content is down to about 60%, then drying conveying is single
Unit 4 is by Solid Conveying and Melting after carbonization to centrifugal unit 5, and uses the cigarette of limekiln generation in course of conveying
Gas is dried, baking temperature about 200 DEG C；Dried calcium carbonate mixtures of impurities is at centrifugal separator
Middle separation, can be by calcium carbonate according to the difference between calcium carbonate and aluminium oxide, ferrum oxide, magnesium oxide etc.
Oxide impurity remove, the calcium carbonate solid after being purified, be incorporated to calcine unit 6 limekiln
Calcining, calcining heat is 850 DEG C, obtains carbide raw materials for production calcium lime powder；Send into carbide unit 7
The calcium lime powder of air flow bed reacts with the coke powder being simultaneously introduced and oxygen-containing gas, produces electricity at 2000 DEG C
Stone；The carbide generated reacts with water in acetylene unit 8, obtains acetylene and carbide slag, the electricity of generation
Rock ballast is after foregoing purification separation, again as carbide raw materials for production, forms closed cycle.
As seen from the above-described embodiment, technical scheme had both purified carbide slag so that carbide slag
Composition fully meets the requirement that carbide produces, and the most directly efficiently utilizes coke powder, shortens technique stream
Journey, reduces process costs, reduces carbide energy consumption simultaneously.
Last it is noted that obvious, above-described embodiment is only by clearly demonstrating what the present invention was made
Citing, and not restriction to embodiment.For those of ordinary skill in the field, exist
Can also make other changes in different forms on the basis of described above.Here without also without
All of embodiment is given exhaustive by method.And the obvious change thus amplified out or variation
Among protection scope of the present invention.
Claims (10)
1. a system for production of calcium carbide from its residue, clean unit that described system includes sequentially arranging,
Dry supply unit, centrifugal unit, calcining unit and carbide unit, wherein,
Described clean unit includes carbonation unit and filter pressing unit, and described carbonation unit includes that carbide slag enters
Mouth, recirculated water entrance, CO2Entrance and carbonized solid slurry outlet；Described filter pressing unit includes that carbonization is solid
Somaplasm entrance and carbonized solid outlet, carbonized solid slurry entrance and the described carbonization list of described filter pressing unit
The carbonized solid slurry outlet of unit is connected, carbonized solid outlet and the described dry conveying of described filter pressing unit
The entrance of unit is connected；
Described centrifugal unit includes centrifugal carbonized solid entrance and the outlet of centrifugal carbonized solid, described centrifugal
Carbonized solid entrance is connected with the outlet of described dry supply unit；
Described calcining unit includes calcining carbonized solid entrance and calcium oxide powder outlet, described calcining carbonization
Solid inlet is connected with the outlet of described centrifugal carbonized solid；
Described carbide unit includes calcium oxide powder entrance, coke powder entrance, oxygen-containing gas entrance, furnace of calcium carbide
Gas outlet and carbide outlet；Described calcium oxide powder entrance exports with the calcium oxide powder of described calcining unit
It is connected.
System the most according to claim 1, it is characterised in that described system also includes pretreatment
Unit, described pretreatment unit includes carbide slag breaker, the middle warehouse of carbide slag being sequentially connected
With carbide slag helix transporting device；The outlet of described carbide slag helix transporting device and described carbonation unit
Carbide slag entrance be connected.
System the most according to claim 1, it is characterised in that described system also includes acetylene list
Unit, described acetylene unit includes the outlet of carbide entrance, water inlet, acetylene and carbide slag outlet, institute
State carbide entrance to be connected with the carbide outlet of described carbide unit；The outlet of described carbide slag and described carbonization
The carbide slag entrance of unit is connected.
System the most according to claim 2, it is characterised in that described system also includes carbide slag
Pond and acetylene unit, described acetylene unit includes the outlet of carbide entrance, water inlet, acetylene and carbide
Slag exports, and described carbide entrance exports with the carbide of described carbide unit and is connected；Described carbide slag bath
Entrance exports with the carbide slag of described acetylene unit and is connected, the outlet of described carbide slag bath and described pre-place
The carbide slag breaker of reason unit is connected.
System the most according to claim 1, it is characterised in that described calcining unit also includes cigarette
Gas recovery port, described off-gas recovery mouth is connected with the dry medium inlet of described dry supply unit.
