CN105941496A - Compound type micro-nano biological repellent and use method thereof - Google Patents

Compound type micro-nano biological repellent and use method thereof Download PDF

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Publication number
CN105941496A
CN105941496A CN201610315288.0A CN201610315288A CN105941496A CN 105941496 A CN105941496 A CN 105941496A CN 201610315288 A CN201610315288 A CN 201610315288A CN 105941496 A CN105941496 A CN 105941496A
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micro
component
nano
prepared
nano granules
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吕建鑫
颜璐洁
郭玮
张洋祎
濮玉兵
吕雪
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/06Oxygen or sulfur directly attached to a cycloaliphatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A01N37/24Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/10Animals; Substances produced thereby or obtained therefrom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/12Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/20Fabaceae or Leguminosae [Pea or Legume family], e.g. pea, lentil, soybean, clover, acacia, honey locust, derris or millettia
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/24Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/36Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0058Biocides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Polymers & Plastics (AREA)
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Abstract

The invention discloses a compound type micro-nano biological repellent and a use method thereof. The compound type micro-nano biological repellent is characterized by being prepared from a component A, a component B and a component C through mixing, wherein the component A is prepared from a component A1, a component A2 and a component A3 through mixing, the component A1 is one or a mixture of micro-nano particles prepared from active ingredients of carophyllin, litsea cubeba oil, cinnamon oil, honeylocust leaf oil and camphor oil, the component A2 is a micro-nano particle prepared from an active ingredient of capsicin, and the component A3 is one or a mixture of micro-nano particles prepared from active ingredients of gland extracts of cats and foxes; the component B is one or a mixture of micro-nano particles prepared from active ingredients of orange flower oil, black pepper oil, artemisia selengensis and small-leaf mugwort; the component C is one or a mixture of micro-nano particles prepared from active ingredients of neem oil, Citrus junos and asarum oil. The compound type micro-nano biological repellent is environment-friendly and non-toxic, is not harmful to people and livestock and cannot influence the environment.

Description

The micro-nano biological repellant of Compositional type and using method thereof
Technical field
The present invention relates to a kind of biological repellant, belong to the interleaving techniques field of micro Nano material and ecological environmental protection engineering, a kind of micro-nano biological repellant of Compositional type and using method thereof.
Background technology
In current biochemistry repellent, it is preferred to use natural product extraction composition, because its avirulence is without damaging people and other animal, and Natural Degradation, will not be to environment.But biological repellant repellent classification in the market is single, is only specifically designed for rat destruction, bird dispelling or anthelmintic ant.This is primarily due to these published repellent formula being grouped into by natural product extraction one-tenth, major part is to be mixed by multiple natural extracts, the physicochemical property of the natural extracts of these opposed polarities is different, different solubility in aqueous solution or organic solution, under given process conditions, the active component of certain extract is well discharged, and the active component of another kind of extract is not, this cause intended plurality of active ingredients is compounded come together to realize strengthening combined drive avoiding effect might not onset.Especially two kinds active component physicochemical property differences are relatively big, such as natural plant composition and the gland extract of animal, are difficulty with being evenly mixed in a dicyandiamide solution.Additionally, the speed that these active ingredient degradation become little molecule is the most different, this result also in cannot timeliness cycle of accurate control repellent, it is impossible to preferably when lost efficacy repellant and carries out anticipation.The phytochemicals production active component that another problem is many is easy to volatilization in solvent phase, and bad preservation, its repellent effect also tends to be affected by ambient temperature, humidity and wind direction.
Summary of the invention
It is an object of the invention to provide one birds, muroid and worm ant class repellant to be combined; formed by the micro/nano level granule mixing of multiple different repellent effects is compounding; owing to being natural product extraction composition; environmental protection, avirulence, nothing remnants, do not result in the micro-nano biological repellant of Compositional type of impact to environment.
In order to reach object above, the technical solution adopted in the present invention is:
The micro-nano biological repellant of this Compositional type; it is characterized in that: it includes that component A, B component and component C are mixed; component A, B component and component C (2 10) in mass ratio: (2 5): 1 compounds; component A is rat destruction micro-nano granules mixture; B component is anthelmintic ant micro-nano granules mixture, and component C is bird dispelling micro-nano granules mixture;Wherein component A is by A1, tri-kinds of components of A2 and A3 (2 10) in mass ratio: (2 5): 1 is mixed, A1 component is the micro-nano granules prepared by syringyl alcohol active component, the micro-nano granules prepared by litsea cubeba oil active component, the micro-nano granules prepared by Oleum Cinnamomi active component, the mixture of any one or several in the micro-nano granules prepared by soap leaf oil active component and the micro-nano granules prepared by Oleum Camphora active component, A2 component is the micro-nano granules prepared by capsaicin active component, A3 component be by the gland extract active component of cat class prepare micro-nano granules and fox gland extract active component prepare micro-nano granules in the mixture of any one or two kinds of;B component is the mixture of any one or several in the micro-nano granules prepared by orange blossom oil, Fructus piperis nigrum oil, Herba chenopodii Artemisia and lobule Chinese mugwort active component;Component C is the mixture of any one or several in the micro-nano granules prepared by stamp-pad ink, Eriocheir sinensis orange and Herba Asari oil active component.
Described micro-nano granules has the average diameter of 400nm 950nm.
Described micro-nano granules is obtained by micro-nano spraying.
The using method of the micro-nano biological repellant of this Compositional type, it is characterized in that: make Compositional type micro-nano biological repellant solution by after the above-mentioned micro-nano biological repellant of prepared Compositional type and water mix homogeneously, with aerosol apparatus, micro-nano for Compositional type biological repellant spray solution is packed or the outer surface of tent at fibrous material;Or by after the above-mentioned micro-nano biological repellant of prepared Compositional type and paint mix homogeneously, with brush brushing at pipe surface of entering the room, cable surface of entering the room, air louver edge, sewer mouth edge, power distribution room cable surface, shelf lower surface or other body surface that need to lay special stress on protecting;Or by after the above-mentioned micro-nano biological repellant of prepared Compositional type and additive mix homogeneously, prepared by extruding machine and there is the PE of repellent effect expect.
The mass ratio of the micro-nano biological repellant of described Compositional type and water is 1:20.
Adding polyacrylic resin weak solution in described Compositional type micro-nano biological repellant solution, the mass ratio of Compositional type micro-nano biological repellant solution and polyacrylic resin weak solution is 200:1.
The mass ratio of the micro-nano biological repellant of described Compositional type and paint is 1:20.
The mass ratio of the micro-nano biological repellant of described Compositional type and additive is 1:20.
The beneficial effects of the present invention is: due to selected be all the micro-nano granules generated by natural product extraction, environmental protection, nontoxic, person poultry harmless;For disclosed prior art, the present invention also has following significant advantage:
(1), repellent dimension increases: by the mixing compounding biological repellant obtained, Mus, bird or worm ant can produce preferable repellent effect and the most mutually exclusive simultaneously.Combined drive avoiding effect is greatly enhanced.On the other hand, by various active component are made micro/nano level granule, the characteristic of active macromolecules has a very large change after micro-nano magnitude, granule surface area can diminish with particle diameter and increases, following exposure to the raising of surface area in medium, can preferably play its active component effect, more effectively be dissolved in the various media of subsequent applications, its particle colloidal stability in subsequent medium also can significantly improve;
(2), by various effective repellent activity compositions prepare the size micro and nano powders granule in same magnitude, evenly, quality is guaranteed in mixing, and product is easier to preserve;
(3), repellent protection timeliness is more easy to be in harmonious proportion controlled: in different application scene, the category biological to repellent and timeliness also differ.Therefore, different component composition proportion can be chosen according to the kind of required repellent biology and the needs of guard time length, accomplish more targetedly and shoot the arrow at the target.
Detailed description of the invention
The specific embodiment of the present invention will be described in further detail below.