6. utilize the method that system described in any one of claim 1 to 5 produces carbide, including with
Lower step:
By < carbide slag of 1mm is placed in described carbonation unit the stirring that adds water, and forms carbide slag slurries；
Described carbide slag slurries in described carbonation unit is passed through containing CO2Gas, in order to reduce described
S, P content and separation magnesium oxide in carbide slag slurries, obtains carbonized solid slurry；
Described carbonized solid slurry purification obtained is delivered in described filter pressing unit, and extruding is tentatively to remove
Water, obtains carbonized solid；
By described dry supply unit, described carbonized solid is transported to described centrifugal unit；Conveying
Described carbonized solid is dried simultaneously, obtains being dried carbonized solid；
Described dry carbonized solid is removed iron oxides impurities at described centrifugal unit by centrifugation,
Obtain centrifugal carbonized solid；
Calcine in the described centrifugal carbonized solid being centrifugally separating to obtain is sent into described calcining unit,
Obtain calcium lime powder；
The described calcium lime powder of calcining gained is put into described carbide unit, adds in described carbide unit
Enter coke powder, and make described calcium lime powder mix with coke powder, generate carbide by oxygen full-boiled process.
Method the most according to claim 6, it is characterised in that described method further comprises the steps of:
By described carbide slag breaker, bulk carbide slag is crushed to < 1mm, and broken carbide
Slag is placed in warehouse in the middle of described carbide slag, by described carbide slag helix transporting device by described broken electricity
Rock ballast is transported to described clean unit.
Method the most according to claim 6, it is characterised in that the solid content of described carbide slag slurries
For 8.0-25wt%.
Method the most according to claim 6, it is characterised in that be passed through institute in described carbide slag slurries
State containing CO2After gas, the pH regulator of described carbide slag slurries is 8-11；Described containing CO2CO in gas2
Volumetric concentration be 15-27%.
Method the most according to claim 6, it is characterised in that described method further comprises the steps of:
The carbide of described generation use dry method carbide acetylene production method generate acetylene and carbide slag, and
Described carbide slag is transported to described carbonation unit or described carbide slag bath.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610282477.2A CN105948049B (en) | 2016-04-29 | 2016-04-29 | A kind of system and method for production of calcium carbide from its residue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610282477.2A CN105948049B (en) | 2016-04-29 | 2016-04-29 | A kind of system and method for production of calcium carbide from its residue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105948049A true CN105948049A (en) | 2016-09-21 |
| CN105948049B CN105948049B (en) | 2018-01-19 |
Family
ID=56914756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610282477.2A Expired - Fee Related CN105948049B (en) | 2016-04-29 | 2016-04-29 | A kind of system and method for production of calcium carbide from its residue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105948049B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106517203A (en) * | 2016-11-09 | 2017-03-22 | 重庆鸿庆达产业有限公司 | Calcium carbide production system |
| CN106542532A (en) * | 2016-11-22 | 2017-03-29 | 北京神雾环境能源科技集团股份有限公司 | The system and method for preparing carbide |
| CN107312559A (en) * | 2017-07-17 | 2017-11-03 | 神雾环保技术股份有限公司 | The system and method that a kind of high temperature pyrolysis gas is recycled |
| CN107720797A (en) * | 2017-11-01 | 2018-02-23 | 神雾环保技术股份有限公司 | The system and method for handling carbide slag |
| CN107935010A (en) * | 2017-12-29 | 2018-04-20 | 神雾环保技术股份有限公司 | The system and method for handling carbide slag |
| CN108083279A (en) * | 2017-12-29 | 2018-05-29 | 神雾环保技术股份有限公司 | The system and method for handling carbide slag |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101830492A (en) * | 2009-06-08 | 2010-09-15 | 王嘉兴 | Material recycling method in calcium carbide industry |
| CN105129800A (en) * | 2015-07-21 | 2015-12-09 | 北京神雾环境能源科技集团股份有限公司 | Process and system of preparing calcium carbide and ethylene through oxygen/coal injection |
| CN204981160U (en) * | 2015-07-21 | 2016-01-20 | 北京神雾环境能源科技集团股份有限公司 | System for oxygen / coal jetting preparation carbide and ethylene |
| CN205740374U (en) * | 2016-04-29 | 2016-11-30 | 神雾环保技术股份有限公司 | A kind of system of production of calcium carbide from its residue |
-
2016
- 2016-04-29 CN CN201610282477.2A patent/CN105948049B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101830492A (en) * | 2009-06-08 | 2010-09-15 | 王嘉兴 | Material recycling method in calcium carbide industry |
| CN105129800A (en) * | 2015-07-21 | 2015-12-09 | 北京神雾环境能源科技集团股份有限公司 | Process and system of preparing calcium carbide and ethylene through oxygen/coal injection |
| CN204981160U (en) * | 2015-07-21 | 2016-01-20 | 北京神雾环境能源科技集团股份有限公司 | System for oxygen / coal jetting preparation carbide and ethylene |
| CN205740374U (en) * | 2016-04-29 | 2016-11-30 | 神雾环保技术股份有限公司 | A kind of system of production of calcium carbide from its residue |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106517203A (en) * | 2016-11-09 | 2017-03-22 | 重庆鸿庆达产业有限公司 | Calcium carbide production system |
| CN106542532A (en) * | 2016-11-22 | 2017-03-29 | 北京神雾环境能源科技集团股份有限公司 | The system and method for preparing carbide |
| CN107312559A (en) * | 2017-07-17 | 2017-11-03 | 神雾环保技术股份有限公司 | The system and method that a kind of high temperature pyrolysis gas is recycled |
| CN107720797A (en) * | 2017-11-01 | 2018-02-23 | 神雾环保技术股份有限公司 | The system and method for handling carbide slag |
| CN107935010A (en) * | 2017-12-29 | 2018-04-20 | 神雾环保技术股份有限公司 | The system and method for handling carbide slag |
| CN108083279A (en) * | 2017-12-29 | 2018-05-29 | 神雾环保技术股份有限公司 | The system and method for handling carbide slag |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105948049B (en) | 2018-01-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105948049A (en) | System and method for producing calcium carbide by utilizing carbide slag | |
| CN102442650B (en) | Method for producing sulfuric acid and co-producing calcium carbide by phosphogypsum | |
| CN106745145B (en) | A kind of method and system device for producing calcium oxide and sulphur from gypsum | |
| CN110917852B (en) | Resource recovery method and resource recovery system for desulfurized fly ash | |
| CN102303883B (en) | Method for preparing calcium oxide and sulfur by double-atmosphere fluidized roasting of desulfurated gypsum | |
| RU2467789C2 (en) | Method and device for processing co2-bearing waste gases | |
| CN104555946B (en) | Method for jointly producing sulphuric acid and cement clinker by using sulphur gas to reduce gypsum | |
| CN106554826B (en) | Circulating fluidized bed coal gasification method and device with fine ash fusion | |
| JP2018538445A (en) | Recovery of lithium from silicate minerals | |
| CN109809456B (en) | System and method for co-producing calcium oxide and sulfur by coal gasification and gypsum calcination | |
| CN103011090B (en) | Method for producing sulfur by using pyrolysis-reducing united technique | |
| CN111234880A (en) | Clean resource treatment method for solid waste and hazardous waste | |
| CN201161187Y (en) | Composite cycle fluidized bed apparatus for phosphogypsum decomposition | |
| US10611657B2 (en) | Method and system for preparing fuel gas by utilizing organic waste with high water content | |
| CN111676037A (en) | System for biomass preparation hydrogen and biochar based on steel slag extract | |
| CN101955166B (en) | Method for decomposing semi-hydrated phosphogypsum | |
| CN109897672A (en) | The device and method produced using circulation of tail gas coal gasification | |
| CN103818884A (en) | Process for decomposing gypsum through spraying and fluidizing | |
| CN205740374U (en) | A kind of system of production of calcium carbide from its residue | |
| CN109775666A (en) | Coal gasification collaboration calcium sulfate calcining and carbon heat reducing prepare the device and method of sulphur | |
| CN103072949A (en) | Method for preparing calcium sulfide through reductive decomposition of phosphogypsum by fluidized bed | |
| CN107902686A (en) | A kind of precipitated calcium carbonate intelligent ecological utilization of resources production method | |
| CN104529205B (en) | cement production device and method | |
| CN106044820A (en) | Method for producing strontium carbonate from carbon dioxide in exhaust gas | |
| CN110681322B (en) | Green calcining equipment, system and process for producing gel material by utilizing bulk solid wastes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180119 Termination date: 20190429 |