Embodiment 1:
The micro-nano biological repellant of this Compositional type; it is characterized in that: it includes that component A, B component and component C are mixed; component A, B component and component C 10:5:1 in mass ratio compounds; component A is rat destruction micro-nano granules mixture; B component is anthelmintic ant micro-nano granules mixture, and component C is bird dispelling micro-nano granules mixture;Wherein component A is mixed by tri-kinds of component 10:5:1 in mass ratio of A1, A2 and A3, A1 component is the micro-nano granules prepared by syringyl alcohol active component, A2 component is the micro-nano granules prepared by capsaicin active component, and A3 component is the micro-nano granules prepared by the gland extract active component of cat class;B component is the micro-nano granules prepared by orange blossom oil active component;Component C is the micro-nano granules prepared by stamp-pad ink active component.
Described micro-nano granules has the average diameter of 400nm 950nm.Described micro-nano granules is obtained by micro-nano spraying.
The using method of the micro-nano biological repellant of this Compositional type, it is characterized in that: make Compositional type micro-nano biological repellant solution by after the above-mentioned micro-nano biological repellant of prepared Compositional type and water mix homogeneously, with aerosol apparatus, micro-nano for Compositional type biological repellant spray solution is packed or the outer surface of tent at material.
The mass ratio of the micro-nano biological repellant of described Compositional type and water is 1:20.
Adding appropriate polyacrylic resin weak solution in described Compositional type micro-nano biological repellant solution to strengthen adhesive attraction, the mass ratio of described Compositional type micro-nano biological repellant solution and polyacrylic resin weak solution is 200:1.
After stirring, it is sprayed on the package material surface equipped with grain, it be observed that half a year, find no worm moth and fly out, the phenomenon that nothing is broken by the teeth by mouse, unfirmly closing is broken.Not executing the packaging material of repellant in contrast groups, loading latter about 4 months Bombycis moris that just fly out of food, with packaging bag areal calculation, every 10 square centimeters to go out worm amount be 2.6.Being reached 35-45% by the damaged by rats rate of breaking, loss of cereal crops reaches 10%.
Embodiment 2:
The micro-nano biological repellant of this Compositional type; it is characterized in that: it includes that component A, B component and component C are mixed; component A, B component and component C 5:5:1 in mass ratio compounds; component A is rat destruction micro-nano granules mixture; B component is anthelmintic ant micro-nano granules mixture, and component C is bird dispelling micro-nano granules mixture;Wherein component A is mixed by tri-kinds of component 5:5:1 in mass ratio of A1, A2 and A3, the mixture that A1 component is the micro-nano granules prepared by litsea cubeba oil active component and the micro-nano granules that prepared by Oleum Cinnamomi active component is mixed to get by equal quality, A2 component is the micro-nano granules prepared by capsaicin active component, and A3 component is the micro-nano granules prepared by the gland extract active component of fox;The mixture that B component is the micro-nano granules prepared by Fructus piperis nigrum oil active component and the micro-nano granules that prepared by Herba chenopodii Artemisia active component is mixed to get by equal quality;Component C is the micro-nano granules prepared by stamp-pad ink active component and the mixture being mixed to get by equal quality by the micro-nano granules that Eriocheir sinensis orange active component is prepared.
Described micro-nano granules has the average diameter of 400nm 950nm.Described micro-nano granules is obtained by micro-nano spraying.
The using method of the micro-nano biological repellant of this Compositional type; it is characterized in that: after the above-mentioned micro-nano biological repellant of prepared Compositional type and paint mix homogeneously, with brush brushing at pipe surface of entering the room, cable surface of entering the room, air louver edge, sewer mouth edge, power distribution room cable surface, shelf lower surface or other body surface that need to lay special stress on protecting.
The mass ratio of the micro-nano biological repellant of described Compositional type and paint is 1:20.
By input Semen arachidis hypogaeae, paint brush is done monitoring mouse density in the place that mouse often haunts, and in brushing rear region, rodent density drops to 0.5% from 15%.Brushing in the place being attached with sugar source, worm ant keeps away row.Brushing outside branch, branch epidermis does not occurs being eaten phenomenon by unfirmly closing.
Embodiment 3:
The micro-nano biological repellant of this Compositional type; it is characterized in that: it includes that component A, B component and component C are mixed; component A, B component and component C 2:2:1 in mass ratio compounds; component A is rat destruction micro-nano granules mixture; B component is anthelmintic ant micro-nano granules mixture, and component C is bird dispelling micro-nano granules mixture;Wherein component A is mixed by tri-kinds of component 2:2:1 in mass ratio of A1, A2 and A3, the mixture that A1 component is the micro-nano granules prepared by soap leaf oil active component and the micro-nano granules that prepared by Oleum Camphora active component is mixed to get by equal quality, A2 component is the micro-nano granules prepared by capsaicin active component, and A3 component is the micro-nano granules prepared by the gland extract active component of cat class and the mixture mixed by equal quality by the micro-nano granules that the gland extract active component of fox is prepared;B component is the micro-nano granules prepared by lobule Chinese mugwort active component;Component C is the micro-nano granules prepared by Herba Asari oil active component.
Described micro-nano granules has the average diameter of 400nm 950nm.Described micro-nano granules is obtained by micro-nano spraying.
The using method of the micro-nano biological repellant of this Compositional type, it is characterised in that: after the above-mentioned micro-nano biological repellant of prepared Compositional type and additive mix homogeneously, prepared by extruding machine and there is the PE of repellent effect expect.
The mass ratio of the micro-nano biological repellant of described Compositional type and additive is 1:20.
Described additive is other suitable additives such as PE matrix resin, antioxidant, rheological agent, PE wax.
With reference to similar industry standard (JB/T10696.10-2011 electric wire machinery and physicochemical property test method), the PE material having repellent effect obtained in said method is carried out rat destruction performance detection, and protection ratio is more than 0.9, belongs to notable level mouse bite preventing function.Coptotermes formosanus Shtrari. moth erosion grade is 1 grade.
Embodiment 4:
The micro-nano biological repellant of this Compositional type; it is characterized in that: it includes that component A, B component and component C are mixed; component A, B component and component C 4:3:1 in mass ratio compounds; component A is rat destruction micro-nano granules mixture; B component is anthelmintic ant micro-nano granules mixture, and component C is bird dispelling micro-nano granules mixture;Wherein component A is by A1, tri-kinds of component 4:3:1 in mass ratio of A2 and A3 are mixed, A1 component is the micro-nano granules prepared by syringyl alcohol active component, the micro-nano granules and the micro-nano granules prepared by Oleum Camphora active component that are prepared by soap leaf oil active component are mixed to get mixture by equal in quality, A2 component is the micro-nano granules prepared by capsaicin active component, A3 component is the micro-nano granules prepared by the gland extract active component of cat class and the mixture being mixed to get by equal quality by the micro-nano granules that the gland extract active component of fox is prepared;B component is the micro-nano granules prepared by Fructus piperis nigrum oil active component, Herba chenopodii Artemisia the active component micro-nano granules prepared and the mixture being mixed to get by equal quality by the micro-nano granules that lobule Chinese mugwort active component is prepared;Component C is the mixture that the micro-nano granules that the micro-nano granules prepared by stamp-pad ink active component, Eriocheir sinensis orange the active component micro-nano granules prepared and Herba Asari oil active component prepare is mixed to get by equal quality.
Described micro-nano granules has the average diameter of 400nm 950nm.Described micro-nano granules is obtained by micro-nano spraying.
The using method of the micro-nano biological repellant of this Compositional type, it is characterised in that: after the above-mentioned micro-nano biological repellant of prepared Compositional type and additive mix homogeneously, prepared by extruding machine and there is the PE of repellent effect expect.Described additive is PE wax.The mass ratio of the micro-nano biological repellant of described Compositional type and additive is 1:20.
With reference to similar industry standard (JB/T10696.10-2011 electric wire machinery and physicochemical property test method), the PE material having repellent effect obtained in said method is carried out rat destruction performance detection, and protection ratio is more than 0.9, belongs to notable level mouse bite preventing function.Coptotermes formosanus Shtrari. moth erosion grade is 1 grade.
Embodiment 5:
The micro-nano biological repellant of this Compositional type; it is characterized in that: it includes that component A, B component and component C are mixed; component A, B component and component C 7:4:1 in mass ratio compounds; component A is rat destruction micro-nano granules mixture; B component is anthelmintic ant micro-nano granules mixture, and component C is bird dispelling micro-nano granules mixture;Wherein component A is mixed by tri-kinds of component 7:4:1 in mass ratio of A1, A2 and A3, A1 component is the micro-nano granules prepared by soap leaf oil active component, A2 component is the micro-nano granules prepared by capsaicin active component, and A3 component is the micro-nano granules prepared by the gland extract active component of fox;B component is the micro-nano granules prepared by lobule Chinese mugwort active component;Component C is the micro-nano granules prepared by Herba Asari oil active component.
Described micro-nano granules has the average diameter of 400nm 950nm.Described micro-nano granules is obtained by micro-nano spraying.
The using method of the micro-nano biological repellant of this Compositional type, it is characterized in that: after the above-mentioned micro-nano biological repellant of prepared Compositional type and the water mix homogeneously of 1:20 in mass ratio, make Compositional type micro-nano biological repellant solution, with aerosol apparatus, micro-nano for Compositional type biological repellant spray solution is packed or the outer surface of tent at material.
Adding polyacrylic resin weak solution in described Compositional type micro-nano biological repellant solution, to strengthen adhesive attraction, the mass ratio of Compositional type micro-nano biological repellant solution and polyacrylic resin weak solution is 200:1.
After stirring, it is sprayed on the package material surface equipped with grain, it be observed that half a year, find no worm moth and fly out, the phenomenon that nothing is broken by the teeth by mouse, unfirmly closing is broken.Not executing the packaging material of repellant in contrast groups, loading latter about 4 months Bombycis moris that just fly out of food, with packaging bag areal calculation, every 10 square centimeters to go out worm amount be 2.6.Being reached 35-45% by the damaged by rats rate of breaking, loss of cereal crops reaches 10%.
Embodiment 6:
The micro-nano biological repellant of this Compositional type; it is characterized in that: it includes that component A, B component and component C are mixed; component A, B component and component C 6:3:1 in mass ratio compounds; component A is rat destruction micro-nano granules mixture; B component is anthelmintic ant micro-nano granules mixture, and component C is bird dispelling micro-nano granules mixture;Wherein component A is by A1, tri-kinds of component 8:4:1 in mass ratio of A2 and A3 are mixed, A1 component is the micro-nano granules prepared by syringyl alcohol active component, the micro-nano granules prepared by litsea cubeba oil active component, the micro-nano granules prepared by Oleum Cinnamomi active component, the mixture that the micro-nano granules prepared by soap leaf oil active component and the micro-nano granules prepared by Oleum Camphora active component are mixed by equal quality, A2 component is the micro-nano granules prepared by capsaicin active component, A3 component is the mixture that mixes by equal quality of micro-nano granules that the gland extract active component of micro-nano granules and the fox prepared by the gland extract active component of cat class prepares;B component is the micro-nano granules prepared by orange blossom oil active component, Fructus piperis nigrum oil the active component micro-nano granules prepared, Herba chenopodii Artemisia the active component micro-nano granules prepared and the mixture mixed by equal quality by the micro-nano granules that lobule Chinese mugwort active component is prepared;Component C is the micro-nano granules prepared by stamp-pad ink active component, Eriocheir sinensis orange the active component micro-nano granules prepared and the mixture mixed by equal quality by the micro-nano granules that Herba Asari oil active component is prepared.
Described micro-nano granules has the average diameter of 400nm 950nm.Described micro-nano granules is obtained by micro-nano spraying.
The using method of the micro-nano biological repellant of this Compositional type; it is characterized in that: after the above-mentioned micro-nano biological repellant of prepared Compositional type and paint mix homogeneously, with brush brushing at pipe surface of entering the room, cable surface of entering the room, air louver edge, sewer mouth edge, power distribution room cable surface, shelf lower surface or other body surface that need to lay special stress on protecting.
The mass ratio of the micro-nano biological repellant of described Compositional type and paint is 1:20.
By input Semen arachidis hypogaeae, paint brush is done monitoring mouse density in the place that mouse often haunts, and in brushing rear region, rodent density drops to 0.5% from 15%.Brushing in the place being attached with sugar source, worm ant keeps away row.Brushing outside branch, branch epidermis does not occurs being eaten phenomenon by unfirmly closing.
Above-described embodiment is some specific embodiments of the present invention; but embodiments of the present invention are also not restricted to the described embodiments; the change made under other any spirit without departing from the present invention and principle, modify, substitute, combine, simplify; all should be the substitute mode of equivalence, within being included in protection scope of the present invention.

Claims (5)

1. the micro-nano biological repellant of Compositional type; it is characterized in that: it includes that component A, B component and component C are mixed; component A, B component and component C (2 10) in mass ratio: (2 5): 1 compounds; component A is rat destruction micro-nano granules mixture; B component is anthelmintic ant micro-nano granules mixture, and component C is bird dispelling micro-nano granules mixture;Wherein component A is by A1, tri-kinds of components of A2 and A3 (2 10) in mass ratio: (2 5): 1 is mixed, A1 component is the micro-nano granules prepared by syringyl alcohol active component, the micro-nano granules prepared by litsea cubeba oil active component, the micro-nano granules prepared by Oleum Cinnamomi active component, the mixture of any one or several in the micro-nano granules prepared by soap leaf oil active component and the micro-nano granules prepared by Oleum Camphora active component, A2 component is the micro-nano granules prepared by capsaicin active component, A3 component be by the gland extract active component of cat class prepare micro-nano granules and fox gland extract active component prepare micro-nano granules in the mixture of any one or two kinds of;B component is the mixture of any one or several in the micro-nano granules prepared by orange blossom oil active component, Fructus piperis nigrum oil the active component micro-nano granules prepared, Herba chenopodii Artemisia the active component micro-nano granules prepared and the micro-nano granules prepared by lobule Chinese mugwort active component;Component C is the mixture of any one or several in the micro-nano granules prepared by stamp-pad ink active component, Eriocheir sinensis orange the active component micro-nano granules prepared and the micro-nano granules prepared by Herba Asari oil active component.
The micro-nano biological repellant of Compositional type the most according to claim 1, it is characterised in that: described micro-nano granules has the average diameter of 400nm 950nm.
The micro-nano biological repellant of Compositional type the most according to claim 1 and 2, it is characterised in that: described micro-nano granules is obtained by micro-nano spraying.
4. the using method of the micro-nano biological repellant of Compositional type prepared according to claim 1, it is characterized in that: make Compositional type micro-nano biological repellant solution by after the above-mentioned micro-nano biological repellant of prepared Compositional type and water mix homogeneously, with aerosol apparatus, micro-nano for Compositional type biological repellant spray solution is packed or the outer surface of tent at fibrous material;Or by after the above-mentioned micro-nano biological repellant of prepared Compositional type and paint mix homogeneously, with brush brushing at pipe surface of entering the room, cable surface of entering the room, air louver edge, sewer mouth edge, power distribution room cable surface, shelf lower surface or other body surface that need to lay special stress on protecting;Or by after the above-mentioned micro-nano biological repellant of prepared Compositional type and additive mix homogeneously, prepared by extruding machine and there is the PE of repellent effect expect.
5. the using method of the micro-nano biological repellant of Compositional type prepared according to claim 4, it is characterised in that: the mass ratio of the micro-nano biological repellant of described Compositional type and water is 1:20;
Adding polyacrylic resin weak solution in described Compositional type micro-nano biological repellant solution, the mass ratio of Compositional type micro-nano biological repellant solution and polyacrylic resin weak solution is 200:1;
The mass ratio of the micro-nano biological repellant of described Compositional type and paint is 1:20;
The mass ratio of the micro-nano biological repellant of described Compositional type and additive is 1:20;
Described additive is PE matrix resin, antioxidant, rheological agent or PE wax.
CN201610315288.0A 2016-05-14 2016-05-14 Compound type micro-nano biological repellent and use method thereof Pending CN105941496A (en)

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Application publication date: 20160921